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David K. Sing

Publications and source records attributed to David K. Sing.

At least 19 recordsLinked to original sources
arXiv2026

Evidence for LP 890-9d via Transit Timing Variations

LP 890-9, also known as SPECULOOS-2 and TOI-4306, is a nearby late-M dwarf hosting two confirmed transiting rocky exoplanets. We analyze 20 JWST/NIRSpec PRISM transits of LP 890-9b and LP 890-9c obtained as part of GO program 7073 and detect statistically significant transit timing variations (TTVs), with peak-to-peak amplitudes of ~17 s and ~35 s, respectively. Using analytic linear TTV theory, we find that the known two-planet configuration cannot reproduce the measured TTV amplitudes or super-period, whereas three-planet models provide substantially better fits. The best-fit configuration places the candidate third planet, LP 890-9d, between planets b and c, with an orbital period of ~4.4 days; however, the current data do not uniquely determine its orbital architecture, and periods spanning 4.0-6.9 days remain plausible. TESS is insensitive to transits of LP 890-9d and we find no evidence for the candidate in JWST observations, although the phase coverage (ranging from ~50% to ~80%) depends strongly on the candidate orbital period. Additional high-precision transit observations of LP 890-9b and LP 890-9c are needed to refine their TTV solutions and further constrain the orbital properties of the third planet.

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arXiv2026

A JWST transiting survey of FGK stellar limb darkening: empirical evidence for quadratic laws and atmospheric model comparisons

We present a study of stellar limb-darkening using JWST transit observations of seven exoplanets orbiting FGK host stars, spanning 4200-6800 K. The wide wavelength coverage and high S/N of NIRISS/SOSS and NIRSpec/PRISM enable precise constraints on the wavelength-dependent limb-darkening. Using Bayesian model selection, we find that the quadratic limb-darkening law is statistically preferred over higher-order laws for most FGK stars, recovers consistent intensity profiles for $>$95% of the stellar disk area, and introduces a minimal bias in the derived transit depths of only $\sim$14 ppm (1$\sigma$) for 6/7 targets. This contrasts with previous studies relying on stellar models. We compare the empirically derived quadratic coefficients to predictions from the PHOENIX, MPS-ATLAS, MURaM, and Stagger stellar atmosphere grids. We introduce a quadratic limb-darkening parameterization in terms of limb intensity ($\ell$) and curvature at mid-$\mu$ ($\delta$), finding that empirical FGK limb darkening is generally more linear than models predict ($\delta \lesssim 0.1$). We identify wavelength-independent offsets between data and model quadratic coefficients, minimized by adopting $\mu_{\rm min} = 0.2$ in intensity calculations; we attribute this in part to models overpredicting limb-darkening near the limb where the plane-parallel approximation breaks down. For spherical PHOENIX models, we derive a $\mu$ rescaling method using a $\tau = 1$ photospheric radius. With these corrections, residual offsets are minimized and all stellar models achieve statistically acceptable fits. We provide recommended limb-darkening offset priors for use in JWST transit analyses, enabling more accurate constraints on exoplanet transmission spectra while accounting for residual stellar model uncertainties.

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arXiv2026

A Clearer View of HAT-P-1 b: JWST NIRSpec G395H Reveals Water, Carbon Dioxide, and Possibly Hydrogen Sulfide

As part of JWST's Exoplanet Grand Tour Survey, we use panchromatic transmission spectroscopy to connect HAT-P-1 b's previously studied optical and near-infrared atmosphere to the longer-wavelength molecular bands accessible with JWST. We present JWST NIRSpec G395H transmission spectroscopy of the hot Jupiter HAT-P-1 b over 2.7--5.3~$\mu$m, and combine the new spectrum with archival HST STIS and WFC3 observations for a 0.3--5.3~$\mu$m atmospheric analysis. We independently reduce the JWST data with the Eureka!, FIREFLy, and Tswift pipelines, finding mutually consistent transmission spectra across the G395H bandpass. Atmospheric retrievals yield strong evidence for H$_2$O and CO$_2$ with Bayes factors of $\log_{10}B_{\mathrm{H_2O}}=8.9$ and $\log_{10}B_{\mathrm{CO_2}}=52.3$, while providing tentative evidence for H$_2$S ($\log_{10}B_{\mathrm{H_2S}}=1.4$). The joint H$_2$O and CO$_2$ constraints favor an atmosphere near chemical equilibrium, with $\log_{10} \text{M/H}=0.99^{+0.19}_{-0.14}$, corresponding to $\sim10\times$ Solar or $\sim9\times$ relative to the near-solar metallicity host star, and a 3$\sigma$ upper limit of C/O $<0.52$. Because H$_2$O and CO$_2$ provide a metallicity comparatively insensitive to vertical mixing in this temperature regime, their combined detection suggests the composition is dominated by bulk enrichment rather than strong disequilibrium transport. We find no significant evidence for clouds; instead, the persistence of molecular structure across the spectrum argues against strong cloud muting. The tentative H$_2$S signal, if confirmed, would further suggest limited photochemical processing at the pressures probed. Together, the molecular inventory, enriched metallicity, and low C/O ratio point to an oxygen-rich atmosphere and establish HAT-P-1 b as a benchmark for comparative studies of hot-Jupiter atmospheric composition.

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arXiv2026

JWST color sequence of transiting exoplanets and directly imaged substellar objects

Color-magnitude diagrams (CMDs) have been foundational across astrophysics, from galaxies and stars to brown dwarfs, and JWST now extends them to transiting exoplanets and self-luminous substellar objects at overlapping temperatures. We compile JWST dayside emission spectra for 13 transiting giant planets, 57 self-luminous objects, and the irradiated brown dwarf ZTF J0038+2030 B, spanning ~350-2600 K and log g = 2.5-5.5, plus ~2150 SPHEREx ultracool dwarfs, converted to synthetic photometry in 2MASS J/Ks and five NIRCam medium bands isolating H2O, CH4, CO2, and CO. Low gravity and inflated radii make transiting planets resemble young substellar objects, with shallower features and redder colors from high-altitude clouds that raise the photosphere. Transiting planets follow the L-dwarf sequence on the J versus J-K CMD, with WASP-80 b (T_eq~800 K) showing no T-dwarf-like blueward turn, suggesting a delayed or suppressed L/T transition in irradiated, low-gravity atmospheres. Methane onset is delayed from substellar to transiting-planet atmospheres, and cloudy radiative-convective models indicate that lower gravity and cloud back-warming shift atmospheres toward CO-dominated chemistry, suppressing photospheric CH4. The irradiated but old, high-gravity brown dwarf ZTF J0038+2030 B (T_day = 1049 K, log g = 5.4) shows a deep, field-T-dwarf-like dayside methane band, implicating gravity rather than irradiation as the dominant control. CO2-to-CO diagnostics place transiting and directly imaged planetary-mass companions at stronger relative CO2 absorption than field brown dwarfs, consistent with metallicity enhancement from planetesimal accretion. These CMD sequences provide a unified, model-testable map for self-luminous and irradiated atmospheres.

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arXiv2026

Asymmetric Aerosol Distribution on the Terminators of the Warm Saturn WASP-69 b Revealed by JWST NIRISS/SOSS

How aerosols form, are transported, and cycle between condensation and evaporation across exoplanet temperature regimes remains poorly understood. Recent models and observations suggest that warm giant planets near $800$--$1000$ K may span a transition between homogeneous and longitudinally heterogeneous aerosol distributions. We present a robust detection of aerosol asymmetry in a giant planet with $T_{\rm eq}\lesssim1000$ K, using the $0.86$--$2.82~\mu$m JWST NIRISS/SOSS transmission spectrum of WASP-69 b. The evening limb shows prominent 1.4 $\mu$m H$_2$O absorption ($\Delta\mathrm{BIC}_{\rm H_2O}=+22.7$), whereas H$_2$O is not detected on the morning limb ($\Delta\mathrm{BIC}_{\rm H_2O}=-8.7$). Atmospheric retrievals reveal significant aerosol opacity on both limbs, with high-altitude, optically thick clouds muting molecular features on the morning limb and lower cloud opacity allowing H$_2$O to emerge on the evening limb. The evening terminator is hotter by $304^{+62}_{-91}$ K, consistent with morning-limb condensates partially evaporating during transport toward the evening limb. This mechanism is independently verified with 3D general circulation models. Stellar contamination or aerosols dominated by photochemical haze do not readily explain the asymmetry. From a limb-resolved analysis, we infer a stellar-to-superstellar atmospheric metallicity, with $\rm[M/H]=0.11^{+0.40}_{-0.46}$ from the equilibrium retrieval and [O/H]$=1.38^{+0.44}_{-0.79}$ from the free retrieval. We also detect an escaping metastable-helium tail extending to $3.08^{+0.50}_{-0.45}\,R_p$. WASP-69 b anchors the cooler edge of the emerging population of planets with asymmetric aerosol distributions and suggests that substantial aerosol opacity may persist on both limbs across this transition.

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arXiv2026

No Helium Detected in LHS 1140 b from Four JWST NIRISS/SOSS Transits

In the effort to determine which low-mass exoplanets have atmospheres, LHS 1140 b remains one of the most favorable targets. Its large size (5.6 $\rm M_{\oplus}$ and 1.7 $\rm R_{\oplus}$) and relatively long orbital period (24.7 days) imply an atmosphere may be likely, and notably, recent interior models favor either a hydrogen-dominated "mini-Neptune" or a "water world" over a true terrestrial planet. Another possibility is that it has a helium-rich atmosphere. This hypothesis is supported by recent ground-based observations that detected the metastable helium triplet during transit. These observations indicated there may be current helium escape from the planet's upper atmosphere, yet the signal was not detected during a subsequent observation, suggesting time-variable escape. Here we present four observations of LHS 1140 b with JWST NIRISS/SOSS, which covers the metastable helium triplet, obtained between 2023 and 2026. These observations span the epoch of the ground-based measurements, and although none were contemporaneous with the ground-based transits, all four are sensitive to helium absorption at the previously reported level. However, we detect no helium absorption in any visit. We reject the best-fit ground-based model at $>3\sigma$ in each visit, and find no clear trend in mass-loss with time. Our results suggest the reported ground-based detection may be spurious, although variability cannot be excluded if detectable helium absorption occurs in $\lesssim50\%$ of transits. The nature of LHS 1140 b thus remains a mystery until future transmission and emission analyses are complete.

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arXiv2026

Exploration of Exoplanet Atmospheres with the James Webb Space Telescope

The James Webb Space Telescope (JWST) is providing transformative characterization capabilities for the study of both transiting and directly imaged extrasolar planets. Observations deep into the infrared in the form of both spectroscopy and coronagraphic imaging means that JWST is uniquely sensitive to most of the physical processes that dictate the properties of exoplanetary atmospheres. The observatory's thermal and pointing stability directly translates into the extreme photometric precision needed for exquisite transiting exoplanet photometry, as well as highly sensitive coronagraphic observations. Over the mission's 20-25 year lifetime, roughly 10$^4$ hours will be dedicated to observations of exoplanet atmospheres, providing a legacy data archive that will allow population-level characterization of exoplanet atmospheres spanning terrestrial planets, sub-Neptunes and gas giants. This effort will also assess the prevalence of atmospheres of rocky planets and thus the degree to which such planets may have conditions conducive to habitability.

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arXiv2026

Flow-Driven Limb-Asymmetry of Haze Distribution Part I: An Analytical Framework for Predicting the Size Distribution of Photochemical Hazes Across the Two Limbs of hot-Jupiters

Photochemical haze, a common aerosol type expected to form in the atmospheres of hot-Jupiters, can become concentrated to different extents between the morning and evening limbs depending on the balance between advection, gravitational settling, and radiation pressure. We present a analytical framework incorporating the effect of gravity, planetary radius, and stellar flux, alongside the particle size of the haze on its resulting relative distribution between the two limbs. Using this framework and further comparing with 3D climate simulations, our framework provides a reasonable first-order estimate of the maximum radius of haze particles which would reach the morning limb and subsequently be trapped by the nightside gyres, resulting in a higher or comparable concentration of haze over the morning limb compared to the evening limb for a given hot-Jupiter atmosphere. We find that the framework performs best for higher-gravity planets, where the transport of haze particles is more strongly controlled by gravitational settling and therefore less sensitive to the approximations made in describing the atmospheric circulation. We further show that for low-gravity hot-Jupiters, even large haze particles can be readily transported to the morning limb before being removed by gravitational settling, whereas for high-gravity hot-Jupiters only small particles can survive transport to the morning limb. Our novel framework provides a rapid way to understand the transport of haze and plan limb asymmetry observations with JWST, constraining the parameter space exploration for full-scale computationally expensive 3D simulations.

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arXiv2026

Mitigating Charge Migration in JWST NIRISS Reveals That KELT-7 b is a Metal-enriched Ultra-hot Jupiter Orbiting a Young Metal-rich Star

We present the first panchromatic JWST transmission spectrum of an ultra-hot Jupiter, combining NIRISS and NIRSpec observations to constrain KELT-7\,b's atmospheric properties. We show evidence for charge migration in our NIRISS SOSS observation between 1--1.5~$\mu$m, a wavelength range crucial to test for enhanced H$^-$ previously inferred from HST WFC3/IR G141 observations. We mitigate charge migration by fitting the ramp after extracting 1D stellar spectra at the group level. This ``late-ramp-fit'' method accurately calculates KELT-7\,b's transmission spectrum between 1--1.5~$\mu$m at higher signal-to-noise. Using the transit-derived stellar mean density during stellar property inference reveals that KELT-7 is a $640\pm100$ Myr-old, $[\text{Fe}/\text{H}]=0.46\pm0.02$ star. Combined with NIRSpec and re-reduced WFC3/UVIS G280 data, our free retrieval analysis shows strong evidence for H$_2$O, CO$_2$, and TiO among high-temperature species, but not H$^-$ or clouds. Unaccounted-for systematics may therefore bias longer-wavelength WFC3/IR G141 transit depths shallower. Our free retrieval, two equilibrium retrievals, and self-consistent grid fit all prefer a high metallicity but find discrepant C/O ratios. Agglomerated together, we constrain a super-stellar $\text{M/H}=92^{+24}_{-23}\times$~Solar and C/O~$\leq0.9$, suggesting enhanced metal accretion in the later stages of KELT-7\,b's formation. Our GCMs explain the observed lack of limb asymmetry with superrotating jet-driven efficient horizontal mixing. The stark contrast between our panchromatic analysis and prior analyses on subsets of these data demonstrates the value of broad wavelength coverage for the comprehensive study of exoplanet atmospheres.

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arXiv2026

Aerosols and hydrocarbons in the atmosphere of a white dwarf planet

Most stars, including our Sun, will one day evolve into red giants and, subsequently, white dwarfs. Several planet candidates have recently been identified orbiting white dwarfs, demonstrating that planets can survive the stellar post-main-sequence stage intact. Little is known about the atmospheric composition of post-main-sequence planets, with the most evolved transiting planets with atmospheric detections to date orbiting subgiants. Here we report an atmospheric detection for the white dwarf planet WD 1856 b, achieved through transmission spectroscopy with the JWST NIRSpec PRISM. Our 0.5-5.0 $\mu$m spectrum reveals the presence of hydrocarbons (odds ratio of $167:1$ to $5377:1$, with $\mathrm{CH}_4$ preferred at $17:1$ to $30:1$), aerosols ($2 \times 10^5:1$ to $2 \times 10^6:1$), and thermal emission from the planetary nightside ($2 \times 10^{63}:1$ to $2 \times 10^{73}:1$). Our spectral analysis constrains WD 1856 b's mass to $4.3$ to $10.9 \mathrm{M}_J$, finds a carbon-enriched atmosphere (with a $\mathrm{CH}_4$ abundance of $\approx 7\%$), and an effective temperature exceeding the expected planetary equilibrium temperature ($390$ to $412 \, \mathrm{K}$ vs. $160 \, \mathrm{K}$). Based on cooling models, these results suggest that WD 1856 b underwent a migration-related reheating event $3.0$ to $5.5 \, \mathrm{Gyr}$ into the white dwarf phase, consistent with post-main-sequence tidal evolution to the present-day $0.02 \, \mathrm{au}$ circular orbit. Our results provide a window into the ultimate fate of giant planets orbiting stars with masses similar to our Sun.

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arXiv2026

Atmospheric asymmetries in WASP-121 b revealed by rotational transits detected with JWST

Close-in exoplanets are tidally locked to their host star and thus exhibit extreme atmospheric temperature gradients. It has been theorized that the fraction of star light absorbed by such planets during transit changes as a function of orbital phase as progressively hotter or colder atmospheric gas rotates into view, but this effect has not been observed so far. Here, we show that two transits of the ultra-hot Jupiter WASP-121 b, acquired with JWST/NIRSpec and NIRISS, exhibit asymmetric transit light curves caused by the planet's rotation during transit. We observe increasing CO absorption and slightly decreasing H$_2$O absorption in the transmission spectrum, as the planet rotates. These results are indicative of a stronger longitudinal temperature gradient across the evening than across the morning terminator, consistent with higher temperatures in the eastern half than in the western half of the dayside. The observed changes of the transmission spectrum with orbital phase are in line with the temperature increase causing thermal dissociation of H$_2$O, while CO remains abundant. The observation of longitudinal gradients of atmospheric temperature and chemistry from the planet's rotational transit provides a new probe for constraining atmospheric heterogeneity using JWST beyond differences between morning and evening terminators from limb asymmetries.

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arXiv2026

Characterizing Transiting Exoplanet Atmospheres in the 2030s with the Hubble Space Telescope

The Hubble Space Telescope inaugurated the era of exoplanet atmospheric characterization. While the James Webb Space Telescope has largely taken up the mantle of infrared atmospheric characterization, Hubble's unique short-wavelength capabilities remain unmatched. Recent theoretical advances in exoplanet atmospheric science combined with new observing strategies, like those offered by WFC3-UVIS/G280, have opened science cases that only Hubble can address for the foreseeable future. In this white paper, we discuss these new windows into the atmospheres of other worlds, focusing on characterization of their hydrostatic lower atmosphere, and identify the critical capabilities necessary for future observations. We highlight three overall science cases that will depend on the continued short-wavelength capabilities of Hubble: measuring aerosol scattering slopes, characterizing metal absorption in ultra-hot Jupiters, and understanding stellar activity with Transit Light Source effect decontamination and flare monitoring. Throughout, we highlight useful synergies between HST and JWST. This article is a response to the call for white papers by the Space Telescope Science Institute on "Building a Roadmap for Hubble science into the 2030s."

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arXiv2026

Magnesium Silicate Clouds in the Atmosphere of HD 209458b from a Rule-Based Tree-Structured Data Reduction

HD 209458b is the canonical hot Jupiter: the first to have its atmosphere measured and the first to hint at the role of aerosols in exoplanet atmospheres through the muting of Na absorption signatures in the optical. Here we present JWST MIRI/LRS transmission observations of HD 209458b from 5-12 microns, directly measuring the absorption signatures of its clouds for the first time. The observations indicate the presence of magnesium silicates, most likely Mg2SiO4 or a mixture of Mg2SiO4 and MgSiO3. We also present a new methodology to reduce observational data, whereby the analysis is formulated as a rule-based model with a tree structure, enabling key decisions to be identified and uncertain decisions to be incorporated into subsequent modeling. With this data reduction, and using a combination of ARCiS free retrievals and PICASO+Virga self consistent forward models, we are able to show that amorphous Mg2SiO4 clouds explain the LRS data to high significance over either a clear (Delta ln(Z)=16.63) or gray cloud atmosphere (Delta ln(Z)=22.26). By combining the LRS dataset with archival JWST NIRCam and HST optical and near-infrared observations, we are able to more robustly constrain the properties of the magnesium silicate condensates, finding particle sizes of approximately 0.1 microns and atmospheric pressures of the clouds of roughly 1-10 millibar. Our results add to the growing detections of silicate clouds as a dominant atmospheric component of hot Jupiters, with the exact silicate species contextualizing the atmospheric chemistry and potentially formation conditions of these planets.

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arXiv2026

Cloudy mornings and clear evenings on a gas giant exoplanet

The spectra of exoplanet atmospheres are affected by aerosols (clouds and hazes) of uncertain origin. Proposed aerosol formation mechanisms include gas condensation or photochemical reactions. We measure the transmission spectrum of the tidally locked gas giant exoplanet WASP-94A b and identify asymmetry in its atmosphere. The morning limb is cooler and cloudy, while the evening limb is hotter and exhibits gaseous H$_2$O absorption features. We interpret this difference as due to the formation of cloud droplets near the morning limb, which evaporate during circulation to the evening limb. The dominant aerosols are clouds cycling between the day and night sides of the atmosphere, not photochemical hazes. The resulting asymmetry can severely bias chemical abundance measurements, unless limb-resolved spectroscopy is available.

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arXiv2026

High Tide or Riptide on the Cosmic Shoreline? A Water-Rich Atmosphere or Stellar Contamination for the Warm Super-Earth GJ~486b from JWST Observations

Planets orbiting M-dwarf stars are prime targets in the search for rocky exoplanet atmospheres. The small size of M dwarfs renders their planets exceptional targets for transmission spectroscopy, facilitating atmospheric characterization. However, it remains unknown whether their host stars' highly variable extreme-UV radiation environments allow atmospheres to persist. With JWST, we have begun to determine whether or not the most favorable rocky worlds orbiting M dwarfs have detectable atmospheres. Here, we present a 2.8-5.2 micron JWST NIRSpec/G395H transmission spectrum of the warm (700 K, 40.3x Earth's insolation) super-Earth GJ 486b (1.3 R$_{\oplus}$ and 3.0 M$_{\oplus}$). The measured spectrum from our two transits of GJ 486b deviates from a flat line at 2.2 - 3.3 $σ$, based on three independent reductions. Through a combination of forward and retrieval models, we determine that GJ 486b either has a water-rich atmosphere (with the most stringent constraint on the retrieved water abundance of H2O > 10% to 2$σ$) or the transmission spectrum is contaminated by water present in cool unocculted starspots. We also find that the measured stellar spectrum is best fit by a stellar model with cool starspots and hot faculae. While both retrieval scenarios provide equal quality fits ($χ^2_ν$ = 1.0) to our NIRSpec/G395H observations, shorter wavelength observations can break this degeneracy and reveal if GJ 486b sustains a water-rich atmosphere.

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arXiv2025

A High-Resolution NUV Transmission Spectrum of KELT-9b: Mg II and Fe II Escaping from the Hottest Known Giant Planet

We present high-resolution NUV observations from Hubble Space Telescope's (HST) Space Telescope Imaging Spectrograph (STIS) data for the hottest known gas planet, KELT-9b. Observations were collected with STIS/E230M (2300-3000 $Å$, R$\sim$ 30,000) and we de-correlate systematic effects from the telescope using jitter detrending. We show the clear presence of the Mg II doublet at 2800 $Å$ and Fe II at 2600 $Å$ in KELT-9b. The Mg II is measured above the planet's Roche transit radius, indicating it is escaping. We fit 1D NLTE atmospheric escape models to these features, demonstrating a significant loss of mass in KELT-9b's atmosphere ($\dot{M} \approx 10^{12} $ g/s); we also find a remarkably high line-broadening corresponding to a velocity of about $50-75$ km/s, and a net blueshift of the Mg II doublet greater than 30 km/s. Future 3D MHD modeling of the spectrum and gas kinematics is likely needed to explain these observations. We interpret these results in the context of the Mg II ``Cosmic Shoreline" and show that the detection of escaping Mg II in KELT-9b and the non-detection in WASP-178b are consistent with the hypothesis that stars hotter than $T_{\mathrm{eff}} \sim$ 8250~K have relatively low levels of XUV radiation due to the lack of a chromosphere. Therefore planets around such early-type stars experience a different degree of atmospheric escape. This result highlights the importance of XUV irradiation in driving atmospheric escape inside and outside the Solar System.

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arXiv2025

A Comprehensive Analysis of the Panchromatic Transmission Spectrum of the Hot-Saturn WASP-96 b: Nondetection of Haze, Possible Sodium Limb Asymmetry, Stellar Characterization, and Formation History

We conduct a reanalysis of the JWST NIRISS/SOSS observation of the hot-Saturn WASP-96 b. Initial analysis of this data revealed an enhanced Rayleigh scattering slope at the blue end of the transmission spectrum, suggesting the presence of hazes at high altitudes. In this work, we report non-detection of this slope, confirming an atmosphere clear of high-altitude aerosols consistent with the pre-JWST results. Also contrary to the initial result, our results indicate the presence of gray cloud deck, although at relatively low altitudes/high pressures. We further combined the NIRISS/SOSS spectrum with VLT, HST, and Spitzer to produce a transmission spectrum from 0.35 $\mu$m to 5 $\mu$m. We constrain the mass fraction of multiple chemical species, including: H$_2$O$=-2.62^{+0.43}_{-0.42}$, K$=-5.76^{+1.05}_{-1.13}$, and Na$=-3.40^{+0.90}_{-0.92}$. C/O ratio and metallicity are tentatively constrained at substellar values (C/O$_{planet}=0.57^{+0.07}_{-0.12}$ and [Fe/H]$_{planet}=0.01^{+0.46}_{-0.52}$ compared to C/O$_{star}=0.92\pm0.25$ and [Fe/H]$_{star}=0.24\pm0.05$). Inputing these composition constraints to interior models, we constrain a core mass of $43^{+8}_{-15}$ M$_\oplus$. This, in addition to our inferred super-stellar refractory-to-oxygen ratio ($\Delta\log_{10}(R/O)=1.48^{+0.57}_{-0.62}$) and substellar C/O ratio, suggests that the core of WASP-96 b likely formed outside of water iceline, underwent disk-driven migration, and accreted its atmosphere inside the carbon soot line. We find evidence of atmospheric leading-trailing terminator asymmetries in the broadened sodium absorption feature with a transit time offset of 50 seconds, while the water features appear symmetric. CH$_4$, CO, and CO$_2$ remain unconstrained due to spectral coverage limits. Upcoming JWST NIRSpec/G395H observations (ID 4082, PI: M. Radica) will be crucial for constraining these carbon-bearing species.

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arXiv2025

Methane on the temperate exo-Saturn TOI-199b

Temperate ($T_{\rm eq}<400$ K) gas giants represent an unexplored frontier in exoplanet atmospheric spectroscopy. Orbiting a G-type star every $\sim100$ days, the Saturn-mass exoplanet TOI-199 b ($T_{\rm eq}=350$ K) is one of the most favorable low-temperature gas giants for atmospheric study. Here, we present its transmission spectrum from a single transit observed with JWST's NIRSpec G395M mode. Despite lower-than-nominal precision due to a pointing misalignment, the spectrum reveals the presence of CH$_4$ (Bayes factor of $\sim$700 in a cloudy atmosphere), corresponding to a metallicity of $\rm{C/H}=13^{+78}_{-12}\times$ solar, although the absence of detectable CO and CO$_2$ at the current precision disfavors metallicities $\gtrsim50\times$ solar. We also tested several haze prescriptions (Titan-like tholin, soot, and water-rich tholin), but the preference for these models is weak (Bayes factors of $\sim 2$ relative to the clear case). The spectrum also shows an increase in transit depth near 3 $\mu$m, which our self-consistent models attribute to either NH$_3$ or, less likely, HCN. Follow-up observations could distinguish between these species, helping determine the planet's vertical mixing regime. The TOI-199 system exhibits strong transit timing variations (TTVs) due to an outer non-transiting giant planet. For planet c, our TTV analysis reduces its mass uncertainty by 50% and prefers a slightly longer orbital period (but still within the conservative habitable zone) and higher eccentricity relative to previous studies. TOI-199 b serves as the first data point for studying clouds and hazes in temperate gas giants, with the detection of spectral features in its transmission spectrum indicating that temperate gas giants are promising targets for detailed atmospheric characterization.

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