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Daria Kubyshkina

Publications and source records attributed to Daria Kubyshkina.

At least 19 recordsLinked to original sources

Escape of Water- and Metal-enriched Atmospheres from compact Hot mini-Neptunes with CHAIN

Recent observations reveal that atmospheric compositions of close-in sub-Neptunes are diverse and can differ strongly from pure H/He-dominated. We assess the possibility of modelling metal-rich and water-rich atmospheres with CHAIN model. We evaluate the major differences between the upper atmosphere photochemistry of such atmospheres compared to H/He, and the impact on atmospheric mass loss rates. We employ CHAIN to model upper atmospheres of two warm and hot sub-Neptune-like planets which were suggested to host possibly water-/metal-rich atmospheres: GJ 9827 d and TOI-238 b. For each planet, we consider a range of compositions between H/He atmospheres with solar metallicities to highly metal- and/or water-rich atmospheres and evaluate how our predictions change with increasing metal/water fractions. We find that for considered sub-Neptunes (1) an increase in water/metal abundance leads both to the increase in atmospheric cooling rates (due to the metal line cooling and molecular cooling processes) and the increase in heating (metal line heating in dense atmospheric layers and metals' ions); (2) due to the increase in cooling and the mean particle weight of the atmosphere, the atmospheric mass loss drops significantly at high water/metal fractions (water mass fractions of >=50% or metal enrichment over 100 times solar), while at low enrichment levels mass loss rates are similar to those of H/He atmospheres with solar abundances or slightly higher; (3) for the same atmospheric mean particle weight, the escape from water-rich atmospheres is generally lower. In the context of atmospheric evolution, it implies that the atmospheres with initially high water fraction in the atmosphere are more stable. Furthermore, due to the preferential escape of H, the atmospheric metal/H ratio is expected to increase significantly with time, leading to the earlier cessation of the hydrodynamic escape.

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Upper atmosphere dynamics and drivers of volatiles loss from terrestrial-type (exo)planets

Volatile loss from exoplanetary atmospheres and its possible implications for the longevity of habitable surface conditions is a topic of vigorous debate currently. The vast majority of the habitable zone terrestrial-like exoplanets known to date orbit low-mass M- and K-dwarf stars and are subject to the conditions drastically different to those of terrestrial planets in the Solar System. In particular, they orbit far closer to their host stars than similar planets around G-dwarfs similar to the Sun. Therefore they receive higher X-ray and UV fluxes, even though luminosities of M- and K-dwarfs are lower than those of heavier stars. Furthermore, due to their slower evolution, M-dwarfs retain high activity on the gigayear timescales. The combination of these two effects has led to claims that most terrestrial planets orbiting M-dwarfs may have their atmospheres stripped from the higher X-ray and UV fluxes of their host stars. Opposing this are researchers who point out that volatile inventories for terrestrial exoplanets are ill-constrained, and hence, they may be able to "weather the storm" of these higher X-ray and UV fluxes. In this chapter, we focus on exploring volatile loss in the upper atmospheres of terrestrial planets in our solar system and applications to those in exoplanetary systems around stars of different types.

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Grid-based exoplanet atmospheric mass loss predictions through neural network

The fast and accurate estimation of planetary mass-loss rates is critical for planet population and evolution modelling. We use machine learning (ML) for fast interpolation across an existing large grid of hydrodynamic upper atmosphere models, providing mass-loss rates for any planet inside the grid boundaries with superior accuracy compared to previously published interpolation schemes. We consider an already available grid comprising about 11000 hydrodynamic upper atmosphere models for training and generate an additional grid of about 250 models for testing purposes. We develop the ML interpolation scheme (dubbed "atmospheric Mass Loss INquiry frameworK"; MLink) using a Dense Neural Network, further comparing the results with what was obtained employing classical approaches (e.g. linear interpolation and radial basis function-based regression). Finally, we study the impact of the different interpolation schemes on the evolution of a small sample of carefully selected synthetic planets. MLink provides high-quality interpolation across the entire parameter space by significantly reducing both the number of points with large interpolation errors and the maximum interpolation error compared to previously available schemes. For most cases, evolutionary tracks computed employing MLink and classical schemes lead to comparable planetary parameters at Gyr-timescales. However, particularly for planets close to the top edge of the radius gap, the difference between the predicted planetary radii at a given age of tracks obtained employing MLink and classical interpolation schemes can exceed the typical observational uncertainties. Machine learning can be successfully used to estimate atmospheric mass-loss rates from model grids paving the way to explore future larger and more complex grids of models computed accounting for more physical processes.

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Magnetic Field Evolution of Hot Exoplanets

Numerical simulations have shown that the strength of planetary magnetic fields depends on the convective energy flux emerging from planetary interiors. Here we model the interior structure of gas giant planets using \texttt{MESA}, to determine the convective energy flux that can drive the generation of magnetic field. This flux is then incorporated in the Christensen et al. dynamo formalism to estimate the maximum dipolar magnetic field $B^\mathrm{(max)}_\mathrm{dip}$ of our simulated planets. First, we explore how the surface field of intensely irradiated hot Jupiters ($\sim 300 M_\oplus$) and hot Neptunes ($\sim 20 M_\oplus$) evolve as they age. Assuming an orbital separation of 0.1 au, for the hot Jupiters, we find that $B^\mathrm{(max)}_\mathrm{dip}$ evolves from 240 G at 500 Myr to 120 G at 5~Gyr. For hot Neptunes, the magnetic field evolves from 11 G at young ages and dies out at $\gtrsim$ 2 Gyr. Furthermore, we also investigate the effects of atmospheric mass fraction, atmospheric evaporation, orbital separations $α$ and additional planetary masses on the derived $B^\mathrm{(max)}_\mathrm{dip}$. We found that $B^\mathrm{(max)}_\mathrm{dip}$ increases with $α$ for very close-in planets and plateaus out after that. Higher atmospheric mass fractions lead in general to stronger surface fields, because they allow for more extensive dynamo regions and stronger convection.

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JWST/NIRISS reveals the water-rich "steam world" atmosphere of GJ 9827 d

With sizable volatile envelopes but smaller radii than the solar system ice giants, sub-Neptunes have been revealed as one of the most common types of planet in the galaxy. While the spectroscopic characterization of larger sub-Neptunes (2.5-4R$_\oplus$) has revealed hydrogen-dominated atmospheres, smaller sub-Neptunes (1.6--2.5R$_\oplus$) could either host thin, rapidly evaporating hydrogen-rich atmospheres or be stable metal-rich "water worlds" with high mean molecular weight atmospheres and a fundamentally different formation and evolutionary history. Here, we present the 0.6--2.8$μ$m JWST NIRISS/SOSS transmission spectrum of GJ 9827 d, the smallest (1.98 R$_\oplus$) warm (T$_\mathrm{eq, A_B=0.3} \sim 620$K) sub-Neptune where atmospheric absorbers have been detected to date. Our two transit observations with NIRISS/SOSS, combined with the existing HST/WFC3 spectrum, enable us to break the clouds-metallicity degeneracy. We detect water in a highly metal-enriched "steam world" atmosphere (O/H of $\sim 4$ by mass and H$_2$O found to be the background gas with a volume mixing ratio of >31%). We further show that these results are robust to stellar contamination through the transit light source effect. We do not detect escaping metastable He, which, combined with previous nondetections of escaping He and H, supports the steam atmosphere scenario. In water-rich atmospheres, hydrogen loss driven by water photolysis happens predominantly in the ionized form which eludes observational constraints. We also detect several flares in the NIRISS/SOSS light-curves with far-UV energies of the order of 10$^{30}$ erg, highlighting the active nature of the star. Further atmospheric characterization of GJ 9827 d probing carbon or sulfur species could reveal the origin of its high metal enrichment.

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Planetary atmospheres Through Time: Effects of Mass Loss and Thermal Evolution

Atmospheric mass loss is a fundamental phenomenon shaping the structure and evolution of planetary atmospheres. It can engage processes ranging from global interactions with the host star and large-scale hydrodynamic outflows to essentially microphysical kinetic effects. The relevance of these processes is expected to change between planets of different properties and at different stages in planetary and stellar evolution. The early evolution of planetary atmospheres, as well as atmospheric escape from close-in planets hosting hydrogen-dominated atmospheres, is thought to be driven by thermal hydrodynamic escape, while the kinetic non-thermal effects are most relevant for the long-term evolution of planets with secondary atmospheres, similar to the inner planets in the Solar System. The relative input of different mechanisms, hence, the mass loss rate, shows a complicated dependence on planetary parameters and the parameters of the host star, where the latter evolve strongly with time. It results in a large variety of possible evolution paths of planetary atmospheres.

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Precise photoionisation treatment and hydrodynamic effects in atmospheric modelling of warm and hot Neptunes

Observational breakthroughs in the exoplanet field of the last decade motivated the development of numerous theoretical models describing atmospheres and mass loss, which is believed to be one of the main drivers of planetary evolution. We aim to outline for which types of close-in planets in the Neptune-mass range the accurate treatment of photoionisation effects is most relevant concerning atmospheric escape and the parameters relevant for interpreting observations. We developed the CHAIN (Cloudy e Hydro Ancora INsieme) model combining 1D hydrodynamic upper atmosphere model with the non-LTE photoionisation and radiative transfer code Cloudy accounting for photochemistry, detailed atomic level populations, and chemical reactions for all elements up to zinc. We apply CHAIN to model the upper atmospheres of a range of Neptune-like planets with masses between 1 and 50 M$_{\oplus}$, varying also the orbital parameters. For the majority of warm and hot Neptunes, we find slower and denser outflows, with lower ion fractions, compared to the predictions of the hydrodynamic model alone. Furthermore, we find significantly different temperature profiles between CHAIN and the hydrodynamic model alone, though the peak values are similar for similar atmospheric compositions. The mass-loss rates predicted by CHAIN are higher for hot, strongly irradiated planets and lower for more moderate planets. All differences between the two models are strongly correlated with the amount of high-energy irradiation. Finally, we find that the hydrodynamic effects impact significantly ionisation and heating. The impact of the precise photoionisation treatment provided by Cloudy strongly depends on the system parameters. This suggests that some of the simplifications typically employed in hydrodynamic modelling might lead to systematic errors when studying planetary atmospheres, even at a population-wide level.

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Metallicity and Spectral Evolution of WASP-39 b: The Limited Role of Hydrodynamic Escape

The recent observations on WASP-39 b by JWST have revealed hints of high metallicity within the atmosphere compared to its host star (Feinstein et al. 2022; Ahrer et al. 2023; Alderson et al. 2023; Rustamkulov et al. 2023; Tsai et al. 2023). There are various theories on how these high metallic atmospheres emerge. In this study, we closely investigate the impact of extreme escape in the form of hydrodynamic escape to see its impact on atmospheric metallicity and spectral features such as CH$_4$, CO$_2$, and SO$_2$. We perform a grid simulation, with an adapted version of MESA that includes hydrodynamic escape (Kubyshkina et al. 2018; 2020), to fully evolve planets with similar masses and radii to the currently observed WASP-39 b estimates. By making use of (photo-)chemical kinetics and radiative transfer codes, we evaluate the transmission spectra at various time intervals throughout the simulation. Our results indicate that the massive size of WASP-39 b limits the metal enhancement to a maximum of ~1.23 the initial metallicity. When incorporating metal drag, this enhancement factor is repressed to an even greater degree, resulting in an enrichment of at most ~0.4%. As a consequence, when assuming an initial solar metallicity, metal-enriched spectral features like SO$_2$ are still missing after ~9 Gyr into the simulation. This paper, thus, demonstrates that hydrodynamic escape cannot be the primary process behind the high metallicity observed in the atmosphere of WASP-39 b, suggesting instead that a metal-enhanced atmosphere was established during its formation.

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Planetary evolution with atmospheric photoevaporation II: Fitting the slope of the radius valley by combining boil-off and XUV-driven escape

The Kepler satellite has revealed a gap between sub-Neptunes and super-Earths that atmospheric escape models had predicted as an evaporation valley. We seek to contrast results from a simple XUV-driven energy-limited (ELIM) escape model against those from a direct hydrodynamic (HYDRO) model. Besides XUV-driven escape, the latter also includes the boil-off regime. We couple the two models to an internal structure model and follow the planets' temporal evolution over Gyr. To see the population-wide imprint of the two models, we first employ a rectangular grid in initial conditions. We then study the slope of the valley also for initial conditions derived from the Kepler planets. For the rectangular grid, we find that the power-law slope of the valley with respect to orbital period is -0.18 and -0.11 in the ELIM and HYDRO model, respectively. For the initial conditions derived from the Kepler planets, the results are similar (-0.16 and -0.10). While the slope found with the ELIM model is steeper than observed, the one of the HYDRO model is in excellent agreement with observations. The reason for the shallower slope is caused by the two regimes in which the ELIM model fails: First, puffy planets at low stellar irradiation. For them, boil-off dominates mass loss. However, boil-off is absent in the ELIM model, thus it underestimates escape relative to HYDRO. Second, massive compact planets at high XUV irradiation. For them, the ELIM approximation overestimates escape relative to the HYDRO case because of cooling by thermal conduction, neglected in the ELIM model. The two effects act together in concert to yield in the HYDRO model a shallower slope of the valley that agrees very well with observations. We conclude that an escape model that includes boil-off and a more realistic treatment of cooling mechanisms can reproduce one of the most important constraints, the valley slope.

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Evidence for the volatile-rich composition of a 1.5-$R_\oplus$ planet

The population of planets smaller than approximately $1.7~R_\oplus$ is widely interpreted as consisting of rocky worlds, generally referred to as super-Earths. This picture is largely corroborated by radial-velocity (RV) mass measurements for close-in super-Earths but lacks constraints at lower insolations. Here we present the results of a detailed study of the Kepler-138 system using 13 Hubble and Spitzer transit observations of the warm-temperate $1.51\pm0.04~R_\oplus$ planet Kepler-138 d ($T_{\mathrm{eq, A_B=0.3}}$~350 K) combined with new Keck/HIRES RV measurements of its host star. We find evidence for a volatile-rich "water world" nature of Kepler-138 d, with a large fraction of its mass contained in a thick volatile layer. This finding is independently supported by transit timing variations, RV observations ($M_d=2.1_{-0.7}^{+0.6}~M_\oplus$), as well as the flat optical/IR transmission spectrum. Quantitatively, we infer a composition of $11_{-4}^{+3}$\% volatiles by mass or ~51% by volume, with a 2000 km deep water mantle and atmosphere on top of a core with an Earth-like silicates/iron ratio. Any hypothetical hydrogen layer consistent with the observations ($<0.003~M_\oplus$) would have swiftly been lost on a ~10 Myr timescale. The bulk composition of Kepler-138 d therefore resembles those of the icy moons rather than the terrestrial planets in the solar system. We conclude that not all super-Earth-sized planets are rocky worlds, but that volatile-rich water worlds exist in an overlapping size regime, especially at lower insolations. Finally, our photodynamical analysis also reveals that Kepler-138 c ($R_c=1.51 \pm 0.04~R_\oplus$, $M_c=2.3_{-0.5}^{+0.6}~M_\oplus$) is a slightly warmer twin of Kepler-138 d, i.e., another water world in the same system, and we infer the presence of Kepler-138 e, a likely non-transiting planet at the inner edge of the habitable zone.

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The mass-radius relation of intermediate-mass planets outlined by hydrodynamic escape and thermal evolution

We employ planetary evolution modeling to reproduce the MR distribution of the 198 so far detected planets with mass and radius measured to the <45% and <15% level, respectively, and less massive than 108Me. We simultaneously account for atmospheric escape, based on the results of hydrodynamic models, and thermal evolution, based on planetary structure evolution models. Since high-energy stellar radiation affects atmospheric evolution, we account for the entire range of possible stellar rotation histories. To set the planetary parameters at formation, we use analytical approximations based on formation models. Finally, we build a grid of synthetic planets with parameters reflecting those of the observed distribution. The predicted radius spread reproduces well the observed MR distribution, except for two distinct groups of outliers (~20% of the population). The first one consists of close-in Saturn-mass planets with Jupiter-like radii for which we underpredict the radius likely because it lacks additional heating similar to that responsible for inflation in hot Jupiters. The second group consists of warm sub-Neptunes, which should host massive primordial H-dominated atmospheres, but instead present high densities indicative of small gaseous envelopes. This suggests that their formation, internal structure, and evolution are different from that of atmospheric evolution through the escape of H-dominated envelopes accreted onto rocky cores. The observed characteristics of low-mass planets (<10-15Me) strongly depend on the impact of atmospheric escape, and thus on the evolution of the host star, while primordial parameters are less relevant. Instead, for more massive planets, the parameters at formation play the dominant role in shaping the final MR distribution.

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Atmospheric mass loss and stellar wind effects in young and old systems I: comparative 3D study of TOI-942 and TOI-421 systems

At young ages, when radiation from the host star is high, and the planet is hot and inflated after formation, planetary atmospheric mass loss can be extremely strong compared to older planets. In turn, stellar winds are faster and denser for young stars compared to evolved main-sequence stars. Their interaction with escaping planetary atmospheres can substantially affect atmospheric mass loss rates, as well as the observable signatures of escaping atmospheres, with both effects expected to occur differently for young and evolved planets. We perform a comparative study of two systems around stars of similar masses but very different ages (50~Myr and 9~Gyr): TOI-942 and TOI-421. Both stars host two sub-Neptune-like planets at similar orbits and in similar mass ranges, which allows a direct comparison of the atmospheric escape and interactions with the stellar winds in the young and old systems. We perform the 3D atmospheric modeling of the four planets in TOI-942 and TOI-421 systems and make the theoretical predictions of possible observational signatures in Ly-alpha absorption. We find that accounting for the stellar wind interacting with planetary atmospheres is crucial for the interpretation of the observations for young planets. Additionally, we show that a particular energy distribution along the XUV spectra has a minor effect on the atmospheric mass-loss rates, but it is of crucial importance for modeling the Ly-alpha absorption and therefore for interpretation of observations.

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Atmospheric mass loss and stellar wind effects in young and old systems II: Is TOI-942 the past of TOI-421 system?

The two planetary systems TOI-942 and TOI-421 share many similar characteristics, apart from their ages (50~Myr and 9~Gyr). Each of the stars hosts two sub-Neptune-like planets at similar orbits and in similar mass ranges. In this paper, we aim to investigate whether the similarity of the host stars and the configuration of the planetary systems can be taken as proof that the two systems were formed and evolved in a similar way. In paper I of this series, we performed a comparative study of these two systems using 3D modeling of atmospheric escape and its interaction with the stellar wind, for the four planets. We demonstrated that though the strong wind of the young star has a crucial effect on observable signatures, its effect on the atmospheric mass loss is minor in the evolutionary context. Here, we use atmosphere evolution models to track the evolution of planets in the younger system TOI-942 and also to constrain the past of the TOI-421 system. We demonstrate that despite all the similarities, the two planetary systems are on two very different evolutionary pathways. The inner planet in the younger system, TOI-942, will likely lose all of its atmosphere and become a super-Earth-like planet, while the outer planet will become a typical sub-Neptune. Concerning the older system, TOI-421, our evolution modeling suggests that they must have started their evolution with very substantial envelopes, which can be a hint of formation beyond the snow line.

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Stellar rotation and its connection to the evolution of hydrogen-dominated atmospheres of exoplanets

The population of known low- to intermediate-mass exoplanets shows a large spread in densities, which is believed to be due to the diversity of planetary atmospheres and thus controlled by planetary atmospheric mass loss. One of the main drivers of long-term atmospheric escape is the absorption of high-energy XUV radiation from the host star. For main sequence solar-like stars, rotation and XUV radiation are closely connected, with faster rotating stars being XUV brighter and with both rotation and XUV decreasing with time. This evolution, however, does not follow a unique path, as stars born with the same mass and metallicity can have widely different initial rotation rates. This non-uniqueness holds up to about 1 Gyr, while atmospheric escape from exoplanets is strongest. The atmospheric mass loss through this period is often deciding the future of the planet and its position in the observed population. Therefore, the diversity of possible stellar histories can be an uncertain factor affecting the predictions of population studies. Here, I explore its relevance for different planets and different host stars.

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A critical assessment of the applicability of the energy-limited approximation for estimating exoplanetary mass-loss rates

Context: The energy-limited (EL) atmospheric escape approach is used to estimate mass-loss rates for a broad range of planets that host hydrogen-dominated atmospheres as well as for performing atmospheric evolution calculations. Aims: We aim to study the applicability range of the EL approximation. Methods: We revise the EL formalism and its assumptions. We also compare its results with those of hydrodynamic simulations, employing a grid covering planets with masses, radii, and equilibrium temperatures ranging between 1 $M_{\oplus}$ and 39 $M_{\oplus}$, 1 $R_{\oplus}$ and 10 $R_{\oplus}$, and 300 and 2000 K, respectively. Results: Within the grid boundaries, we find that the EL approximation gives a correct order of magnitude estimate for mass-loss rates for about 76% of the planets, but there can be departures from hydrodynamic simulations by up to three orders of magnitude in individual cases. Furthermore, we find that planets for which the mass-loss rates are correctly estimated by the EL approximation to within one order of magnitude have intermediate gravitational potentials as well as low-to-intermediate equilibrium temperatures and irradiation fluxes of extreme ultraviolet and X-ray radiation. However, for planets with low or high gravitational potentials, or high equilibrium temperatures and irradiation fluxes, the approximation fails in most cases. Conclusions: The EL approximation should not be used for planetary evolution calculations that require computing mass-loss rates for planets that cover a broad parameter space. In this case, it is very likely that the EL approximation would at times return mass-loss rates of up to several orders of magnitude above or below those predicted by hydrodynamic simulations. For planetary atmospheric evolution calculations, interpolation routines or approximations based on grids of hydrodynamic models should be used instead.

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Extending a grid of hydrodynamic planetary upper atmosphere models

In this research note, we outline the extension of the grid of upper atmosphere models first presented in Kubyshkina et al. (2018a). The original grid is based on a 1D hydrodynamic model and consists of about 7000 models covering planets of the size from Earth to twice Neptune at orbits corresponding to equilibrium temperatures between 300 and 2000 K around solar-like (0.4 to 1.3 solar mass) stars. The extended and revised grid of models consists of 10235 points and covers a planetary mass range of up to 109 Earth masses, which allows one to outline the transition between low- and high-gravity hot planets in short orbital separations. We prepared the interpolation tool allowing one to use the grid to define the mass-loss of a planet that falls into the parameter range of the grid. We provide a comparison of our results to common analytical models.

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How does the mass and activity history of the host star affect the population of low-mass planets?

The evolution of the atmospheres of low and intermediate-mass planets is strongly connected to the physical properties of their host stars. The types and the past activities of planet-hosting stars can, therefore, affect the overall planetary population. In this paper, we perform a comparative study of sub-Neptune-like planets orbiting stars of different masses and different evolutionary histories. We discuss the general patterns of the evolved population as a function of parameters and environments of planets. As a model of the atmospheric evolution, we employ the own framework combining planetary evolution in MESA with the realistic prescription of the escape of hydrogen-dominated atmospheres. {We find that the final populations look qualitatively similar in terms of the atmospheres survival around different stars, but qualitatively different, with this difference accentuated for planets orbiting more massive stars. We show that a planet has larger chances of keeping its primordial atmosphere in the habitable zone of a solar mass star compared to M or K dwarfs and if it starts the evolution having a relatively compact envelope.} We also address the problem of the uncertain initial temperatures (luminosities) of planets and show that this issue is only of particular importance for planets exposed to extreme atmospheric mass-losses.

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The multi-planet system TOI-421 -- A warm Neptune and a super puffy mini-Neptune transiting a G9 V star in a visual binary

We report the discovery of a warm Neptune and a hot sub-Neptune transiting TOI-421 (BD-14 1137, TIC 94986319), a bright (V=9.9) G9 dwarf star in a visual binary system observed by the TESS space mission in Sectors 5 and 6. We performed ground-based follow-up observations -- comprised of LCOGT transit photometry, NIRC2 adaptive optics imaging, and FIES, CORALIE, HARPS, HIRES, and PFS high-precision Doppler measurements -- and confirmed the planetary nature of the 16-day transiting candidate announced by the TESS team. We discovered an additional radial velocity signal with a period of 5 days induced by the presence of a second planet in the system, which we also found to transit its host star. We found that the inner mini-Neptune, TOI-421b, has an orbital period of Pb =5.19672 +- 0.00049 days, a mass of Mb = 7.17 +- 0.66 Mearth and a radius of Rb = 2.68+0.19-0.18 Rearth, whereas the outer warm Neptune, TOI-421 c, has a period of Pc =16.06819 +- 0.00035 days, a mass of Mc = 16.42+1.06-1.04 Mearth, a radius of Rc = 5.09+0.16-0.15 Rearth and a density of rho_c =0.685+0.080-0.072 g cm-3 . With its characteristics the inner planet (rho_b=2.05+0.52-0.41 g cm-3) is placed in the intriguing class of the super-puffy mini-Neptunes. TOI-421b and TOI-421c are found to be well suitable for atmospheric characterization. Our atmospheric simulations predict significant Ly-alpha transit absorption, due to strong hydrogen escape in both planets, and the presence of detectable CH_4 in the atmosphere of TOI-421c if equilibrium chemistry is assumed.

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