arXiv subjects

David A. Williams

Publications and source records attributed to David A. Williams.

At least 37 records · Page 2Linked to original sources

arXiv2017

Probing the dark exciton states of a single quantum dot using photocurrent spectroscopy in magnetic fields

We report on high-resolution photoluminescence (PL) and photocurrent (PC) spectroscopies of a single self-assembled InAs/GaAs quantum dot (QD) embedded in an n-i-Schottky device with an applied magnetic field in Faraday and Voigt geometries. The single-QD PC spectrum of neutral exciton (X$^0$) is obtained by sweeping the bias-dependent X$^0$ transition energy to achieve resonance with a fixed narrow-bandwidth laser through quantum-confined Stark effect. With a magnetic field applied in Faraday geometry, the diamagnetic effect and the Zeeman splitting of X$^0$ are observed both in PL and PC spectra. When the magnetic field is applied in Voigt geometry, the mixture of bright and dark states results in an observation of dark exciton states, which are confirmed by the polarization-resolved PL and PC spectra.

cond-mat.mes-hall↗

arXiv2017

A study of methanol and silicon monoxide production through episodic explosions of grain mantles in the Central Molecular Zone

Methanol (CH$_3$OH) is found to be abundant and widespread towards the Central Molecular Zone, the inner few hundred parsecs of our Galaxy. Its origin is, however, not fully understood. It was proposed that the high cosmic ray ionisation rate in this region could lead to a more efficient non-thermal desorption of this species formed on grain surfaces, but it would also mean that this species is destroyed in a relatively short timescale. In a first step, we run chemical models with a high cosmic ray ionisation rate and find that this scenario can only reproduce the lowest abundances of methanol derived in this region ($\sim$10$^{-9}$-10$^{-8}$). In a second step, we investigate another scenario based on episodic explosions of grain mantles. We find a good agreement between the predicted abundances of methanol and the observations. We find that the dominant route for the formation of methanol is through hydrogenation of CO on the grains followed by the desorption due to the grain mantle explosion. The cyclic aspect of this model can explain the widespread presence of methanol without requiring any additional mechanism. We also model silicon monoxide (SiO), another species detected in several molecular clouds of the Galactic Centre. An agreement is found with observations for a high depletion of Si (Si/H $\sim$ 10$^{-8}$) with respect to the solar abundance.

astro-ph.GA↗

arXiv2016

On the chemistry of hydrides of N atoms and O$^+$ ions

Previous work by various authors has suggested that the detection by Herschel/HIFI of nitrogen hydrides along the low density lines of sight towards G10.6-0.4 (W31C) cannot be accounted for by gas-phase chemical models. In this paper we investigate the role of surface reactions on dust grains in diffuse regions, and we find that formation of the hydrides by surface reactions on dust grains with efficiency comparable to that for H$_2$ formation reconciles models with observations of nitrogen hydrides. However, similar surface reactions do not contribute significantly to the hydrides of O$^+$ ions detected by Herschel/HIFI present along many sight lines in the Galaxy. The O$^+$ hydrides can be accounted for by conventional gas-phase chemistry either in diffuse clouds of very low density with normal cosmic ray fluxes or in somewhat denser diffuse clouds with high cosmic ray fluxes. Hydride chemistry in dense dark clouds appears to be dominated by gas-phase ion-molecule reactions.

astro-ph.GA↗

arXiv2016

Surface Albedo and Spectral Variability of Ceres

Previous observations suggested that Ceres has active but possibly sporadic water outgassing, and possibly varying spectral characteristics in a time scale of months. We used all available data of Ceres collected in the past three decades from the ground and the Hubble Space Telescope, and the newly acquired images by Dawn Framing Camera to search for spectral and albedo variability on Ceres, in both a global scale and local regions, particularly the bright spots inside Occator crater, over time scales of a few months to decades. Our analysis has placed an upper limit on the possible temporal albedo variation on Ceres. Sporadic water vapor venting, or any possibly ongoing activity on Ceres, is not significant enough to change the albedo or the area of the bright features in Occator crater by >15%, or the global albedo by >3% over various time scales that we searched. Recently reported spectral slope variations can be explained by changing Sun-Ceres-Earth geometry. The active area on Ceres is less than 1 km$^2$, too small to cause global albedo and spectral variations detectable in our data. Impact ejecta due to impacting projectiles of tens of meters in size like those known to cause observable changes to the surface albedo on Asteroid Scheila cannot cause detectable albedo change on Ceres due to its relatively large size and strong gravity. The water vapor activity on Ceres is independent of Ceres' heliocentric distance, rulling out the possibility of comet-like sublimation process as a possible mechanism driving the activity.

astro-ph.EP↗

arXiv2015

Observation of coupling between zero- and two-dimensional semiconductor systems based on anomalous diamagnetic effects

We report the direct observation of coupling between a single self-assembled InAs quantum dot and a wetting layer, based on strong diamagnetic shifts of many-body exciton states using magneto-photoluminescence spectroscopy. An extremely large positive diamagnetic coefficient is observed when an electron in the wetting layer combines with a hole in the quantum dot; the coefficient is nearly one order of magnitude larger than that of the exciton states confined in the quantum dots. Recombination of electrons with holes in a quantum dot of the coupled system leads to an unusual negative diamagnetic effect, which is five times stronger than that in a pure quantum dot system. This effect can be attributed to the expansion of the wavefunction of remaining electrons in the wetting layer or the spread of electrons in the excited states of the quantum dot to the wetting layer after recombination. In this case, the wavefunction extent of the final states in the quantum dot plane is much larger than that of the initial states because of the absence of holes in the quantum dot to attract electrons. The properties of emitted photons that depend on the large electron wavefunction extents in the wetting layer indicate that the coupling occurs between systems of different dimensionality, which is also verified from the results obtained by applying a magnetic field in different configurations. This study paves a new way to observe hybrid states with zero- and two-dimensional structures, which could be useful for investigating the Kondo physics and implementing spin-based solid-state quantum information processing.

cond-mat.mes-hall↗

arXiv2015

The extragalactic background light, the Hubble constant, and anomalies: conclusions from 20 years of TeV gamma-ray observations

Ground-based observatories have been collecting 0.2 - 20 TeV gamma rays from blazars for about twenty years. These gamma rays can experience absorption along the line of sight due to interactions with the extragalactic background light (EBL). In this paper, we show that the gamma-ray optical depth can be reduced to the convolution product of an EBL kernel with the EBL intensity, assuming a particular form for the EBL evolution. We extract the absorption signal from the most extensive set of TeV spectra from blazars collected so far and unveil a broad-band EBL spectrum from mid-ultraviolet to far infrared. This spectrum is in good agreement with the accumulated emission of galaxies, constraining unresolved populations of sources. We propose a data-driven estimate of the Hubble constant based on the comparison of local and gamma-ray measurements of the EBL. After setting stringent upper-limits on the redshift of four TeV blazars, we investigate the 106 gamma-ray spectra in our sample and find no significant evidence for anomalies. The intrinsic TeV spectra are not harder than their GeV counterpart, and no spectral upturn is visible at the highest optical depths. Finally, we investigate a modification of the pair-creation threshold due to Lorentz invariance violation. A mild excess prevents us from ruling out an effect at the Planck energy, and we constrain for the first time the energy scale of the modification to values larger than sixty percent of the Planck energy.

astro-ph.CO↗

arXiv2015

Performance of Silicon Photomultipliers for the Dual-Mirror Medium-Sized Telescopes of the Cherenkov Telescope Array

Gamma-ray observations in the very-high-energy domain (E > 30 GeV) can exploit the imaging of few-nanosecond Cherenkov flashes from atmospheric particle showers. Photomultipliers have been used as the primary photosensors to detect gamma-ray induced Cherenkov light for the past 25 years, but they are increasingly challenged by the swift progress of silicon photomultipliers (SiPMs). We are working to identify the optimal photosensors for medium-sized Schwarzschild-Couder telescopes (SCT), which are proposed to contribute a significant fraction of the sensitivity of the Cherenkov Telescope Array in its core energy range. We present the capabilities of the latest SiPMs from the Hamamatsu, SensL, and Excelitas companies that we have characterized in our laboratory, and compare them to the SiPMs equipping the prototype SCT camera that is under construction.

astro-ph.IM↗

arXiv2015

Gamma-ray cosmology and fundamental physics with TeV blazars: results from 20 years of observations

Gamma rays from TeV blazars have been detected by ground-based experiments for more than two decades. We have collected the most extensive set of archival spectra from these sources in order to constrain the processes affecting gamma-ray propagation on cosmological distances. We discuss our results on the diffuse photon field that populates universe, called the extragalactic background light, on the expansion rate of the Universe, and on fundamental physics in the form of axion-like particles and Lorentz-invariance violation. Specifically, we present a spectrum of the extragalactic background light from 0.26 to 105 microns constructed from the gamma-ray observations, we measure a value of the Hubble constant compatible with other estimates, and we constrain the energy scale at which Lorentz-invariance violation impacts gamma-ray absorption by the extragalactic background light to be larger than sixty percent of the Planck scale.

astro-ph.CO↗

arXiv2015

Longitudinal wave function control in single quantum dots with an applied magnetic field

Controlling single-particle wave functions in single semiconductor quantum dots is in demand to implement solid-state quantum information processing and spintronics. Normally, particle wave functions can be tuned transversely by an perpendicular magnetic field. We report a longitudinal wave function control in single quantum dots with a magnetic field. For a pure InAs quantum dot with a shape of pyramid or truncated pyramid, the hole wave function always occupies the base because of the less confinement at base, which induces a permanent dipole oriented from base to apex. With applying magnetic field along the base-apex direction, the hole wave function shrinks in the base plane. Because of the linear changing of the confinement for hole wave function from base to apex, the center of effective mass moves up during shrinking process. Due to the uniform confine potential for electrons, the center of effective mass of electrons does not move much, which results in a permanent dipole moment change and an inverted electron-hole alignment along the magnetic field direction. Manipulating the wave function longitudinally not only provides an alternative way to control the charge distribution with magnetic field but also a new method to tune electron-hole interaction in single quantum dots.

cond-mat.mes-hall↗

arXiv2014

Charge state control in single InAs/GaAs quantum dots by external electric and magnetic fields

We report a photoluminescence (PL) spectroscopy study of charge state control in single self-assembled InAs/GaAs quantum dots by applying electric and/or magnetic fields at 4.2 K. Neutral and charged exciton complexes were observed under applied bias voltages from -0.5 V to 0.5 V by controlling the carrier tunneling. The highly negatively charged exciton emission becomes stronger with increasing pumping power, arising from the fact that electrons have a smaller effective mass than holes and are more easily captured by the quantum dots. The integrated PL intensity of negatively charged excitons is affected significantly by a magnetic field applied along the sample growth axis. This observation is explained by a reduction in the electron drift velocity caused by an applied magnetic field, which increases the probability of non-resonantly excited electrons being trapped by localized potentials at the wetting layer interface, and results in fewer electrons distributed in the quantum dots. The hole drift velocity is also affected by the magnetic field, but it is much weaker.

cond-mat.mes-hall↗

arXiv2014

Champagne Flutes and Brandy Snifters: Modelling Protostellar Outflow-Cloud Chemical Interfaces

A rich variety of molecular species has now been observed towards hot cores in star forming regions and in the interstellar medium. An increasing body of evidence from millimetre interferometers suggests that many of these form at the interfaces between protostellar outflows and their natal molecular clouds. However, current models have remained unable to explain the origin of the observational bias towards wide-angled "brandy snifter" shaped outflows over narrower "champagne flute" shapes in carbon monoxide imaging. Furthermore, these wide-angled systems exhibit unusually high abundances of the molecular ion HCO$^+$. We present results from a chemo-dynamic model of such regions where a rich chemistry arises naturally as a result of turbulent mixing between cold, dense molecular gas and the hot, ionized outflow material. The injecta drives a rich and rapid ion-neutral chemistry in qualitative and quantitative agreement with the observations. The observational bias towards wide-angled outflows is explained naturally by the geometry-dependent ion injection rate causing rapid dissociation of CO in the younger systems.

astro-ph.GA↗

arXiv2013

On the Redshift of the Very High Energy Blazar 3C 66A

As a bright gamma-ray source, 3C 66A is of great interest to the high-energy astrophysics community, having a potential for placing cosmological constraints on models for the extragalactic background light (EBL) and the processes which contribute to this photon field. No firm spectroscopic redshift measurement has been possible for this blazar due to a lack of intrinsic emission and absorption features in optical spectra. We present new far-ultraviolet spectra from the Hubble Space Telescope/Cosmic Origins Spectrograph (HST/COS) of the BL Lac object 3C 66A covering the wavelength range 1132 to 1800 Angstroms . The data show a smooth continuum with intergalactic medium absorption features which can be used to place a firm lower limit on the blazar redshift of z>0.3347. An upper limit is set by statistically treating the non-detection of additional absorbers beyond z=0.3347, indicating a redshift of less than 0.41 at 99% confidence and ruling out z>0.444 at 99.9% confidence. We conclude by showing how the redshift limits derived from the COS spectra remove the potential for this gamma-ray emitting blazar to place an upper limit on the flux of the EBL using high energy data from a flare in October of 2009.

astro-ph.CO↗

arXiv2013

Gamma-Ray Burst Science in the Era of the Cherenkov Telescope Array

We outline the science prospects for gamma-ray bursts (GRBs) with the Cherenkov Telescope Array (CTA), the next-generation ground-based gamma-ray observatory operating at energies above few tens of GeV. With its low energy threshold, large effective area and rapid slewing capabilities, CTA will be able to measure the spectra and variability of GRBs at multi-GeV energies with unprecedented photon statistics, and thereby break new ground in elucidating the physics of GRBs, which is still poorly understood. Such measurements will also provide crucial diagnostics of ultra-high-energy cosmic ray and neutrino production in GRBs, advance observational cosmology by probing the high-redshift extragalactic background light and intergalactic magnetic fields, and contribute to fundamental physics by testing Lorentz invariance violation with high precision. Aiming to quantify these goals, we present some simulated observations of GRB spectra and light curves, together with estimates of their detection rates with CTA. Although the expected detection rate is modest, of order a few GRBs per year, hundreds or more high-energy photons per burst may be attainable once they are detected. We also address various issues related to following up alerts from satellites and other facilities with CTA, as well as follow-up observations at other wavelengths. The possibility of discovering and observing GRBs from their onset including short GRBs during a wide-field survey mode is also briefly discussed.

astro-ph.HE↗

arXiv2012

On the redshift of the blazar PKS0447-439

PKS0447-439 is one of the BL Lacertae objects that have been detected at very high energy. There has been a recent report of a lower limit of z>1.246 for the redshift of this blazar, challenging the current paradigm in which very high-energy gamma-rays cannot freely propagate in the z>1 universe. In this research note, we present a new MagE/Magellan spectrum of PKS0447-439 with exquisite signal-to-noise (S/N>150 at 6500A). Our analysis confirms the presence of the previously-reported absorption line at 6280A, which we identify, however, with a known telluric absorption, invalidating the claim that this blazar lies at z>1. Since no other extragalactic spectral features are detected, we cannot establish a redshift based on our spectrum.

astro-ph.CO↗

arXiv2012

IACT observations of gamma-ray bursts: prospects for the Cherenkov Telescope Array

Gamma rays at rest frame energies as high as 90 GeV have been reported from gamma-ray bursts (GRBs) by the Fermi Large Area Telescope (LAT). There is considerable hope that a confirmed GRB detection will be possible with the upcoming Cherenkov Telescope Array (CTA), which will have a larger effective area and better low-energy sensitivity than current-generation imaging atmospheric Cherenkov telescopes (IACTs). To estimate the likelihood of such a detection, we have developed a phenomenological model for GRB emission between 1 GeV and 1 TeV that is motivated by the high-energy GRB detections of Fermi-LAT, and allows us to extrapolate the statistics of GRBs seen by lower energy instruments such as the Swift-BAT and BATSE on the Compton Gamma-ray Observatory. We show a number of statistics for detected GRBs, and describe how the detectability of GRBs with CTA could vary based on a number of parameters, such as the typical observation delay between the burst onset and the start of ground observations. We also consider the possibility of using GBM on Fermi as a finder of GRBs for rapid ground follow-up. While the uncertainty of GBM localization is problematic, the small field-of-view for IACTs can potentially be overcome by scanning over the GBM error region. Overall, our results indicate that CTA should be able to detect one GRB every 20 to 30 months with our baseline instrument model, assuming consistently rapid pursuit of GRB alerts, and provided that spectral breaks below 100 GeV are not a common feature of the bright GRB population. With a more optimistic instrument model, the detection rate can be as high as 1 to 2 GRBs per year.

astro-ph.HE↗

arXiv2011

Prospects of GRB observations for CTA from a phenomenological model

Very high energy (VHE, i.e. $\gtrsim 10$ GeV) photons from Gamma-Ray Bursts (GRBs), as high as 90 GeV in rest frame energy, have been detected by the $Fermi$ Large Area Telescope (LAT). This provides hope for a high statistics GRB detection by a ground-based instrument in the VHE domain. We here report on our estimates of the expected GRB detection rate and $γ$-ray rate (in case of detection) for the next generation ground-based Imaging Air Cherenkov Telescopes (IACTs): the Cherenkov Telescope Array (CTA). Moreover, we investigated the effect critical design parameters of CTA have on our predictions and we compare the performance of various observing strategies for the array pointing. Our estimations are based on a phenomenological model which uses temporal and spectral information from GRBs detected by $Fermi$-LAT as well as other instruments operating at lower energy. While detection of VHE emission from GRBs has eluded ground-based instruments thus far, our results suggest it should be within reach of CTA with a rate between 0.35 and 1.6 GRBs/year depending on the characteristics of the true GRB population and the performance that CTA will eventually achieve.

astro-ph.HE↗

arXiv2011

Excitation of the aromatic infrared emission bands: Chemical energy in hydrogenated amorphous carbon particles?

We outline a model for the heating of hydrogenated amorphous (HAC) dust via the release of stored chemical energy and show that this energy (~12 kJ/mole) is sufficient to heat dust grains of classical size (50-1000 Å) to temperatures at which they can emit at 3.3 μm and other "UIR" wavelengths. Using laboratory data, we show that this heating process is consistent with a concentration of a few percent of dangling bonds in HAC and may be initiated by the recombination of trapped H atoms. We suggest that the release of chemical energy from dust represents an additional source of excitation for the UIR bands relaxing the previous requirement that only stochastically heated molecules having fewer than ~ 50 atoms can produce emission at 3.3 μm.

astro-ph.GA↗

arXiv2010

Chemistry in Evaporating Ices: Unexplored Territory

We suggest that three-body chemistry may occur in warm high density gas evaporating in transient co\textendash desorption events on interstellar ices. Using a highly idealised computational model we explore the chemical conversion from simple species of the ice to more complex species containing several heavy atoms, as a function of density and of adopted three body rate coefficients. We predict that there is a wide range of densities and rate coefficients in which a significant chemical conversion may occur. We discuss the implications of this idea for the astrochemistry of hot cores.

astro-ph.GA↗