arXiv subjects

Daniel Bruns

Publications and source records attributed to Daniel Bruns.

4 recordsLinked to original sources

arXiv2024

Connected Network Model for the Mechanical Loss of Amorphous Materials

Dissipation in amorphous solids at low frequencies is commonly attributed to activated transitions of isolated two-level systems (TLS) that come in resonance with elastic or electric fields. Materials with low mechanical or dielectric loss are urgently needed for applications in gravitational wave detection, high precision sensors, and quantum computing. Using atomistic modeling, we explore the energy landscape of amorphous silicon and titanium dioxide, and find that the pairs of energy minima that constitute single TLS form a sparsely connected network with complex topologies. Motivated by this observation, we develop an analytically tractable theory for mechanical loss of the full network from a nonequilibrium thermodynamic perspective. We demonstrate that the connectivity of the network introduces new mechanisms that can both reduce low frequency dissipation through additional low energy relaxation pathways, and increase dissipation through a broad distribution of energy minima. As a result, the connected network model predicts mechanical loss with distinct frequency profiles compared to the isolated TLS model. This not only calls into question the validity of the TLS model, but also gives us many new avenues and properties to analyze for the targeted design of low mechanical loss materials.

cond-mat.mtrl-sci↗

arXiv2021

Nanotube heat conductors under tensile strain: Reducing the three-phonon scattering strength of acoustic phonons

Acoustic phonons play a special role in lattice heat transport, and confining these low-energy modes in low-dimensional materials may enable nontrivial transport phenomena. By applying lowest-order anharmonic perturbation theory to an atomistic model of a carbon nanotube, we investigate numerically and analytically the spectrum of three-phonon scattering channels in which at least one phonon is of low energy. Our calculations show that acoustic longitudinal (LA), flexural (FA), and twisting (TW) modes in nanotubes exhibit a distinct dissipative behavior in the long-wavelength limit, $|k| \rightarrow 0$, which manifests itself in scattering rates that scale as $Γ_{\rm{LA}}\sim |k|^{-1/2}$, $Γ_{\rm{FA}}\sim k^0$, and $Γ_{\rm{TW}}\sim |k|^{1/2}$. These scaling relations are a consequence of the harmonic lattice approximation and critically depend on the condition that tubes are free of mechanical strain. In this regard, we show that small amounts of tensile lattice strain $ε$ reduce the strength of anharmonic scattering, resulting in strain-modulated rates that, in the long-wavelength limit, obey $Γ\sim ε^{r} |k|^{s}$ with $r\leq 0$ and $s\geq 1$, irrespectively of acoustic mode polarization. Under the single-mode relaxation time approximation of the linearized Peierls-Boltzmann equation (PBE), the long-tube limit of lattice thermal conductivity in stress-free and stretched tube configurations can be unambiguously characterized. Going beyond relaxation time approximations, analytical results obtained in the present study may help to benchmark numerical routines which aim at deriving the thermal conductivity of nanotubes from an exact solution of the PBE.

cond-mat.mes-hall↗

arXiv2020

Heat transport in carbon nanotubes: Length dependence of phononic conductivity from the Boltzmann transport equation and molecular dynamics

In this article, we address lattice heat transport in single-walled carbon nanotubes (CNTs) by a quantum mechanical calculation of three-phonon scattering rates in the framework of the Boltzmann transport equation (BTE) and classical molecular dynamics (MD) simulation. Under a consistent choice of an empirical, realistic atomic interaction potential, we compare the tube length dependence of the lattice thermal conductivity (TC) at room temperature determined from an iterative solution of the BTE and from a nonequilibrium MD (NEMD) approach. Qualitatively similar trends are found in the limit of short tubes, where an extensive regime of ballistic heat transport prevailing in CNTs of lengths $L\lesssim 1\,\rm{μm}$ is independently confirmed. In the limit of long tubes, the BTE approach suggests a saturation of TC with tube length, whereas direct NEMD simulations of tubes extending up to $L=10\,\rm{μm}$ are demonstrated to be insufficient to settle the question of whether a fully diffusive heat transport regime and an intrinsic value of TC exist for CNTs. Noting that acoustic phonon lifetimes lie at the heart of a saturation of TC with tube length as per the BTE framework, we complement the quantum mechanical prediction of acoustic phonon lifetimes with an analysis of phonon modes in the framework of equilibrium MD (EMD). A normal mode analysis (NMA) with an emphasis on long wavelength acoustic modes corroborates the BTE prediction that heat transport in CNTs in the long tube limit is governed by the low attenuation rates of longitudinal and twisting phonons.

cond-mat.mes-hall↗

arXiv2019

Tuning morphology and thermal transport of asymmetric smart polymer blends by macromolecular engineering

A grand challenge in designing polymeric materials is to tune their properties by macromolecular engineering. In this context, one of the drawbacks that often limits broader applications under high temperature conditions is their poor thermal conductivity $κ$. Using molecular dynamics simulations, we establish a structure-property relationship in hydrogen bonded polymer blends for possible improvement of $κ$. For this purpose, we investigate two experimentally relevant hydrogen bonded systems -- one system consists of short poly({N}-acryloyl piperidine) (PAP) blended with longer chains of poly(acrylic acid) (PAA) and the second system is a mixture of PAA and short poly(acrylamide) (PAM) chains. Simulation results show that PAA-PAP blends are at the onset of phase separation over the full range of PAP monomer mole fraction $ϕ_{PAP}$, which intensifies even more for $ϕ_{PAP} > 0.3$. While PAA and PAP interact with preferential hydrogen bonding, phase separation is triggered by the dominant van der Waals attraction between the hydrophobic side groups of PAP. However, if PAP is replaced with PAM, which has a similar chemical structure as PAP without the hydrophobic side group, PAA-PAM blends show much improved solubility. Better solubility is due to the preferential hydrogen bonding between PAA and PAM. As a result, PAM oligomers act as cross-linking bridges between PAA chains resulting in a three dimensional highly cross-linked network. While $κ$ for PAA-PAP blends remain almost invariant with $ϕ_{PAP}$, PAA-PAM systems show improved $κ$ with increasing PAM concentration and also with respect to PAA-PAP blends. Consistent with the theoretical prediction for the thermal transport of amorphous polymers, we show that $κ$ is proportional to the materials stiffness, i.e., the bulk modulus K and sound velocity v of PAA-PAM blends.

cond-mat.soft↗