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David Koch

Publications and source records attributed to David Koch.

At least 19 recordsLinked to original sources

Laser Powder Bed Fusion of anisotropic Nd-Fe-B bonded magnets utilizing an in situ mechanical alignment approach

Nd-Fe-B bonded magnets are an important class of permanent magnets, employed in many technological sectors. The Additive Manufacturing (AM) processes enables the fabrication of net-shape bonded magnets with complex geometries, allowing to tailor their magnetic stray field specifically for a given application. A crucial challenge to be addressed concerning AM of bonded magnets is the production of magnetically anisotropic components. The common approaches presented in the literature up to now, required a post-printing procedure or the complex integration of a magnetic field source into the AM process. Here, we present a technique to fabricate anisotropic bonded magnets via Laser Powder Bed Fusion (LPBF) by utilizing the mechanical alignment of anisotropic particles in a single step, without the need for a magnetic field source. Anisotropic bonded magnets were fabricated using a mixture of anisotropic Nd-Fe-B powder (MQA-38-14) and polyamide-12 (PA12). This magnetic powder consists of ellipsoidal particles, where the easy magnetization axis is distributed perpendicular to their longest side, which can be exploited to generate magnetic texture. Depending on the particle size used as feedstock, the degree of alignment ( ) can be tailored to a maximum of = 0.78. The fabricated anisotropic bonded magnets exhibited a maximum remanence of Jr = 377 mT and an energy product of (BH)max = 28.6 kJ/m3, respectively.

physics.app-ph

Reactive single-step hot-pressing and magnetocaloric performance of polycrystalline Fe$_2$Al$_{1.15-x}$B$_2$Ge$_x$Ga$_x$ ($x=0, 0.05$) MAB phases

Reactive single-step hot-pressing at 1473 K and 35 MPa for 4 h produces dense, bulk, near single-phase, low-cost and low-criticality Fe$_2$Al$_{1.15}$B$_2$ and Fe$_2$Al$_{1.1}$B$_2$Ge$_{0.05}$Ga$_{0.05}$ MAB samples, showing a second-order magnetic phase transition with favorable magnetocaloric properties around room temperature. The magnetic as well as magnetocaloric properties can be tailored upon Ge and Ga doping, leading to an increase of Curie temperature $T_C$ and spontaneous magnetization $m_S$. The maximum isothermal entropy change $\Delta s_{T,max}$ of hot-pressed Fe$_2$Al$_{1.15}$B$_2$ in magnetic field changes of 2 and 5 T amounts to 2.5 and 5 J(kgK)$^{-1}$ at 287.5 K and increases by Ge and Ga addition to 3.1 and 6.2 J(kgK)$^{-1}$ at 306.5 K, respectively. The directly measured maximum adiabatic temperature change $\Delta T_{ad,max}$ is improved by the composition modification from 0.9 to 1.1 K in magnetic field changes of 1.93 T. Overall, we demonstrate that hot-pressing provides a much faster, more scalable and processing cost reducing alternative compared to conventional synthesis routes to produce heat exchangers for magnetic cooling devices. Therefore, our criticality assessment shows that hot-pressed Fe-based MAB phases provide a promising compromise of material and processing cost, criticality and magnetocaloric performance, demonstrating the potential for low-cost and low-criticality magnetocaloric applications around room temperature.

cond-mat.mtrl-sci

Additive manufacturing of Ni-Mn-Sn shape memory Heusler alloy -- Microstructure and magnetic properties from powder to printed parts

Ni-Mn-based Heusler alloys like Ni-Mn-Sn show an elastocaloric as well as magnetocaloric effect during the magneto-structural phase transition, making this material interesting for solid-state cooling application. Material processing by additive manufacturing can overcome difficulties related to machinability of the alloys, caused by their intrinsic brittleness. Since the magnetic properties and transition temperature are highly sensitive to the chemical composition, it is essential to understand and monitoring these properties over the entire processing chain. In the present work the microstructural and magnetic properties from gas-atomized powder to post-processed Ni-Mn-Sn alloy are investigated. Direct energy deposition was used for processing, promoting the evolution of a polycrystalline microstructure being characterized by elongated grains along the building direction. A complete and sharp martensitic transformation can be achieved after applying a subsequent heat treatment at 1173 K for 24 h. The Mn-evaporation of 1.3 at. % and the formation of Mn-oxide during DED-processing lead to an increase of the transition temperature of 45 K and a decrease of magnetization, clearly pointing at the necessity of controlling the composition, oxygen partial pressure and magnetic properties over the entire processing chain.

cond-mat.mtrl-sci

Dissipation losses limiting first-order phase transition materials in cryogenic caloric cooling: A case study on all-d-metal Ni(-Co)-Mn-Ti Heusler alloys

Ni-Mn-based Heusler alloys, in particular all-d-metal Ni(-Co)-Mn-Ti, are highly promising materials for energy-efficient solid-state refrigeration as large multicaloric effects can be achieved across their magnetostructural martensitic transformation. However, no comprehensive study on the crucially important transition entropy change $\Delta s_t$ exists so far for Ni(-Co)-Mn-Ti. Here, we present a systematic study analyzing the composition and temperature dependence of $\Delta s_t$. Our results reveal a substantial structural entropy change contribution of approximately 65 J(kgK)$^{-1}$, which is compensated at lower temperatures by an increasingly negative entropy change associated with the magnetic subsystem. This leads to compensation temperatures $T_{comp}$ of 75 K and 300 K in Ni$_{35}$Co$_{15}$Mn$_{50-y}$Ti$_{y}$ and Ni$_{33}$Co$_{17}$Mn$_{50-y}$Ti$_{y}$, respectively, below which the martensitic transformations are arrested. In addition, we simultaneously measured the responses of the magnetic, structural and electronic subsystems to the temperature- and field-induced martensitic transformation near $T_{comp}$, showing an abnormal increase of hysteresis and consequently dissipation energy at cryogenic temperatures. Simultaneous measurements of magnetization and adiabatic temperature change $\Delta T_{ad}$ in pulsed magnetic fields reveal a change in sign of $\Delta T_{ad}$ and a substantial positive and irreversible $\Delta T_{ad}$ up to 15 K at 15 K as a consequence of increased dissipation losses and decreased heat capacity. Most importantly, this phenomenon is universal, it applies to any first-order material with non-negligible hysteresis and any stimulus, effectively limiting the utilization of their caloric effects for gas liquefaction at cryogenic temperatures.

cond-mat.mtrl-sci

Influence of microstructure on the application of Ni-Mn-In Heusler compounds for multicaloric cooling using magnetic field and uniaxial stress

Novel multicaloric cooling utilizing the giant caloric response of Ni-Mn-based metamagnetic shape-memory alloys to different external stimuli such as magnetic field, uniaxial stress and hydrostatic pressure is a promising candidate for energy-efficient and environmentally-friendly refrigeration. However, the role of microstructure when several external fields are applied simultaneously or sequentially has been scarcely discussed in literature. Here, we synthesized ternary Ni-Mn-In alloys by suction casting and arc melting and analyzed the microstructural influence on the response to magnetic fields and uniaxial stress. By combining SEM-EBSD and stress-strain data, a significant effect of texture on the stress-induced martensitic transformation is revealed. It is shown that a <001> texture can strongly reduce the critical transformation stresses. The effect of grain size on the material failure is demonstrated and its influence on the magnetic-field-induced transformation dynamics is investigated. Temperature-stress and temperature-magnetic field phase diagrams are established and single caloric performances are characterized in terms of ${\Delta}{s_T}$ and ${\Delta}{T_{ad}}$. The cyclic ${\Delta}{T_{ad}}$ values are compared to the ones achieved in the multicaloric exploiting-hysteresis cycle. It turns out that a suction-cast microstructure and the combination of both stimuli enables outstanding caloric effects in moderate external fields which can significantly exceed the single caloric performances. In particular for Ni-Mn-In, the maximum cyclic effect in magnetic fields of 1.9 T is increased by more than 200 % to -4.1 K when a moderate sequential stress of 55 MPa is applied. Our results illustrate the crucial role of microstructure for multicaloric cooling using Ni-Mn-based metamagnetic shape-memory alloys.

cond-mat.mtrl-sci

Microstructure engineering of metamagnetic Ni-Mn-based Heusler compounds by Fe-doping: A roadmap towards excellent cyclic stability combined with large elastocaloric and magnetocaloric effects

Ni-Mn-based metamagnetic shape-memory alloys exhibit a giant thermal response to magnetic fields and uniaxial stress which can be utilized in single caloric or multicaloric cooling concepts for energy-efficient and sustainable refrigeration. However, during cyclic operation these alloys suffer from structural and functional fatigue as a result of their high intrinsic brittleness. Here, we present based on Fe-doping of Ni-Mn-In a microstructure design strategy which simultaneously improves cyclic stability and maintains the excellent magnetocaloric and elastocaloric properties. Our results reveal that precipitation of a strongly Fe-enriched and In-depleted coherent secondary gamma-phase at grain boundaries can ensure excellent mechanical stability by hindering intergranular fracture during cyclic loading. In this way, a large elastocaloric effect of -4.5 K was achieved for more than 16000 cycles without structural or functional degradation, which corresponds to an increase of the cyclic stability by more than three orders of magnitude as compared to single-phase Ni-Mn-In-(Fe). In addition, we demonstrate that the large magnetocaloric effect of single-phase Ni-Mn-In-(Fe) can be preserved in the dual-phase material when the secondary gamma-phase is exclusively formed at grain boundaries as the martensitic transformation within the Heusler matrix is barely affected. This way, an adiabatic temperature change of -3 K and an isothermal entropy change of 15 $Jkg^{-1}K^{-1}$ was obtained in 2 T for dual-phase Ni-Mn-In-Fe. We expect that this concept can be applied to other single caloric and mutlicaloric materials, therewith paving the way for solid-state caloric cooling applications.

cond-mat.mtrl-sci

Controlling the oxidation of magnetic and electrically conductive solid-solution iron-rhodium nanoparticles synthesized by Laser Ablation in Liquids

This study focuses on the synthesis of FeRh nanoparticles via pulsed laser ablation in liquid and on controlling the oxidation of the synthesized nanoparticles. Formation of monomodal {\gamma}-FeRh nanoparticles was confirmed by transmission electron microscopy (TEM) and their composition confirmed by atom probe tomography (APT). On these particles, three major contributors to oxidation were analysed: 1) dissolved oxygen in the organic solvents, 2) the bound oxygen in the solvent and 3) oxygen in the atmosphere above the solvent. The decrease of oxidation for optimized ablation conditions was confirmed through energy-dispersive X-ray (EDX) and M\"ossbauer spectroscopy. Furthermore, the time dependence of oxidation was monitored for dried FeRh nanoparticles powders using ferromagnetic resonance spectroscopy (FMR). By magnetophoretic separation, B2-FeRh nanoparticles could be extracted from the solution and characteristic differences of nanostrand formation between {\gamma}-FeRh and B2-FeRh nanoparticles were observed.

cond-mat.mtrl-sci

The Occurrence of Rocky Habitable Zone Planets Around Solar-Like Stars from Kepler Data

We present occurrence rates for rocky planets in the habitable zones (HZ) of main-sequence dwarf stars based on the Kepler DR25 planet candidate catalog and Gaia-based stellar properties. We provide the first analysis in terms of star-dependent instellation flux, which allows us to track HZ planets. We define $\eta_\oplus$ as the HZ occurrence of planets with radius between 0.5 and 1.5 $R_\oplus$ orbiting stars with effective temperatures between 4800 K and 6300 K. We find that $\eta_\oplus$ for the conservative HZ is between $0.37^{+0.48}_{-0.21}$ (errors reflect 68\% credible intervals) and $0.60^{+0.90}_{-0.36}$ planets per star, while the optimistic HZ occurrence is between $0.58^{+0.73}_{-0.33}$ and $0.88^{+1.28}_{-0.51}$ planets per star. These bounds reflect two extreme assumptions about the extrapolation of completeness beyond orbital periods where DR25 completeness data are available. The large uncertainties are due to the small number of detected small HZ planets. We find similar occurrence rates using both a Poisson likelihood Bayesian analysis and Approximate Bayesian Computation. Our results are corrected for catalog completeness and reliability. Both completeness and the planet occurrence rate are dependent on stellar effective temperature. We also present occurrence rates for various stellar populations and planet size ranges. We estimate with $95\%$ confidence that, on average, the nearest HZ planet around G and K dwarfs is about 6 pc away, and there are about 4 HZ rocky planets around G and K dwarfs within 10 pc of the Sun.

astro-ph.EP

Visual Estimation of Building Condition with Patch-level ConvNets

The condition of a building is an important factor for real estate valuation. Currently, the estimation of condition is determined by real estate appraisers which makes it subjective to a certain degree. We propose a novel vision-based approach for the assessment of the building condition from exterior views of the building. To this end, we develop a multi-scale patch-based pattern extraction approach and combine it with convolutional neural networks to estimate building condition from visual clues. Our evaluation shows that visually estimated building condition can serve as a proxy for condition estimates by appraisers.

cs.CV

Automatic Prediction of Building Age from Photographs

We present a first method for the automated age estimation of buildings from unconstrained photographs. To this end, we propose a two-stage approach that firstly learns characteristic visual patterns for different building epochs at patch-level and then globally aggregates patch-level age estimates over the building. We compile evaluation datasets from different sources and perform an detailed evaluation of our approach, its sensitivity to parameters, and the capabilities of the employed deep networks to learn characteristic visual age-related patterns. Results show that our approach is able to estimate building age at a surprisingly high level that even outperforms human evaluators and thereby sets a new performance baseline. This work represents a first step towards the automated assessment of building parameters for automated price prediction.

cs.CV

Kepler-16: A Transiting Circumbinary Planet

We report the detection of a planet whose orbit surrounds a pair of low-mass stars. Data from the Kepler spacecraft reveal transits of the planet across both stars, in addition to the mutual eclipses of the stars, giving precise constraints on the absolute dimensions of all three bodies. The planet is comparable to Saturn in mass and size, and is on a nearly circular 229-day orbit around its two parent stars. The eclipsing stars are 20% and 69% as massive as the sun, and have an eccentric 41-day orbit. The motions of all three bodies are confined to within 0.5 degree of a single plane, suggesting that the planet formed within a circumbinary disk.

astro-ph.EP

Spin-Orbit Alignment for the Circumbinary Planet Host Kepler-16A

Kepler-16 is an eccentric low-mass eclipsing binary with a circumbinary transiting planet. Here we investigate the angular momentum of the primary star, based on Kepler photometry and Keck spectroscopy. The primary star's rotation period is 35.1 +/- 1.0 days, and its projected obliquity with respect to the stellar binary orbit is 1.6 +/- 2.4 degrees. Therefore the three largest sources of angular momentum---the stellar orbit, the planetary orbit, and the primary's rotation---are all closely aligned. This finding supports a formation scenario involving accretion from a single disk. Alternatively, tides may have realigned the stars despite their relatively wide separation (0.2 AU), a hypothesis that is supported by the agreement between the measured rotation period and the "pseudosynchronous" period of tidal evolution theory. The rotation period, chromospheric activity level, and fractional light variations suggest a main-sequence age of 2-4 Gyr. Evolutionary models of low-mass stars can match the observed masses and radii of the primary and secondary stars to within about 3%.

astro-ph.EP

Discovery and Atmospheric Characterization of Giant Planet Kepler-12b: An Inflated Radius Outlier

We report the discovery of planet Kepler-12b (KOI-20), which at 1.695\pm0.030 RJ is among the handful of planets with super-inflated radii above 1.65 RJ. Orbiting its slightly evolved G0 host with a 4.438-day period, this 0.431\pm0.041 MJ planet is the least-irradiated within this largest-planet-radius group, which has important implications for planetary physics. The planet's inflated radius and low mass lead to a very low density of 0.111\pm0.010 g cm-3. We detect the occultation of the planet at a significance of 3.7{\sigma} in the Kepler bandpass. This yields a geometric albedo of 0.14\pm0.04; the planetary flux is due to a combination of scattered light and emitted thermal flux. We use multiple observations with Warm Spitzer to detect the occultation at 7{\sigma} and 4{\sigma} in the 3.6 and 4.5 {\mu}m bandpasses, respectively. The occultation photometry timing is consistent with a circular orbit, at e < 0.01 (1{\sigma}), and e < 0.09 (3{\sigma}). The occultation detections across the three bands favor an atmospheric model with no dayside temperature inversion. The Kepler occultation detection provides significant leverage, but conclusions regarding temperature structure are preliminary, given our ignorance of opacity sources at optical wavelengths in hot Jupiter atmospheres. If Kepler-12b and HD 209458b, which intercept similar incident stellar fluxes, have the same heavy element masses, the interior energy source needed to explain the large radius of Kepler-12b is three times larger than that of HD 209458b. This may suggest that more than one radius-inflation mechanism is at work for Kepler-12b, or that it is less heavy-element rich than other transiting planets.

astro-ph.EP

The hot-Jupiter Kepler-17b: discovery, obliquity from stroboscopic starspots, and atmospheric characterization

This paper reports the discovery and characterization of the transiting hot giant exoplanet Kepler-17b. The planet has an orbital period of 1.486 days, and radial velocity measurements from the Hobby-Eberly Telescope (HET) show a Doppler signal of 420+/-15 m.s-1. From a transit-based estimate of the host star's mean density, combined with an estimate of the stellar effective temperature T_eff=5630+/-100 K from high-resolution spectra, we infer a stellar host mass of 1.061+/-0.067 M_sun and a stellar radius of 1.019+/-0.033 R_jup. We estimate the planet mass and radius to be Mp=2.450+/-0.114 M_jup and Rp=1.312+/-0.018 R_jup and a planet density near 1.35 g.cm-3. The host star is active, with dark spots that are frequently occulted by the planet. The continuous monitoring of the star reveals a stellar rotation period of 11.89 days, 8 times the the planet's orbital period; this period ratio produces stroboscopic effects on the occulted starspots. The temporal pattern of these spot-crossing events shows that the planet's orbit is prograde and the star's obliquity is smaller than 15 deg. We detected planetary occultations of Kepler-17b with both the Kepler and Spitzer Space Telescopes. We use these observations to constrain the eccentricity, e, and find that it is consistent with a circular orbit (e<0.0011). The brightness temperatures of the planet the infrared bandpasses are T_3.6um=1880+/-100 K and T4.5um=1770+/-150 K. We measure the optical geometric albedo A_g in the Kepler bandpass and find A_g = 0.10+/-0.02. The observations are best described by atmospheric models for which most of the incident energy is re-radiated away from the day side.

astro-ph.EP

Kepler Eclipsing Binary Stars. II. 2165 Eclipsing Binaries in the Second Data Release

The Kepler Mission provides nearly continuous monitoring of ~156 000 objects with unprecedented photometric precision. Coincident with the first data release, we presented a catalog of 1879 eclipsing binary systems identified within the 115 square degree Kepler FOV. Here, we provide an updated catalog augmented with the second Kepler data release which increases the baseline nearly 4-fold to 125 days. 386 new systems have been added, ephemerides and principle parameters have been recomputed. We have removed 42 previously cataloged systems that are now clearly recognized as short-period pulsating variables and another 58 blended systems where we have determined that the Kepler target object is not itself the eclipsing binary. A number of interesting objects are identified. We present several exemplary cases: 4 EBs that exhibit extra (tertiary) eclipse events; and 8 systems that show clear eclipse timing variations indicative of the presence of additional bodies bound in the system. We have updated the period and galactic latitude distribution diagrams. With these changes, the total number of identified eclipsing binary systems in the Kepler field-of-view has increased to 2165, 1.4% of the Kepler target stars.

astro-ph.SR

Five Kepler target stars that show multiple transiting exoplanet candidates

We present and discuss five candidate exoplanetary systems identified with the Kepler spacecraft. These five systems show transits from multiple exoplanet candidates. Should these objects prove to be planetary in nature, then these five systems open new opportunities for the field of exoplanets and provide new insights into the formation and dynamical evolution of planetary systems. We discuss the methods used to identify multiple transiting objects from the Kepler photometry as well as the false-positive rejection methods that have been applied to these data. One system shows transits from three distinct objects while the remaining four systems show transits from two objects. Three systems have planet candidates that are near mean motion commensurabilities---two near 2:1 and one just outside 5:2. We discuss the implications that multitransiting systems have on the distribution of orbital inclinations in planetary systems, and hence their dynamical histories; as well as their likely masses and chemical compositions. A Monte Carlo study indicates that, with additional data, most of these systems should exhibit detectable transit timing variations (TTV) due to gravitational interactions---though none are apparent in these data. We also discuss new challenges that arise in TTV analyses due to the presence of more than two planets in a system.

astro-ph.EP

Photometric Variability in Kepler Target Stars. II. An Overview of Amplitude, Periodicity, and Rotation in First Quarter Data

We provide an overview of stellar variability in the first quarter of data from the Kepler mission. The intent of this paper is to examine the entire sample of over 150,000 target stars for periodic behavior in their lightcurves, and relate this to stellar characteristics. These data constitute an unprecedented study of stellar variability given its great precision and complete time coverage (with a half hour cadence). Because the full Kepler pipeline is not currently suitable for a study of stellar variability of this sort, we describe our procedures for treating the "raw" pipeline data. About half of the total sample exhibits convincing periodic variability up to two weeks, with amplitudes ranging from differential intensity changes less than 10^{-4} up to more than 10 percent. K and M dwarfs have a greater fraction of period behavior than G dwarfs. The giants in the sample have distinctive quasi-periodic behavior, but are not periodic in the way we define it. Not all periodicities are due to rotation, and the most significant period is not necessarily the rotation period. We discuss properties of the lightcurves, and in particular look at a sample of very clearly periodic G dwarfs. It is clear that a large number of them do vary because of rotation and starspots, but it will take further analysis to fully exploit this.

astro-ph.SR

White-light flares on cool stars in the Kepler Quarter 1 Data

We present the results of a search for white light flares on the ~23,000 cool dwarfs in the Kepler Quarter 1 long cadence data. We have identified 373 flaring stars, some of which flare multiple times during the observation period. We calculate relative flare energies, flare rates and durations, and compare these with the quiescent photometric variability of our sample. We find that M dwarfs tend to flare more frequently but for shorter durations than K dwarfs, and that they emit more energy relative to their quiescent luminosity in a given flare than K dwarfs. Stars that are more photometrically variable in quiescence tend to emit relatively more energy during flares, but variability is only weakly correlated with flare frequency. We estimate distances for our sample of flare stars and find that the flaring fraction agrees well with other observations of flare statistics for stars within 300 pc above the Galactic Plane. These observations provide a more rounded view of stellar flares by sampling stars that have not been pre-selected by their activity, and are informative for understanding the influence of these flares on planetary habitability.

astro-ph.SR