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Di Zhou

Publications and source records attributed to Di Zhou.

At least 19 recordsLinked to original sources

Yttrium Superhydrides Revisited: Advanced Experimental and Theoretical Studies of YH$_6$, YH$_9$ and YH$_{10}$

Yttrium polyhydrides are benchmark materials in high-pressure superconductivity, yet several key properties of the Y-H system remain insufficiently characterized. Here we combine contact transport, contactless radio-frequency measurements, pulsed-field experiments, and first-principles calculations to reinvestigate YH$_6$, YH$_9$, and YH$_{10}$ in the pressure range 140-213 GPa. Yttrium hydrides YH$_6$ ($\textit{$T_c$}$ = 218-221 K) and YH$_9$ ($\textit{$T_c$}$ = 235-237 K) demonstrate narrow superconducting transitions ($\textit{${\Delta}$T$_c$}$ = 2-5 K), approaching the limit imposed by thermal fluctuations. Pulsed-field measurements on YH$_6$ up to 60 T establish an extended superconducting phase diagram with a linear slope $\textit{dB$_{c2}$/dT}$ = -0.52 T/K, pronounced transition broadening above 30 T, and negligible normal-state magnetoresistance. We report the radio-frequency AC susceptibility study of YH$_6$, providing evidence for superconductivity via high-frequency field screening in a contactless geometry. Experiments involving Pd incorporation, Pd thin-film sputtering, and Al alloying show strong suppression of high-temperature superconductivity, with no transitions detected above 78-120 K. Finally, using density-functional theory with the stochastic self-consistent harmonic approximation, superconducting density-functional theory, and full-bandwidth Migdal-Eliashberg calculations, we show that anharmonic effects substantially reduce the predicted $\textit{$T_c$}$ of cubic YH$_{10}$ to approximately 260-270 K. These results strongly disfavor room-temperature superconductivity in binary yttrium superhydrides.

cond-mat.supr-con

3D Topologically Polarized Elastic Metamaterials Enable Asymmetric Energy Isolation at Low Frequencies

Topologically polarized elasticity has been extensively studied in lower-dimensions, yet its three-dimensional (3D) counterpart remains largely unexplored. Here, we demonstrate omnidirectional topological elasticity in 3D structures that incorporate bending stiffness, which elevates zero-frequency topological mechanical states into finite-frequency phononic modes. These modes are localized at a single boundary, creating a pronounced stiffness contrast in both static and finite-frequency dynamic regimes. This three-dimensional structure exhibits highly polarized mechanical behavior across all spatial dimensions, establishing omnidirectional asymmetric topological elasticity. Experimental and numerical results confirm robust, asymmetric energy isolation, arising from the interplay between bulk topological polarization and boundary-localized surface modes. Our findings establish a paradigm for 3D metamaterials, with promising applications in vibration shielding and directional wave manipulation.

cond-mat.soft

Stability Analysis of Superconductivity in $\textit{P6/mmm}$-LaSc$_2$H$_{24}$ and its Experimental Reproducibility from La-Sc Alloys

In this work, we analyze the feasibility of room-temperature superconductivity in the lanthanum-scandium hydride $\textit{P6/mmm}$-LaSc$_2$H$_{24}$. We demonstrate that the electron-phonon coupling calculations performed using the ${\sigma}$-broadening of the double ${\delta}$-function at the Fermi surface lead to a very strong dependence of $\textit{T$_c$}({\sigma})$ on the arbitrary ${\sigma}$, whereas the tetrahedral method for the electron-phonon interaction is free from this drawback and leads to $\textit{T$_c$}$ > 300 K at 300 GPa in agreement with previous predictions. By analyzing the stability of the metallic state of LaSc$_2$H$_{24}$ at 250-300 GPa, we show that this compound is at the edge of the stability region (${\xi}$ = 0.54), similar to $\textit{fcc}$ LaH$_{10}$ at 140-150 GPa. Seven experimental attempts to synthesize LaSc$_2$H$_{24}$ at 250-280 GPa starting from the (La,Sc$_2$) alloy are unsuccessful and indicate the absence of even traces of superconductivity at 245-300 K in all the resulting La-Sc-H hydrides. The method for preparing the precursor by simultaneous deposition of La and Sc metals may be a key factor for the successful synthesis of LaSc$_2$H$_{24}$.

cond-mat.supr-con

Smoothing the Landscape: Causal Structure Learning via Diffusion Denoising Objectives

Understanding causal dependencies in observational data is critical for informing decision-making. These relationships are often modeled as Bayesian Networks (BNs) and Directed Acyclic Graphs (DAGs). Existing methods, such as NOTEARS and DAG-GNN, often face issues with scalability and stability in high-dimensional data, especially when there is a feature-sample imbalance. Here, we show that the denoising score matching objective of diffusion models could smooth the gradients for faster, more stable convergence. We also propose an adaptive k-hop acyclicity constraint that improves runtime over existing solutions that require matrix inversion. We name this framework Denoising Diffusion Causal Discovery (DDCD). Unlike generative diffusion models, DDCD utilizes the reverse denoising process to infer a parameterized causal structure rather than to generate data. We demonstrate the competitive performance of DDCDs on synthetic benchmarking data. We also show that our methods are practically useful by conducting qualitative analyses on two real-world examples. Code is available at this url: https://github.com/haozhu233/ddcd.

cs.LG

Mechanical Origin of High-Temperature Thermal Stability in Platinum Oxides

Platinum oxides are vital catalysts, but their limited thermal stability hinders applications. Recent studies have uncovered a structural transition in two-dimensional platinum oxides that significantly enhances their thermal resilience by several hundred Kelvin. Herein, we demonstrate that this enhanced stability stems from the mechanical robustness of the elastic network at the atomic scale. Prior to the transition, an over-constrained lattice generates localized states of self-stress through an incommensurate Moir\'{e} pattern with the platinum substrate, reducing thermal endurance. After the transition, the oxide shifts to a mechanically flexible structure with balanced degrees of freedom and constraints. The isostatic network, together with the platinum substrate, forms a commensurate Moir\'{e} superlattice that relaxes elastic energy and enhances stability. These findings highlight the fundamental role of network connectivity in governing thermal stability, and provide a design principle for catalysts in extreme environments.

cond-mat.mtrl-sci

Superhydrides on the way to ambient pressure: weak localization and persistent X-ray photoconductivity in BaSiH$_{8}$

Reducing the stabilization pressure of superhydrides represents one of the most important challenges in hydrogen-saturated compound chemistry. Moving in this direction, we studied the Ba-Si-H system at 0-142 GPa using transport measurements, 1H nuclear magnetic resonance, single-crystal and powder X-ray diffraction in the temperature range of 4-317 K. We synthesized the previously predicted cubic BaSiH$_{8}$ at pressures of 18-31 GPa. Remarkably, we demonstrate that BaSiH$_8$ remains stable upon decompression to ambient conditions and can be recovered from the diamond anvil cell. Obtained Ba-Si polyhydrides exhibit metallic and superconducting properties ($\textit{T$_c$}$ = 9 K, $\textit{B$_{c2}$}$(0)=13-16 T) at 142 GPa. However, at pressures below 50 GPa, these hydrides behave as degenerate semiconductors (bandgap < 0.4 meV) or poor metals with weak electron localization, negative magnetoresistance, photovoltaic effect, and persistent photoconductivity in the X-ray and visible range. Our work demonstrates the high-pressure synthesis of Ba-Si polyhydrides that remain stable upon decompression to ambient conditions, overcoming a critical bottleneck in superhydride chemistry and establishing a foundation for practical applications in hydrogen storage.

cond-mat.supr-con

Phonon Echo from Multi-Level Systems and Many-Body Interactions in Low-Temperature Glasses

At low temperatures, glasses exhibit distinctive properties compared to crystalline solids. A notable example is the phonon echo, a phenomenon that motivated the two-level-system (TLS) model. This model has successfully explained many universal anomalies in glasses. Here, we extend the TLS framework to a multi-level system and show that phonon echoes persist when nonlinear energy structures and disorder are included. By incorporating virtual phonon exchange, we introduce many-body interactions between these multi-level systems, leading to nonlinear eigen-energies that enhance the echo signal. Meanwhile, finite-temperature thermal fluctuations cause dephasing, resulting in a decay of echo amplitude over time. The analytical and numerical results are consistent across semi-classical and quantum regimes. Our work validates the multi-level-system model and underscores the role of many-body interactions in low-temperature glassy dynamics.

cond-mat.dis-nn

Radio-Frequency Gasket for Studies of Superconductivity in Diamond Anvil Cells

This work presents the development and testing of a novel radio-frequency (RF) gasket with a Lenz lens surface geometry for contactless measurements in diamond anvil cells (DACs). Conventional RF approaches, which fabricate the Lenz lens onto the diamond anvil itself, preclude the placement of electrical circuits. Our method overcomes this limitation by transferring the RF sensor to a composite Ta-based gasket. The sensor consists of single-turn microcoils that are formed by magnetron sputtering a gold film onto an insulating Ta$_2$O$_5$ layer. The Lenz lens topology is then patterned using focused ion beam etching. We validated this technique using polycrystalline Cu1234 and Bi2212 high-$\textit{T$_c$}$ superconductors at ambient and high pressures. The measurements consistently identified the superconducting transition temperature across carrier frequencies from 111 kHz to 200 MHz. This new gasket technique establishes a reliable and sensitive tool for contactless studies of superconductivity under high pressure.

cond-mat.supr-con

Regional Resource Management for Service Provisioning in LEO Satellite Networks: A Topology Feature-Based DRL Approach

Satellite networks with wide coverage are considered natural extensions to terrestrial networks for their long-distance end-to-end (E2E) service provisioning. However, the inherent topology dynamics of low earth orbit satellite networks and the uncertain network scales bring an inevitable requirement that resource chains for E2E service provisioning must be efficiently re-planned. Therefore, achieving highly adaptive resource management is of great significance in practical deployment applications. This paper first designs a regional resource management (RRM) mode and further formulates the RRM problem that can provide a unified decision space independent of the network scale. Subsequently, leveraging the RRM mode and deep reinforcement learning framework, we develop a topology feature-based dynamic and adaptive resource management algorithm to combat the varying network scales. The proposed algorithm successfully takes into account the fixed output dimension of the neural network and the changing resource chains for E2E service provisioning. The matched design of the service orientation information and phased reward function effectively improves the service performance of the algorithm under the RRM mode. The numerical results demonstrate that the proposed algorithm with the best convergence performance and fastest convergence rate significantly improves service performance for varying network scales, with gains over compared algorithms of more than 2.7%, 11.9%, and 10.2%, respectively.

cs.NI

Effect of subgrid-scale anisotropy on wall-modeled large-eddy simulation of turbulent flow with smooth-body separation

We examine the role of anisotropic subgrid-scale (SGS) stress in wall-modeled large-eddy simulation (WMLES) of flow over a spanwise-uniform Gaussian-shaped bump, with emphasis on predicting flow separation. The simulations show that eddy-viscosity-based SGS models often yield non-monotonic predictions of the mean separation bubble size on the leeward side under grid refinement, whereas models incorporating anisotropic SGS stress produce more consistent results. To identify where SGS anisotropy is most critical, we introduce anisotropic SGS stress in selected regions of the domain. The results reveal that the windward side, where a strong favorable pressure gradient (FPG) occurs, is crucial in determining downstream separation. Analysis of the Reynolds stress transport equation shows that fluctuations of anisotropic SGS stress modify SGS dissipation and diffusion in this region, thereby altering the Reynolds stress and the onset of separation. Examination of the mean streamwise momentum equation indicates that at coarse resolutions, the mean SGS shear stress dominates, and the differences between the eddy-viscosity-based and anisotropic models remain minor. With grid refinement, resolved Reynolds stresses increasingly govern the near-wall momentum transport, and the influence of SGS stress fluctuations grows as they determine the SGS dissipation and diffusion of Reynolds stresses. Component-wise analysis of the SGS stress tensor further shows that the improvement arises mainly from including significant normal stress contributions. An a priori study using filtered direct numerical simulation of turbulent Couette-Poiseuille flow confirms that wall-bounded turbulence under FPG is highly anisotropic and that anisotropic SGS models provide a more realistic SGS stress representation than eddy-viscosity-based models.

physics.flu-dyn

Data-driven Sensor Placement for Predictive Applications: A Correlation-Assisted Attribution Framework (CAAF)

Optimal sensor placement (OSP) is critical for efficient, accurate monitoring, control, and inference in complex physical systems. We propose a machine-learning-based feature attribution (FA) framework to identify OSP for target predictions. FA quantifies input contributions to a model output; however, it struggles with highly correlated input data often encountered in practical applications for OSP. To address this, we propose a Correlation-Assisted Attribution Framework (CAAF), which introduces a clustering step on the candidate sensor locations before performing FA to reduce redundancy and enhance generalizability. We first illustrate the core principles of the proposed framework through a series of validation cases, then demonstrate its effectiveness in realistic dynamical systems such as structural health monitoring, airfoil lift prediction, and wall-normal velocity estimation for turbulent channel flow. The results show that the CAAF outperforms alternative approaches that typically struggle due to the presence of nonlinear dynamics, chaotic behavior, and multi-scale interactions, and enables the effective application of FA for identifying OSP in real-world environments.

cs.CE

Interlayer coupling enhanced superconductivity near 100 K in La$_{3-x}$Nd$_x$Ni$_2$O$_7$

Systematically controlling the superconducting transition temperature ($T_\text{c}$) in the bilayer Ruddlesden-Popper nickelate La$_3$Ni$_2$O$_7$ remains a significant challenge. Here, we address this by synthesizing high-quality polycrystalline La$_{3-x}$Nd$_x$Ni$_2$O$_7$ ($0 \leq x \leq 2.4$) with record-level rare-earth substitution. Nd doping compresses the lattice, particularly along the $c$ axis, enhances the spin density wave transition temperature, and elevates the pressure required for the orthorhombic-to-tetragonal structural transition. Superconductivity is observed across all doping levels under high pressures, with the onset $T_\text{c}$ rising to $\sim$93~K for $x = 2.1$ and $2.4$ from the electronic transport measurement. Using the radio-frequency transmission technique, newly applied to nickelate superconductors, we detect signatures of superconductivity at $98 \pm 2$~K in the $x=2.4$ compound, pushing the $T_\text{c}$ frontier further. We identify a universal linear relationship where $T_\text{c}$ decreases with the $c$-axis lattice parameter at a rate of approximately $-28$~K/\AA, demonstrating that enhanced interlayer magnetic exchange coupling is the dominant mechanism for superconducting pairing. Our work establishes the critical role of magnetism and provides a unified structural descriptor for elevating $T_\text{c}$ in bilayer nickelates.

cond-mat.supr-con

3C Resources Joint Allocation for Time-Deterministic Remote Sensing Image Backhaul in the Space-Ground Integrated Network

Low-Earth-orbit (LEO) satellites assist observation satellites (OSs) to compress and backhaul more time-determined images (TDI) has become a new paradigm, which is used to enhance the timeout caused by the limited computing resources of OSs. However, how to capture the time-varying and dynamic characteristics of multi-dimensional resources is challenging for efficient collaborative scheduling. Motivated by this factor, we design a highly succinct multi-dimensional resource time-expanded graph (MDR-TEG) modell. Specifically, by employing a slots division mechanism and introducing an external virtual node, the time-varying communication, caching, and computing (3C) resources are depicted in low complexity by the link weights within, between, and outside the slots. Based on the MDR-TEG, the maximizing successful transmission ratio of TDI (MSTR-TDI) is modeled as a mixed integer linear programming (MILP) problem. Which further relaxed decomposed into two tractable sub-problems: maximizing the successful transmission rate of images (MSTRI) and ensuring the timeliness problem (ETP). Subsequently, an efficient subgradient of relaxation computing constraint (SRCC) algorithm is proposed. The upper and lower bounds of MSTR-TDI are obtained by solving the two subproblems and the dual problem (DP), and the direction of the next iteration is obtained by feedback. Furthermore, arranging the sending sequences of images to improve the quality of the solution. The approximate optimal solution of MSTR-TDI is eventually obtained through repeated iterations. The simulation results verify the superiority of the proposed MDR-TEG model and the effectiveness of the SRCC.

eess.SY

Physics-informed Neural-operator Predictive Control for Drag Reduction in Turbulent Flows

Assessing turbulence control effects for wall friction numerically is a significant challenge since it requires expensive simulations of turbulent fluid dynamics. We instead propose an efficient deep reinforcement learning (RL) framework for modeling and control of turbulent flows. It is model-based RL for predictive control (PC), where both the policy and the observer models for turbulence control are learned jointly using Physics Informed Neural Operators (PINO), which are discretization invariant and can capture fine scales in turbulent flows accurately. Our PINO-PC outperforms prior model-free reinforcement learning methods in various challenging scenarios where the flows are of high Reynolds numbers and unseen, i.e., not provided during model training. We find that PINO-PC achieves a drag reduction of 39.0\% under a bulk-velocity Reynolds number of 15,000, outperforming previous fluid control methods by more than 32\%.

cs.LG

Stability and Superconductivity of Ternary Polyhydrides

We review five years of experimental and theoretical attempts (2020-2025) to enhance the superconducting critical temperature ($\textit{T$_c$}$) of hydrogen-rich compounds by alloying binary superhydrides with additional elements. Despite predictions of higher $\textit{T$_c$}$ in ternary systems such as La-Y-H, La-Ce-H, and Ca-Mg-H, experiments consistently show that the maximum $\textit{T$_c$}$ in disordered ternary superhydrides does not exceed that of the best binary parent hydrides within experimental uncertainty. Instead, alloying primarily stabilizes high-symmetry polyhydride phases at lower pressures, enabling $\textit{T$_c$}$ = 200 K near 110-120 GPa, while also improving vortex pinning and upper critical fields. Magnetic dopants suppress $\textit{T$_c$}$, whereas nonmagnetic additives leave it nearly unchanged, reminiscent of Anderson's theorem. These findings indicate that alloying is unlikely to raise $\textit{T$_c$}$, but can reduce the pressures required to stabilize high-$\textit{T$_c$}$ phases. We propose that fully ordered ternary hydrides, synthesized via controlled hydrogenation of intermetallic precursors, offer a promising route toward this goal. One of the most promising compounds of this kind is the recently discovered LaSc$_2$H$_{24}$.

cond-mat.supr-con

Radio-Frequency Method for Detecting Superconductivity Under High Pressure

We introduce a contactless technique for probing superconductivity and magnetic ordering transitions in micron-sized samples under extreme pressure. Utilizing a multistage Lenz lens system, directly sputtered onto diamond anvils, we realize a radio-frequency (RF, 50 kHz - 200 MHz) transformer with a sample of 50-100 $\mu$m in diameter, as its core. This configuration enables efficient transfer and focusing of an electromagnetic field within the diamond anvil cell's chamber. Consequently, the transmitted RF signal exhibits high sensitivity to variations in the sample's surface conductivity and magnetic permeability. We validate this method by determining the critical temperatures ($T_{\text{c}}$) of known superconductors, including NbTi, MgB$_2$, Hg-1223, Bi-2212, YBCO, and REBCO in various magnetic fields, as well as the magnetic ordering temperatures of Gd and Tb. Notably, we apply this technique to the LaH$_{10-x}$, CeH$_{9-10}$, and (La,Ce)H$_{10-12}$ superhydrides at a pressure of about 1-1.5 Mbar. The observed superconducting transitions in Ce and La superhydrides at 90-110 K and 215-242 K, respectively, correlate with the $T_{\text{c}}$'s determined via traditional electrical-resistance measurements. Moreover, we show how multiple repetitions of the RF experiment with the La-Ce superhydride make it possible to detect the increase in $T_{\text{c}}$ over time up to $\approx$ 260-270 K. This finding indicates the possibility of reaching a critical $T_{\text{c}}$ around 0$^\circ$C in the La-based superhydrides.

cond-mat.supr-con

Topological edge states and amplitude-dependent delocalization in quasiperiodic elliptically geared lattices

We present a class of mechanical lattices based on elliptical gears with quasiperiodic modulation and geometric nonlinearity, capable of exhibiting topologically protected modes and amplitude-driven transitions. Starting from a one-dimensional chain of modulated elliptical gears, we demonstrate the emergence of localized edge states arising from quasiperiodic variation in the gears' moments of inertia, analogous to the topological edge modes of the Aubry-Andre-Harper model. Under increasing excitation amplitude, the system undergoes a nonlinear transition, where edge localization breaks down and energy delocalizes into the bulk. By coupling multiple such chains with varying modulation phase, we construct a two-dimensional lattice in which the phase acts as a synthetic dimension. This structure supports topological wave propagation along the synthetic dimension. Nonlinearity again induces a breakdown of topological states, leading to complex, amplitude-dependent wave propagation. We further propose a numerical continuation approach to analyzing the periodic orbits and their linear stability, effectively discovering the boundary of the basin of bounded motion and detecting the occurrence of delocalization under certain excitation amplitudes. Our results reveal that elliptical geared systems offer a passive, amplitude-dependent platform for exploring topological phenomena and synthetic dimensionality in mechanical metamaterials.

physics.app-ph

Floquet odd-parity collinear magnets

Altermagnets (AMs), recently discovered unconventional magnets distinct from both ferro- and antiferromagnets, have rapidly emerged as a prominent research topic in condensed matter physics. AMs are characterized by alternating collinear magnetic moments with zero net magnetization in real space, and spin splittings with even-parity symmetry in momentum space. However, their counterparts exhibiting odd-parity spin splittings are generally thought to be absent in collinear magnets. Here, we show that such unconventional odd-parity magnets can be induced from collinear antiferromagnets by symmetry engineering. Remarkably, using effective model analysis within Floquet-theory framework, we demonstrate that circularly polarized light irradiation of conventional antiferromagnetic lattices breaks a spin-preserving pseudo-time-reversal symmetry and induces both $p$- and $f$-wave magnets, realizing novel magnetic states dubbed Floquet odd-parity collinear magnets. Moreover, we also uncover light-induced antiferromagnetic Chern insulating states in the $f$-wave magnets. The proposed Floquet odd-parity magnet is confirmed by first-principles calculations of MnPSe$_{3}$ under circularly polarized light. Our work not only proposes a new class of unconventional magnets, but also opens an avenue for light-induced magnetic phenomena in spintronic applications.

cond-mat.mes-hall