arXiv subjects

David Barton

Publications and source records attributed to David Barton.

15 recordsLinked to original sources

arXiv2026

Materials for Quantum Information Science: Roles in the Quantum Evolution 2.0

Quantum information science is entering a second phase, the Quantum Evolution 2.0, in which the challenge has shifted from demonstrating coherent control of individual quantum states to building scalable multi-qubit processors and networks. This transition places materials science at the center of the field. Across superconducting circuits, quantum defects, quantum photonic devices, and emerging materials platforms, including two-dimensional materials and heterostructures, performance is now limited less by device design than by poorly controlled surfaces, buried interfaces, and defects whose atomic identities remain incompletely known. This review surveys the materials challenges of these quantum platforms together with the characterization methods needed to resolve them. For each platform we identify the dominant decoherence mechanisms, the current state of materials understanding, and the most pressing open materials problems. A cross-platform comparison then reveals a shared structure-coherence problem. The implicated material chemistry recurs across platforms, involving light elements in disordered or buried environments, yet no platform can quantitatively connect a specific atomic-scale structure to a measured change in coherence. We close by identifying three needs, mechanistic understanding of decoherence at the atomistic level, high-throughput proxy metrics predictive of device performance, and characterization tools built for quantum materials, whose resolution would advance coherence, scalability, and integration across all platforms.

quant-ph↗

arXiv2026

Monolithic Barium Titanate Nanophotonics and Electro-optics

Barium titanate-on-insulator (BTOI) is a compelling material for high-speed integrated photonic modulators due to its large Pockels coefficient (r42 > 1200 pm/V in bulk), which allows for the miniaturization of modulators while maintaining strong electro-optic performance. Sub-wavelength nanostructures monolithically etched into BTOI are particularly exciting, as they offer a path toward subwavelength light-matter interaction and reduced modulator energy consumption. Here, we design, fabricate, and characterize monolithic one-dimensional nanophotonic crystals (PhCs) and high-Q (230k) photonic-crystal Fabry-Perot (FP) cavities in BTOI. We develop and optimize a nanofabrication process that yields anisotropic (75-degree sidewalls) and deep etching that features low optical loss, with racetrack resonators achieving intrinsic quality factors near 1 million and propagation losses of about 0.5 dB/cm. Our photonic crystals exhibit bandgap contrasts greater than 40 dB, and FP cavities reach loaded quality factors up to 230k. We verify ferroelectric domain alignment via second-harmonic generation microscopy and extract an effective Pockels coefficient of 154 pm/V. By probing the microwave response at the PhC band edge, where modulation bandwidth is set by the material's electro-optic response rather than cavity photon lifetime, we measure a 3-dB electro-optic bandwidth of 11 GHz and a 6-dB bandwidth of 21 GHz, consistent with the frequency-dependent roll-off of BTO's r42 coefficient near 10 GHz. Finally, we show a variety of modulation effects in resonators and at photonic crystal band edges, including sideband-resolved modulation, resonant bandwidth-limited modulation, and photonic-crystal based single sideband modulation and frequency comb generation.

physics.optics↗

arXiv2026

Collective Radiative Enhancement of Rare-Earth Ions in Lithium Niobate via Engineered LargeArea Nanohole Arrays

Conventional approaches to light-matter interactions rely on engineering photonic density of states. More recently, tailoring the spatial geometry of atoms or emitters themselves has emerged as a powerful and complementary route to control collective radiative properties. Here we experimentally realize a geometry-engineered ensemble of rare-earth ions by fabricating a periodic array of subwavelength gold nanoholes on lithium niobate implanted with thulium ions, forming a semi-two-dimensional array of quantum emitters embedded in a high-index crystalline thin film. The hybrid structure can simultaneously support localized and lattice plasmon resonances from the metallic array and collective atomic resonances from the ion ensemble. Using time-resolved photoluminescence and temperature-dependent measurements, we observe enhanced radiative emission attributed to collective atomic effects mediated by the nanohole lattice, distinct from single-emitter Purcell enhancement. Our results demonstrate a new regime of light-matter interaction opening a pathway toward broadband and scalable, geometry-controlled quantum optical interfaces in solid-state platforms.

physics.optics↗

arXiv2026

Programmable and nonvolatile computing with composition tuning in thin film lithium niobate

Matrix-vector multiplications are fundamental operations in artificial intelligence and high-throughput computations, and are executed repeatedly during training and inference. Their high energy cost in electronic processors motivate scalable photonic computing approaches that reduce the energy required per operation. Thin film lithium niobate is a dominant photonic platform due to its large electro-optic effect. However, it lacks nonvolatile index tuning mechanisms, which promise to pave the way for energy-efficient photonic computing. Here, we explore electrochemical lithiation as a route to nonvolatile matrix-vector multiplications in thin film lithium niobate. The lithium niobate phase is stable at room temperature over a 2% Li composition window with an associated composition-dependent refractive index. We computationally demonstrate this as a programmable, low-loss approach to perform matrix-vector multiplications by using composition to control matrix weights. We design Mach-Zehnder interferometers to perform image processing tasks under realistic material loss constraints. We also design microring resonators for iterative weight updates, using gradient descent training to program target matrix operations with matrix-vector multiplication accuracy validated at 1.6% average relative error. These demonstrations show a facile route towards nonvolatile photonic computing in thin film lithium niobate, addressing a critical requirement for energy-efficient photonic matrix operations at scale.

physics.optics↗

arXiv2025

Text2Touch: Tactile In-Hand Manipulation with LLM-Designed Reward Functions

Large language models (LLMs) are beginning to automate reward design for dexterous manipulation. However, no prior work has considered tactile sensing, which is known to be critical for human-like dexterity. We present Text2Touch, bringing LLM-crafted rewards to the challenging task of multi-axis in-hand object rotation with real-world vision based tactile sensing in palm-up and palm-down configurations. Our prompt engineering strategy scales to over 70 environment variables, and sim-to-real distillation enables successful policy transfer to a tactile-enabled fully actuated four-fingered dexterous robot hand. Text2Touch significantly outperforms a carefully tuned human-engineered baseline, demonstrating superior rotation speed and stability while relying on reward functions that are an order of magnitude shorter and simpler. These results illustrate how LLM-designed rewards can significantly reduce the time from concept to deployable dexterous tactile skills, supporting more rapid and scalable multimodal robot learning. Project website: https://hpfield.github.io/text2touch-website

cs.RO↗

arXiv2025

GHz-speed wavefront shaping metasurface modulators enabled by resonant electro-optic nanoantennas

Electrically tunable metasurfaces that control the amplitude and phase of light through biasing of nanoscale antennas present a route to compact, sub-micron thick modulator devices. However, most platforms face limitations in bandwidth, absolute optical efficiency, and tuning response. Here, we present electro-optically tunable metasurfaces capable of both GHz amplitude modulation and transmissive wavefront shaping in the telecom range. Our resonant electro-optic nanoantenna design consists of a silicon nanobar atop thin-film lithium niobate, with gold electrodes. The silicon nanobar is a periodically perturbed optical waveguide that supports high quality factor (Q $>$ 1000) guided mode resonances excited with free space light. Applying a voltage bias to the lithium niobate tunes its refractive index, modulating the resonant behavior of the silicon nanobar through evanescent mode overlap. We demonstrate an absolute transmittance modulation of 7.1% with $\pm$5 V applied voltage, and show the dependence of this modulation behavior on the resonance quality factor. We additionally study the electrode limitations on modulation bandwidth, demonstrating bandwidths exceeding 800 MHz. Finally, we show how this resonant antenna platform can be used to design wavefront shaping metasurfaces. We demonstrate a beamsplitting metasurface device, whose diffraction efficiency can be modulated with a bandwidth of 1.03 GHz. The high-speed modulation and wavefront control capabilities of this platform provide a foundation for compact, high bandwidth free space communications and sensing devices.

physics.optics↗

arXiv2024

Modeling Nonlinear Oscillator Networks Using Physics-Informed Hybrid Reservoir Computing

Surrogate modeling of non-linear oscillator networks remains challenging due to discrepancies between simplified analytical models and real-world complexity. To bridge this gap, we investigate hybrid reservoir computing, combining reservoir computing with "expert" analytical models. Simulating the absence of an exact model, we first test the surrogate models with parameter errors in their expert model. Second, in a residual physics task, we assess their performance when their expert model lacks key non-linear coupling terms present in an extended ground-truth model. We focus on short-term forecasting across diverse dynamical regimes, evaluating the use of these surrogates for control applications. We show that hybrid reservoir computers generally outperform standard reservoir computers and exhibit greater robustness to parameter tuning. This advantage is less pronounced in the residual physics task. Notably, unlike standard reservoir computers, the performance of the hybrid does not degrade when crossing an observed spectral radius threshold. Furthermore, there is good performance for dynamical regimes not accessible to the expert model, demonstrating the contribution of the reservoir.

eess.SY↗

arXiv2024

Realtime observation of a tungsten-promoted size regulation mechanism in a rhodium catalyst at atomic resolution

The static and genuine structure of small rhodium and rhodium/tungsten nanoparticles on an alumina support can be imaged with atomic resolution even if single digit atom clusters are investigated. Low dose rate electron microscopy is key to the achievement and can generally be applied to investigate any similar material. In such conditions it becomes feasible to identify the chemical composition of nanocrystals from quantitative contrast analyses alone by counting atoms. The ability to fully characterize an unaltered, initial state of the objects allows targeting structural excitations or conformational changes induced by the electron beam itself. For the specific case of catalytic Rh:W particles we stimulate a tungsten-promoted size regulation mechanism in real time that is driven by Oswald ripening and can be understood by a strong binding of tungsten atoms to the oxygen atoms of the support, which builds up strain as the cluster sizes increase.

cond-mat.mtrl-sci↗

arXiv2024

A Thin Film Lithium Niobate Near-Infrared Platform for Multiplexing Quantum Nodes

Practical quantum networks will require quantum nodes consisting of many memory qubits. This in turn will increase the complexity of the photonic circuits needed to control each qubit and will require strategies to multiplex memories and overcome the inhomogeneous distribution of their transition frequencies. Integrated photonics operating at visible to near-infrared (VNIR) wavelength range, compatible with the transition frequencies of leading quantum memory systems, can provide solutions to these needs. In this work, we realize a VNIR thin-film lithium niobate (TFLN) integrated photonics platform with the key components to meet these requirements. These include low-loss couplers ($<$ 1 dB/facet), switches ($>$ 20 dB extinction), and high-bandwidth electro-optic modulators ($>$ 50 GHz). With these devices we demonstrate high-efficiency and CW-compatible frequency shifting ($>$ 50 $\%$ efficiency at 15 GHz), as well as simultaneous laser amplitude and frequency control through a nested modulator structure. Finally, we highlight an architecture for multiplexing quantum memories using the demonstrated TFLN components, and outline how this platform can enable a 2-order of magnitude improvement in entanglement rates over single memory nodes. Our results demonstrate that TFLN can meet the necessary performance and scalability benchmarks to enable large-scale quantum nodes.

physics.optics↗

arXiv2024

Integrated electro-optics on thin-film lithium niobate

Electro-optics serves as the crucial bridge between electronics and photonics, unlocking a wide array of applications ranging from communications and computing to sensing and quantum information. Integrated electro-optics approaches in particular enable essential electronic high-speed control for photonics while offering substantial photonic parallelism for electronics. Recent strides in thin-film lithium niobate photonics have ushered revolutionary advancements in electro-optics. This technology not only offers the requisite strong electro-optic coupling but also boasts ultra-low optical loss and high microwave bandwidth. Further, its tight confinement and compatibility with nanofabrication allow for unprecedented reconfigurability and scalability, facilitating the creation of novel and intricate devices and systems that were once deemed nearly impossible in bulk systems. Building upon this platform, the field has witnessed the emergence of various groundbreaking electro-optic devices surpassing the current state of the art, and introducing functionalities that were previously non-existent. This technological leap forward provides a unique framework to explore various realms of physics as well, including photonic non-Hermitian synthetic dimensions, active topological physics, and quantum electro-optics. In this review, we present the fundamental principles of electro-optics, drawing connections between fundamental science and the forefront of technology. We discuss the accomplishments and future prospects of integrated electro-optics, enabled by thin-film lithium niobate platform.

physics.optics↗

arXiv2023

Coherent control of a superconducting qubit using light

Quantum communications technologies require a network of quantum processors connected with low loss and low noise communication channels capable of distributing entangled states. Superconducting microwave qubits operating in cryogenic environments have emerged as promising candidates for quantum processor nodes. However, scaling these systems is challenging because they require bulky microwave components with high thermal loads that can quickly overwhelm the cooling power of a dilution refrigerator. Telecommunication frequency optical signals, meanwhile, can be fabricated in significantly smaller form factors while avoiding challenges due to high signal loss, noise sensitivity, and thermal loads due to their high carrier frequency and propagation in silica optical fibers. Transduction of information via coherent links between optical and microwave frequencies is therefore critical to leverage the advantages of optics for superconducting microwave qubits, while also enabling superconducting processors to be linked with low-loss optical interconnects. Here, we demonstrate coherent optical control of a superconducting qubit. We achieve this by developing a microwave-optical quantum transducer that operates with up to 1.18% conversion efficiency with low added microwave noise, and demonstrate optically-driven Rabi oscillations in a superconducting qubit.

quant-ph↗

arXiv2021

Femtosecond Pulse Generation via an Integrated Electro-Optic Time Lens

Integrated femtosecond pulse and frequency comb sources are critical components for a wide range of applications. The leading approaches for on-chip pulse generation rely on mode locking inside microresonator with either third-order nonlinearity or with semiconductor gain. These approaches, however, are limited in noise performance, wavelength tunability and repetition rates. Alternatively, sub-picosecond pulses can be synthesized without mode-locking, by modulating a continuous-wave (CW) single-frequency laser using a cascade of electro-optic (EO) modulators. This method is particularly attractive due to its simplicity, robustness, and frequency-agility but has been realized only on a tabletop using multiple discrete EO modulators and requiring optical amplifiers (to overcome large insertion losses), microwave amplifiers, and phase shifters. Here we demonstrate a chip-scale femtosecond pulse source implemented on an integrated lithium niobate (LN) photonic platform18, using cascaded low-loss electro-optic amplitude and phase modulators and chirped Bragg grating, forming a time-lens system. The device is driven by a CW distributed feedback (DFB) chip laser and controlled by a single CW microwave source without the need for any stabilization or locking. We measure femtosecond pulse trains (520 fs duration) with a 30-GHz repetition rate, flat-top optical spectra with a 10-dB optical bandwidth of 12.6 nm, individual comb-line powers above 0.1 milliwatt, and pulse energies of 0.54 picojoule. Our results represent a tunable, robust and low-cost integrated pulsed light source with CW-to-pulse conversion efficiencies an order of magnitude higher than achieved with previous integrated sources. Our pulse generator can find applications from ultrafast optical measurement to networks of distributed quantum computers.

physics.optics↗

arXiv2020

Ultra-low doping and local charge variation in graphene measured by Raman: experiment and simulation

Avoiding charge density variations and impurities in graphene is vital for high-quality graphene-based devices. Here, we demonstrate an optical method using Raman 2D peak-split to monitor charge density variations in the range 1-25e10 cm-2. We compare Raman signatures with electrostatically gated Raman and transport measurements to correlate the 2D peak-split with the charge density on graphene with high precision. We found that the Raman 2D peak-split and peak areas linearly varies with the charge density, where a lower charge density results in a larger 2D peak-split. We simulate Raman 2D spectra under various doping conditions to study the correlation between Raman 2D peak and charge puddles. These simulations give qualitative agreement with experimental results. Our work provides a simple and non-invasive optical method for estimating the doping level, local charge density variation and transport properties of graphene before fabricating graphene devices, with up to two orders of magnitude higher precision than previously reported optical methods.

physics.app-ph↗

arXiv2019

Monitoring the low doping regime in graphene using Raman 2D peak-splits: Comparison of gated Raman and transport measurements

Avoiding charge density fluctuations and impurities in graphene is vital for high-quality graphene-based devices. Traditional characterization methods require device fabrication and electrical transport measurements, which are labor-intensive and time-consuming. Existing optical methods using Raman spectroscopy only work for doping levels higher than ~10^12 cm^-2. Here, we propose an optical method using Raman 2D peak-splitting (split between the Raman 2D1 and 2D2 peaks at low doping levels). Electrostatically gated Raman measurements combined with transport measurements were used to correlate the 2D peak-split with the charge density on graphene with high precision (2x10^10 cm^-2 per 2D peak-split wavenumber). We found that the Raman 2D peak-split has a strong correlation with the charge density at low doping levels, and that a lower charge density results in a larger 2D peak-split. Our work provides a simple and non-invasive optical method to quantify the doping level of graphene from 10^10 cm^-2 to 10^12 cm^-2, two orders of magnitude higher precision than previously reported optical methods. This method provides a platform for estimating the doping level and quality of graphene before fabricating graphene devices

physics.app-ph↗

arXiv2017

Active Polarization Control with a Parity-Time Symmetric Plasmonic Resonator

Control of the polarization state of light is essential for many technologies, but is often limited by weak light-matter interactions that necessitate long device path lengths or significantly reduce the signal intensity. Here, we investigate a nanoscale plasmonic aperture capable of modifying the polarization state of far-field transmitted light without loss in the probe signal. The aperture is a coaxial resonator consisting of a dielectric ring embedded within a metallic film; parity-time ($\mathcal{PT}$) symmetric inclusions of loss and gain within the dielectric ring enable polarization control. Since the coaxial aperture enables near-thresholdless $\mathcal{PT}$ symmetry breaking, polarization control is achieved with realistic levels of loss and gain. Exploiting this sensitivity, we show that the aperture can function as a tunable waveplate, with the transmitted ellipticity of circularly polarized incident light changing continuously with the dissipation coefficient from $\pi/2$ to 0 (i.e. linear polarization). Rotation of linearly polarized light with unity efficiency is also possible, with a continuously-tunable degree of rotation. This compact, low-threshold, and reconfigurable polarizer may enable next-generation, high-efficiency displays, routers, modulators, and metasurfaces.

physics.optics↗