arXiv subjects

Dipankar Mandal

Publications and source records attributed to Dipankar Mandal.

7 recordsLinked to original sources

arXiv2026

Above Room-Temperature Phase Transition in Helicoidal 2D Halide Perovskite Enables Pyro-Phototronic Control

Bridging pyro-phototronic and ferroelectric properties in a single material not only gives rise to exotic physical phenomena but also provides strategy to build-up next-generation multi-functional energy harvesting devices. The layered halide perovskites are emerging class of synergetic 2D-materials of exceptional light-induced functionalities. Here, we report synthesis of a lead-free perovskite (3-fluorobenzylamine)2CuCl4 of partially fluorinated aromatic rings. Molecular chains are chiral in helicoids so to render flexibility, energy-transfer, and freedom to tailor tunable pyro-phototronics on light illumination. The fluorinated framework promotes ferroelectric-to-paraelectric transition point (TC), as high as \textasciitilde 412 K of wide range of workably. A giant pyro-photronic response is distinctly evident even upon UV-visible light-illuminations. A significantly high pyro-photronic current of 60 nA was achieved under an illumination of {\lambda}ex\textasciitilde 365 nm (27 mW) in a self-powered configuration. Consequently, an intricate coupling of the spontaneous polarization to the optical properties is visualized from the piezo response force microscopy (PFM) responses. In particular, the polar domains get diminished reversibly in on-off steps of the light irradiations. It indicates, the light provides another degree of the freedom to control the features for the applications of optoelectronic devices, optical memories, photo/thermo-chromic systems, and energy-harvesters.

cond-mat.mtrl-sci↗

arXiv2024

Ultrahigh pyroelectricity in monoelemental 2D tellurium

We report an ultrahigh pyroelectric response in van der Waals bonded layers of two-dimensional (2D) tellurium (Te) nanosheets (thickness, d = 4 to 5 nm) at periodic on-off temperature oscillations. For the first time a large pyroelectric coefficient, Pc ~ 3 mC.m-2.K-1, is observed which is eightfold higher than the traditional state-of-the-art pyroelectrics (lead zirconate titanate, PZT). The first-principles calculations point out that the breakdown of centro-symmetry in the 1-3 Te-layers (P-3m1 space group) of a non-centrosymmetry (higher-order symmetry of C2 space group) on an angular twist in the Te-Te bonds of an exotic electronic state in 2D Te. The angular Te-Te twisting elicits a surface-enhanced Raman band at 101 cm-1 (absent in bulk Te). The stimulation of the Born effective charge, in-plane piezoelectricity and thermal expansion coefficient are shown to tailor the large pyroelectricity. Thus, 2D Te nanosheets present a new paradigm for the wide application of pyroelectric materials for developing thermal energy-based flexible electronics.

cond-mat.mtrl-sci↗

arXiv2024

Can Entanglement-enhanced Quantum Kernels Improve Data Classification?

Classical machine learning, extensively utilized across diverse domains, faces limitations in speed, efficiency, parallelism, and processing of complex datasets. In contrast, quantum machine learning algorithms offer significant advantages, including exponentially faster computations, enhanced data handling capabilities, inherent parallelism, and improved optimization for complex problems. In this study, we used the entanglement-enhanced quantum kernel in quantum support vector machine to train complex respiratory data sets. Compared to classical algorithms, our findings reveal that QSVM performs better with 45% higher accuracy for complex respiratory data sets while maintaining comparable performance with linear datasets in contrast to their classical counterparts executed on a 2-qubit system. Through our study, we investigate the efficacy of the QSVM-Kernel algorithm in harnessing the enhanced dimensionality of the quantum Hilbert space for effectively training complex datasets.

quant-ph↗

arXiv2021

$δ$-PVDF Based Flexible Nanogenerator

Delta ($δ$) phase comprising polyvinylidene fluoride (PVDF) nanoparticles are fabricated through electrospray technique by applying 0.1 MV/m electric field at ambient temperature and pressure, which is 10$^{3}$ times lower than the typical value, required for $δ$-phase transformation. The X-ray diffraction (XRD) and selected area electron diffraction (SAED) patterns are clearly indicating the $δ$-phase formation. The piezo- and ferro- electric response of the $δ$-PVDF nanoparticles has been demonstrated through scanning probe microscopic technique based on piezoresponse force microscopy (PFM). The vertical piezoelectric response, indicated by d$_{33}$ coefficient, is found $\sim$-11 pm/V. Kink propagation model is adopted to justify the $δ$-phase conversion in electrospray system. The electrical response from $δ$-PVDF nanoparticle comprised nanogenerator under the external impacts and acoustic signal indicates that molecular ferroelectric dipoles responsible for piezoelectric responses, are poled in-situ during nanoparticle formation, thus further electrical poling is not necessary.

physics.app-ph↗

arXiv2020

Design of a Self-powered Smart Mask for COVID-19

Usage of a face mask has become mandatory in many countries after the outbreak of SARS-CoV-2, and its usefulness in combating the pandemic is a proven fact. There have been many advancements in the design of a face mask and the present treatise describes a face mask in which a simple textile triboelectric nanogenerator (TENG) serves the purpose of filtration of SARS-CoV-2. The proposed mask is designed with multilayer protection sheets, in which the first two layers act as triboelectric (TE) filter and the outer one is a smart filter. The conjugated effect of contact electrification, and electrostatic induction of the proposed smart mask are effective in inactivating the span of virus-ladden aerosols in a bidirectional way. Five pairs of triboseries fabrics i.e. nylon - polyester, cotton - polyester, poly(methyl methacrylate) - PVDF, lylon - PVDF and polypropylene - polyester have been optimized in this study in terms of their effective tribo-electric charge densities as 83.13, 211.48, 38.62, 69 and 74.25 nC/m2, respectively. This smart mask can be used by a wide range of people because of its simple mechanism, self-driven (harvesting mechanical energy from daily activities, e.g. breathing, talking, or other facial movements functionalities, and effective filtration efficiency and thus, it is expected to be potentially beneficial to slow down the devastating impact of COVID-19.

physics.med-ph↗

arXiv2019

Rollable Magnetoelectric Energy Harvester as Wireless IoT Sensor

Perhaps the most abundant form of waste energy in our surrounding is the parasitic magnetic noise arising from electrical power transmission system. In this work, a flexible and rollable magneto-mechano-electric nanogenerator (MMENG) based wireless IoT sensor has been demonstrated in order to capture and utilize the magnetic noise. Free standing magnetoelectric (ME) composites are fabricated by combining magnetostrictive nickel ferrite nanoparticles and piezoelectric polyvinylidene-co-trifluoroethylene polymer. The magnetoelectric 0-3 type nanocomposites possess maximum ME co-efficient of 11.43 mV/cm-Oe. Even, without magnetic bias field 99 % of the maximum ME co-efficient value is observed due to self-bias effect. As a result, the MMENG generates sufficient peak-to-peak open circuit voltage, output power density and successfully operates commercial capacitor under the weak and low frequency stray magnetic field arising from the power cable of home appliances such as, electric kettle. Finally, the harvested electrical signal has been wirelessly transmitted to a smart phone in order to demonstrate the possibility of position monitoring system construction. This cost effective and easy to integrate approach with tailored size and shape of device configuration is expected to be explored in next-generation self-powered IoT sensors including implantable biomedical devices and human health monitoring sensory systems.

cond-mat.mtrl-sci↗

arXiv2011

Preparation of Silver Nanoparticles Doped PVDF: Formation of Piezoelectric Polymorph

The preparation of polymorphism control of Poly(vinylidene fluoride) (PVDF) by silver nanoparticles (Ag NPs) is investigated. The Ag NPs were prepared by simple one step process from AgNO3, where N,N-dimethylformamide(DMF) act as reducing agent as well the solvent of the host polymer, PVDF. It was observed that PVDF is one of the best stabilizers of Ag NPs. The thick films (10-20 μm) were prepared by simple solution casting followed by solvent drying and crystallizing PVDF polymorph. Here we observed that PVDF polymorph can be control by the content of the Ag NPs regardless of other processing conditions. The formation piezoelectric polymorph (β phase) by adequate amount of Ag NPs doping in PVDF was explained by the specific interaction between the surface charge of the Ag NPs and electric dipoles (CF2 dipoles) comprising in PVDF. In this work we also address the suitable technique for correct crystallographic phase identification in PVDF, as a large number of works in this field have already been misled. The significant higher temperature shift of melting temperature of β-phase was observed by Ag NPs doping, which has prime importance in diverse fields of electronic applications, i.e. IR-sensors, piezoelectric and pyroelectric sensor,transducers as well as actuators.

cond-mat.mtrl-sci↗