arXiv subjects

David Grant

Publications and source records attributed to David Grant.

At least 19 recordsLinked to original sources

arXiv2026

Magnesium Silicate Clouds in the Atmosphere of HD 209458b from a Rule-Based Tree-Structured Data Reduction

HD 209458b is the canonical hot Jupiter: the first to have its atmosphere measured and the first to hint at the role of aerosols in exoplanet atmospheres through the muting of Na absorption signatures in the optical. Here we present JWST MIRI/LRS transmission observations of HD 209458b from 5-12 microns, directly measuring the absorption signatures of its clouds for the first time. The observations indicate the presence of magnesium silicates, most likely Mg2SiO4 or a mixture of Mg2SiO4 and MgSiO3. We also present a new methodology to reduce observational data, whereby the analysis is formulated as a rule-based model with a tree structure, enabling key decisions to be identified and uncertain decisions to be incorporated into subsequent modeling. With this data reduction, and using a combination of ARCiS free retrievals and PICASO+Virga self consistent forward models, we are able to show that amorphous Mg2SiO4 clouds explain the LRS data to high significance over either a clear (Delta ln(Z)=16.63) or gray cloud atmosphere (Delta ln(Z)=22.26). By combining the LRS dataset with archival JWST NIRCam and HST optical and near-infrared observations, we are able to more robustly constrain the properties of the magnesium silicate condensates, finding particle sizes of approximately 0.1 microns and atmospheric pressures of the clouds of roughly 1-10 millibar. Our results add to the growing detections of silicate clouds as a dominant atmospheric component of hot Jupiters, with the exact silicate species contextualizing the atmospheric chemistry and potentially formation conditions of these planets.

astro-ph.EP↗

arXiv2025

JWST-TST DREAMS: NIRSpec/PRISM Transmission Spectroscopy of the Habitable Zone Planet TRAPPIST-1 e

TRAPPIST-1 e is one of the very few rocky exoplanets that is both amenable to atmospheric characterization and that resides in the habitable zone of its star -- located at a distance from its star such that it might, with the right atmosphere, sustain liquid water on its surface. Here, we present a set of 4 JWST/NIRSpec PRISM transmission spectra of TRAPPIST-1 e obtained from mid to late 2023. Our transmission spectra exhibit similar levels of stellar contamination as observed in prior works for other planets in the TRAPPIST-1 system (Lim et al, 2023; Radica et al., 2024), but over a wider wavelength range, showcasing the challenge of characterizing the TRAPPIST-1 planets even at relatively long wavelengths (3-5 um). While we show that current stellar modeling frameworks are unable to explain the stellar contamination features in our spectra, we demonstrate that we can marginalize over those features instead using Gaussian Processes, which enables us to perform novel exoplanet atmospheric inferences with our transmission spectra. In particular, we are able to rule out cloudy, primary H$_2$-dominated ($\gtrsim$ 80$\%$ by volume) atmospheres at better than a 3$\sigma$ level. Constraints on possible secondary atmospheres on TRAPPIST-1 e are presented in a companion paper (Glidden et al., 2025). Our work showcases how JWST is breaking ground into the precisions needed to constrain the atmospheric composition of habitable-zone rocky exoplanets.

astro-ph.EP↗

arXiv2025

JWST-TST DREAMS: Secondary Atmosphere Constraints for the Habitable Zone Planet TRAPPIST-1 e

The TRAPPIST-1 system offers one of the best opportunities to characterize temperate terrestrial planets beyond our own solar system. Within the TRAPPIST-1 system, planet e stands out as highly likely to sustain surface liquid water if it possesses an atmosphere. Recently, we reported the first JWST/NIRSpec PRISM transmission spectra of TRAPPIST-1 e, revealing significant stellar contamination, which varied between the four visits. Here, we assess the range of planetary atmospheres consistent with our transmission spectrum. We explore a wide range of atmospheric scenarios via a hierarchy of forward modeling and retrievals. We do not obtain strong evidence for or against an atmosphere. Our results weakly disfavor CO$_2$-rich atmospheres for pressures corresponding to the surface of Venus and Mars and the cloud tops of Venus at 2$\sigma$. We exclude H$_2$-rich atmospheres containing CO$_2$ and CH$_4$ in agreement with past work, but find that higher mean molecular weight, N$_2$-rich atmospheres with trace CO$_2$ and CH$_4$ are permitted by the data. Both a bare rock and N$_2$-rich atmospheric scenario provide adequate fits to the data, but do not fully explain all features, which may be due to either uncorrected stellar contamination or atmospheric signals. Ongoing JWST observations of TRAPPIST-1 e, exploiting consecutive transits with TRAPPIST-1 b, will offer stronger constraints via a more effective stellar contamination correction. The present work is part of the JWST Telescope Scientist Team (JWST-TST) Guaranteed Time Observations, which is performing a Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

astro-ph.EP↗

arXiv2025

Modeling tails of escaping gas in exoplanet atmospheres with Harmonica

Exoplanets that reside close to their host stars, and therefore receive substantial amounts of X-ray and ultraviolet radiation, are prone to suffer from strong atmospheric escape. This can lead to the creation of an envelope of escaping gas along the planet's orbital trajectory, often referred to as a tail. When transiting in front of their host star, these tails can not only produce larger depths in the transit light curves, but also introduce significant asymmetries between ingress and egress. Using the publicly available software Harmonica, we present a method to model the light curves of transiting planets surrounded by extended envelopes of escaping gas, and subsequently infer the shape and size of the latter. We apply this method to the JWST NIRISS/SOSS observations of HAT-P-18b, which show pronounced helium tail features in its spectroscopic light curve of the metastable helium triplet at 10830 \r{A}. Our model reveals that, in order to fit the observed light curve of HAT-P-18b, the planet must possess a trailing helium tail of $15.79^{+1.14}_{-1.05}$ planetary radii. We carry out injection-recovery tests to validate the effectiveness of the proposed methodology. We demonstrate that, with sufficient precision, we would be able to fit a multi-layer envelope to the data, which would provide insight into the relative radial variations in the opacity profile.

astro-ph.EP↗

arXiv2025

The HUSTLE Program: The UV to Near-IR Transmission Spectrum of the Hot Jupiter KELT-7b

The ultraviolet and optical wavelength ranges have proven to be a key addition to infrared observations of exoplanet atmospheres, as they offer unique insights into the properties of clouds and hazes and are sensitive to signatures of disequilibrium chemistry. Here we present the 0.2-0.8 $\mu$m transmission spectrum of the Teq = 2000 K Jupiter KELT-7b, acquired with HST WFC3/UVIS G280 as part of the HUSTLE Treasury program. We combined this new spectrum with the previously published HST WFC3/IR G141 (1.1-1.7 $\mu$m) spectrum and Spitzer photometric points at 3.6$\mu$m and 4.5$\mu$m, to reveal a generally featureless transmission spectrum between 0.2 and 1.7 $\mu$m, with a slight downward slope towards bluer wavelengths, and a asymmetric water feature in the 1.1-1.7 $\mu$m band. Retrieval models conclude that the 0.2 - 1.7$\mu$m spectrum is primarily explained by a high H- abundance ($\sim 10^{-5}$), significantly above the equilibrium chemistry prediction ($\sim 10^{-12}$), suggesting disequilibrium in KELT-7b's upper atmosphere. Our retrievals also suggest the presence of bright inhomogeneities in the stellar surface, and tentative evidence of CO2 at the Spitzer wavelengths. We demonstrate that with the UV-optical coverage provided by WFC3 UVIS/G280, we are able to confirm the presence and constrain the abundance of H-, and obtain evidence for bright stellar inhomogeneities that would have been overlooked using infrared data alone. Observations redward of 1$\mu$m with JWST should be able to further constrain the abundance of H-, as well as confirm the presence of CO2 inferred by the two Spitzer datapoints.

astro-ph.EP↗

arXiv2024

JWST-TST DREAMS: A Precise Water Abundance for Hot Jupiter WASP-17b from the NIRISS SOSS Transmission Spectrum

Water has proven to be ubiquitously detected in near-infrared (NIR) transmission spectroscopy observations of hot Jupiter atmospheres, including WASP-17b. However, previous analyses of WASP-17b's atmosphere based upon Hubble Space Telescope (HST) and Spitzer data could not constrain the water abundance, finding that sub-solar, super-solar and bimodal posterior distributions were all statistically valid. In this work, we observe one transit of the hot Jupiter WASP-17b using JWST's Near Infrared Imager and Slitless Spectrograph Single Object Slitless Spectroscopy (NIRISS SOSS) mode. We analyze our data using three independent data analysis pipelines, finding excellent agreement between results. Our transmission spectrum shows multiple H$_2$O absorption features and a flatter slope towards the optical than seen in previous HST observations. We analyze our spectrum using both PICASO+Virga forward models and free retrievals. POSEIDON retrievals provide a well-constrained super-solar $\log$(H$_2$O) abundance (-2.96$^{+0.31}_{-0.24}$), breaking the degeneracy from the previous HST/Spitzer analysis. We verify our POSEIDON results with petitRADTRANS retrievals. Additionally, we constrain the abundance of $\log$(H$^-$), -10.19$^{+0.30}_{-0.23}$, finding that our model including H$^-$ is preferred over our model without H$^-$ to 5.1 $\sigma$. Furthermore, we constrain the $\log$(K) abundance (-8.07$^{+0.58}_{-0.52}$) in WASP-17b's atmosphere for the first time using space-based observations. Our abundance constraints demonstrate the power of NIRISS SOSS's increased resolution, precision, and wavelength range to improve upon previous NIR space-based results. This work is part of a series of studies by our JWST Telescope Scientist Team (JWST-TST), in which we use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

astro-ph.EP↗

arXiv2024

JWST-TST DREAMS: A Super-Solar Metallicity in WASP-17 b Dayside Atmosphere from NIRISS SOSS Eclipse Spectroscopy

We present the first emission spectrum of the hot Jupiter WASP-17 b using one eclipse observation from the JWST Near Infrared Imager and Slitless Spectrograph (NIRISS) Single Object Slitless Spectroscopy (SOSS) mode. Covering a wavelength range of 0.6 to 2.8 microns, our retrieval analysis reveals a strong detection of H2O in WASP-17b dayside atmosphere (6.4sigma). Our retrievals consistently favor a super-solar dayside H2O abundance and a non-inverted temperature-pressure profile over a large pressure range. Additionally, our examination of the brightness temperature reveals excess emission below 1 microns, suggesting the possibility of a high internal temperature (600 to 700 K) and/or contributions from reflected light. We highlight that JWST emission spectroscopy retrieval results can be sensitive to whether negative eclipse depths are allowed at optical wavelengths during light curve fitting. Our findings deepen our understanding of WASP-17b atmospheric composition while also highlighting the sensitivity of our results to pressure-temperature profile parameterizations. This work is part of a series of studies by our JWST Telescope Scientist Team (JWST-TST), in which we will use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

astro-ph.EP↗

arXiv2024

JWST-TST DREAMS: Non-Uniform Dayside Emission for WASP-17b from MIRI/LRS

We present the first spectroscopic characterisation of the dayside atmosphere of WASP-17b in the mid-infrared using a single JWST MIRI/LRS eclipse observation. From forward-model fits to the 5-12 $\mu$m emission spectrum, we tightly constrain the heat redistribution factor of WASP-17b to be 0.92$\pm$0.02 at the pressures probed by this data, indicative of inefficient global heat redistribution. We also marginally detect a supersolar abundance of water, consistent with previous findings for WASP-17b, but note our weak constraints on this parameter. These results reflect the thermodynamically rich but chemically poor information content of MIRI/LRS emission data for high-temperature hot Jupiters. Using the eclipse mapping method, which utilises the signals that the spatial emission profile of an exoplanet imprints on the eclipse light curve during ingress/egress due to its partial occultation by the host star, we also construct the first eclipse map of WASP-17b, allowing us to diagnose its multidimensional atmospheric dynamics for the first time. We find a day-night temperature contrast of order 1000 K at the pressures probed by this data, consistent with our derived heat redistribution factor, along with an eastward longitudinal hotspot offset of $18.7^{+11.1\deg}_{-3.8}$, indicative of the presence of an equatorial jet induced by day-night thermal forcing being the dominant redistributor of heat from the substellar point. These dynamics are consistent with general circulation model predictions for WASP-17b. This work is part of a series of studies by the JWST Telescope Scientist Team (JWST-TST), in which we use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

astro-ph.EP↗

arXiv2024

A Digital Twin Framework for Liquid-cooled Supercomputers as Demonstrated at Exascale

We present ExaDigiT, an open-source framework for developing comprehensive digital twins of liquid-cooled supercomputers. It integrates three main modules: (1) a resource allocator and power simulator, (2) a transient thermo-fluidic cooling model, and (3) an augmented reality model of the supercomputer and central energy plant. The framework enables the study of "what-if" scenarios, system optimizations, and virtual prototyping of future systems. Using Frontier as a case study, we demonstrate the framework's capabilities by replaying six months of system telemetry for systematic verification and validation. Such a comprehensive analysis of a liquid-cooled exascale supercomputer is the first of its kind. ExaDigiT elucidates complex transient cooling system dynamics, runs synthetic or real workloads, and predicts energy losses due to rectification and voltage conversion. Throughout our paper, we present lessons learned to benefit HPC practitioners developing similar digital twins. We envision the digital twin will be a key enabler for sustainable, energy-efficient supercomputing.

cs.DC↗

arXiv2024

Quartz Clouds in the Dayside Atmosphere of the Quintessential Hot Jupiter HD 189733 b

Recent mid-infrared observations with JWST/MIRI have resulted in the first direct detections of absorption features from silicate clouds in the transmission spectra of two transiting exoplanets, WASP-17 b and WASP-107 b. In this paper, we measure the mid-infrared ($5-12$ $\mu$m) dayside emission spectrum of the benchmark hot Jupiter HD 189733 b with MIRI LRS by combining data from two secondary eclipse observations. We confirm the previous detection of H$_2$O absorption at 6.5 $\mu$m from Spitzer/IRS and additionally detect H$_2$S as well as an absorption feature at 8.7 $\mu$m in both secondary eclipse observations. The excess absorption at 8.7 $\mu$m can be explained by the presence of small ($\sim$0.01 $\mu$m) grains of SiO$_2$[s] in the uppermost layers of HD 189733 b's dayside atmosphere. This is the first direct detection of silicate clouds in HD 189733 b's atmosphere, and the first detection of a distinct absorption feature from silicate clouds on the day side of any hot Jupiter. We find that models including SiO$_2$[s] are preferred by $6-7\sigma$ over clear models and those with other potential cloud species. The high altitude location of these silicate particles is best explained by formation in the hottest regions of HD 189733 b's dayside atmosphere near the substellar point. We additionally find that HD 189733 b's emission spectrum longward of 9 $\mu$m displays residual features not well captured by our current atmospheric models. When combined with other JWST observations of HD 189733 b's transmission and emission spectrum at shorter wavelengths, these observations will provide us with the most detailed picture to date of the atmospheric composition and cloud properties of this benchmark hot Jupiter.

astro-ph.EP↗

arXiv2024

ExoTiC-LD: thirty seconds to stellar limb-darkening coefficients

Stellar limb darkening is the observed variation in brightness of a star between its centre and edge (or limb) when viewed in the plane of the sky. Stellar brightness is maximal at the centre and then decreases radially and monotonically towards the limb -- hence the term "limb darkening". This effect is crucial for finding and characterising planets beyond our Solar System, known as exoplanets, as these planets are often studied when crossing in front of their host stars. As such, limb darkening is directly linked to the exoplanet signals. Limb darkening is typically modelled by one of various functional forms, as outlined in Claret (2000) and Sing (2010), and the coefficients of these functions is what ExoTiC-LD is designed to compute. A wide variety of functional forms are supported, including those benchmarked by Espinoza & Jord\'an (2016) as well as reparameterisations suggested by Kipping (2013).

astro-ph.IM↗

arXiv2023

An analytical theory for the resolution attainable using eclipse mapping of exoplanets

We present an analytic theory for the resolution attainable via eclipse mapping of exoplanets, based on the Fourier components of the brightness distribution on the planetary disk. We find that the impact parameter determines which features can and cannot be seen, via the angle of the stellar edge relative to the axis of the orbit during the eclipse. We estimate the signal-to-noise ratio as a function of mapping resolution, and use this to determine the attainable resolution for a given star-planet system. We test this theory against numerical simulations and find good agreement; in particular, our predictions for the resolution as a function of stellar edge angle are accurate to the simulated data to within 10% over a wide range of angles. Our prediction for the number of spatial modes that can be constrained given a light curve error is similarly accurate. Finally, we give a list of exoplanets with the best expected resolution for observations with the NIRISS SOSS, NIRSpec G395H, and MIRI LRS instruments on JWST.

astro-ph.EP↗

arXiv2023

JWST-TST DREAMS: Quartz Clouds in the Atmosphere of WASP-17b

Clouds are prevalent in many of the exoplanet atmospheres that have been observed to date. For transiting exoplanets, we know if clouds are present because they mute spectral features and cause wavelength-dependent scattering. While the exact composition of these clouds is largely unknown, this information is vital to understanding the chemistry and energy budget of planetary atmospheres. In this work, we observe one transit of the hot Jupiter WASP-17b with JWST's MIRI LRS and generate a transmission spectrum from 5-12 $\rm{\mu}$m. These wavelengths allow us to probe absorption due to the vibrational modes of various predicted cloud species. Our transmission spectrum shows additional opacity centered at 8.6 $\rm{\mu}$m, and detailed atmospheric modeling and retrievals identify this feature as SiO$_2$(s) (quartz) clouds. The SiO$_2$(s) clouds model is preferred at 3.5-4.2$\sigma$ versus a cloud-free model and at 2.6$\sigma$ versus a generic aerosol prescription. We find the SiO$_2$(s) clouds are comprised of small ${\sim}0.01$ $\rm{\mu}$m particles, which extend to high altitudes in the atmosphere. The atmosphere also shows a depletion of H$_2$O, a finding consistent with the formation of high-temperature aerosols from oxygen-rich species. This work is part of a series of studies by our JWST Telescope Scientist Team (JWST-TST), in which we will use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

astro-ph.EP↗

arXiv2023

Tracing the colliding winds of $\eta$ Carinae in He I

$\eta$ Carinae is an extremely luminous and energetic colliding-wind binary. The combination of its orbit and orientation, with respect to our line of sight, enables direct investigation of the conditions and geometry of the colliding winds. We analyse optical He I 5876 and 7065 $\unicode{x212B}$ line profiles from the Global Jet Watch observatories covering the last 1.3 orbital periods. The sustained coverage throughout apastron reveals the distinct dynamics of the emitting versus absorbing components: the emission lines follow orbital velocities whilst one of the absorption lines is detected only around apastron ($0.08 < \phi < 0.95$) and exhibits velocities that deviate substantially from the orbital motion. To interpret these deviations, we conjecture that this He I absorption component is formed in the post-shock primary wind, and is only detected when our line of sight intersects with the shock cone formed by the collision of the two winds. We formulate a geometrical model for the colliding winds in terms of a hyperboloid in which the opening angle and location of its apex are parameterised in terms of the ratio of the wind momentum of the primary star to that of companion. We fit this geometrical model to the absorption velocities, finding results that are concordant with the panchromatic observations and simulations of $\eta$ Carinae. The model presented here is an extremely sensitive probe of the exact geometry of the wind momentum balance of binary stars, and can be extended to probe the latitudinal dependence of mass loss.

astro-ph.SR↗

arXiv2023

Detection of carbon monoxide's 4.6 micron fundamental band structure in WASP-39b's atmosphere with JWST NIRSpec G395H

Carbon monoxide (CO) is predicted to be the dominant carbon-bearing molecule in giant planet atmospheres, and, along with water, is important for discerning the oxygen and therefore carbon-to-oxygen ratio of these planets. The fundamental absorption mode of CO has a broad double-branched structure composed of many individual absorption lines from 4.3 to 5.1 $\mathrm{\mu}$m, which can now be spectroscopically measured with JWST. Here we present a technique for detecting the rotational sub-band structure of CO at medium resolution with the NIRSpec G395H instrument. We use a single transit observation of the hot Jupiter WASP-39b from the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) program at the native resolution of the instrument ($R \,{\sim} 2700$) to resolve the CO absorption structure. We robustly detect absorption by CO, with an increase in transit depth of 264 $\pm$ 68 ppm, in agreement with the predicted CO contribution from the best-fit model at low resolution. This detection confirms our theoretical expectations that CO is the dominant carbon-bearing molecule in WASP-39b's atmosphere, and further supports the conclusions of low C/O and super-solar metallicities presented in the JTEC ERS papers for WASP-39b.

astro-ph.EP↗

arXiv2022

Transmission strings: a technique for spatially mapping exoplanet atmospheres around their terminators

Exoplanet transmission spectra, which measure the absorption of light passing through a planet's atmosphere during transit, are most often assessed globally, resulting in a single spectrum per planetary atmosphere. However, the inherent three-dimensional nature of planetary atmospheres, via thermal, chemical, and dynamical processes, can imprint inhomogeneous structure and properties in the observables. In this work, we devise a technique for spatially mapping the atmospheres of exoplanets in transmission. Our approach relaxes the assumption that transit light curves are created from circular stars occulted by circular planets, and instead we allow for flexibility in the planet's sky-projected shape. We define the planet's radius to be a single-valued function of angle around its limb, and we refer to this mathematical object as a transmission string. These transmission strings are parameterised in terms of Fourier series, a choice motivated by these series having adjustable complexity, generating physically practical shapes, while being reducible to the classical circular case. The utility of our technique is primarily intended for high-precision multi-wavelength light curves, from which inferences of transmission spectra can be made as a function of angle around a planet's terminator, enabling analysis of the multidimensional physics at play in exoplanet atmospheres. More generally, the technique can be applied to any transit light curve to derive the shape of the transiting body. The algorithm we develop is available as an open-source package, called harmonica.

astro-ph.EP↗

arXiv2022

Early Release Science of the Exoplanet WASP-39b with JWST NIRSpec G395H

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $\mu$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$\sigma$) and H$_2$O (21.5$\sigma$), and identify SO$_2$ as the source of absorption at 4.1 $\mu$m (4.8$\sigma$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range.

astro-ph.EP↗

arXiv2022

Photochemically-produced SO$_2$ in the atmosphere of WASP-39b

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $\mu$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $\mu$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$\sigma$) and G395H (4.5$\sigma$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.

astro-ph.EP↗