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Daniel Martínez-Gil

Publications and source records attributed to Daniel Martínez-Gil.

5 recordsLinked to original sources

Ultracold Amplification Proposal for Parity Violation in Chiral Molecules

We propose a theoretical mechanism to indirectly detect the small parity-violating energy difference (PVED) between chiral enantiomers through a macroscopic enantiomeric excess observed in an ultracold gas. We consider that chiral molecules are formed resonantly via ultracold collisions of achiral diatomic molecules, with PVED inducing a slight asymmetry in the resonance energies of right- and left-handed configurations. After formation, chiral molecules evolve within a Bose-Einstein condensate (BEC), incorporating nonlinear interactions, tunneling between enantiomeric states, intrinsic PVED, and thermal conversion rates. These collective dynamics enable amplification of the microscopic bias into a global population imbalance. Using coupled rate equations, we show that, under realistic regimes, a complete enantiomeric excess can be achieved even for extremely small intrinsic asymmetries. We illustrate the model with concrete examples (HSOH, H$_2$Se$_2$, H$_2$Te$_2$), predicting observable enantiomeric excesses under plausible experimental conditions. We also consider non-PVED effects that could be amplified under the proposed mechanism, including electric and magnetic fields as well as thermal fluctuations, the latter being illustrated through the aforementioned molecular examples. Overall, our results suggest that ultracold physics could provide a new pathway to probe molecular parity violation, a fundamental weak effect that remains experimentally undetected.

cond-mat.quant-gas↗

Exact Classicalization of N-Level Quantum Systems Interacting with a Bath: Theory and Applications

In this manuscript, starting from a five-step algorithmic procedure for exactly classicalizing the dynamics of N-level quantum systems, we incorporate a classical bath of harmonic oscillators to model environmental interactions. Using the geometry of complex projective spaces CP(N-1) and a Langevin formalism, we obtain N-1 Hamilton's equations which encode both the quantum system and the bath degrees of freedom, representing a generalization of the Caldeira-Legget model in a complex projective space. We demonstrate the efficacy of the method by applying it to two paradigmatic systems: a two-qubit system in CP(3) under entangling interactions, reproducing quantum observables such as state populations, quaternionic population differences and concurrence, and the seven-state Fenna-Matthews-Olson (FMO) complex in CP(6), reproducing state populations in the picosecond timescale.

quant-ph↗

An Exact Five-Step Method for Classicalizing N-level Quantum Systems: Application to Quantum Entanglement Dynamics

In this manuscript, we present a general and exact method for classicalizing the dynamics of any $N$-level quantum system, transforming quantum evolution into a classical-like framework using the geometry of complex projective spaces $\mathbb{CP}^{N-1}$. The method can be expressed as five-step algorithmic procedure to derive a classical Hamiltonian and a symplectic structure for the Poisson brackets, yielding $N-1$ Hamilton's equations that precisely replicate the quantum dynamics, including complex phenomena like entanglement. We demonstrate the method's efficacy by classicalizing two interacting qubits in $\mathbb{CP}^3$, exactly reproducing quantum observables such as quantum probabilities, quaternionic population differences and the concurrence, capturing entanglement dynamics via a classical analog.

quant-ph↗

Chiral environment effects on the dynamics of a central chiral molecule

In this work, we develop a system {\it plus} environment approach for interacting chiral molecules under a quantum-classical description of the spin-spin model using a Caldeira-Leggett-like coupling. After presenting the interacting model, we show that a long-ranged parity-nonconserving interaction, encoded within a non-linear Schrödinger equation, produces an energy difference between the two enantiomers of the central chiral molecule when it interacts with a chiral environment. Three examples of such interactions are considered, with particular focus on $Z^0$-photon vacuum polarization. Finally, we reveal a {\it chirality transmission effect} phenomenon, where the time-averaged population difference of the central molecule is amplified when the chiral asymmetry of the environment is considered.

quant-ph↗

On the role of true and false chirality in producing parity violating energy differences

In this work we tackle the problem of showing which type of influences can lift the degeneracy between truly and falsely chiral systems, showing that only when both systems and influences are both truly (falsely) chiral, a parity violating energy difference between left- and right-handed systems can be produced. In particular, after considering the enantiomers of a chiral molecule as paradigmatic truly chiral systems, we rigorously show, under a quantum field theoretically approach, that only a truly chiral influence such as the $Z^{0}$-mediated electroweak interaction can lift the degeneracy between enantiomers. On the contrary, we explicitly show that a falsely chiral influence, such as an axion-mediated interaction in chiral molecules, can not lift the aforementioned degeneracy. These results extend Barron's seminal ideas [L. D. Barron, True and false chirality and parity violation, Chem. Phys. Lett {\bf 123}, 423 (1986)] to a quantum field theory-based approach.

quant-ph↗