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David W. Tam

Publications and source records attributed to David W. Tam.

At least 19 recordsLinked to original sources

Quasi-one-dimensional spin excitations in the iron pnictide NaFe$_{0.53}$Cu$_{0.47}$As

Spectroscopic measurements in model one-dimensional (1D) correlated systems offer insights for understanding their two-dimensional counterparts, which include the cuprate and iron pnictide/chalcogenide superconductors. A major challenge is the identification of such correlated systems with dominantly 1D physics. In this work, inelastic neutron scattering measurements on NaFe$_{0.53}$Cu$_{0.47}$As single crystal directly reveal quasi-1D spin excitations, resulting from atomic order that lead to magnetic Fe and nonmagnetic Cu chains. The dominant exchange interaction is antiferromagnetic along the chain ($SJ_{\rm \parallel}\approx90.1(3)$~meV), whereas the inter-chain couplings are much weaker ($SJ_{\rm \perp}\approx-2.4(1)$~meV and $SJ_{\rm c}\approx0.15(5)$~meV). The quasi-1D spin excitations in NaFe$_{0.53}$Cu$_{0.47}$As stem from both the Néel and stripe vectors, with Néel excitations sensitive to Fe impurities on the Cu site. The spin excitations in quasi-1D NaFe$_{0.53}$Cu$_{0.47}$As and quasi-2D FeSe exhibit a striking resemblance, suggesting a common origin for their coexistent stripe and Néel excitations. Our findings demonstrate magnetic dilution in NaFeAs leads to dimension reduction of its magnetic degree of freedom, presenting a strategy for discovering low-dimensional quantum materials.

cond-mat.str-el

Anomalous Electrical Transport in the Kagome Magnet YbFe$_6$Ge$_6$

Two-dimensional (2D) kagome metals offer a unique platform for exploring electron correlation phenomena derived from quantum many-body effects. Here, we report a combined study of electrical magnetotransport and neutron scattering on YbFe$_6$Ge$_6$, where the Fe moments in the 2D kagome layers exhibit an $A$-type collinear antiferromagnetic order below $T_{\rm{N}} \approx 500$ K. Interactions between the Fe ions in the layers and the localized Yb magnetic ions in between reorient the $c$-axis aligned Fe moments to the kagome plane below $T_{\rm{SR}} \approx 63$ K. Our magnetotransport measurements show an intriguing anomalous Hall effect (AHE) that emerges in the spin-reorientated collinear state, accompanied by the closing of the spin anisotropy gap as revealed from inelastic neutron scattering. The gapless spin excitations and the Yb-Fe interaction are able to support a dynamic scalar spin chirality, which explains the observed AHE. Therefore, our study demonstrates spin fluctuations may provide an additional scattering channel for the conduction electrons and give rise to AHE even in a collinear antiferromagnet.

cond-mat.str-el

Characterization of Nuclear and Magnetic Structures of Wolframite-Type MgReO4 and ZnReO4

We utilized high-pressure methods to synthesize the oxides AReO$4$ (A=Zn, Mg) and characterized their crystal structures as monoclinic wolframite-type. By combining muon spin spectroscopy ($μ^+$SR) with DFT calculations for muon stopping sites, we identify two possible magnetic spin structures for both compounds: $Γ_3$ with the propagation vector $\mathbf{k} = (0,1/2,0)$ and $Γ_4$ with $\mathbf{k} = (0,0,0)$. In both cases, the magnetic moments are canted from the principal axes within the $ac$-plane. The ordered moment of the proposed structures is $\mathbf{0.29(5)~μ\mathrm{B}}$ for $Γ_3$ and $\mathbf{0.25(8)~μ_\mathrm{B}}$ for $Γ_4$. The low moment is consistent with the absence of a magnetic contribution to the neutron powder diffraction (NPD) spectra. Bond valence sum (BVS) analysis supports the oxidation state of Re being Re$^{6+}$ in the compounds, and we suggest that a combination of $t_\mathrm{2g}$ orbital splitting due to spin-orbit coupling (SOC) and $d$-$p$ orbital hybridization is responsible for the strongly suppressed ordered magnetic moment.

cond-mat.mtrl-sci

Spin-charge-lattice coupling across the charge density wave transition in a Kagome lattice antiferromagnet

Understanding spin and lattice excitations in a metallic magnetic ordered system form the basis to unveil the magnetic and lattice exchange couplings and their interactions with itinerant electrons. Kagome lattice antiferromagnet FeGe is interesting because it displays rare charge density wave (CDW) deep inside the antiferromagnetic ordered phase that interacts with the magnetic order. We use neutron scattering to study the evolution of spin and lattice excitations across the CDW transition $T_{\rm CDW}$ in FeGe. While spin excitations below $\sim$100 meV can be well described by spin waves of a spin-1 Heisenberg Hamiltonian, spin excitations at higher energies are centered around the Brillouin zone boundary and extend up to $\sim180$ meV consistent with quasiparticle excitations across spin-polarized electron-hole Fermi surfaces. Furthermore, $c$-axis spin wave dispersion and Fe-Ge optical phonon modes show a clear hardening below $T_{\rm CDW}$ due to spin-charge-lattice coupling but with no evidence for a phonon Kohn anomaly. By comparing our experimental results with density functional theory calculations in absolute units, we conclude that FeGe is a Hund's metal in the intermediate correlated regime where magnetism has contributions from both itinerant and localized electrons arising from spin polarized electronic bands near the Fermi level.

cond-mat.str-el

Emergent photons and fractionalized excitations in a quantum spin liquid

A quantum spin liquid (QSL) arises from a highly entangled superposition of many degenerate classical ground states in a frustrated magnet, and is characterized by emergent gauge fields and deconfined fractionalized excitations (spinons). Because such a novel phase of matter is relevant to high-transition-temperature superconductivity and quantum computation, the microscopic understanding of QSL states is a long-sought goal in condensed matter physics. The 3D pyrochlore lattice of corner-sharing tetrahedra can host a QSL with U(1) gauge fields called quantum spin ice (QSI), which is a quantum (with effective $S=1/2$) analog of the classical (with large effective moment) spin ice. A key difference between QSI and classical spin ice is the predicted presence of the linearly dispersing collective excitations near zero energy, dubbed the "photons", arising from emergent quantum electrodynamics, in addition to the spinons at higher energies. Recently, 3D pyrochlore systems Ce2M2O7 (M = Sn, Zr, Hf) have been suggested as effective $S=1/2$ QSI candidates, but there has been no evidence of quasielastic magnetic scattering signals from photons, a key signature for a QSI. Here, we use polarized neutron scattering experiments on single crystals of Ce2Zr2O7 to conclusively demonstrate the presence of magnetic excitations near zero energy at 50 mK in addition to signatures of spinons at higher energies. By comparing the energy (E), wave vector (Q), and polarization dependence of the magnetic excitations with theoretical calculations, we conclude that Ce2Zr2O7 is the first example of a dipolar-octupolar $π$ flux QSI with dominant dipolar Ising interactions, therefore identifying a microscopic Hamiltonian responsible for a QSL.

cond-mat.str-el

Flat-band hybridization between $f$ and $d$ states near the Fermi energy of SmCoIn$_5$

We present high-quality angle-resolved photoemission (ARPES) and density functional theory calculations (DFT+U) of SmCoIn$_5$. We find broad agreement with previously published studies of LaCoIn$_5$ and CeCoIn$_5$, confirming that the Sm $4f$ electrons are mostly localized. Nevertheless, our model is consistent with an additional delocalized Sm component, stemming from hybridization between the $4f$ electrons and the metallic bands at "hot spot" positions in the Brillouin zone. The dominant hot spot, called $γ_Z$, is similar to a source of delocalized $f$ states found in previous experimental and theoretical studies of CeCoIn$_5$. In this work, we identify and focus on the role of the Co $d$ states in exploring the relationship between heavy quasiparticles and the magnetic interactions in SmCoIn$_5$, which lead to a magnetically ordered ground state from within an intermediate valence scenario. Specifically, we find a globally flat band consisting of Co $d$ states near $E=-0.7$ eV, indicating the possibility of enhanced electronic and magnetic interactions in the "115" family of materials through localization in the Co layer, and we discuss a possible origin in geometric frustration. We also show that the delocalized Sm $4f$ states can hybridize directly with the Co $3d_{xz}$/$3d_{yz}$ orbitals, which occurs in our model at the Brillouin zone boundary point $R$ in a band that is locally flat and touches the Fermi level from above. Our work identifies microscopic ingredients for additional magnetic interactions in the "115" materials beyond the RKKY mechanism, and strongly suggests that the Co $d$ bands are an important ingredient in the formation of both magnetic and superconducting ground states.

cond-mat.str-el

Charge fluctuations in the intermediate-valence ground state of SmCoIn$_5$

The microscopic mechanism of heavy band formation, relevant for unconventional superconductivity in CeCoIn$_5$ and other Ce-based heavy fermion materials, depends strongly on the efficiency with which $f$ electrons are delocalized from the rare earth sites and participate in a Kondo lattice. Replacing Ce$^{3+}$ ($4f^1$, $J=5/2$) with Sm$^{3+}$ ($4f^5$, $J=5/2$), we show that a combination of crystal field and on-site Coulomb repulsion causes SmCoIn$_5$ to exhibit a $Γ_7$ ground state similar to CeCoIn$_5$ with multiple $f$ electrons. Remarkably, we also find that with this ground state, SmCoIn$_5$ exhibits a temperature-induced valence crossover consistent with a Kondo scenario, leading to increased delocalization of $f$ holes below a temperature scale set by the crystal field, $T_v$ $\approx$ 60 K. Our result provides evidence that in the case of many $f$ electrons, the crystal field remains the most important tuning knob in controlling the efficiency of delocalization near a heavy fermion quantum critical point, and additionally clarifies that charge fluctuations play a general role in the ground state of "115" materials.

cond-mat.str-el

In-plane uniaxial pressure-induced out-of-plane antiferromagnetic moment and critical fluctuations in BaFe$_2$As$_2$

A small in-plane external uniaxial pressure has been widely used as an effective method to acquire single domain iron pnictide BaFe$_2$As$_2$, which exhibits twin-domains without uniaxial strain below the tetragonal-to-orthorhombic structural (nematic) transition temperature $T_s$. Although it is generally assumed that such a pressure will not affect the intrinsic electronic/magnetic properties of the system, it is known to enhance the antiferromagnetic (AF) ordering temperature $T_N$ ($<T_s$) and create in-plane resistivity anisotropy above $T_s$. Here we use neutron polarization analysis to show that such a strain on BaFe$_2$As$_2$ also induces a static or quasi-static out-of-plane ($c$-axis) AF order and its associated critical spin fluctuations near $T_N/T_s$. Therefore, uniaxial pressure necessary to detwin single crystals of BaFe$_2$As$_2$ actually rotates the easy axis of the collinear AF order near $T_N/T_s$, and such effect due to spin-orbit coupling must be taken into account to unveil the intrinsic electronic/magnetic properties of the system.

cond-mat.supr-con

Orbital-selective spin waves in detwinned NaFeAs

The existence of orbital-dependent electronic correlations has been recognized as an essential ingredient to describe the physics of iron-based superconductors. NaFeAs, a parent compound of iron based superconductors, exhibits a tetragonal-to-orthorhombic lattice distortion below $T_s\approx 60$ K, forming an electronic nematic phase with two 90$^\circ$ rotated (twinned) domains, and orders antiferromagnetically below $T_N\approx 42$ K. We use inelastic neutron scattering to study spin waves in uniaxial pressure-detwinned NaFeAs. By comparing the data with combined density functional theory and dynamical mean-field theory calculations, we conclude that spin waves up to an energy scale of $E_\text{crossover} \approx 100$ meV are dominated by $d_{yz}$-$d_{yz}$ intra-orbital scattering processes, which have the two-fold ($C_2$) rotational symmetry of the underlying lattice. On the other hand, the spin wave excitations above $E_\text{crossover}$, which have approximately fourfold ($C_4$) rotational symmetry, arise from the $d_{xy}$-$d_{xy}$ intra-orbital scattering that controls the overall magnetic bandwidth in this material. In addition, we find that the low-energy ($E\approx 6$ meV) spin excitations change from approximate $C_4$ to $C_2$ rotational symmetry below a temperature $T^\ast$ ($>T_s$), while spin excitations at energies above $E_\text{crossover}$ have approximate $C_4$ rotational symmetry and are weakly temperature dependent. These results are consistent with angle resolved photoemission spectroscopy measurements, where the presence of an uniaxial strain necessary to detwin NaFeAs also raises the onset temperature $T^\ast$ of observable orbital-dependent band splitting to above $T_s$, thus supporting the notion of orbital selective spin waves in the nematic phase of iron-based superconductors.

cond-mat.supr-con

Anisotropic effect of a magnetic field on the neutron spin resonance in FeSe

We use inelastic neutron scattering to study the effect of a magnetic field on the neutron spin resonance (Er = 3.6 meV) of superconducting FeSe (Tc = 9 K). While a field aligned along the in-plane direction broadens and suppresses the resonance, a c-axis aligned field does so much more efficiently, consistent with the anisotropic field-induced suppression of the superfluid density from the heat capacity measurements. These results suggest that the resonance in FeSe is associated with the superconducting electrons arising from orbital selective quasi-particle excitations between the hole and electron Fermi surfaces.

cond-mat.str-el

Uniaxial $c$-axis pressure effects on underdoped BaFe$_2$(As$_{0.72}$P$_{0.28}$)$_2$ superconductor

The optimal superconductivity ($T_c \approx 30 $ K) in BaFe$_2$(As$_{1-x}$P$_x$)$_2$ can be reached when the coupled antiferromagnetic (AF) order ($T_N$) and orthorhombic lattice distortion ($T_s$) are suppressed to zero temperature with increasing of P concentration or hydrostatic pressure. Here we use transport and neutron scattering to study the $c$-axis pressure effects on electronic phases in underdoped BaFe$_2$(As$_{0.72}$P$_{0.28}$)$_2$, which has $T_N = T_s\approx 40$ K and $T_c \approx $ 28 K at zero pressure. With increasing $c$-axis pressure, $T_N$ and $T_s$ are slightly enhanced around $P_c \sim 20 $ MPa. Upon further increasing pressure, AF order is gradually suppressed to zero, while $T_c$ is enhanced to 30 K. Our results reveal the importance of magnetoelastic couplings in BaFe$_2$(As$_{1-x}$P$_x$)$_2$, suggesting that the $c$-axis pressure can be used as a tuning parameter to manipulate the electronic phases in iron pnictides.

cond-mat.supr-con

Experimental signatures of a three-dimensional quantum spin liquid in effective spin-1/2 Ce2Zr2O7 pyrochlore

A quantum spin liquid (QSL) is a state of matter where unpaired electrons' spins in a solid are quantum entangled, but do not show magnetic order in the zero-temperature limit. Because such a state may be important to the microscopic origin of high-transition temperature superconductivity and useful for quantum computation, the experimental realization of QSL is a long-sought goal in condensed matter physics. Although neutron scattering experiments on the two-dimensional (2D) spin-1/2 kagome-lattice ZnCu3(OD)6Cl2 and effective spin-1/2 triangular lattice YbMgGaO4 have found evidence for a continuum of magnetic excitations, the hallmark of a QSL carrying 'fractionalized quantum excitations', at very low temperature, magnetic and nonmagnetic site chemical disorder complicates the interpretation of the data. Recently, the three-dimensional (3D) Ce3+ pyrochlore lattice Ce2Sn2O7 has been suggested as a clean, effective spin-1/2 QSL candidate, but there is no evidence of a spin excitation continuum. Here we use thermodynamic, muon spin relaxation (μ SR), and neutron scattering experiments on single crystals of Ce2Zr2O7, a compound isostructural to Ce2Sn2O7, to demonstrate the absence of magnetic ordering and the presence of a spin excitation continuum at 35 mK, consistent with the expectation of a QSL. Since our neutron diffraction and diffuse scattering measurements on Ce2Zr2O7 reveal no evidence of oxygen deficiency and magnetic/nonmagnetic ion disorder as seen in other pyrochlores, Ce2Zr2O7 may be the first example of a 3D QSL material with minimum magnetic and nonmagnetic chemical disorder.

cond-mat.str-el

Plaquette instability competing with bicollinear ground state in detwinned FeTe

We use inelastic neutron scattering to show that long-range spin waves arising from the static bicollinear antiferromagnetic (AF) order in FeTe, which have twofold rotational symmetry in a fully detwinned crystal, rapidly dissolve above $E\approx 26$ meV into ridges of scattering with fourfold rotational symmetry and a nearly isotropic magnetic fluctuation spectrum. With increasing temperature above $T_N\approx 68$ K, the twofold spin waves change into broad regions of scattering with fourfold symmetry. Since the scattering patterns from plaquette magnetic order generated within a bilinear biquadratic Hamiltonian have fourfold rotational symmetry consistent with the high-energy, spin-isotropic spin waves of FeTe, we conclude that the bicollinear AF state in FeTe is quasidegenerate with plaquette magnetic order, providing evidence for the strongly frustrated nature of the local moments in iron chalcogenide family of iron-based superconductors.

cond-mat.str-el

Impact of the first order antiferromagnetic phase transition on the paramagnetic spin excitations and nematic phase of SrFe$_2$As$_2$

Understanding the nature of the electronic nematic phase in iron pnictide superconductors is important for elucidating its impact on high-temperature superconductivity. Here we use transport and inelastic neutron scattering to study spin excitations and in-plane resistivity anisotropy in uniaxial pressure detwinned BaFe$_2$As$_2$ and SrFe$_2$As$_2$, the parent compounds of iron pnictide superconductors. While BaFe$_2$As$_2$ exhibits weakly first order tetragonal-to-orthorhombic structural and antiferromagnetic (AF) phase transitions below $T_s > T_N\approx 138$ K, SrFe$_2$As$_2$ has strongly coupled first order structural and AF transitions below $T_s= T_N\approx 210$ K. We find that the direct signatures of the nematic phase persist to lower temperatures above the phase transition in the case of SrFe$_2$As$_2$ compared to BaFe$_2$As$_2$. Our findings support the conclusion that the strongly first-order nature of the magnetic transition in SrFe$_2$As$_2$ weakens the nematic phase and resistivity anisotropy in the system.

cond-mat.supr-con

Incommensurate magnetism near quantum criticality in CeNiAsO

Two phase transitions in the tetragonal strongly correlated electron system CeNiAsO were probed by neutron scattering and zero field muon spin rotation. For $T <T_{N1}$ = 8.7(3) K, a second order phase transition yields an incommensurate spin density wave with wave vector $\textbf{k} = (0.44(4), 0, 0)$. For $T < T_{N2}$ = 7.6(3) K, we find co-planar commensurate order with a moment of $0.37(5)~μ_B$, reduced to $30 \%$ of the saturation moment of the $|\pm\frac{1}{2}\rangle$ Kramers doublet ground state, which we establish by inelastic neutron scattering. Muon spin rotation in $\rm CeNiAs_{1-x}P_xO$ shows the commensurate order only exists for x $\le$ 0.1 so the transition at $x_c$ = 0.4(1) is from an incommensurate longitudinal spin density wave to a paramagnetic Fermi liquid.

cond-mat.str-el

c-axis pressure induced antiferromagnetic order in optimally P-doped BaFe2(As0.70P0.30)2 superconductor

Superconductivity in BaFe2(As1-xPx)2 iron pnictides emerges when its in-plane two-dimensional (2D) orthorhombic lattice distortion associated with nematic phase at Ts and three-dimensional (3D) collinear antiferromagnetic (AF) order at TN (Ts = TN) are gradually suppressed with increasing x, reaching optimal superconductivity around x = 0.30 with Tc $\approx$ 30 K. Here we show that a moderate uniaxial pressure along the c-axis in BaFe2(As0.70P0.30)2 spontaneously induces a 3D collinear AF order with TN = Ts > 30 K, while only slightly suppresses Tc. Although a ~ 400 MPa pressure compresses the c-axis lattice while expanding the in-plane lattice and increasing the nearest-neighbor Fe-Fe distance, it barely changes the average iron-pnictogen height in BaFe2(As0.70P0.30)2. Therefore, the pressure- induced AF order must arise from a strong in-plane magnetoelastic coupling, suggesting that the 2D nematic phase is a competing state with superconductivity.

cond-mat.supr-con

Stabilization of $s$-wave superconductivity through arsenic $p$-orbital hybridization in electron-doped BaFe$_2$As$_2$

Using random-phase approximation spin-fluctuation theory, we study the influence of the hybridization between iron $d$-orbitals and pnictide $p$-orbitals on the superconducting pairing state in iron-based superconductors. The calculations are performed for a 16-orbital Hubbard-Hund tight-binding model of BaFe$_2$As$_2$ that includes the As-$p$ orbital degrees of freedom in addition to the Fe-$d$ orbitals and compared to calculations for a 10-orbital Fe-$d$ only model. In both models we find a leading $s^\pm$ pairing state and a subleading $d_ {x^2-y^2}$-wave state in the parent compound. Upon doping, we find that the $s^\pm$ state remains the leading state in the 16-orbital model up to a doping level of 0.475 electrons per unit cell, at which the hole Fermi surface pockets at the zone center start to disappear. This is in contrast to the 10-orbital model, where the $d$-wave state becomes the leading state at a doping of less than 0.2 electrons. This improved stability of $s^\pm$ pairing is found to arise from a decrease of $d_{xy}$ orbital weight on the electron pockets due to hybridization with the As-$p$ orbitals and the resulting reduction of near $(π,π)$ spin-fluctuation scattering which favors the competing $d$-wave state. These results show that the orbital dependent hybridization of Fermi surface Bloch states with the usually neglected $p$-orbital states is an important ingredient in an improved itinerant pairing theory.

cond-mat.supr-con

Spin Waves in Detwinned BaFe$_2$As$_2$

Understanding magnetic interactions in the parent compounds of high-temperature superconductors forms the basis for determining their role for the mechanism of superconductivity. For parent compounds of iron pnictide superconductors such as $A$Fe$_2$As$_2$ ($A=$ Ba, Ca, Sr), although spin excitations have been mapped out throughout the entire Brillouin zone (BZ), measurements were carried out on twinned samples and did not allow for a conclusive determination of the spin dynamics. Here we use inelastic neutron scattering to completely map out spin excitations of $\sim$100\% detwinned BaFe$_2$As$_2$. By comparing observed spectra with theoretical calculations, we conclude that the spin excitations can be well described by an itinerant model with important contributions from electronic correlations.

cond-mat.supr-con