arXiv subjects

Daniel J. Bosworth

Publications and source records attributed to Daniel J. Bosworth.

5 recordsLinked to original sources

arXiv2024

Metastable doubly-charged Rydberg molecules

H$_3^{2+}$ is a one-electron system with three positive nuclei and is known to be unstable in its electronic ground-state. We examine an analogous one-electron system composed of a $^{87}$Rb Rydberg atom interacting with a pair of cations and predict the existence of metastable vibrationally-bound states of $^{87}$Rb$_3^{2+}$. These molecules are long-range trimers whose stability rests on the presence of core-shell electrons and favourable scaling of the Rydberg atom's quadrupole moment with the principal quantum number $n$. Unlike recently observed ion-Rydberg dimers, whose binding is due to internal flipping of the Rydberg atom's dipole moment, the binding of $^{87}$Rb$_3^{2+}$ arises from the interaction of the ions with the Rydberg atom's quadrupole moment. The stability of these trimers is highly sensitive to $n$. We do not expect these states to exist below $n=24$ and for $n \leq 35$, their lifetime is limited by tunnelling of the Rydberg electron. In contrast, at very large $n$ the lifetime will be limited by tunnelling of the vibrational wavepacket. In between these limits, we expect a range of bound states at intermediate $n$ for which both tunnelling rates are smaller than the radiative decay rate of the Rydberg state.

physics.atom-ph↗

arXiv2024

$In$ $situ$ observation of non-polar to strongly polar atom-ion collision dynamics

The onset of collision dynamics between an ion and a Rydberg atom is studied in a regime characterized by a multitude of collision channels. These channels arise from coupling between a non-polar Rydberg state and numerous highly polar Stark states. The interaction potentials formed by the polar Stark states show a substantial difference in spatial gradient compared to the non-polar state leading to a separation of collisional timescales, which is observed in situ. For collision energies in the range of $k_\textrm{B}\cdotμ$K to $k_\textrm{B}\cdot$K, the dynamics exhibit a counter-intuitive dependence on temperature, resulting in faster collision dynamics for cold - initially "slow" - systems. Dipole selection rules enable us to prepare the collision pair on the non-polar potential in a highly controlled manner, which determines occupation of the collision channels. The experimental observations are supported by semi-classical simulations, which model the pair state evolution and provide evidence for tunable non-adiabatic dynamics.

physics.atom-ph↗

arXiv2023

Excited state preparation of trapped ultracold atoms via swept potentials

We study the out-of-equilibrium dynamics of non-interacting atoms confined within a one-dimensional harmonic trap triggered by dragging an external long-range potential through the system. The symmetry-breaking nature of this moving potential couples adjacent eigenstates in the atoms' effective potential, leading to an energy landscape reminscent of systems exhibiting trap-induced shape resonances. These couplings may be exploited to selectively excite the atoms into higher vibrational states of the harmonic trap by controlling the motion of the dragged potential. To this end, we consider two protocols designs: the first protocol strives to maintain adiabaticity at critical points during the atoms' dynamics, whilst the second protocol utilises the fast tunnelling of the atoms within their effective double-well potential. These protocols take place in the few to many millisecond regime and achieve high-fidelity excitation of the atoms into pure vibrational states and superpositions thereof. Overall, our study highlights the significance of dragged potentials for controlling and manipulating atom dynamics and offers intuitive protocols for achieving desired excitations.

cond-mat.quant-gas↗

arXiv2023

Spectral properties of a three body atom-ion hybrid system

We consider a hybrid atom-ion system consisting of a pair of bosons interacting with a single ion in a quasi-one-dimensional trapping geometry. Building upon a model potential for the atom-ion interaction developed in earlier theoretical works, we investigate the behaviour of the low-energy eigenstates for varying contact interaction strength $g$ among the atoms. In particular, we contrast the two cases of a static and a mobile ion. Our study is carried out by means of the Multi-Layer Multi-Configuration Time-Dependent Hartree method for Bosons, a numerically-exact $\textit{ab initio}$ method for the efficient simulation of entangled mixtures. We find that repulsive atom interactions induce locally-distinct modifications of the atomic probability distribution unique to each eigenstate. Whilst the atoms on average separate from each other with increasing $g$, they do not necessarily separate from the ion. The mobility of the ion leads in general to greater separations among the atoms as well as between the atoms and the ion. Notably, we observe an exchange between the kinetic energy of the atoms and the atom-ion interaction energy for all eigenstates, which is both interaction- and mobility-induced. For the ground state, we provide an intuitive description by constructing an effective Hamiltonian for each species, which aptly captures the response of the atoms to the ion's mobility. Furthermore, the effective picture predicts enhanced localisation of the ion, in agreement with our results from exact numerical simulations.

quant-ph↗

arXiv2023

Charged ultralong-range Rydberg trimers

We show that the recently observed class of long-range ion-Rydberg molecules can be divided into two families of states, which are characterised by their unique electronic structures resulting from the ion-induced admixture of quantum defect-split Rydberg $n$P states with different low-field seeking high-$l$ states. We predict that in both cases these diatomic molecular states can bind additional ground state atoms lying within the orbit of the Rydberg electron, thereby forming charged ultralong-range Rydberg molecules (ULRM) with binding energies similar to that of conventional non-polar ULRM. To demonstrate this, we consider a Rydberg atom interacting with a single ground state atom and an ion. The additional atom breaks the system's cylindrical symmetry, which leads to mixing between states that would otherwise be decoupled. The electronic structure is obtained using exact diagonalisation over a finite basis and the vibrational structure is determined using the Multi-Configuration Time-Dependent Hartree method. Due to the lobe-like structure of the electronic density, bound trimers with both linear and nonlinear geometrical configurations of the three nuclei are possible. The predicted trimer binding energies and excitation series are distinct enough from those of the ion-Rydberg dimer to be observed using current experimental techniques.

physics.atom-ph↗