arXiv subjects

Daniel Lisak

Publications and source records attributed to Daniel Lisak.

9 recordsLinked to original sources

arXiv2026

Cavity Ring-Down Spectroscopy at Benchmark-Level Sub-Permille Accuracy Enabled by a System-Level Detection Transfer Function

Cavity ring-down spectroscopy (CRDS) is widely used for sensitive optical absorption measurements, but its quantitative accuracy can be limited at the few-percent level by systematic distortions originating in the CRDS detection system, particularly at short ring-down times. These limitations can restrict demanding spectroscopic applications requiring sub-permille accuracy, including atmospheric sensing, tests of ab initio theory and fundamental physics, and quantum-based optical gas standards. Here we develop a methodology based on a system-level detection transfer function describing the complete CRDS detection-system response, including detector, electronics, and digitization stages, and use it to correct previously unaccounted-for instrumental distortions in retrieved absorption. We demonstrate the method on a CO absorption line measured down to very short ring-down times using multiple independent CRDS detection configurations, initially exhibiting line-area biases of up to 14%. After applying the transfer-function correction, all systems converge to a common value, with the bias relative to the most accurate ab initio-validated reference data reaching the sub-permille level and the accuracy improving by a factor of 41--87. The proposed framework brings well-established CRDS to the level of the most accurate reference methods without requiring specialized measurement schemes or external calibration standards, making benchmark-quality measurements more widely accessible.

physics.optics↗

arXiv2025

Leveraging resonant frequencies of an optical cavity for spectroscopic measurement of gas temperature and concentration

We introduce a spectroscopic approach to primary gas thermometry, harnessing precise optical cavity resonance frequencies and ab initio molecular line intensity calculations. By utilizing CO (3-0) vibrational band lines and cavity mode dispersion spectroscopy, we achieve an uncertainty of 82 ppm (24 mK at 296 K) in line-intensity-ratio thermometry (LRT) - over an order of magnitude lower than any previously reported spectroscopic thermometry at gas pressures above 1.2 kPa. This method extends high-precision spectroscopic thermometry across a pressure range an order of magnitude larger than prior techniques, enabling a fully optical, non-contact, and molecule-selective primary amount-of-substance measurement. We further demonstrate sub-permille uncertainty in gas concentration measurements across pressures from 50 Pa to 20 kPa, significantly enhancing the precision and versatility of spectroscopic gas metrology.

physics.optics↗

arXiv2025

Cavity-enhanced spectroscopy in the deep cryogenic regime -- new hydrogen technologies for quantum sensing

Spectrometers based on high-finesse optical cavities have proven to be powerful tools for applied and fundamental studies. Extending this technology to the deep cryogenic regime is beneficial in many ways: Doppler broadening is reduced, peak absorption is enhanced, the Boltzmann distribution of rotational states is narrowed, all unwanted molecular species disturbing the spectra are frozen out, and dense spectra of complex polyatomic molecules become easier to assign. We demonstrate a cavity-enhanced spectrometer fully operating in the deep cryogenic regime down to 4 K. We solved several technological challenges that allowed us to uniformly cool not only the sample but also the entire cavity, including the mirrors and cavity length actuator, which ensures the thermodynamic equilibrium of a gas sample. Our technology well isolates the cavity from external noise and cryocooler vibrations. This instrument enables a variety of fundamental and practical applications. We demonstrate a few examples based on accurate spectroscopy of cryogenic hydrogen molecules: accurate test of the quantum electrodynamics for molecules; realization of the primary SI standards for temperature, concentration and pressure in the deep cryogenic regime; measurement of the H$_{2}$ phase diagram; and determination of the ortho-para spin isomer conversion rate.

physics.atom-ph↗

arXiv2024

Heterodyne dispersive cavity ring-down spectroscopy exploiting eigenmode frequencies for high-fidelity measurements

Measuring low light absorption with combined uncertainty < 1 permille is crucial in a wide range of applications. Popular cavity ring-down spectroscopy can provide ultra-high precision, below 0.01 permille, but its accuracy is strongly dependent on the measurement capabilities of the detection system and typically is about 10 permille. Here, we exploit the optical frequency information carried by the ring-down cavity electromagnetic field, not explored in conventional CRDS, for high-fidelity spectroscopy. Instead of measuring only the decaying light intensity, we perform heterodyne detection of ring-downs followed by Fourier analysis to provide exact frequencies of optical cavity modes and a dispersive spectrum of a gas sample from them. This approach is insensitive to inaccuracies in light intensity measurements and eliminates the problem of detector band nonlinearity, the main cause of measurement error in traditional CRDS. Using the CO and HD line intensities as examples, we demonstrate the sub-permille accuracy of our method, confirmed by the best ab initio results, and the long-term repeatability of our dispersion measurements at 10^(-4) level. Such results have not been achieved in optical spectroscopy before. The high accuracy of the presented method indicates its potential in atmospheric studies, isotope ratio metrology, thermometry, and the establishment of primary gas standards.

physics.optics↗

arXiv2023

Engineering the sensitivity of macroscopic physical systems to variations in the fine-structure constant

Experiments aimed at searching for variations in the fine-structure constant $\alpha$ are based on spectroscopy of transitions in microscopic bound systems, such as atoms and ions, or resonances in optical cavities. The sensitivities of these systems to variations in $\alpha$ are typically on the order of unity and are fixed for a given system. For heavy atoms, highly charged ions and nuclear transitions, the sensitivity can be increased by benefiting from the relativistic effects and favorable arrangement of quantum states. This article proposes a new method for controlling the sensitivity factor of macroscopic physical systems. Specific concepts of optical cavities with tunable sensitivity to $\alpha$ are described. These systems show qualitatively different properties from those of previous studies of the sensitivity of macroscopic systems to variations in $\alpha$, in which the sensitivity was found to be fixed and fundamentally limited to an order of unity. Although possible experimental constraints attainable with the specific optical cavity arrangements proposed in this article do not yet exceed the present best constraints on $\alpha$ variations, this work paves the way for developing new approaches to searching for variations in the fundamental constants of physics.

physics.atom-ph↗

arXiv2018

Measurement of electron-calcium ionization integral cross section using an ion trap with a low-energy, pulsed electron gun

An apparatus for production of various atomic and molecular ions inside a linear Paul trap has been set up. The system applies a custom-made, low energy, pulsed electron gun to produce ions in electron impact process. Such ionization method can find some interesting possible applications such as derivation of ions inaccessible other-ways, which can be used in molecular ion experiments. The technique allows also for determination of cross sections for various collisional processes. As a feasibility study, the apparatus was used for determination of ionization integral cross section of calcium in the 16--160 eV range of electron impact energy. The obtained cross section values are discussed and compared with existing data sets.

physics.ins-det↗

arXiv2016

Searching for topological defect dark matter with optical atomic clocks

The total mass density of the Universe appears to be dominated by dark matter. However, beyond its gravitational interactions at the galactic scale, little is known about its nature. Extensions of the quantum electrodynamics Lagrangian with dark-matter coupling terms may result in changes to Standard Model parameters. Recently, it was proposed that a network of atomic clocks could be used to search for transient signals of a hypothetical dark matter in the form of stable topological defects. The clocks become desynchronized when a dark-matter object sweeps through the network. This pioneering approach, which is applicable only for distant clocks, is limited by the quality of the fibre links. Here, we present an alternative experimental approach that is applicable to both closely spaced and distant optical atomic clocks and benefits from their individual susceptibilities to dark matter, hence not requiring fibre links. We explore a new dimension of astrophysical observations by constraining the strength of atomic coupling to the hypothetical dark-matter cosmic objects. Our experimental constraint exceeds the previous limits; in fact, it not only reaches the ultimate level expected to be achievable with a constellation of GPS atomic clocks but also has a large potential for improvement.

physics.atom-ph↗

arXiv2015

Absolute measurement of the ${}^{1}S_{0}$ - ${}^{3}P_{0}$ clock transition in neutral ${}^{88}$Sr over the 330 km-long stabilized fibre optic link

We report a stability below $7\times 10{}^{-17}$ of two independent optical lattice clocks operating with bosonic ${}^{88}$Sr isotope. The value (429228066418008.3(1.9)${}_{syst}$(0.9)${}_{stat}$~Hz) of the absolute frequency of the ${}^{1}S_{0}$ - ${}^{3}P_{0}$ transition was measured with an optical frequency comb referenced to the local representation of the UTC by the 330 km-long stabilized fibre optical link. The result was verified by series of measurements on two independent optical lattice clocks and agrees with recommendation of Bureau International des Poids et Mesures.

physics.atom-ph↗

arXiv2014

Recommended isolated-line profile for representing high-resolution spectroscopic transitions (IUPAC Technical Report)

The report of an IUPAC Task Group, formed in 2011 on "Intensities and line shapes in high-resolution spectra of water isotopologues from experiment and theory" (Project No. 2011-022-2-100), on line profiles of isolated high-resolution rotational-vibrational transitions perturbed by neutral gas-phase molecules is presented. The well-documented inadequacies of the Voigt profile (VP), used almost universally by databases and radiative-transfer codes, to represent pressure effects and Doppler broadening in isolated vibrational-rotational and pure rotational transitions of the water molecule have resulted in the development of a variety of alternative line-profile models. These models capture more of the physics of the influence of pressure on line shapes but, in general, at the price of greater complexity. The Task Group recommends that the partially Correlated quadratic-Speed-Dependent Hard-Collision profile should be adopted as the appropriate model for high-resolution spectroscopy. For simplicity this should be called the Hartmann--Tran profile (HTP). The HTP is sophisticated enough to capture the various collisional contributions to the isolated line shape, can be computed in a straightforward and rapid manner, and reduces to simpler profiles, including the Voigt profile, under certain simplifying assumptions.

physics.optics↗