SearcharxivSearch

arXiv subjects

Daniya Davis

Publications and source records attributed to Daniya Davis.

4 recordsLinked to original sources

Activity-Driven Dewetting and Rupture in Thin Liquid Films

Thin-film dewetting is classically governed by an adhesion-mediated spinodal instability in which curvature-driven diffusion controls post-rupture coarsening. We show that internal activity fundamentally restructures this instability. Using a minimal microscopic model of an active liquid film on a solid substrate, we identify a competition between active stresses and film-substrate adhesion that produces two independently regulated dynamical length scales: vertical liquid accumulation and lateral rupture propagation. While passive films exhibit universal diffusion-limited growth, $\ell_z(t)\sim t^{1/3}$, activity converts transport from curvature-controlled diffusion to persistence-driven motion, yielding a continuous increase of the coarsening exponent from $\approx 0.33$ to $\approx 0.6$. The growth law analysis shows that persistent self-propulsion introduces an advective flux that competes with curvature-induced chemical potential gradients, enhancing growth when the persistence length becomes comparable to the evolving domain size. Simultaneously, the rupture front transitions from dissipative spreading to strongly accelerated propagation approaching ballistic scaling. This decoupling shows that activity does not simply renormalize effective surface forces but generates a distinct nonequilibrium interfacial instability governed by the balance between persistence length and adhesion. The results provide a minimal physical mechanism linking classical thin-film dewetting to dewetting-like rupture observed in active and biological materials.

cond-mat.soft

Phase separation and rheology of segregating binary fluid under shear

We employ molecular dynamics simulation to study the phase separation and rheological properties of a three-dimensional binary liquid mixture with hydrodynamics undergoing simple shear deformation. The impact of shear intensity on domain growth is investigated, with a focus on how shear primarily distorts the domains, leading to the formation of anisotropic structures. The structural anisotropy is quantified by evaluating domain sizes along the flow and shear direction. The rheological properties of the system is studied in terms of shear stress and excess viscosity. At low shear rates, the system behaves like a Newtonian fluid. However, the strong-shear case is marked by a transition characterized by non-Newtonian behavior.

cond-mat.soft

Kinetics Of Vapor-Liquid And Vapor-Solid Phase Separation Under Gravity

We study the kinetics of vapor-liquid and vapor-solid phase separation of a hydrodynamics preserving three-dimensional one component Lennard Jones system in the presence of external gravitational field using extensive molecular dynamic simulation. A bicontinuous domain structure is formed when the homogeneous system near the critical density is quenched inside the coexistence region. In the absence of gravity, the domain morphology is statistically self-similar and the length scale grows as per the existing laws. However, the presence of gravity destroys the isotropy of the system and affects the scaling laws. We observe an accelerated domain growth in the direction of the field at late time which resembles sedimentation process. Consequently, a new length scale emerges which strongly depends on the field strength. Similar behavior is observed in the direction perpendicular to the applied field, with a different growth rate. Finally, the validity of Porod's law and Superuniversality in such anisotropic systems is verified in terms of two-point equal time order parameter correlation function and static structure factor.

cond-mat.soft

Surface directed spinodal decomposition of fluids confined in cylindrical pore

The surface directed spinodal decomposition of a binary liquid confined inside cylindrical pore is investigated using molecular dynamics simulation. One component of the liquid wets the pore surface while the other remains neutral. A variety of wetting conditions are studied. For the partial wetting case, after an initial period of phase separation, the domains organize themselves into plug-like structure and the system enters into a metastable state. Therefore, a complete phase separation is never achieved. Analysis of domain growth and the structure factor suggests an one-dimensional growth dynamics for partial wetting case. As the wetting interaction is increased beyond a critical value, a transition from the plug-like to tube-like domain formation is observed which corresponds to the full wetting morphology. Thus, a complete phase separation is achieved as the wetting species moves towards the pore surface and forms layers enclosing the non wetting species residing around the axis of the cylinder. The coarsening dynamics of both the species are studied separately. The wetting species is found to follow a two-dimensional domain growth dynamics with a growth exponent 1/2 in the viscous hydrodynamic regime. This was substantiated by the Porod tail of the structure factor. On the other hand, the domain grows linearly with time for the non wetting species. This suggests that the non wetting species behaves akin to a three-dimensional bulk system. An appropriate reasoning is presented to justify the given observations.

cond-mat.soft