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Dhruvajyoti Barah

Publications and source records attributed to Dhruvajyoti Barah.

2 recordsLinked to original sources

Mask-free fast patterning of organic light-emitting diode pixels using laser-assisted close-space sublimation

Existing patterning processes for organic light-emitting diode displays offer micrometer-scale precision but are constrained by long processing times for large-area substrates. In this work, we study a fast growth method for patterned organic film deposition, aimed at applications including active-matrix organic light-emitting diode displays. The approach employs a specially engineered donor substrate in a close-space sublimation configuration combined with laser heating. The donor substrate incorporates spatially patterned absorber and reflector layers that enable selective, one-step or two-step transfer of organic material onto a receiver substrate. We analyze the optical response and heat-transfer dynamics that govern the selective transfer mechanism and demonstrate precise pixel patterning with micrometer-scale spatial fidelity. The reliability and practical applicability of the method are validated by fabricating light-emitting diode devices by using this rapid transfer process and benchmarking their performance against devices produced via conventional vacuum thermal evaporation. The resulting devices exhibit comparable optoelectronic performance, confirming the robustness and technological relevance of the proposed strategy for scalable fabrication of patterned organic light-emitting diodes for display application.

physics.optics↗

Nature of excitons in PPDT2FBT: PCBM solar cell: Role played by PCBM

In organic semiconductor based bulk heterojunction solar cells, the presence of acceptor increases the formation of charge transfer (CT) excitons, thereby leading to higher exciton dissociation probabilities. In this work we used steady state EA measurements to probe the change in the nature of excitons as the blend composition of the solar cell active layer material is varied. We investigated blends of poly[(2,5-bis(2-hexyldecyloxy)phenylene)-alt-(5,6-difluoro-4,7-di(thiophen-2-yl)benzo[c]-[1,2,5]thiadiazole)] (PPDT2FBT) and (6,6)-Phenyl C71 butyric acid methyl ester (PCBM). Analysis of the EA spectra showed that in presence of fullerene based acceptor, like PCBM, CT characteristics of the excitons were modified, though, no new CT signature was observed in the blend. Enhancement in the CT characteristic in the blend was reflected in the photoluminescence (PL) measurements of the blends, where, PL quenching of $\sim$ 63\% was observed for 1\% PCBM. The quenching reaches saturation at about 20\% PCBM. However, the maximum efficiency of the devices was obtained for the blend having 50\% PCBM. Comparing experimental results with simulations, the variation of the device efficiency with PCBM percentage was shown to be arising from multiple factors like increase in polarizability and dipole moment of excitons, and the efficiency of the carrier collection from the bulk of the active layer.

physics.app-ph↗