arXiv subjects

David Zueco

Publications and source records attributed to David Zueco.

At least 37 records · Page 2Linked to original sources

arXiv2022

Non-Gaussian Variational Wavefunctions for Interacting Bosons on the Lattice

A variational method for studying the ground state of strongly interacting quantum many-body bosonic systems is presented. Our approach constructs a class of extensive variational non-Gaussian wavefunctions which extend Gaussian states by means of nonlinear canonical transformations (NLCT) on the fields of the theory under consideration. We illustrate this method with the one dimensional Bose-Hubbard model for which the proposal presented here, provides a family of approximate ground states at arbitrarily large values of the interaction strength. We find that, for different values of the interaction, the non-Gaussian NLCT-trial states sensibly improve the ground state energy estimation when the system is in the Mott phase.

cond-mat.str-el↗

arXiv2022

Dispersive readout of molecular spin qudits

We study the physics of a magnetic molecule described by a "giant" spin with multiple ($d > 2$) spin states interacting with the quantized cavity field produced by a superconducting resonator. By means of the input-output formalism, we derive an expression for the output modes in the dispersive regime of operation. It includes the effect of magnetic anisotropy, which makes different spin transitions addressable. We find that the measurement of the cavity transmission allows to uniquely determine the spin state of the qudits. We discuss, from an effective Hamiltonian perspective, the conditions under which the qudit read-out is a non-demolition measurement and consider possible experimental protocols to perform it. Finally, we illustrate our results with simulations performed for realistic models of existing magnetic molecules.

quant-ph↗

arXiv2022

Ultrastrong waveguide QED with giant atoms

Quantum optics with giant emitters has shown a new route for the observation and manipulation of non-Markovian properties in waveguide-QED. In this paper we extend the theory of giant atoms, hitherto restricted to the perturbative light-matter regime, to deal with the ultrastrong coupling regime. Using static and dynamical polaron methods we address the low energy subspace of a giant atom coupled to an Ohmic waveguide beyond the standard rotating wave approximation. We analyze the equilibrium properties of the system by computing the atomic frequency renormalization as a function of the coupling characterizing the localization-delocalization quantum phase transition for a giant atom. We show that virtual photons dressing the ground state are non-exponentially localized around the contact points but decay as a power-law. Dynamics of an initially excited giant atom are studied, pointing out the effects of ultrastrong coupling on the Lamb shift and the spontaneous emission decay rate. Finally we comment on the existence of the so-called oscillating bound states beyond the rotating wave approximation.

quant-ph↗

arXiv2022

Quantum kernels to learn the phases of quantum matter

Classical machine learning has succeeded in the prediction of both classical and quantum phases of matter. Notably, kernel methods stand out for their ability to provide interpretable results, relating the learning process with the physical order parameter explicitly. Here, we exploit quantum kernels instead. They are naturally related to the \emph{fidelity} and thus it is possible to interpret the learning process with the help of quantum information tools. In particular, we use a support vector machine (with a quantum kernel) to predict and characterize second order quantum phase transitions. We explain and understand the process of learning when the fidelity per site (rather than the fidelity) is used. The general theory is tested in the Ising chain in transverse field. We show that for small-sized systems, the algorithm gives accurate results, even when trained away from criticality. Besides, for larger sizes we confirm the success of the technique by extracting the correct critical exponent $ν$. Finally, we present two algorithms, one based on fidelity and one based on the fidelity per site, to classify the phases of matter in a quantum processor.

quant-ph↗

arXiv2022

Effective theory for matter in non-perturbative cavity QED

Starting from a general material system of $N$ particles coupled to a cavity, we use a coherent-state path integral formulation to produce a non-perturbative effective theory for the material degrees of freedom. We tackle the effects of image charges, the $A^2$ term and a multimode arbitrary-geometry cavity. The resulting (non-local) action has the photonic degrees of freedom replaced by an effective position-dependent interaction between the particles. In the large-$N$ limit, we discuss how the theory can be cast into an effective Hamiltonian where the cavity induced interactions are made explicit. The theory is applicable, beyond cavity QED, to any system where bulk material is linearly coupled to a diagonalizable bosonic bath. We highlight the differences of the theory with other well-known methods and numerically study its finite-size scaling on the Dicke model. Finally, we showcase its descriptive power with three examples: photon condensation, the 2D free electron gas in a cavity and the modification of magnetic interactions between molecular spins; recovering, condensing and extending some recent results in the literature.

quant-ph↗

arXiv2021

Optimal control of molecular spin qudits

We demonstrate, numerically, the possibility of manipulating the spin states of molecular nanomagnets with shaped microwave pulses designed with quantum optimal control theory techniques. The state-to-state or full gate transformations can be performed in this way in shorter times than using simple monochromatic resonant pulses. This enhancement in the operation rates can therefore mitigate the effect of decoherence. The optimization protocols and their potential for practical implementations are illustrated by simulations performed for a simple molecular cluster hosting a single Gd$^{3+}$ ion. Its eight accessible levels (corresponding to a total spin $S=7/2$) allow encoding an $8$-level qudit or a system of three coupled qubits. All necessary gates required for universal operation can be obtained with optimal pulses using the intrinsic couplings present in this system. The application of optimal control techniques can facilitate the implementation of quantum technologies based on molecular spin qudits.

quant-ph↗

arXiv2021

Distant emitters in ultrastrong waveguide QED: Ground-state properties and non-Markovian dynamics

Starting from the paradigmatic spin-boson model (SBM), we investigate the static and dynamical properties of a system of two distant two-level emitters coupled to a one-dimensional Ohmic waveguide beyond the rotating wave approximation. Employing static and dynamical polaron Ansätze we study the effects of finite separation distance on the behavior of the photon-mediated Ising-like interaction, qubit frequency renormalization, ground-state magnetization, and entanglement entropy of the two-qubit system. Based on previous works we derive an effective approximate Hamiltonian for the two-impurity SBM that preserves the excitation-number and thus facilitates the analytical treatment. In particular, it allows us to introduce non-Markovianity arising from delay-feedback effects in two distant emitters in the so-called ultrastrong coupling (USC) regime. We test our results with numerical simulations performed over a discretized circuit-QED model, finding perfect agreement with previous results, and showing interesting dynamical effects arising in ultrastrong waveguide QED with distant emitters. In particular, we revisit the Fermi two-atom problem showing that, in the USC regime, initial correlations yield two different evolutions for symmetric and antisymmetric states even before the emitters become causally connected. Finally, we demonstrate that the collective dynamics, e.g., superradiance or subradiance, are affected not only by the distance between emitters, but also by the coupling, due to significant frequency renormalization. This constitutes another dynamical consequence of the USC regime.

quant-ph↗

arXiv2021

Photon Condensation and Enhanced Magnetism in Cavity QED

A system of magnetic molecules coupled to microwave cavities ($LC$ resonators) undergoes the equilibrium superradiant phase transition. The transition is experimentally observable. The effect of the coupling is first illustrated by the vacuum-induced ferromagnetic order in a quantum Ising model and then by the modification of the magnetic phase diagram of ${\rm Fe_8}$ dipolar crystals, exemplifying the cooperation between intrinsic and photon-induced spin-spin interactions. Finally, a transmission experiment is shown to resolve the transition, measuring the quantum electrodynamical control of magnetism.

quant-ph↗

arXiv2021

Chemical tuning of spin clock transitions in molecular monomers based on nuclear spin-free Ni(II)

We report the existence of a sizeable quantum tunnelling splitting between the two lowest electronic spin levels of mononuclear Ni complexes. The level anti-crossing, or magnetic clock transition, associated with this gap has been directly monitored by heat capacity experiments. The comparison of these results with those obtained for a Co derivative, for which tunnelling is forbidden by symmetry, shows that the clock transition leads to an effective suppression of intermolecular spin-spin interactions. In addition, we show that the quantum tunnelling splitting admits a chemical tuning via the modification of the ligand shell that determines the crystal field and the magnetic anisotropy. These properties are crucial to realize model spin qubits that combine the necessary resilience against decoherence, a proper interfacing with other qubits and with the control circuitry and the ability to initialize them by cooling.

quant-ph↗

arXiv2020

Perfect state transfer on hypercubes and its implementation using superconducting qubits

We propose a protocol for perfect state transfer between any pair of vertices in a hypercube. Given a pair of distinct vertices in the hypercube we determine a sub-hypercube that contains the pair of vertices as antipodal vertices. Then a switching process is introduced for determining the sub-hypercube of a memory enhanced hypercube that facilitates perfect state transfer between the desired pair of vertices. Furthermore, we propose a physical architecture for the pretty good state transfer implementation of our switching protocol with fidelity arbitrary close to unity, using superconducting transmon qubits with tunable couplings. The switching is realised by the control over the effective coupling between the qubits resulting from the effect of ancilla qubit couplers for the graph edges. We also report an error bound on the fidelity of state transfer due to faulty implementation of our protocol.

quant-ph↗

arXiv2020

Chiral current circulation and $\mathcal{PT}$ symmetry in a trimer of oscillators

We present a simple quantum theory of a bosonic trimer in a triangular configuration, subject to gain and loss in an open quantum systems approach. Importantly, the coupling constants between each oscillator are augmented by complex arguments, which give rise to various asymmetries. In particular, one may tune the complex phases to induce chiral currents, including the special case of completely unidirectional (or one-way) circulation when certain conditions are met regarding the coherent and incoherent couplings. When our general theory is recast into a specific non-Hermitian Hamiltonian, we find interesting features in the trimer population dynamics close to the exceptional points between phases of broken and unbroken $\mathcal{PT}$ symmetry. Our theoretical work provides perspectives for the experimental realization of chiral transport at the nanoscale in a variety of accessible nanophotonic and nanoplasmonic systems, and paves the way for the potential actualization of nonreciprocal devices.

cond-mat.mes-hall↗

arXiv2020

A dissymmetric [Gd$_{2}$] coordination molecular dimer hosting six addressable spin qubits

Artificial magnetic molecules are suitable hosts to one or several spin qubits, which could then implement small-scale algorithms. In order to become of practical use, such molecular spin processors need to increase the dimension $d$ of the available computational space and fulfill the highly demanding conditions that warrant universal operations. Here, we design, synthesize and fully characterize dissymetric molecular dimers hosting either one or two Gd(III) ions. The strong sensitivity of Gd(III) magnetic anisotropy to the symmetry of its local coordination gives rise to different zero-field splittings at each coordination site. As a result, the [LaGd] and [GdLu] complexes provide realizations of distinct $d = 8$ spin qudits, whereas the [Gd$_{2}$] dimer meets all requirements, including a complete set of operations, to act as a $d = 64$ all-electron spin qudit (or, equivalenty, as six addressable qubits). Electron paramagnetic resonance experiments show that the relevant resonant transitions between different spin states can be coherently controlled, with coherence times T$_{M}$ of the order of $1$ $μ$s limited by intramolecular hyperfine interactions. Coordination complexes with embedded quantum functionalities are promising building blocks for quantum computation and simulation hybrid platforms.

quant-ph↗

arXiv2020

Gauge Principle and Gauge Invariance in Quantum Two-Level Systems

The quantum Rabi model is a widespread description for the coupling between a two-level system and a quantized single mode of an electromagnetic resonator. Issues about this model's gauge invariance have been raised. These issues become evident when the light-matter interaction reaches the so-called ultrastrong coupling regime. Recently, a modified quantum Rabi model able to provide gauge-invariant physical results in any interaction regime was introduced [Nature Physics 15, 803 (2019)]. Here we provide an alternative derivation of this result, based on the implementation in two-state systems of the gauge principle, which is the principle from which all the fundamental interactions in quantum field theory are derived. The adopted procedure can be regarded as the two-site version of the general method used to implement the gauge principle in lattice gauge theories. Applying this method, we also obtain the gauge-invariant quantum Rabi model for asymmetric two-state systems, and the multi-mode gauge-invariant quantum Rabi model beyond the dipole approximation.

quant-ph↗

arXiv2020

Spin squeezing by one-photon-two-atom excitations processes in atomic ensembles

It has been shown elsewhere that two spatially separated atoms can jointly absorb one photon, whose frequency is equal to the sum of the transition frequencies of the two atoms. We describe this process in the presence of an ensemble of many two-level atoms, and show that it can be used to generate spin squeezing and entanglement. This resonant collective process allows to create a sizeable squeezing already at the single-photon limit. It represents a novel way for generating manybody spin-spin interactions, yielding a two-axis twisting-like interaction among the spins, which is very effcient for the generation of spin squeezing. We perform explicit calculations for ensembles of magnetic molecules coupled to a superconducting coplanar cavities. This system represents an attractive on-chip architecture for the realization of improved sensing.

quant-ph↗

arXiv2020

Gauge freedom, quantum measurements, and time-dependent interactions in cavity and circuit QED

The interaction between the electromagnetic field inside a cavity and natural or artificial atoms has played a crucial role in developing our understanding of light-matter interaction, and is central to various quantum technologies. Recently, new regimes beyond the weak and strong light-matter coupling have been explored in several settings. These regimes, where the interaction strength is comparable (ultrastrong) or even higher (deep-strong) than the transition frequencies in the system, can give rise to new physical effects and applications. At the same time, they challenge our understanding of cavity QED. When the interaction strength is so high, fundamental issues like the proper definition of subsystems and of their quantum measurements, the structure of light-matter ground states, or the analysis of time-dependent interactions are subject to ambiguities leading to even qualitatively distinct predictions. The resolution of these ambiguities is also important for understanding and designing next-generation quantum devices that will exploit the ultrastrong coupling regime. Here we discuss and provide solutions to these issues.

quant-ph↗

arXiv2020

Bound states in ultrastrong waveguide QED

We discuss the properties of bound states in finite-bandwidth waveguide QED beyond the Rotating Wave Approximation or excitation number conserving light-matter coupling models. Therefore, we extend the \emph{standard} calculations to a broader range of light-matter strengths, in particular, in the so-called ultrastrong coupling regime. We do this using the Polaron technique. Our main results are as follows. We compute the spontaneous emission rate, which is renormalized as compared to the Fermi Golden Rule formula. We generalise the existence criteria for bound states, their properties and their role in the qubits thermalization. We discuss effective spin-spin interactions through both vacuum fluctuations and bound states. Finally, we sketch a perfect state-transfer protocol among distant emitters.

quant-ph↗

arXiv2019

QED with magnetic textures

Coherent exchange between photons and different matter excitations (like qubits, acoustic surface waves or spins) allows for the entanglement of light and matter and provides a toolbox for performing fundamental quantum physics. On top of that, coherent exchange is a basic ingredient in the majority of quantum information processors. In this work, we develop the theory for coupling between magnetic textures (vortices and skyrmions) stabilized in ferromagnetic nanodiscs and photons generated in a circuit. In particular, we show how to perform broadband spectroscopy of the magnetic textures by sending photons through a transmission line and recording the transmission. We also discuss the possibility of reaching the strong coupling regime between these texture excitations and a single photon residing in a cavity.

cond-mat.mes-hall↗

arXiv2019

Single photons by quenching the vacuum

Heisenberg's uncertainty principle implies that the quantum vacuum is not empty but fluctuates. These fluctuations can be converted into radiation through nonadiabatic changes in the Hamiltonian. Here, we discuss how to control this vacuum radiation, engineering a single-photon emitter out of a two-level system (2LS) ultrastrongly coupled to a finite-band waveguide in a vacuum state. More precisely, we show the 2LS nonlinearity shapes the vacuum radiation into a nonGaussian superposition of even and odd cat states. When the 2LS bare frequency lays within the band gaps, this emission can be well approximated by individual photons. This picture is confirmed by a characterization of the ground and bound states, and a study of the dynamics with matrix product states and polaron Hamiltonian methods.

quant-ph↗