arXiv subjects

Dipten Bhattacharya

Publications and source records attributed to Dipten Bhattacharya.

43 records · Page 3Linked to original sources

arXiv2006

Dielectric anomaly at the orbital order-disorder transition in LaMnO_(3+delta)

We report a novel dielectric anomaly around the Jahn-Teller orbital order-disorder transition temperature T_JT in LaMnO_(3+delta). The transition has been characterized by resistivity (rho)versus temperature (T), calorimetry, and temperature-dependent X-ray diffraction studies. Measurements of complex dielectric permittivity epsilon* (= epsilon'-i.epsilon'') over a low-frequency range (1 Hz - 10 MHz)across T_JT reveal a distinct anomaly. This observation, and the reported relatively high static dielectric constant at T = 0 (epsilon0 \~18-20), possibly indicate that the orbital order gives rise to intrinsic polarization that undergoes transition at T_JT. The frequency dispersion of the dielectric response at any given temperature, however, reveals that the dielectric response consists of Maxwell-Wagner component, due to interfaces, within such a low frequency range. The T_JT and the nature of the anomaly in epsilon'(omega,T), epsilon''(omega,T) at T_JT, of course, vary - from a sharp upward feature to a smeared plateau and then a downward trend - depending on the Mn^4+ concentration of the sample. The observation of an intrinsic dielectric response due to long-range orbital order in LaMnO_3 - where no ferroelectric order is possible due to the absence of off-centre distortion in MnO_6 octahedra - may throw a new light onto these classes of materials vis-a-vis multiferroic materials.

cond-mat.str-el↗

arXiv2006

Particle-size dependence of orbital order-disorder transition in LaMnO3

The latent heat (L) associated with the orbital order-disorder transition at T_JT is found to depend significantly on the average particle size (d) of LaMnO3. It rises slowly with the decrease in d down to ~100 nm and then jumps by more than an order of magnitude in between d ~ 100 nm and ~30 nm. Finally, L falls sharply to zero at a critical particle size d_c ~ 19 nm. The transition temperature T_JT also exhibits an almost similar trend of variation with the particle size, near d ~ 30 nm and below, even though the extent of variation is relatively small. The zero-field-cooled (ZFC) and field-cooled (FC) magnetization versus temperature study over a temperature range 10-300 K reveals that the antiferromagnetic transition temperature decreases with d while the temperature range, over which the ZFC and FC data diverge, increases with the drop in d. The FC magnetization also is found to increase sharply with the drop in particle size. A conjecture of nonmonotonic variation in orbital domain structure with decrease in particle size - from smaller domains with large number of boundaries to larger domains with small number of boundaries due to lesser lattice defects and, finally, down to even finer domain structures with higher degree of metastability - along with increase in surface area in core-shell structure, could possibly rationalize the observed L versus d and T_JT versus d patterns. Transmission electron microscopy data provide evidence for presence of core-shell structure as well as for increase in lattice defects in finer particles.

cond-mat.str-el↗

arXiv2006

Particle size dependence of magnetization and phase transition near T_N in multiferroic BiFeO3

We report results of a comprehensive study of the phase transition at T_N (~643 K) as a function of particle size in multiferroic BiFeO3 system. We employed electrical, thermal, and temperature dependent X-ray diffraction (XRD) studies in order to characterize the transition in a host of samples. We also carried out detailed magnetic measurements over a temperature regime 2-300 K under a magnetic field 100-10000 Oe both on bulk and nano-crystalline systems. While in the bulk system a sharp endothermic peak at T_N together with a broad feature, ranging over nearly ~150 K (Delta_T), could be observed in calorimetry, the nanoscale systems exhibit only the broad feature. The characteristic dielectric anomaly, expected at T_N, is found to occur both at T_O and T_N across Delta_T in the bulk sample. The Maxwell-Wagner component due to interfaces between heterogenous regions with different conductivities is also present. The magnetic properties, measured at lower temperature, corroborate our observations in calorimetry. The metastability increases in the nanoscale BiFeO3 with divergence between zero-field cooled (ZFC) and field cooled (FC) magnetization below ~100 K and faster magnetic relaxation. Interestingly, in nanoscale BiFeO3, one also observes finite coercivity at lower temperature which points out that suitable design of particle size and shape may induce ferromagnetism. The inhomogeneous distribution of Bi/Fe-ions and/or oxygen non-stoichiometry seems to be giving rise to broad features in thermal, magnetic as well as in electrical responses.

cond-mat.mtrl-sci↗

arXiv2004

Reentrant metallic transition at a temperature above Tc at the breakdown of cooperative Jahn-Teller orbital order in perovskite manganites

We report an interesting reentrant metallic resistivity pattern beyond a characteristic temperature T* which is higher than other such characteristic transition temperatures like T(c)(Curie point), T(N) (Neel point), T(CO) (charge order onset point) or T(OO) (orbital order onset point) in a range of rare-erath perovskite manganites (RE(1-x)A(x)MnO(3); RE = La, Nd, Y; A = Sr, Ca; x = 0.0-0.5). Such a behavior is normally observed in doped manganites with doping level (x) higher than the critical doping level x(c) (= 0.17-0.22) required for the metallic ground state to emerge and hence in a system where cooperative Jahn-Teller orbital order has already undergone a breakdown. However, the observation made in the La(1-x)Ca(x)MnO(3) (x = 0.0-0.5) series turns out to be an exception to this general trend.

cond-mat.str-el↗

arXiv2004

Orbital order-disorder transition in La(1-x)Nd(x)MnO(3) (x = 0.0-1.0) and La(1-x-y)Nd(yx)Sr(y)MnO(3) (x = 0.1; y = 0.05,0.1)

The nature of orbital order-disorder transition has been studied in the La(1-x)Nd(x)MnO(3) (x = 0.0-1.0) series which covers the entire range between two end points - LaMnO(3) and NdMnO(3) - as well as in La(0.85)Nd(0.1)Sr(0.05)MnO(3) and La(0.8)Nd(0.1)Sr(0.1)MnO(3). It has been observed that the first-order nature of the transition gives way to higher order with the increase in "x" in the case of pure manganites. The latent heat (L) associated with the transition, first, drops with a steeper slope within x = 0.0-0.3 and, then, gradually over a range 0.3 or rise in average Mn-O-Mn bond bending angle while no apparent correlation could be observed with doping induced disorder sigma^2. The cooperative nature of the orbital order, therefore, appears to be robust.

cond-mat.str-el↗

arXiv2000

Role of intergranular silver in modulating the aperiodicity in disordered Josephson junction arrays : impact on relaxation of intergranular critical state

Relaxation of the intergranular critical state has been observed at a very low applied magnetic field (10-50 Oe) over a temperature regime of 20-77 K in bulk polycrystalline YBa(2)Cu(3)O(7-x) (YBCO) and Bi(1.75)Pb(0.35)Sr(2)Ca(2)Cu(3)O(10+x) (BPSCCO) samples. In such a disordered Josephson junction network, the relaxation is slower than the intragranular relaxation and, hence, it yields higher flux pinning energy U0 than the corresponding intragranular values. Silver addition seems to have given rise to much uniformity in the grain boundary characteristics which results in sharp drop in the flux pinning energy since it depends on the variation of the junction coupling energy EJ across the network. While U0 ~ 0.5 and 0.55 eV for the parent BPSCCO and YBCO samples, respectively, in silver added (10-15 wt%) samples the corresponding values are ~0.15 and 0.27 eV. The distribution functions m(U) for the flux pinning energy and n(theta) for the grain boundary mis-alignment angle(theta) have been evaluated from the experimentally observed patterns of magnetic relaxation and variation of the grain boundary critical fields with temperature. The distribution functions become narrower in the case of silver added samples reflecing a reduction in the degree of disorder. The variation of the effective vortex mass m* with the variation in the degree of disorder is observed. Considering the width of the superconducting transition delTc as the measure of the degree of disorder (inhomogeneity), it has been shown that the transport critical current density Jc follows a relationship Jc exp(-delTc) while the flux pinning energy U ~ delTc. These relations may help in devising a suitable strategy for achieving the desired effect : high Jc yet slower decay rate, i.e., large U.

cond-mat.supr-con↗

arXiv2000

On the factors affecting the high temperature insulator-metal transition in rare-earth manganites

The measurement of resistivity across a wide temperature range - from 15 to 1473 K - in rare-earth manganite series of compounds reveals a very interesting feature : normally observed insulating pattern beyond Tc (Curie Point) gives way to a reentrant metallic pattern around a characteristic temperature T*. The transport activation barrier Ea collapses to zero around T*. T* is found to be dependent on the carrier concentration or the concentration of the Jahn-Teller-active Mn(3+) ions as well as on the average A-site radius for a fixed carrier concentration. These factors govern the effective lattice distortion and hence lead to the variation in the conduction bandwidth. Our data cover a wide range - from T*>>Tc for smaller bandwidth to T* tending towards Tc for larger bandwidth. These results seem to provide evidence of the onset of lattice distortion at high temperature (around T*) and its variation. Since lattice distortion governs the magnetic, transport and other important behaviors significantly, our data assume importance as they offer a new measure of the effective distortion and its tunability.

cond-mat.str-el↗