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Daniel T. Robb

Publications and source records attributed to Daniel T. Robb.

5 recordsLinked to original sources

Dynamic Phase Transitions in Mean-Field Ginzburg-Landau Models: Conjugate Fields and Fourier-Mode Scaling

Dynamic phase transitions of periodically forced mean-field ferromagnets are often described by a single order parameter and a scalar conjugate field. Building from previous work, we show that, at the critical period $P_c$ of the mean-field Ginzburg-Landau (MFGL) dynamics with energy $F(m)=am^2+bm^4-hm$, the correct conjugate field is the entire even-Fourier component part of the applied field. The correct order parameter is $z_k=\sqrt{\bigl|\,m_k^2-|m_{k,c}|^2\,\bigr|}$, where $m_k$ is the $k^{th}$ Fourier component of the magnetization m(t), and $m_{k,c}$ is the $k^{th}$ Fourier component at the critical period. Using high-accuracy limit-cycle integration and Fourier analysis, we first confirm that, for periodic fields that contain only odd components, the symmetry-broken branch below $P_c$ exhibits $z_k \propto \varepsilon^{1/2}$ (computationally tested for modes $k\le30$), where $\varepsilon=(P_c-P)/P_c$. This provides strong evidence that the 1/2 scaling holds for all Fourier modes. We then find three robust facts: (1) Exactly at $P_c$, adding a small perturbation composed of even Fourier components with an overall field multiplier $h_{mult}$ yields $z_k \propto h_{mult}^{1/3}$ across many $k$. (2) Mode-resolved deviations obey a parity rule: $|\delta m_{2n}| \propto h_{mult}^{1/3}$ and $|\delta m_{2n+1}| \propto h_{mult}^{2/3}$. (3) These scalings persist in two MFGL models with higher-order nonlinearities.

cond-mat.stat-mech

Extended Order Parameter and Conjugate Field for the Dynamic Phase Transition in a Ginzburg-Landau Mean-Field Model in an Oscillating Field

We present numerical evidence for an extended order parameter and conjugate field for the dynamic phase transition in a Ginzburg-Landau mean-field model driven by an oscillating field. The order parameter, previously taken to be the time-averaged magnetization, comprises the deviations of the Fourier components of the magnetization from their values at the critical period. The conjugate field, previously taken to be the time-averaged magnetic field, comprises the even Fourier components of the field. The scaling exponents beta and delta associated with the extended order parameter and conjugate field are shown numerically to be consistent with their values in the equilibrium mean-field model.

cond-mat.stat-mech

Synthesis of Silver Colloids: Experiment and Computational Model

We summarize our recent results that model the formation of uniform spherical silver colloids prepared by mixing iso-ascorbic acid and silver-amine complex solutions in the absence of dispersants. We found that the experimental results can be modeled effectively by the two-stage formation mechanism used previously to model the preparation of colloidal gold spheres. The equilibrium concentration of silver atoms and the surface tension of silver precursor nanocrystals are both treated as free parameters, and the experimental reaction time scale is fit by a narrow region of this two-parameter space. The kinetic parameter required to match the final particle size is found to be very close to that used previously in modeling the formation of uniform gold particles, suggesting that similar kinetics governs the aggregation process. The model also reproduces semi quantitatively the effects of temperature and solvent viscosity on particle synthesis.

cond-mat.soft

Computational model for the formation of uniform silver spheres by aggregation of nanosize precursors

We present results of computational modeling of the formation of uniform spherical silver particles prepared by rapid mixing of ascorbic acid and silver-amine complex solutions in the absence of a dispersing agent. Using an accelerated integration scheme to speed up the calculation of particle size distributions in the latter stages, we find that the recently reported experimental results -- some of which are summarized here -- can be modeled effectively by the two-stage formation mechanism used previously to model the preparation of uniform gold spheres. We treat both the equilibrium concentration of silver atoms and the surface tension of silver precursor nanocrystals as free parameters, and find that the experimental reaction time scale is fit by a narrow region of this two-parameter space. The kinetic parameter required to quantitatively match the final particle size is found to be very close to that used previously in modeling the formation of gold particles, suggesting that similar kinetics governs the aggregation process and providing evidence that the two-stage model of burst nucleation of nanocrystalline precursors followed by their aggregation to form the final colloids can be applied to systems both with and without dispersing agents. The model also reproduced semiquantitatively the effects of solvent viscosity and temperature on the particle preparation.

cond-mat.soft

EC-FORC: A New Cyclic Voltammetry Based Method for Examining Phase Transitions and Predicting Equilibrium

We propose a new, cyclic-voltammetry based experimental technique that can not only differentiate between discontinuous and continuous phase transitions in an adsorbate layer, but also quite accurately recover equilibrium behavior from dynamic analysis of systems with a continuous phase transition. The Electrochemical first-order reversal curve (EC-FORC) diagram for a discontinuous phase transition (nucleation and growth), such as occurs in underpotential deposition, is characterized by a negative region, while such a region does not exist for a continuous phase transition, such as occurs in the electrosorption of Br on Ag(100). Moreover, for systems with a continuous phase transition, the minima of the individual EC-FORCs trace the equilibrium curve, even at very high scan rates. Since obtaining experimental data for the EC-FORC method would require only a simple reprogramming of the potentiostat used in conventional cyclic-voltammetry experiments, we believe that this method has significant potential for easy, rapid, in-situ analysis of systems undergoing electrochemical deposition.

physics.chem-ph