arXiv subjects

David John

Publications and source records attributed to David John.

4 recordsLinked to original sources

arXiv2026

Ytterbium charge state and stabilization in the Ba(Ca)F$_2$ host by electron paramagnetic resonance and infrared photoluminescence

Lanthanide-doped fluorides are promising materials for advanced photonic and quantum applications due to their wide bandgap, low phonon energy, and chemical stability. In this work, we present a systematic comparative study of ytterbium incorporation at low doping levels (0.05--0.2 mol\%) in BaF$_2$ and CaF$_2$ single crystals, focusing on the interplay between host lattice properties, charge-state stabilization, and defect formation mechanisms. Using a combination of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance (EPR), transmittance, and infrared photoluminescence (IR PL), we explore how host lattice properties affect the stabilization of Yb$^{3+}$ and Yb$^{2+}$ ions. XRD confirmed cubic phase purity and lattice parameter stability in both hosts, while XPS revealed surface chemical composition variations associated with charge-compensating defects and trace impurities. EPR spectra indicated that BaF$_2$ favored perturbed Yb$^{3+}$ environments with increasing dopant levels, while CaF$_2$ maintained predominantly unperturbed sites, suggesting a more favorable ionic match for Yb$^{2+}$. Photothermal deflection spectroscopy (PDS) and IR PL results showed host-specific optical responses, with CaF$_2$ exhibiting crystal-field splitting and broader local field effects. These results reveal a clear decoupling between long-range structural stability and local lattice perturbations, and demonstrate that host cation identity governs the balance between Yb$^{2+}$ and Yb$^{3+}$ stabilization as well as defect-driven optical behavior. This offers valuable insights for optimizing rare-earth-doped fluoride crystals in laser, scintillator, and quantum device applications.

cond-mat.mtrl-sci↗

arXiv2025

First frequency phase transfer from the 3 mm to the 1 mm band on an Earth-sized baseline

Frequency Phase Transfer (FPT) is a technique designed to increase coherence and sensitivity in radio interferometry by making use of the non-dispersive nature of the troposphere to calibrate high-frequency data using solutions derived at a lower frequency. While the Korean VLBI Network has pioneered the use of simultaneous multi-band systems for routine FPT up to an observing frequency of 130 GHz, this technique remains largely untested in the (sub)millimeter regime. A recent effort has been made to outfit dual-band systems at (sub)millimeter observatories participating in the Event Horizon Telescope (EHT) and to test the feasibility and performance of FPT up to the observing frequencies of the EHT. We present the results of simultaneous dual-frequency observations conducted in January 2024 on an Earth-sized baseline between the IRAM 30-m in Spain and the JCMT and SMA in Hawai`i. We performed simultaneous observations at 86 and 215 GHz on the bright sources J0958+6533 and OJ287, with strong detections obtained at both frequencies. We observe a strong correlation between the interferometric phases at the two frequencies, matching the trend expected for atmospheric fluctuations and demonstrating for the first time the viability of FPT for VLBI at a wavelength of $\sim$1 millimeter. We show that the application of FPT systematically increases the 215 GHz coherence on all averaging timescales. In addition, the use of the co-located JCMT and SMA as a single dual-frequency station demonstrates the feasibility of paired-antenna FPT for VLBI for the first time, with implications for future array capabilities (e.g., ALMA sub-arraying and ngVLA calibration strategies).

astro-ph.IM↗

arXiv2024

Upcycling Human Excrement: The Gut Microbiome to Soil Microbiome Axis

Human excrement composting (HEC) is a sustainable strategy for human excrement (HE) management that recycles nutrients and mitigates health risks while reducing reliance on freshwater, fossil fuels, and fertilizers. We present a comprehensive microbial time series analysis of HEC and show that the initial gut-like microbiome of HEC systems transitions to a microbiome similar to soil and traditional compost in fifteen biological replicates tracked weekly for one year.

q-bio.GN↗

arXiv2023

A search for pulsars around Sgr A* in the first Event Horizon Telescope dataset

The Event Horizon Telescope (EHT) observed in 2017 the supermassive black hole at the center of the Milky Way, Sagittarius A* (Sgr A*), at a frequency of 228.1 GHz ($\lambda$=1.3 mm). The fundamental physics tests that even a single pulsar orbiting Sgr A* would enable motivate searching for pulsars in EHT datasets. The high observing frequency means that pulsars - which typically exhibit steep emission spectra - are expected to be very faint. However, it also negates pulse scattering, an effect that could hinder pulsar detections in the Galactic Center. Additionally, magnetars or a secondary inverse Compton emission could be stronger at millimeter wavelengths than at lower frequencies. We present a search for pulsars close to Sgr A* using the data from the three most-sensitive stations in the EHT 2017 campaign: the Atacama Large Millimeter/submillimeter Array, the Large Millimeter Telescope and the IRAM 30 m Telescope. We apply three detection methods based on Fourier-domain analysis, the Fast-Folding-Algorithm and single pulse search targeting both pulsars and burst-like transient emission; using the simultaneity of the observations to confirm potential candidates. No new pulsars or significant bursts were found. Being the first pulsar search ever carried out at such high radio frequencies, we detail our analysis methods and give a detailed estimation of the sensitivity of the search. We conclude that the EHT 2017 observations are only sensitive to a small fraction ($\lesssim$2.2%) of the pulsars that may exist close to Sgr A*, motivating further searches for fainter pulsars in the region.

astro-ph.HE↗