arXiv subjects

Danil A. Prishchenko

Publications and source records attributed to Danil A. Prishchenko.

3 recordsLinked to original sources

arXiv2022

Acoustic phonon dispersion of $α$-RuCl$_3$

Acoustic phonons have recently been posited as playing an integral role in explaining the half-quantized thermal Hall effect in $α$-RuCl$_3$. Therefore, we present much needed inelastic x-ray scattering measurements of its acoustic phonon dispersion, along with calculations using the frozen-phonon method. We also discuss a temperature study which conclusively shows a first-order structural transition to a non-$C2/m$ space group at low temperature. Together these results are an important backbone for future theoretical and experimental studies of $α$-RuCl$_3$.

cond-mat.str-el↗

arXiv2019

Anisotropic two-dimensional screening at the surface of black phosphorus

Screening in reduced dimensions has strong consequences on the electronic properties in van der Waals semiconductors, impacting the quasiparticle band gap and exciton binding energy. Screening in these materials is typically treated isotropically, yet black phosphorus exhibits in-plane electronic anisotropy seen in its effective mass, carrier mobility, excitonic wavefunctions, and plasmonic dispersion. Here, we use the adsorption of individual potassium atoms on the surface of black phosphorus to vary the near-surface doping over a wide range, while simultaneously probing the dielectric screening via the ordering of the adsorbed atoms. Using scanning tunneling microscopy, we visualize the role of strongly anisotropic screening which leads to the formation of potassium chains with a well-defined orientation and spacing. We quantify the mean interaction potential utilizing statistical methods and find that the dimensionality and anisotropy of the screening is consistent with the presence of a band-bending induced confinement potential near the surface. We corroborate the observed behavior with coverage-dependent studies of the electronic structure with angle-resolved photoemission.

cond-mat.mes-hall↗

arXiv2016

Antiferroelectric instability in kagome francisites Cu$_3$Bi(SeO$_3$)$_2$O$_2$X (X = Cl, Br)

Density-functional calculations of lattice dynamics and high-resolution synchrotron powder diffraction uncover antiferroelectric distortion in the kagome francisite Cu$_3$Bi(SeO$_3$)$_2$O$_2$Cl below 115K. Its Br-containing analogue is stable in the room-temperature crystal structure down to at least 10K, although the Br compound is on the verge of a similar antiferroelectric instability and reveals local displacements of Cu and Br atoms. The I-containing compound is stable in its room-temperature structure according to density-functional calculations. We show that the distortion involves cooperative displacements of Cu and Cl atoms, and originates from the optimization of interatomic distances for weakly bonded halogen atoms. The distortion introduces a tangible deformation of the kagome spin lattice and may be responsible for the reduced net magnetization of the Cl compound compared to the Br one. The polar structure of Cu$_3$Bi(SeO$_3$)$_2$O$_2$Cl is only slightly higher in energy than the non-polar antiferroelectric structure, but no convincing evidence of its formation could be obtained.

cond-mat.mtrl-sci↗