arXiv subjects

Detlef Lohse

Publications and source records attributed to Detlef Lohse.

At least 37 records · Page 2Linked to original sources

arXiv2025

Why and when merging surface nanobubbles jump

Gas bubble accumulation on substrates reduces the efficiency of many physicochemical processes, such as water electrolysis. For microbubbles, where buoyancy is negligible, coalescence-induced jumping driven by the release of surface energy provides an efficient pathway for their early detachment. At the nanoscale, however, gas compressibility breaks volume conservation during coalescence, suppressing surface energy release and seemingly disabling this detachment route. Using molecular dynamics simulations, continuum numerical simulations, and theoretical analysis, we show that surface nanobubbles with sufficiently large contact angles can nevertheless detach after coalescence. In this regime, detachment is powered by the release of pressure energy associated with nanobubble volume expansion. This finding thus establishes a unified driving mechanism for coalescence-induced bubble detachment across all length scales.

cond-mat.soft↗

arXiv2025

Solute mixing in porous media with dispersion and buoyancy

We analyse the process of convective mixing in two-dimensional, homogeneous and isotropic porous media with dispersion. We considered a Rayleigh-Taylor instability in which the presence of a solute produces density differences driving the flow. The effect of dispersion is modelled using an anisotropic Fickian dispersion tensor (Bear, J. Geophys. Res. 1961). In addition to molecular diffusion ($D_m^*$), the solute is redistributed by an additional spreading, in longitudinal and transverse flow directions, which is quantified by the coefficients $D_l^*$ and $D_t^*$, respectively, and it is produced by the presence of the pores. The flow is controlled by three dimensionless parameters: the Rayleigh-Darcy number $Ra$, defining the relative strength of convection and diffusion, and the dispersion parameters $r=D_l^*/D_t^*$ and $Δ=D_m^*/D_t^*$. With the aid of numerical Darcy simulations, we investigate the mixing dynamics without and with dispersion. We find that in absence of dispersion ($Δ\to\infty$) the dynamics is self-similar and independent of $Ra$, and the flow evolves following several regimes, which we analyse. Then we analyse the effect of dispersion on the flow evolution for a fixed value of the Rayleigh-Darcy number ($Ra=10^4$). A detailed analysis of the molecular and dispersive components of the mean scalar dissipation reveals a complex interplay between flow structures and solute mixing. The proposed theoretical framework, in combination with pore-scale simulations and bead packs experiments, can be used to validate and improve current dispersion models to obtain more reliable estimates of solute transport and spreading in buoyancy-driven subsurface flows.

physics.flu-dyn↗

arXiv2025

Symmetry Breaking in Chemical Systems: Engineering Complexity through Self-Organization and Marangoni Flows

Far from equilibrium, chemical and biological systems can form complex patterns and waves through reaction-diffusion coupling. Fluid motion often interferes with these self-organized concentration patterns. In this study, we investigate the influence of Marangoni-driven flows inside a thin layer of fluid ascending the outer surfaces of hydrophilic obstacles on the spatio-temporal dynamics of chemical waves in the modified Belousov-Zhabotinsky reaction. Our observations reveal that circular waves originate nearly simultaneously at the obstacles and propagate outward. In a covered setup, where evaporation is minimal, the wavefronts maintain their circular shape. However, in an uncovered setup with significant evaporation and resulting Marangoni flows, the interplay between surface tension-driven Marangoni flows and gravity destabilizes the wavefronts, creating distinctive flower-like patterns around the obstacles. Our analysis shows that here solutal Marangoni forces are more relevant than thermal ones. Our experiments further show that the number of petals formed increases linearly with the obstacle's diameter, though a minimum diameter is required for these instabilities to appear. These findings demonstrate the potential to 'engineer' specific wave patterns, offering a method to control and direct reaction dynamics. This capability is especially important for developing microfluidic devices requiring precise control over chemical wave propagation.

physics.flu-dyn↗

arXiv2025

Internal flow and concentration in neighbouring evaporating binary droplets and rivulets

In this paper, the evaporation of neighbouring multi-component droplets or rivulets - often found in applications such as inkjet printing, spray cooling, and pesticide delivery - is studied numerically and theoretically. The proximity induces a shielding effect that reduces individual evaporation rates and disrupts the symmetry of both the concentration profile and the flow field in the liquids. We examine how the symmetry of flow and concentration fields is affected by key parameters, namely the contact angle, the inter-droplet (or inter-rivulet) distance, and the magnitude of surface tension gradient forces (i.e. the Marangoni number). We focus on binary mixtures, such as water and 1,2-hexanediol, where only one component evaporates and evaporation is slow, thereby allowing simplifications to the governing equations. To manage the complexity of the full three-dimensional droplet problem, we begin with a two-dimensional model of neighbouring rivulets. Solving the complete transient equations for rivulets with pinned contact lines and fixed inter-rivulet distance reveals that the asymmetry - quantified by the position of the interfacial stagnation point of the flow - diminishes over time. Using a validated quasi-stationary model, we find, with increasing contact angle and inter-rivulet distance, that the stagnation point migrates closer to the centre, yet it remains unaffected by the Marangoni number. A simplified lubrication model applied to droplets shows similar dependencies on contact angle and distance, although here the stagnation point appears to vary with the Marangoni number. We attribute this dependence to the additional azimuthal flow in droplets, leading to a non-linear evolution of the concentration and therefore a non-trivial dependence of the symmetry on the Marangoni number.

physics.flu-dyn↗

arXiv2025

Non-monotonic surface tension leads to spontaneous symmetry breaking in a binary evaporating drop

The evaporation of water/1,2-hexanediol binary drops shows remarkable segregation dynamics, with hexanediol-rich spots forming at the rim, thus breaking axisymmetry. While the segregation of hexanediol near the rim can be attributed to the preferential evaporation of water, the symmetry-breaking and spot formation could not yet be successfully explained. With three-dimensional simulations and azimuthal stability analysis of a minimal model, we investigate the flow and composition in the drop. We show that a slightly non-monotonic surface tension causes the emergence of a counter-rotating Marangoni vortex in the hexanediol-rich rim region, which subsequently becomes azimuthally unstable and forms the observed spots. Accurate measurements with several different methods reveal that the surface tension is indeed non-monotonic. This work provides valuable insight for applications like inkjet printing or spray cooling.

physics.flu-dyn↗

arXiv2025

Hidden in plain sight: How evaporation impacts the pendant drop method

The surface tension of a liquid, which drives most free surface flows at small scales, is often measured with the pendant drop method due to its simplicity and reliability. When the drop is suspended in air, controlling the ambient temperature and humidity is usually an afterthought, resulting in evaporation of the drop during the measurement. Here, we investigate the effect of evaporation on the measured surface tension using experiments and numerical simulations. In the experiments, we measured the evolution of the droplet temperature, which can drastically reduce by ($ΔT \approx 10 \degC$) due to evaporative cooling, and thereby altering the measured surface tension by more than 1 mN/m. This finding can be reproduced by numerical simulations, which additionally allows for controlled investigations of the individual influences of further effects on the pendant drop method, namely shape deformations by evaporation-driven flows in the gas-phase and in the liquid-phase including the resulting Marangoni flow. We provide a simple passive method to control the relative humidity without requiring additional instrumentation. Our findings are particularly pertinent to Marangoni flows which are driven by surface tension gradients, and which are consequently highly sensitive to measurement inaccuracies. We apply our method with different aqueous mixtures of glycerol and various diols. Our results and insights have implications for various applications, ranging from inkjet printing to agricultural sprays. Finally, we have meticulously documented our setup and procedure for future reference.

physics.flu-dyn↗

arXiv2025

Buoyancy-driven flow regimes for a melting vertical ice cylinder in saline water

The presence of salt in seawater significantly affects the melt rate and morphological evolution of ice. This study investigates the melting process of a vertical cylinder in saline water using a combination of laboratory experiments and direct numerical simulations. The two-dimensional (2D) direct numerical simulations and 3D experiments achieve thermal Rayleigh numbers up to $\text{Ra}_{T}= \mathcal{O}\left(10^{9}\right)$ and saline Rayleigh numbers up to $\text{Ra}_{S}=\mathcal{O}\left(10^{12}\right)$. Some 3D simulations of the vertical ice cylinder are conducted at $\text{Ra}_{T}= \mathcal{O}\left(10^{5}\right)$ to confirm that the results in 2D simulations are qualitatively similar to those in 3D simulations. The mean melt rate exhibits a non-monotonic relationship with ambient salinity. With increasing salinity, the mean melt rate initially decreases towards the point where thermal and saline effects balance, after which it increases again. Based on the ambient salinity, the flow can be categorized into three regimes: temperature-driven flow, salinity-driven flow, and thermal-saline competing flow. In the temperature-driven and competing flow regimes, we find that the mean melt rate follows a $\text{Ra}_{T_d}^{1/4}$ scaling. In contrast, in the salinity-driven flow regime, we see a transition from a $\text{Ra}_{T_d}^{1/4}$ to a $\text{Ra}_{T_d}^{1/3}$ scaling. Additionally, the mean melt rate follows a $\text{Ra}_{S_d}^{1/3}$ scaling in this regime. The ice cylinder develops distinct morphologies in different flow regimes. In the thermal-saline competing flow regime, distinctive scallop (dimpled) patterns emerge along the ice cylinder due to the competition between thermal buoyancy and saline buoyancy. We observe these scallop patterns to migrate downwards over time, due to local differences in the melt rate, for which we provide a qualitative explanation.

physics.flu-dyn↗

arXiv2025

Pinning induced motion and internal flow in neighbouring evaporating multi-component drops

The evaporation of multi-component sessile droplets is key in many physicochemical applications such as inkjet printing, spray cooling, and micro-fabrication. Past fundamental research has primarily concentrated on single drops, though in applications they are rarely isolated. Here, we experimentally explore the effect of neighbouring drops on the evaporation process, employing direct imaging, confocal microscopy, and PTV. Remarkably, the centres of the drops move away from each other rather than towards each other, as we would expect due to the shielding effect at the side of the neighbouring drop and the resulting reduced evaporation on that side. We find that pinning-induced motion mediated by suspended particles in the droplets is the cause of this counter-intuitive behaviour. Finally, the azimuthal dependence of the radial velocity in the drop is compared to the evaporative flux and a perfect agreement is found.

physics.flu-dyn↗

arXiv2025

Bistability in radiatively heated melt ponds

Melting and solidification processes, intertwined with convective flows, play a fundamental role in geophysical contexts. One of these processes is the formation of melt ponds on glaciers, ice shelves, and sea ice. It is driven by solar radiation and is of great significance for the Earth's heat balance, as it significantly lowers the albedo. Through direct numerical simulations and theoretical analysis, we unveil a bistability phenomenon in the melt pond dynamics. As solar radiation intensity and the melt pond's initial depth vary, an abrupt transition occurs: This tipping point transforms the system from a stable fully frozen state to another stable equilibrium state, characterized by a distinct melt pond depth. The physics of this transition can be understood within a heat flux balance model, which exhibits excellent agreement with our numerical results. Together with the Grossmann-Lohse theory for internally heated convection, the model correctly predicts the bulk temperature and the flow strength within the melt ponds, offering insight into the coupling of phase transitions with adjacent turbulent flows and the interplay between convective melting and radiation-driven processes.

physics.flu-dyn↗

arXiv2025

Melting of floating ice cylinders in fresh and saline environments

We experimentally investigated the melting of floating ice cylinders. Experiments were carried out in a tank, with ice cylinders with radii between 5 cm and 12 cm, floating horizontally with their axis perpendicular to gravity. The water in the tank was at room temperature, with salinities ranging from 0 g/L to 35 g/L. These conditions correspond to Rayleigh numbers in the range $10^5 \lesssim \mathrm{Ra} \lesssim 10^9$. The relative density and thus the floating behaviour was varied by employing ice made of H$_2$O-D$_2$O mixtures. In addition, we explored a two-layer stable stratification. We studied the morphological evolution of the cross-section of the cylinders and interpreted our observations in the context of their interaction with the convective flow. The cylinders only capsize in fresh water but not when the ambient is saline. This behaviour can be explained by the balance between the torques exerted by buoyancy and drag, which change as the cylinder melts and rotates. We modelled the oscillatory motion of the cylinders after a capsize as a damped non-linear oscillator. The downward plume of the ice cylinders follows the expected scalings for a line-source plume. The plume's Reynolds number scales with Rayleigh number in two regimes, namely $\mathrm{Re} \propto \mathrm{Ra}^{1/2}$ for $\mathrm{Ra} < O(10^7)$ and $\mathrm{Re} \propto \mathrm{Ra}^{1/3}$ for $\mathrm{Ra} > O(10^7)$, and the heat transfer (nondimensional as Nusselt number) scales as $\mathrm{Nu} \propto \mathrm{Ra}^{1/3}$. Although the addition of salt substantially alters the solutal, thermal and momentum boundary layers, these scaling relations hold irrespectively of the initial size or the water salinity. While important differences exist between our experiments and real icebergs, our results can qualitatively be connected to natural phenomena occurring in fjords and around isolated icebergs.

physics.flu-dyn↗

arXiv2025

Viscoelasticity reduces the droplet size in mucosalivary film fragmentation during intense respiratory events

We examine the fundamental fluid dynamical mechanisms dictating the generation of bioaerosols in the human trachea during intense respiratory events such as coughing and sneezing, with an emphasis on the role played by the mucosalivary fluid viscoelasticity. An experimental investigation of the shear-induced fragmentation of a mucosalivary-mimetic fluid in a confined geometry reveals that viscoelastic liquids undergo atomization in a manner akin to Newtonian liquids -- via the formation of bag-like structures -- which ultimately rupture through the appearance of retracting holes on the bag surface. Droplets are produced via the unstable retraction of liquid rims bounding these holes. However, in comparison to Newtonian liquids, viscoelastic bags inflate to larger sizes -- implying thinner sheets and, consequently smaller droplets upon rupture. Numerical simulations support that the smaller droplets can be attributed to the thinner sheets, with a more uniform thickness, for viscoelastic bags prior to rupture. Hence, we highlight the role of the viscoelasticity in determining the thickness of the intermediate bag-like structures, which, in turn, govern the droplet size distribution of the expelled aerosol.

physics.flu-dyn↗

arXiv2025

Viscoelastic Worthington jets & droplets produced by bursting bubbles

Bubble bursting and subsequent collapse of the open cavity at free surfaces of contaminated liquids can generate aerosol droplets, facilitating pathogen transport. After film rupture, capillary waves focus at the cavity base, potentially generating fast Worthington jets that are responsible for ejecting the droplets away from the source. While extensively studied for Newtonian fluids, the influence of non-Newtonian rheology on this process remains poorly understood. Here, we employ direct numerical simulations to investigate the bubble cavity collapse in viscoelastic media, such as polymeric liquids. We find that the jet and drop formation are dictated by two dimensionless parameters: the elastocapillary number $Ec$ (the ratio of the elastic modulus and the Laplace pressure) and the Deborah number $De$ (the ratio of the relaxation time and the inertio-capillary timescale). We show that for low values of $Ec$ and $De$, the viscoelastic liquid adopts a Newtonian-like behavior, where the dynamics are governed by the solvent Ohnesorge number $Oh_s$ (the ratio of visco-capillary and inertio-capillary timescales). In contrast, for large values $Ec$ and $De$, the enhanced elastic stresses completely suppress the formation of the jet. For some cases with intermediate values of $Ec$ and $De$, smaller droplets are produced compared to Newtonian fluids, potentially enhancing aerosol dispersal. By mapping the phase space spanned by $Ec$, $De$, and $Oh_s$, we reveal three distinct flow regimes: (i) jets forming droplets, (ii) jets without droplet formation, and (iii) absence of jet formation. Our results elucidate the mechanisms underlying aerosol suppression versus fine spray formation in polymeric liquids, with implications for pathogen transmission and industrial processes involving viscoelastic fluids.

physics.flu-dyn↗

arXiv2025

Marangoni flow driven hysteresis and azimuthal symmetry breaking in evaporating binary droplets

The non-uniform evaporation rate at the liquid-gas interface of binary droplets induces solutal Marangoni flows. In glycerol-water mixtures (positive Marangoni number, where the more volatile fluid has higher surface tension), these flows stabilise into steady patterns. Conversely, in water-ethanol mixtures (negative Marangoni number, where the less volatile fluid has higher surface tension), Marangoni instabilities emerge, producing seemingly chaotic flows. This behaviour arises from the opposing signs of the Marangoni number. Perturbations locally reducing surface tension at the interface drive Marangoni flows away from the perturbed region. Incompressibility enforces a return flow, drawing fluid from the bulk towards the interface. In mixtures with a negative Marangoni number, preferential evaporation of the lower-surface-tension component leads to a higher concentration of the higher-surface-tension component at the interface as compared to the bulk. The return flow therefore creates a positive feedback loop, further reducing surface tension and enhancing the instability. We investigate bistable quasi-stationary solutions in evaporating binary droplets with negative Marangoni numbers and we examine symmetry breaking across a range of Marangoni number and contact angles. Remarkably, droplets with low contact angle show instabilities at lower critical Marangoni numbers than droplets with larger contact angles. Our numerical simulations reveal that interactions between droplet height profiles and non-uniform evaporation rates trigger azimuthal Marangoni instabilities in flat droplets. This geometrically confined instability can even destabilise mixtures with positive Marangoni numbers, particularly for concave liquid-gas interfaces. Finally, through Lyapunov exponent analysis, we confirm the chaotic nature of flows in droplets with a negative Marangoni number.

physics.flu-dyn↗

arXiv2025

Frozen Cheerios effect: Particle-particle interaction induced by an advancing solidification front

Particles at liquid interfaces have the tendency to cluster due to capillary forces competing with gravitational buoyancy (i.e., normal to the distorted free surface). This is known as the Cheerios effect. Here we experimentally and theoretically study the interaction between two submerged particles near an advancing water-ice interface during the freezing process. Particles that are thermally more conductive than water are observed to attract each other and form clusters once frozen. We call this feature the frozen Cheerios effect, where interactions are driven by alterations to the direction of the experienced repelling force (i.e., normal to the distorted isotherm). On the other hand, particles less conductive than water separate, highlighting the importance of thermal conduction during freezing. Based on existing models for single particle trapping in ice, we develop an understanding of multiple particle interaction. We find that the overall efficacy of the particle-particle interaction critically depends on the solidification front velocity. Our theory explains why the thermal conductivity mismatch between the particles and water dictates the attractive/repulsive nature of the particle-particle interaction.

cond-mat.soft↗

arXiv2025

Unifying theory of scaling in drop impact: Forces & maximum spreading diameter

The dynamics of drop impact on a rigid surface -- omnipresent in nature and technology -- strongly depends on the droplet's velocity, its size, and its material properties. The main characteristics are the droplet's force exerted on the surface and its maximal spreading radius. The crucial question is: How do they depend on the (dimensionless) control parameters, which are the Weber number $We$ (non-dimensionalized kinetic energy) and the Ohnesorge number $Oh$ (dimensionless viscosity)? Here we perform direct numerical simulations over the huge parameter range $1\le We \le 10^3$ and $10^{-3}\le Oh \le 10^2$ and in particular develop a unifying theoretical approach, which is inspired by the Grossmann-Lohse theory for wall-bounded turbulence [J. Fluid Mech. 407, 27 (2000); PRL 86, 3316 (2001)]. The key idea is to split the energy dissipation rate into the different phases of the impact process, in which different physical mechanisms dominate. The theory can consistently and quantitatively account for the $We$ and $Oh$ dependences of the maximal impact force and the maximal spreading diameter over the huge parameter space. It also clarifies why viscous dissipation plays a significant role during impact, even for low-viscosity droplets (low $Oh$), in contrast to what had been assumed in prior theories.

physics.flu-dyn↗

arXiv2025

Evaporating sessile droplets: solutal Marangoni effects overwhelm thermal Marangoni flow

When an evaporating water droplet is deposited on a thermally conductive substrate, the minimum temperature will be at the apex due to evaporative cooling. Consequently, density and surface tension gradients emerge within the droplet and at the droplet-gas interface, giving rise to competing flows from, respectively, the apex towards the contact line (thermal-buoyancy-driven flow) and the other way around (thermal Marangoni flow). In small droplets with a diameter below the capillary length, the thermal Marangoni effects are expected to dominate over thermal buoyancy ("thermal Rayleigh") effects. However, contrary to these theoretical predictions, our experiments mostly show a dominant circulation from the apex towards the contact line, indicating a prevailing of thermal Rayleigh convection. Furthermore, our experiments often show an unexpected asymmetric flow that persisted for several minutes. We hypothesise that a tiny amount of contaminants, commonly encountered in experiments with water/air interfaces, act as surfactants and counteract the thermal surface tension gradients at the interface and thereby promote the dominance of Rayleigh convection. Our finite element numerical simulations demonstrate that, under our specified experimental conditions, a mere 0.5% reduction in the static surface tension caused by surfactants leads to a reversal in the flow direction, compared to the theoretical prediction without contaminants. Additionally, we investigate the linear stability of the axisymmetric solutions, revealing that the presence of surfactants also affects the axial symmetry of the flow.

physics.flu-dyn↗

arXiv2025

The role of viscosity on drop impact forces on non-wetting surfaces

A liquid drop impacting a rigid substrate undergoes deformation and spreading due to normal reaction forces, which are counteracted by surface tension. On a non-wetting substrate, the drop subsequently retracts and takes off. Our recent work (Zhang et al., \textit{Phys. Rev. Lett.}, vol. 129, 2022, 104501) revealed two peaks in the temporal evolution of the normal force $F(t)$ -- one at impact and another at jump-off. The second peak coincides with a Worthington jet formation, which vanishes at high viscosities due to increased viscous dissipation affecting flow focusing. In this article, using experiments, direct numerical simulations, and scaling arguments, we characterize both the peak amplitude $F_1$ at impact and the one at take off ($F_2$) and elucidate their dependency on the control parameters: the Weber number $We$ (dimensionless impact kinetic energy) and the Ohnesorge number $Oh$ (dimensionless viscosity). The first peak amplitude $F_1$ and the time $t_1$ to reach it depend on inertial timescales for low viscosity liquids, remaining nearly constant for viscosities up to 100 times that of water. For high viscosity liquids, we balance the rate of change in kinetic energy with viscous dissipation to obtain new scaling laws: $F_1/F_ρ\sim \sqrt{Oh}$ and $t_1/τ_ρ\sim 1/\sqrt{Oh}$, where $F_ρ$ and $τ_ρ$ are the inertial force and time scales, respectively, which are consistent with our data. The time $t_2$ at which the amplitude $F_2$ appears is set by the inertio-capillary timescale $τ_γ$, independent of both the viscosity and the impact velocity of the drop. However, these properties dictate the magnitude of this amplitude.

physics.flu-dyn↗

arXiv2025

A front-tracking immersed-boundary framework for simulating Lagrangian melting problems

In so-called Lagrangian melting problems, a solid immersed in a fluid medium is free to rotate and translate in tandem with its phase-change from solid to liquid. Such configurations may be classified as a fluid-solid interaction (FSI) problem coupled to phase-change. Our present work proposes a numerical method capable of simulating these Lagrangian melting problems and adopts a front-tracking immersed-boundary (IB) method. We use the moving least squares IB framework, a well-established method for simulating a diverse range of FSI problems and extend this framework to accommodate melting by additionally imposing the Stefan condition at the interface. In the spirit of canonical front-tracking methods, the immersed solid is represented by a discrete triangulated mesh which is separate from the Eulerian mesh in which the governing flow equations are solved. A known requirement for these methods is the need for comparable Eulerian and Lagrangian grid spacings to stabilise interpolation and spreading operations between the two grids. For a melting object, this requirement is inevitably violated unless interventional remeshing is introduced. Our work therefore presents a novel dynamic remeshing procedure to overcome this. The remeshing is based on a gradual coarsening of the triangulated Lagrangian mesh and amounts to a negligible computational burden per timestep owing to the incremental and local nature of its operations, making it a scalable approach. Moreover, the coarsening is coupled to a volume-conserving smoothing procedure detailed by Kuprat et al. (2001), ensuring a zero net volume change in the remeshing step to machine precision. This added feature makes our present method highly specialised to the study of melting problems, where precise measurements of the melting solid's volume is often the primary predictive quantity of interest.

physics.flu-dyn↗