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Daniela Moretti

Publications and source records attributed to Daniela Moretti.

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Role of mass fluctuations in the diffusion of clusters of Brownian particles with activity

Motivated by the anomalous diffusion observed in clusters of active Brownian particles (ABPs), where the center-of-mass diffusion coefficient scales as $D\sim N^{-1/2}$ with respect to the number $N$ of particles in the cluster, we derive a minimal theoretical framework starting from the single-particle Langevin equations. The model consists of two coupled stochastic equations: one for the cluster center-of-mass trajectory and one for the mass evolution $N(t)$, explicitly accounting for stochastic displacements induced by particle attachment and detachment. We specialize and validate the framework against ABP simulations of isolated clusters in stationary conditions, where $N(t)$ follows a Gaussian process with mean $N_0$, variance $\propto N_0^\beta$, and persistence time $\propto N_0^\kappa$. Analytical solution of the coupled equations yields the long-time diffusion coefficient as the sum of two contributions: a conventional term $\propto N_0^{-1}$) due to thermal noise plus summation of active forces, and a fluctuation-driven term $\propto N_0^{-\delta}$ with $\delta=2-2/d-\beta+\kappa$, where $d$ is the spatial dimension. We demonstrate that anomalous scaling emerges whenever the second term becomes dominant. The model predicts $D\sim N^{-\alpha}$ with $\alpha=0.63\pm0.06$, in good quantitative agreement with large-scale ABP simulations.

cond-mat.stat-mech

Supercoiling DNA with a free end

In this work, we combine coarse-grained Brownian dynamics simulations and mean-field theory to study supercoiling dynamics, as well as the steady-state profiles of twist and writhe, in an open DNA polymer where one of the free ends is subjected to a constant torque. Even though the other end is free, and hence can spin and release torsional stress, we observe that the entire chain transitions between a swollen and a plectonemic phase as the torque increases beyond a critical threshold. In the plectonemic phase, we observe a non-linear twist profile in the steady state, resulting from the mutual interconversion between the injected twist and geometrical writhe, which distributes inhomogeneously along the chain. We also show that the non-equilibrium dynamics of twist accumulation is diffusive, and that writhe diffusion is negligible in this geometry, as plectonemes remain localised near the end that is being rotated. We discuss the feasibility of testing our results with single-molecule experiments.

cond-mat.soft

Transverse Self-Propulsion Enhances the Aggregation of Active Dumbbells

We investigate a two-dimensional system of active Brownian dumbbells using molecular dynamics simulations. In this model, each dumbbell is driven by an active force oriented perpendicular to the axis connecting its two constituent beads. We characterize the resulting phase behavior and find that, across all values of activity, the system undergoes phase separation between dilute and dense phases. The dense phase exhibits hexatic order, and for large enough activity, we observe a marked increase in local polarization, with dumbbells predominantly oriented towards the interior of the clusters. Compared to the case of axially self-propelled dumbbells, we find that the binodal region is enlarged towards lower densities at all activities. This shift arises because dumbbells with transverse propulsion can more easily form stable cluster cores, serving as nucleation seeds, and show a highly suppressed escaping rate from the cluster boundary. Finally, we observe that clusters exhibit spontaneous rotation, with the modulus of the angular velocity scaling as $\omega\sim r_g^{-2}$, where $r_g$ is the cluster's radius of gyration. This contrasts with axially propelled dumbbells, where the scaling follows $\omega\sim r_g^{-1}$. We develop a simplified analytical model to rationalize this scaling behavior.

cond-mat.soft

Two-states Brownian particle in a Harmonic Potential

We study the behaviour of a Brownian particle in the overdamped regime in the presence of a harmonic potential, assuming its diffusion coefficient to randomly jump between two distinct values. In particular, we characterize the probability distribution of the particle position and provide detailed expressions for the mean square displacement and the kurtosis. We highlight non-Gaussian behaviour even within the long-term limit carried over with an excess of probability both in the central part and in the distribution's tails. Moreover, when one of the two diffusion coefficients assumes the value zero, we provide evidence that the probability distribution develops a cusp. Most of our results are analytical, and corroborated by numerical simulations.

cond-mat.stat-mech