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Debdeep Jena

Publications and source records attributed to Debdeep Jena.

At least 19 recordsLinked to original sources

Fabrication-free assessment of microwave losses in germanium-based dielectrics and superconductors

We present a flip-chip-based sensing scheme to measure effective microwave losses associated with target materials for quantum technologies, without requiring any device fabrication on the material under test. Using this approach, we quantify the microwave losses of a strain-engineered Ge/SiGe quantum well heterostructure and investigate losses arising from its Ge substrate and intermediate layers. The quality factors of the fabricated microwave resonators agree with the losses of dielectric materials independently extracted from flip-chip sensing measurements. We further study the superconductor platinum silicon germanide (PtSiGe) prepared by thermal reaction with a deposited Pt film, finding high microwave losses that limit the suitability of the films studied here as the sole superconductor for high-quality resonator applications. By coating Pt with Nb prior to the reaction, we observe a substantial reduction in microwave loss and a nearly three-fold enhancement of the transport critical temperature. The temperature dependence of the microwave loss is consistent with gap inhomogeneity in both superconducting films. These results identify constraints on material choices, provide design guidance for microwave circuits on planar Ge heterostructures, and demonstrate a fast-turnaround testing method for new materials for superconducting quantum circuits.

quant-ph

Second-Order Optical Nonlinearity of AlScN Films Grown By Molecular Beam Epitaxy

Alloys of AlN have rapidly emerged as a material platform for nonlinear optics. In this paper, we measure the second-order optical nonlinearity of AlScN films grown directly on nitrided c-plane sapphire by molecular beam epitaxy. This direct growth approach, which bypasses a thick AlN buffer layer, allows us to isolate the true nonlinear response of the AlScN film. Our results show a large enhancement of d31, but a suppression of d33 in AlScN films compared to AlN. We observe that d31 can be as high as 4.92 pm/V , which is 60 times larger than that of AlN. The development of AlScN-based photonic devices can enable energy-efficient nonlinear optical operations that can be epitaxially integrated with electronic and photonic devices based on Si, GaN and AlN.

cond-mat.mtrl-sci

High-Q superconducting microwave resonators using MBE titanium nitride

Using molecular beam epitaxy, we have realized thin films of titanium nitride (TiN) on c-plane sapphire that exhibit the lowest observed full-width at half maximum X-ray rocking curve width of 18 arcsec. Though the (111) oriented TiN exhibits an abrupt and crystalline interface with sapphire, for the first time we observe sub-surface defects in the sapphire substrate, which nucleate structural defects in the epitaxial TiN layer. Using quarter-wavelength coplanar waveguide (CPW) resonators in a 3 \textmu m/6 \textmu m/3 \textmu m gap/strip/gap lines in a hanger geometry, we find the internal quality factor of the TiN resonators to be $>10^{6}$ in the single-photon $\langle n \rangle \sim 1$ limit at 5.8 GHz and 10 mK, rising to $>20 \times 10^{6}$ at $\langle n \rangle \sim 10^{6}$. The results are of high interest for applications of superconducting TiN in several areas, and provide a path towards epitaxial Josephson junctions with crystalline barriers in the future for high coherence qubits.

cond-mat.supr-con

Loss Mechanisms in Cryogenic Microwave Epitaxial AlN Resonators

Epitaxial aluminum nitride (AlN) thin-film bulk acoustic resonators (FBARs) enable low loss filtering for future 6G systems. They also provide a compact approach for qubit sensing at cryogenic temperatures. However, these devices are rarely characterized systematically from room temperature to cryogenic temperatures, and the mechanisms that limit their cryogenic performance remain unclear. In this work, we study a 15.6 GHz epitaxial AlN FBAR from room temperature to cryogenic temperatures to identify losses from the AlN film and those introduced by the electrodes, anchors, and other device layers. Small signal RF measurements from 294 K down to 6.5 K show an increase in the raw Qmax from 363 to 1589. A temperature dependent model that includes phonon phonon scattering, thermoelastic damping, dielectric loss, electrical loss, and anchor loss helps explain the measured Q(T) trend and identifies a transition from the Landau Rumer to the Akhiezer regime near 270 K. The model indicates that acoustic energy leakage through the anchors limits Q at cryogenic temperatures, while electrical loss dominates at higher temperatures. These results point to two routes toward higher cryogenic Q: better acoustic isolation of the anchors and lower loss electrodes, including superconducting electrodes. Improved anchor design benefits both high frequency 6G filters and cryogenic quantum microwave circuits, while superconducting electrodes are particularly useful for cryogenic operation.

cond-mat.mes-hall

Dependence of the Mn sticking coefficient on Ga-rich, N-rich, and Ga/N-flux-free conditions in GaN grown by plasma-assisted molecular beam epitaxy

This brief report examines the influence of Ga/N flux conditions on Mn incorporation in GaN. Mn-doped GaN layers were grown at 680$^{\circ}$C by molecular beam epitaxy on a Ga-polar GaN(0001) template substrate under Ga-rich, N-rich, and no-flux conditions (i.e., Mn $\delta$ doping). Mn incorporation was highest under N-rich condition, lowest under Ga-rich condition, and intermediate in the absence of Ga and N fluxes. For the growth conditions examined in this study, the corresponding Mn sticking coefficients, relative to that of the N-rich condition, were determined to be 0.31 for no-flux growth and 0.01 for the Ga-rich growth.

cond-mat.mtrl-sci

Shubnikov-de Haas oscillations of two-dimensional electron gases in AlYN/GaN and AlScN/GaN heterostructures

AlYN and AlScN have recently emerged as promising nitride materials that can be integrated with GaN to form two-dimensional electron gases (2DEGs) at heterojunctions. Electron transport properties in these heterostructures have been enhanced through careful design and optimization of epitaxial growth conditions. In this work, we report for the first time Shubnikov-de Haas (SdH) oscillations of 2DEGs in AlYN/GaN and AlScN/GaN heterostructures, grown by metal-organic chemical vapor deposition. SdH oscillations provide direct access to key 2DEG parameters at the Fermi level: (1) carrier density, (2) electron effective mass (m* ~ 0.24 me for AlYN/GaN and m* ~ 0.25 me for AlScN/GaN), and (3) quantum scattering time (~ 68 fs for AlYN/GaN and ~ 70 fs for AlScN/GaN). These measurements of fundamental transport properties provide critical insights for advancing emerging nitride semiconductors for future high-frequency and power electronics.

cond-mat.mes-hall

Edge emission from 265~nm UV-C LEDs grown by MBE on bulk AlN

UV-C LEDs pseudomorphically grown by MBE on bulk AlN substrates emitting at 265 nm are demonstrated. High current density up to 800 A/cm$^2$, 5 orders of on/off ratio, and low differential on-resistance of 2.6 m$\Omega\cdot$cm$^2$ at the highest current density is achieved. The LED heterostructure has a high refractive index waveguide core surrounded by n- and p-cladding layers similar to a laser diode designed for mode confinement at 270 nm to facilitate edge emission and collection of photons. Edge-emitting devices are made by cleaving the fabricated LEDs along the $m$-plane of the wurtzite crystal. Electrical injection results in emission of high energy 4.7 eV photons that are collected from the cleaved edge of the LEDs corresponding to the optical bandgap of the AlGaN active region. The contribution of power dissipation across the n- and p-regions of the diode is discussed. The n-contact resistance to n-AlGaN is identified as the largest contributor to the series resistance of the LED in the present generation of devices.

physics.optics

Low Resistance Non-Alloyed Ohmic Contacts to High Al Composition n-type AlGaN

Ohmic contacts to high (>70\%) Al content n-type Al$_x$Ga$_{1-x}$N ultra-wide bandgap semiconductor layers in nitride electronic and photonic devices are typically fabricated by a lift-off process and high temperature ($>700^\circ$C) thermal alloying. These conditions often result in significant structural deformations of the fabricated structures and impose a harsh thermal budget on all other aspects of the device. Here, we report the fabrication of \textit{non-alloyed} \textit{as-deposited} ohmic contacts to 71\% n+AlGaN ($E_\text{g}\sim5.4$~eV) with a free carrier concentration of roughly $7\times 10^{19}$~cm$^{-3}$ and a resistivity of 4 - 5.5 m$\Omega$cm (among the lowest reported for Al$_{0.71}$Ga$_{0.29}$N) with linear $I-V$ characteristics and a contact resistivity of $\rho_\text{c}=(4.4\pm1.0)\times10^{-4}$~$\Omega$cm$^2$ (measured at zero voltage). Contacts with this quality are formed by two separate fabrication schemes: (i) metal-first patterning, and (ii) lift-off with an oxygen asher descum prior to metal deposition. Given the low threading dislocation density in the single-crystal AlN substrate used for epitaxy, the smooth morphology of the contacted epitaxial surface, and the non-alloyed nature of the contacts, this contact resistivity is attributed purely to thermionic field emission through the metal-semiconductor junction. Contact resistivity extraction at low current injection enables us to model these results using a thermionic field-emission model of contact resistivity, yielding a barrier height for Ti/Al$_{0.71}$Ga$_{0.29}$N of $(0.81\pm0.02)$ eV.

cond-mat.mtrl-sci

Effect of substrate miscut angle on critical thickness, structural and electronic properties of MBE-grown NbN films on c-plane sapphire

We report the structural and electronic properties of niobium nitride (NbN) thin films grown by molecular beam epitaxy on c-plane sapphire with miscut angles of $0.5^\text{o}$, $2^\text{o}$, $4^\text{o}$, and $10^\text{o}$ towards m-axis. X-ray diffraction (XRD) scans reveal that the full width at half maximum of the rocking curves around the 1 1 1 reflection of these NbN films decreases with increasing miscut. Starting from 76 arcsecs on $0.5^\text{o}$ miscut, the FWHM reduces to almost 20 arcsecs on $10^\text{o}$ miscut sapphire indicating improved structural quality. Scanning transmission electron microscopy (STEM) images indicate that NbN on c-sapphire has around 10 nm critical thickness, irrespective of the substrate miscut, above which it turns columnar. The improved structural property is correlated with a marginal increment in superconducting transition temperature $T_\text{c}$ from 12.1 K for NbN on $0.5^\text{o}$ miscut sapphire to 12.5 K for NbN on $10^\text{o}$ miscut sapphire.

cond-mat.supr-con

High Mobility Multiple-Channel AlScN/GaN Heterostructures

Aluminum scandium nitride (AlScN) is a promising barrier material for gallium nitride (GaN)-based transistors for the next generation of radio-frequency electronic devices. In this work, we examine the transport properties of two dimensional electron gases (2DEGs) in single- and multi-channel AlScN/GaN heterostructures grown by molecular beam epitaxy, and demonstrate the lowest sheet resistance among AlScN-based systems reported to date. Assorted schemes of GaN/AlN interlayers are first introduced in single-channel structures between AlScN and GaN to improve conductivity, increasing electron mobility up to $1370$ cm$^{2}$/V$\cdot$s at 300 K and $4160$ cm$^{2}$/V$\cdot$s at 77 K, reducing the sheet resistance down to 170 $\Omega/\square$ and 70 $\Omega/\square$ respectively. These improvements are then leveraged in multi-channel heterostructures, reaching sheet resistances of 65 $\Omega/\square$ for three channels and 45 $\Omega/\square$ for five channels at 300 K, further reduced to 21 $\Omega/\square$ and 13 $\Omega/\square$ at 2 K, respectively, confirming the presence of multiple 2DEGs. Structural characterization indicates pseudomorphic growth with smooth surfaces, while partial barrier relaxation and surface roughening are observed at high scandium content, with no impact on mobility. This first demonstration of ultra-low sheet resistance multi-channel AlScN/GaN heterostructures places AlScN on par with state-of-the-art multi-channel Al(In)N/GaN systems, showcasing its capacity to advance existing and enable new high-speed, high-power electronic devices.

cond-mat.mtrl-sci

A Compact Model for Polar Multiple-Channel Field Effect Transistors: A Case Study in III-V Nitride Semiconductors

A compact analytical model is developed for the mobile charge density of polar multiple channel field effect transistors. Two dimensional electron and hole gases can be potentially induced by spontaneous and piezoelectric polarization in polar heterostructures. Focusing on the active region of devices that employ a multiple quantum-well layout, the total electron and hole populations are estimated from fundamental electrostatic and quantum mechanical principles. Hole gas depletion techniques, revolving around intentional donor doping, are modeled and evaluated, culminating in a generalized closed-form equation for the mobile carrier density across the doping schemes examined. The utility of this model is illustrated for the III-Nitride material system, exploring AlGaN/GaN, AlInN/GaN and AlScN/GaN heterostructures. The compact framework provided herein considerably elucidates and enhances the efficiency of multi-layered transistor design.

physics.app-ph

Lorentzian Switching Dynamics in HZO-based FeMEMS Synapses for Neuromorphic Weight Storage

Neuromorphic computing demands synaptic elements that can store and update weights with high precision while being read non-destructively. Conventional ferroelectric synapses store weights in remnant polarization states and might require destructive electrical readout, limiting endurance and reliability. We demonstrate a ferroelectric MEMS (FeMEMS) based synapse in which analog weights are stored in the piezoelectric coefficient $d_{31,eff}$ of a released Hf$_{0.5}$Zr$_{0.5}$O$_2$ (HZO) MEMS unimorph. Partial switching of ferroelectric domains modulates $d_{31,eff}$, and a low-amplitude mechanical drive reads out the weight without read-disturb in the device yielding more than 7-bit of programming levels. The mechanical switching distribution function follows a Lorentzian distribution as a logarithmic function of partial poling voltage ($V_p$) consistent with nucleation-limited switching (NLS), and the median threshold extracted from electromechanical data obeys a Merz-type field-time law with a dimensionless exponent $\alpha = 3.62$. These relationships establish a quantitative link between mechanical weights and electrical switching kinetics. This mechanically read synapse avoids depolarization and charge-injection effects, provides bipolar weights (well suited for excitatory and inhibitory synapses), directly reveals partial domain populations, and offers a robust, energy-efficient route toward high-bit neuromorphic hardware.

cs.ET

Generalized quantum limits of electrical contact resistance and thermal boundary resistance

The importance of electrical contact resistance and thermal boundary resistance has increased dramatically as devices are scaled to atomic limits. The use of a rich range of materials with various bandstructures (e.g. parabolic, conical), and in geometries exploiting various dimensionalities (e.g. 1D wires, 2D sheets, and 3D bulk) will increase in the future. Here we derive a single general expression for the quantum limit of electrical contact resistivity for various bandstructures and all dimensions. A corresponding result for the quantum limit of thermal boundary resistance is also derived. These results will be useful to quantitatively co-design, benchmark, and guide the lowering of electrical and thermal boundary resistances for energy efficient devices.

cond-mat.mtrl-sci

XHEMTs on Ultrawide Bandgap Single-Crystal AlN Substrates

AlN has the largest bandgap in the wurtzite III-nitride semiconductor family, making it an ideal barrier for a thin GaN channel to achieve strong carrier confinement in field-effect transistors, analogous to silicon-on-insulator technology. Unlike SiO$_2$/Si/SiO$_2$, AlN/GaN/AlN can be grown fully epitaxially, enabling high carrier mobilities suitable for high-frequency applications. However, developing these heterostructures and related devices has been hindered by challenges in strain management, polarization effects, defect control and charge trapping. Here, the AlN single-crystal high electron mobility transistor (XHEMT) is introduced, a new nitride transistor technology designed to address these issues. The XHEMT structure features a pseudomorphic GaN channel sandwiched between AlN layers, grown on single-crystal AlN substrates. First-generation XHEMTs demonstrate RF performance on par with the state-of-the-art GaN HEMTs, achieving 5.92 W/mm output power and 65% peak power-added efficiency at 10 GHz under 17 V drain bias. These devices overcome several limitations present in conventional GaN HEMTs, which are grown on lattice-mismatched foreign substrates that introduce undesirable dislocations and exacerbated thermal resistance. With the recent availability of 100-mm AlN substrates and AlN's high thermal conductivity (340 W/m$\cdot$K), XHEMTs show strong potential for next-generation RF electronics.

cond-mat.mtrl-sci

The effect of boron incorporation on leakage and wake-up in ferroelectric Al_{1-x}Sc_xN

This study explores the influence of boron incorporation on the structural and electrical properties of ferroelectric Aluminum Scandium Nitride (Al_{1-x}Sc_xN ) thin films, focusing on leakage currents, wake-up effects, and imprint behavior. Al_{1-x}Sc_xN films were incorporated with varying boron concentrations and analyzed under different deposition conditions to determine their structural integrity and ferroelectric performance. Key findings include a reduction in leakage currents, non-trivial alterations in bandgap energy as well as an increasing coercive fields with increasing boron content. Films with 6-13 at.% boron exhibited N-polar growth, while those with 16 at.% boron showed mixed polarity after deposition, which affected their ferroelectric response during the initial switching cycles - as did the addition of boron itself compared to pure Al1-xScxN . With increasing boron content, wake-up became gradually more pronounced and was strongest for pure Al_{1-x}B_xN .

cond-mat.mtrl-sci

Epitaxial high-K AlBN barrier GaN HEMTs

We report a polarization-induced 2D electron gas (2DEG) at an epitaxial AlBN/GaN heterojunction grown on a SiC substrate. Using this 2DEG in a long conducting channel, we realize ultra-thin barrier AlBN/GaN high electron mobility transistors that exhibit current densities of more than 0.25 A/mm, clean current saturation, a low pinch-off voltage of -0.43 V, and a peak transconductance of 0.14 S/mm. Transistor performance in this preliminary realization is limited by the contact resistance. Capacitance-voltage measurements reveal that introducing 7 % B in the epitaxial AlBN barrier on GaN boosts the relative dielectric constant of AlBN to 16, higher than the AlN dielectric constant of 9. Epitaxial high-K barrier AlBN/GaN HEMTs can thus extend performance beyond the capabilities of current GaN transistors.

physics.app-ph

Growth and characterization of single crystal cubic TaN and hexagonal Ta$_2$N films on c-plane Sapphire

Two single crystal phases of tantalum nitride were stabilized on c-plane sapphire using molecular beam epitaxy. The phases were identified to be $\delta$-TaN with a rocksalt cubic structure and $\gamma$-Ta$_2$N with a hexagonal structure. Atomic force microscopy scans revealed smooth surfaces for both the films with root mean square roughnesses less than 0.3 nm. Phase-purity of these films was determined by x-ray diffraction. Raman spectrum of the phase-pure $\delta$-TaN and $\gamma$-Ta$_2$N obtained will serve as a future reference to determine phase-purity of tantalum nitride films. Further, the room-temperature and low-temperature electronic transport measurements indicated that both of these phases are metallic at room temperature with resistivities of 586.2 $\mu\Omega$-cm for the 30 nm $\delta$-TaN film and 75.5 $\mu\Omega$-cm for the 38 nm $\gamma$-Ta$_2$N film and become superconducting below 3.6 K and 0.48 K respectively. The superconducting transition temperature reduces with applied magnetic field as expected. Ginzburg-Landau fitting revealed a 0 K critical magnetic field and coherence length of 18 T and 4.2 nm for the 30 nm $\delta$-TaN film and 96 mT and 59 nm for the 38 nm $\gamma$-Ta$_2$N film. These tantalum nitride films are of high interest for superconducting resonators and qubits.

cond-mat.supr-con

Shubnikov-de Haas oscillations in coherently strained AlN/GaN/AlN quantum wells on bulk AlN substrates

We report the observation of Shubnikov-de Haas (SdH) oscillations in coherently strained, low-dislocation AlN/GaN/AlN quantum wells (QWs), including both undoped and $\delta$-doped structures. SdH measurements reveal a single subband occupation in the undoped GaN QW and two subband occupation in the $\delta$-doped GaN QW. More importantly, SdH oscillations enable direct measurement of critical two-dimensional electron gas (2DEG) parameters at the Fermi level: carrier density and ground state energy level, electron effective mass ($m^* \approx 0.289\,m_{\rm e}$ for undoped GaN QW and $m^* \approx 0.298\,m_{\rm e}$ for $\delta$-doped GaN QW), and quantum scattering time ($\tau_{\rm q} \approx 83.4 \, \text{fs}$ for undoped GaN QW and $\tau_{\rm q} \approx 130.6 \, \text{fs}$ for $\delta$-doped GaN QW). These findings provide important insights into the fundamental properties of 2DEGs that are strongly quantum confined in the thin GaN QWs, essential for designing nitride heterostructures for high-performance electronic applications.

cond-mat.mtrl-sci