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David K. Sing

Publications and source records attributed to David K. Sing.

At least 91 records · Page 5Linked to original sources

Strong H$_2$O and CO emission features in the spectrum of KELT-20b driven by stellar UV irradiation

Know thy star, know thy planetary atmosphere. Every exoplanet with atmospheric measurements orbits around a star, and the stellar environment directly affects the planetary atmosphere. Here we present the emission spectrum of ultra-hot Jupiter KELT-20b which provides an observational link between host star properties and planet atmospheric thermal structure. It is currently the only planet with thermal emission measurements in the $T_{eq}\sim$2200K range that orbits around an early A-type star. By comparing it with other similar ultra-hot Jupiters around FGK stars, we can better understand how different host star types influence planetary atmospheres. The emission spectrum covers 0.6 to 4.5 $μm$ with data from TESS, HST WFC3/G141, and Spitzer 4.5 $μm$ channel. KELT-20b has a 1.4 $μm$ water feature strength metric of S$_{H_2O}$ = -0.097$\pm$0.02 and a blackbody brightness temperature difference of 528K between WFC3/G141 (T$_b$=2402$\pm$14K) and Spitzer 4.5 $μm$ channel (T$_b$=2930$\pm59$K). These very large H$_2$O and CO emission features combined with the A-type host star make KELT-20b a unique planet among other similar hot Jupiters. The abundant FUV, NUV, and optical radiation from its host star (T$_{eff}=8720\pm250$K) is expected to be the key that drives its strong thermal inversion and prominent emission features based on previous PHOENIX models calculations.

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The Emission Spectrum of the Hot Jupiter WASP-79b from HST/WFC3

Here we present a thermal emission spectrum of WASP-79b, obtained via Hubble Space Telescope Wide Field Camera 3 G141 observations as part of the PanCET program. As we did not observe the ingress or egress of WASP-79b's secondary eclipse, we consider two scenarios: a fixed mid-eclipse time based on the expected occurrence time, and a mid-eclipse time as a free parameter. In both scenarios, we can measure thermal emission from WASP-79b from 1.1 to 1.7 $μ$m at 2.4$σ$ confidence consistent with a 1900 K brightness temperature for the planet. We combine our observations with Spitzer dayside photometry (3.6 and 4.5 $μ$m) and compare these observations to a grid of atmospheric forward models that span a range of metallicities, carbon-to-oxygen ratios, and recirculation factors. Given the strength of the planetary emission and the precision of our measurements, we found a wide range of forward models to be consistent with our data. The best-match equilibrium model suggests that WASP-79b's dayside has a solar metallicity and carbon-to-oxygen ratio, alongside a recirculation factor of 0.75. Models including significant H- opacity provide the best match to WASP-79b's emission spectrum near 1.58 $μ$m. However, models featuring high-temperature cloud species-formed via vigorous vertical mixing and low sedimentation efficiencies-with little day-to-night energy transport also match WASP-79b's emission spectrum. Given the broad range of equilibrium chemistry, disequilibrium chemistry, and cloudy atmospheric models consistent with our observations of WASP-79b's dayside emission, further observations will be necessary to constrain WASP-79b's dayside atmospheric properties.

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A unique hot Jupiter spectral sequence with evidence for compositional diversity

The emergent spectra of close-in, giant exoplanets ("hot Jupiters") are expected to be distinct from those of self-luminous objects with similar effective temperatures because hot Jupiters are primarily heated from above by their host stars rather than internally from the release of energy from their formation. Theoretical models predict a continuum of dayside spectra for hot Jupiters as a function of irradiation level, with the coolest planets having absorption features in their spectra, intermediate-temperature planets having emission features due to thermal inversions, and the hottest planets having blackbody-like spectra due to molecular dissociation and continuum opacity from the H- ion. Absorption and emission features have been detected in the spectra of a number of individual hot Jupiters, and population-level trends have been observed in photometric measurements. However, there has been no unified, population-level study of the thermal emission spectra of hot Jupiters such as has been done for cooler brown dwarfs and transmission spectra of hot Jupiters. Here we show that hot Jupiter secondary eclipse spectra centered around a water absorption band at 1.4 microns follow a common trend in water feature strength with temperature. The observed trend is broadly consistent with model predictions for how the thermal structures of solar-composition planets vary with irradiation level. Nevertheless, the ensemble of planets exhibits some degree of scatter around the mean trend for solar composition planets. The spread can be accounted for if the planets have modest variations in metallicity and/or elemental abundance ratios, which is expected from planet formation models. (abridged abstract)

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Detection of Ionized Calcium in the Atmosphere of the Ultra-Hot Jupiter WASP-76b

Recent observations of the ultra-hot Jupiter WASP-76b have revealed a diversity of atmospheric species. Here we present new high-resolution transit spectroscopy of WASP-76b with GRACES at the Gemini North Observatory, serving as a baseline for the Large and Long Program "Exploring the Diversity of Exoplanet Atmospheres at High Spectral Resolution" (Exoplanets with Gemini Spectroscopy, or ExoGemS for short). With a broad spectral range of $400 - 1050$ nm, these observations allow us to search for a suite of atomic species. We recover absorption features due to neutral sodium (Na I), and report a new detection of the ionized calcium (Ca II) triplet at ~ $850$ nm in the atmosphere of WASP-76b, complementing a previous detection of the Ca II H & K lines. The triplet has line depths of $0.295 \pm 0.034$% at ~ $849.2$ nm, $0.574 \pm 0.041$% at ~ $854.2$ nm, and $0.454 \pm 0.024$% at ~ $866.2$ nm, corresponding to effective radii close to (but within) the planet's Roche radius. These measured line depths are significantly larger than those predicted by model LTE and NLTE spectra obtained on the basis of a pressure-temperature profile computed assuming radiative equilibrium. The discrepancy suggests that the layers probed by our observations are either significantly hotter than predicted by radiative equilibrium and/or in a hydrodynamic state. Our results shed light on the exotic atmosphere of this ultra-hot world, and will inform future analyses from the ExoGemS survey.

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The Hubble PanCET program: Transit and Eclipse Spectroscopy of the Strongly Irradiated Giant Exoplanet WASP-76b

Ultra-hot Jupiters with equilibrium temperature greater than 2000K are uniquely interesting targets as they provide us crucial insights into how atmospheres behave under extreme conditions. This class of giant planets receives intense radiation from their host star and usually has strongly irradiated and highly inflated atmospheres. At such high temperature, cloud formation is expected to be suppressed and thermal dissociation of water vapor could occur. We observed the ultra-hot Jupiter WASP-76b with 7 transits and 5 eclipses using the Hubble Space Telescope (HST) and $Spitzer$ for a comprehensive study of its atmospheric chemical and physical processes. We detect TiO and H$_2$O absorption in the optical and near-infrared transit spectrum. Additional absorption by a number of neutral and ionized heavy metals like Fe, Ni, Ti, and SiO help explain the short wavelength transit spectrum. The secondary eclipse spectrum shows muted water feature but a strong CO emission feature in Spitzer's 4.5 $μ$m band indicating an inverted temperature pressure profile. We analyzed both the transit and emission spectrum with a combination of self-consistent PHOENIX models and retrieval models (ATMO $\&$ PLATON). Both spectra are well fitted by the self-consistent PHOENIX forward atmosphere model in chemical and radiative equilibrium at solar metallicity, adding to the growing evidence that both TiO/VO and NUV heavy metals opacity are prominent NUV-optical opacity sources in the stratospheres of ultra-hot Jupiters.

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An inventory of atomic species in the atmosphere of WASP-121b using UVES high-resolution spectroscopy

Ultra-hot Jupiters (UHJs) present excellent targets for atmospheric characterisation. Their hot dayside temperatures (T $\gtrsim$ 2200 K) strongly suppress the formation of condensates, leading to clear and highly-inflated atmospheres extremely conducive to transmission spectroscopy. Recent studies using optical high-resolution spectra have discovered a plethora of neutral and ionised atomic species in UHJs, placing constraints on their atmospheric structure and composition. Our recent work has presented a search for molecular features and detection of Fe I in the UHJ WASP-121b using VLT/UVES transmission spectroscopy. Here, we present a systematic search for atomic species in its atmosphere using cross-correlation methods. In a single transit, we uncover potential signals of 17 atomic species which we investigate further, categorising 5 as strong detections, 3 as tentative detections, and 9 as weak signals worthy of further exploration. We confirm previous detections of Cr I, V I, Ca I, K I and exospheric H I and Ca II made with HARPS and ESPRESSO, and independently re-recover our previous detection of Fe I at 8.8 $σ$ using both the blue and red arms of the UVES data. We also add a novel detection of Sc II at 4.2 $σ$. Our results further demonstrate the richness of UHJs for optical high-resolution spectroscopy.

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Ground-Based Transmission Spectroscopy with VLT FORS2: Evidence for faculae and clouds in the optical spectrum of the warm Saturn WASP-110b

We present a ground-based optical transmission spectrum for the warm Saturn-mass exoplanet WASP-110b from two transit observations made with the FOcal Reducer and Spectrograph (FORS2) on the Very Large Telescope (VLT). The spectrum covers the wavelength range from 4000 to 8333Å, which is binned in 46 transit depths measured to an averaged precision of 220 parts per million (ppm) over an averaged 80Å~bin for a Vmag=12.8 star. The measured transit depths are unaffected by a dilution from a close A-type field dwarf, which was fully resolved. The overall main characteristic of the transmission spectrum is an increasing radius with wavelength and a lack of the theoretically predicted pressure-broadened sodium and potassium absorption features for a cloud-free atmosphere. We analyze archival high-resolution optical spectroscopy and find evidence for low to moderate activity of the host star, which we take into account in the atmospheric retrieval analysis. Using the AURA retrieval code, we find that the observed transmission spectrum can be best explained by a combination of unocculted stellar faculae and a cloud deck. Transmission spectra of cloud-free and hazy atmospheres are rejected at a high confidence. With a possible cloud deck at its terminator, WASP-110b joins the increasing population of irradiated hot-Jupiter exoplanets with cloudy atmospheres observed in transmission.

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HST PanCET Program: A Complete Near-UV to Infrared Transmission Spectrum for the Hot Jupiter WASP-79b

We present a new optical transmission spectrum of the hot Jupiter WASP-79b. We observed three transits with the STIS instrument mounted on HST, spanning 0.3 - 1.0 um. Combining these transits with previous observations, we construct a complete 0.3 - 5.0 um transmission spectrum of WASP-79b. Both HST and ground-based observations show decreasing transit depths towards blue wavelengths, contrary to expectations from Rayleigh scattering or hazes. We infer atmospheric and stellar properties from the full near-UV to infrared transmission spectrum of WASP-79b using three independent retrieval codes, all of which yield consistent results. Our retrievals confirm previous detections of H$_{2}$O (at 4.0$σ$ confidence), while providing moderate evidence of H$^{-}$ bound-free opacity (3.3$σ$) and strong evidence of stellar contamination from unocculted faculae (4.7$σ$). The retrieved H$_{2}$O abundance ($\sim$ 1$\%$) suggests a super-stellar atmospheric metallicity, though stellar or sub-stellar abundances remain consistent with present observations (O/H = 0.3 - 34$\times$ stellar). All three retrieval codes obtain a precise H$^{-}$ abundance constraint: log(X$_{\rm{H^{-}}}$) $\approx$ -8.0 $\pm$ 0.7. The potential presence of H$^{-}$ suggests that JWST observations may be sensitive to ionic chemistry in the atmosphere of WASP-79b. The inferred faculae are $\sim$ 500 K hotter than the stellar photosphere, covering $\sim$ 15$\%$ of the stellar surface. Our analysis underscores the importance of observing UV - optical transmission spectra in order to disentangle the influence of unocculted stellar heterogeneities from planetary transmission spectra.

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A New Window into Planet Formation and Migration: Refractory-to-Volatile Elemental Ratios in Ultra-hot Jupiters

A primary goal of exoplanet characterization is to use a planet's current composition to understand how that planet formed. For example, the C/O ratio has long been recognized as carrying important information on the chemistry of volatile species. Refractory elements, like Fe, Mg, and Si, are usually not considered in this conversation because they condense into solids like Fe(s) or MgSiO$_3$ and would be removed from the observable, gaseous atmosphere in exoplanets cooler than about 2000~K. However, planets hotter than about 2000~K, called ultra-hot Jupiters (UHJs), are warm enough to largely avoid the condensation of refractory species. In this paper, we explore the insight that the measurement of refractory abundances can provide into a planet's origins. Through refractory-to-volatile elemental abundance ratios, we can estimate a planet's atmospheric rock-to-ice fraction and constrain planet formation and migration scenarios. We first relate a planet's present-day refractory-to-volatile ratio to its rock-to-ice ratio from formation using various compositional models for the rocky and icy components of the protoplanetary disk. We discuss potential confounding factors like the sequestration of heavy metals in the core and condensation. We then show such a measurement using atmospheric retrievals of the low-resolution UV-IR transmission spectrum of WASP-121b with PETRA, from which we estimate a refractory-to-volatile ratio of 5.0$^{+6.0}_{-2.7}\times$ solar and a rock-to-ice ratio greater than 2/3. This result is consistent with significant atmospheric enrichment by rocky planetismals. Lastly, we discuss the rich future potential for measuring refractory-to-volatile ratios in ultra-hot Jupiters with the arrival of JWST and by combining observations at low- and high-resolution.

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Gemini/GMOS Optical Transmission Spectroscopy of WASP-121b: signs of variability in an ultra-hot Jupiter?

We present ground-based, spectroscopic observations of two transits of the ultra-hot Jupiter WASP-121b covering the wavelength range $\approx$500 - 950 nm using Gemini/GMOS. We use a Gaussian process framework to model instrumental systematics in the light curves, and also demonstrate the use of the more generalised Student's-T process to verify our results. We find that our measured transmission spectrum, whilst showing overall agreement, is slightly discrepant with results obtained using HST/STIS, particularly for wavelengths shortward of $\approx$650 nm. In contrast to the STIS results, we find evidence for an increasing blueward slope and little evidence for absorption from either TiO or VO in our retrieval, in agreement with a number of recent studies performed at high-resolution. We suggest that this might point to some other absorbers, particularly some combination of recently detected atomic metals, in addition to scattering by hazes, being responsible for the excess optical absorption and observed vertical thermal inversion. Our results are also broadly consistent with previous ground-based photometry and 3D GCM predictions, however, these assumed different chemistry to our retrievals. In addition, we show that the GMOS observations are repeatable over short periods (days), similarly to the HST/STIS observations. Their difference over longer periods (months) could well be the result of temporal variability in the atmospheric properties (i.e. weather) as predicted by theoretical models of ultra-hot Jupiters; however, more mundane explanations such as instrumental systematics and stellar activity cannot be fully ruled out, and we encourage future observations to explore this possibility.

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TESS observations of the WASP-121 b phase curve

We study the red-optical photometry of the ultra-hot Jupiter WASP-121 b as observed by the Transiting Exoplanet Survey Satellite (TESS) and model its atmosphere through a radiative transfer simulation. Given its short orbital period of $\sim1.275$ days, inflated state and bright host star, WASP-121 b is exceptionally favorable for detailed atmospheric characterization. Towards this purpose, we use \texttt{allesfitter} to characterize its full red-optical phase curve, including the planetary phase modulation and the secondary eclipse. We measure the day and nightside brightness temperatures in the TESS passband as $3012\substack{+40 \\ -42}$ K and $2022\substack{+254 \\ -602}$ K, respectively, and do not find a statistically significant phase shift between the brightest and substellar points. This is consistent with an inefficient heat recirculation on the planet. We then perform an atmospheric retrieval analysis to infer the dayside atmospheric properties of WASP-121 b such as its bulk composition, albedo and heat recirculation. We confirm the temperature inversion in the atmosphere and suggest H$^-$, TiO and VO as potential causes of the inversion, absorbing heat at optical wavelengths at low pressures. Future HST and JWST observations of WASP-121 b will benefit from its first full phase curve measured by TESS.

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Evidence of a Clear Atmosphere for WASP-62b: the Only Known Transiting Gas Giant in the JWST Continuous Viewing Zone

Exoplanets with cloud-free, haze-free atmospheres at the pressures probed by transmission spectroscopy represent a valuable opportunity for detailed atmospheric characterization and precise chemical abundance constraints. We present the first optical to infrared (0.3-5 microns) transmission spectrum of the hot Jupiter WASP-62b, measured with Hubble/STIS and Spitzer/IRAC. The spectrum is characterized by a 5.1-sigma detection of Na I absorption at 0.59 microns, in which the pressure-broadened wings of the Na D-lines are observed from space for the first time. A spectral feature at 0.4 microns is tentatively attributed to SiH at 2.1-sigma confidence. Our retrieval analyses are consistent with a cloud-free atmosphere without significant contamination from stellar heterogeneities. We simulate James Webb Space Telescope (JWST) observations, for a combination of instrument modes, to assess the atmospheric characterization potential of WASP-62b. We demonstrate that JWST can conclusively detect Na, H2O, FeH, and SiH within the scope of its Early Release Science (ERS) program. As the only transiting giant planet currently known in the JWST Continuous Viewing Zone, WASP-62b could prove a benchmark giant exoplanet for detailed atmospheric characterization in the James Webb era.

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The Hubble PanCET Program: A Metal-rich Atmosphere for the Inflated Hot Jupiter HAT-P-41b

We present a comprehensive analysis of the 0.3--5\,$μ$m transit spectrum for the inflated hot Jupiter HAT-P-41b. The planet was observed in transit with Hubble STIS and WFC3 as part of the Hubble Panchromatic Comparative Exoplanet Treasury (PanCET) program, and we combine those data with warm \textit{Spitzer} transit observations. We extract transit depths from each of the data sets, presenting the STIS transit spectrum (0.29--0.93\,$μ$m) for the first time. We retrieve the transit spectrum both with a free-chemistry retrieval suite (AURA) and a complementary chemical equilibrium retrieval suite (PLATON) to constrain the atmospheric properties at the day-night terminator. Both methods provide an excellent fit to the observed spectrum. Both AURA and PLATON retrieve a metal-rich atmosphere for almost all model assumptions (most likely O/H ratio of $\log_{10}{Z/Z_{\odot}} = 1.46^{+0.53}_{-0.68}$ and $\log_{10}{Z/Z_{\odot}} = 2.33^{+0.23}_{-0.25}$, respectively); this is driven by a 4.9-$σ$ detection of H$_2$O as well as evidence of gas absorption in the optical ($>$2.7-$σ$ detection) due to Na, AlO and/or VO/TiO, though no individual species is strongly detected. Both retrievals determine the transit spectrum to be consistent with a clear atmosphere, with no evidence of haze or high-altitude clouds. Interior modeling constraints on the maximum atmospheric metallicity ($\log_{10}{Z/Z_{\odot}} < 1.7$) favor the AURA results. The inferred elemental oxygen abundance suggests that HAT-P-41b has one of the most metal-rich atmospheres of any hot Jupiters known to date. Overall, the inferred high metallicity and high inflation make HAT-P-41b an interesting test case for planet formation theories.

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Into the UV: The Atmosphere of the Hot Jupiter HAT-P-41b Revealed

For solar-system objects, ultraviolet spectroscopy has been critical in identifying sources for stratospheric heating and measuring the abundances of a variety of hydrocarbon and sulfur-bearing species, produced via photochemical mechanisms, as well as oxygen and ozone. To date, less than 20 exoplanets have been probed in this critical wavelength range (0.2-0.4 um). Here we use data from Hubble's newly implemented WFC3 UVIS G280 grism to probe the atmosphere of the hot Jupiter HAT-P-41b in the ultraviolet through optical in combination with observations at infrared wavelengths. We analyze and interpret HAT-P-41b's 0.2-5.0 um transmission spectrum using a broad range of methodologies including multiple treatments of data systematics as well as comparisons with atmospheric forward, cloud microphysical, and multiple atmospheric retrieval models. Although some analysis and interpretation methods favor the presence of clouds or potentially a combination of Na, VO, AlO, and CrH to explain the ultraviolet through optical portions of HAT-P-41b's transmission spectrum, we find that the presence of a significant H- opacity provides the most robust explanation. We obtain a constraint for the abundance of H-, log(H-) = -8.65 +/- 0.62 in HAT-P-41b's atmosphere, which is several orders of magnitude larger than predictions from equilibrium chemistry for a 1700 - 1950 K hot Jupiter. We show that a combination of photochemical and collisional processes on hot hydrogen-dominated exoplanets can readily supply the necessary amount of H- and suggest that such processes are at work in HAT-P-41b and many other hot Jupiter atmospheres.

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WASP-127b transmission spectrum]{Abundance measurements of H$_{2}$O and carbon-bearing species in the atmosphere of WASP-127b confirm its super-solar metallicity

The chemical abundances of exoplanet atmospheres may provide valuable information about the bulk compositions, formation pathways, and evolutionary histories of planets. Exoplanets with large, relatively cloud-free atmospheres, and which orbit bright stars provide the best opportunities for accurate abundance measurements. For this reason, we measured the transmission spectrum of the bright (V~10.2), large (1.37 R$_{J}$), sub-Saturn mass (0.19 M$_{J}$) exoplanet WASP-127b across the near-UV to near-infrared wavelength range (0.3 - 5 $μ$m), using the Hubble and Spitzer Space Telescopes. Our results show a feature-rich transmission spectrum, with absorption from Na, H$_{2}$O, and CO$_{2}$, and wavelength-dependent scattering from small-particle condensates. We ran two types of atmospheric retrieval models: one enforcing chemical equilibrium, and the other which fit the abundances freely. Our retrieved abundances at chemical equilibrium for Na, O and C are all super-solar, with abundances relative to solar values of 9$^{+15}_{-6}$, 16$^{+7}_{-5}$, and 26$^{+12}_{-9}$ respectively. Despite giving conflicting C/O ratios, both retrievals gave super-solar CO$_{2}$ volume mixing ratios, which adds to the likelihood that WASP-127b's bulk metallicity is super-solar, since CO$_{2}$ abundance is highly sensitive to atmospheric metallicity. We detect water at a significance of 13.7 $σ$. Our detection of Na is in agreement with previous ground-based detections, though we find a much lower abundance, and we also do not find evidence for Li or K despite increased sensitivity. In the future, spectroscopy with JWST will be able to constrain WASP-127b's C/O ratio, and may reveal the formation history of this metal-enriched, highly observable exoplanet.

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A Library of Self-Consistent Simulated Exoplanet Atmospheres

We present a publicly available library of model atmospheres with radiative-convective equilibrium Pressure-Temperature ($P$-$T$) profiles fully consistent with equilibrium chemical abundances, and the corresponding emission and transmission spectrum with R$\sim$5000 at 0.2 $μ$m decreasing to R$\sim$35 at 30 $μ$m, for 89 hot Jupiter exoplanets, for four re-circulation factors, six metallicities and six C/O ratios. We find the choice of condensation process (local/rainout) alters the $P$-$T$ profile and thereby the spectrum substantially, potentially detectable by JWST. We find H$^-$ opacity can contribute to form a strong temperature inversion in ultra-hot Jupiters for C/O ratios $\geq$ 1 and can make transmission spectra features flat in the optical, alongside altering the entire emission spectra. We highlight how adopting different model choices such as thermal ionisation, opacities, line-wing profiles and the methodology of varying the C/O ratio, effects the $P$-$T$ structure and the spectrum. We show the role of Fe opacity to form primary/secondary inversion in the atmosphere. We use WASP-17b and WASP-121b as test cases to demonstrate the effect of grid parameters across their full range, while highlighting some important findings, concerning the overall atmospheric structure, chemical transition regimes and their observables. Finally, we apply this library to the current transmission and emission spectra observations of WASP-121b, which shows H$_2$O and tentative evidence for VO at the limb, and H$_2$O emission feature indicative of inversion on the dayside, with very low energy redistribution, thereby demonstrating the applicability of library for planning and interpreting observations of transmission and emission spectrum.

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A library of ATMO forward model transmission spectra for hot Jupiter exoplanets

We present a grid of forward model transmission spectra, adopting an isothermal temperature-pressure profile, alongside corresponding equilibrium chemical abundances for 117 observationally significant hot exoplanets (Equilibrium Temperatures of 547-2710 K). This model grid has been developed using a 1D radiative-convective-chemical equilibrium model termed ATMO, with up-to-date high temperature opacities. We present an interpretation of observations of ten exoplanets, including best fit parameters and $χ^{2}$ maps. In agreement with previous works, we find a continuum from clear to hazy/cloudy atmospheres for this sample of hot Jupiters. The data for all the 10 planets are consistent with sub-solar to solar C/O ratio, 0.005 to 10 times solar metallicity and water rather than a methane dominated infrared spectra. We then explore the range of simulated atmospheric spectra for different exoplanets, based on characteristics such as temperature, metallicity, C/O-ratio, haziness and cloudiness. We find a transition value for the metallicity between 10 and 50 times solar, which leads to substantial changes in the transmission spectra. We also find a transition value of C/O ratio, from water to carbon species dominated infrared spectra, as found by previous works, revealing a temperature dependence of this transition point ranging from $\sim$0.56 to $\sim$1-1.3 for equilibrium temperatures from $\sim$900 to $\sim$2600 K. We highlight the potential of the spectral features of HCN and C$_2$H$_2$ to constrain the metallicities and C/O ratios of planets, using JWST observations. Finally, our entire grid ($\sim$460,000 simulations) is publicly available and can be used directly with the JWST simulator PandExo for planning observations.

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The HST PanCET Program: An Optical to Infrared Transmission Spectrum of HAT-P-32Ab

We present a 0.3-5 micron transmission spectrum of the hot Jupiter HAT-P-32Ab observed with the Space Telescope Imaging Spectrograph (STIS) and Wide Field Camera 3 (WFC3) instruments mounted on the Hubble Space Telescope, combined with Spitzer Infrared Array Camera (IRAC) photometry. The spectrum is composed of 51 spectrophotometric bins with widths ranging between 150 and 400 Å, measured to a median precision of 215 ppm. Comparisons of the observed transmission spectrum to a grid of 1D radiative-convective equilibrium models indicate the presence of clouds/hazes, consistent with previous transit observations and secondary eclipse measurements. To provide more robust constraints on the planet's atmospheric properties, we perform the first full optical to infrared retrieval analysis for this planet. The retrieved spectrum is consistent with a limb temperature of 1248$\pm$92 K, a thick cloud deck, enhanced Rayleigh scattering, and $\sim$10x solar H2O abundance. We find log($Z/Z_{\odot}$) = 2.41$_{-0.07}^{+0.06}$, in agreement with the mass-metallicity relation derived for the Solar System.

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