David J. Payne | Searcharxiv

arXiv2025

Aqueous Preparation of CsPbBr3 Perovskite Nanocrystals Under Ambient Conditio

Metal halide perovskites (MHPs) have had a profound impact on numerous emerging optoelectronic technologies, achieving performance metrics that rival or exceed incumbent materials. This impact is underpinned by the exceptional properties of MHPs, including tuneable band gaps, high absorption coefficients, long carrier diffusion lengths and combined with uncomplicated synthesis methods. However, current MHP production relies on the toxic solvents, which pose significant environmental and health risks. Moreover, these methods often require complex multi component solvent systems and thermal processing to achieve the desired material phases, further hindering scalability and sustainability. Overcoming these challenges is critical to the future development of MHP-based technologies. Overcoming these challenges is critical to the future development of MHP-based technologies. Here, we present a novel water-based solvent system and synthetic approach for the preparation of size-controlled CsPbBr3 perovskite nanocrystals in ambient air and at room temperature. The photoluminescence quantum yield (PLQY) of CsPbBr3 erovskite nanocrystals (PNCs) exceeds 60 precent. To demonstrate the light to current conversion ability of our PNCs a series of photoconductors were prepared, with the best performing devices achieving a specific detectivity (D*) of 1.2 x 10^11 Jones. Thus, this green, scalable, and low-cost approach offers a sustainable pathway for precise size and compositional control of MHP nanocrystals, opening new possibilities for environmentally friendly optoelectronic applications.

cond-mat.mtrl-sci↗

arXiv2018

The role of spin-orbit coupling in the electronic structure of IrO$_2$

The delicate interplay of electronic charge, spin, and orbital degrees of freedom is in the heart of many novel phenomena across the transition metal oxide family. Here, by combining high- resolution angle resolved photoemission spectroscopy and first principles calculations (with and without spin-orbit coupling), the electronic structure of the rutile binary iridate, IrO$_2$ is investigated. The detailed study of electronic bands measured on a high-quality single crystalline sample, and use of a wide range of photon energy provide a huge improvement over the previous studies. The excellent agreement between theory and experimental results shows that the single-particle DFT description of IrO$_2$ band structure is adequate, without the need of invoking any treatment of correlation effects. Although many observed features point to a 3D nature of the electronic structure, clear surface effects are revealed. The discussion of the orbital character of the relevant bands crossing the Fermi level sheds light on spin orbit coupling-driven phenomena in this material, unveiling a spin-orbit induced avoided crossing, a property likely to play key role in its large spin Hall effect.

cond-mat.mtrl-sci↗