arXiv subjects

Dmitry A. Semenov

Publications and source records attributed to Dmitry A. Semenov.

At least 19 recordsLinked to original sources

arXiv2025

On Linking Planet Formation Models, Protoplanetary Disk Properties, and Mature Gas Giant Exoplanet Atmospheres

Measuring a single elemental ratio (e.g., carbon-to-oxygen) provides insufficient information for understanding the formation mechanisms and evolution that affect our observations of gas giant planet atmospheres. Although the fields of planet formation, protoplanetary disks, and exoplanets are well established and interconnected, our understanding of how to self-consistently and accurately link the theoretical and observational aspects of these fields together is lacking. To foster interdisciplinary conversations, the Max-Planck Institut für Astronomie (MPIA) hosted a week-long workshop called, "Challenge Accepted: Linking Planet Formation with Present-Day Atmospheres." Here, we summarize the latest theories and results in planet formation modeling, protoplanetary disk observations, and atmospheric observations of gas giant atmospheres to address one of the challenges of hosting interdisciplinary conferences: ensuring everyone is aware of the state-of-the-art results and technical language from each discipline represented. Additionally, we highlight key discussions held at the workshop. Our main conclusion is that it is unclear what the ideal observable is to make this link between formation scenarios and exoplanet atmospheres, whether it be multiple elemental abundance ratios, measuring refractory budgets, or something else. Based on discussions held throughout the workshop, we provide several key takeaways of what the workshop attendees feel need the most improvement and exploration within each discipline.

astro-ph.EP↗

arXiv2025

Deep Mantle-Atmosphere Coupling and Carbonaceous Bombardment: Options for Biomolecule Formation on an Oxidized Early Earth

Understanding what environmental conditions prevailed on early Earth during the Hadean eon, and how this set the stage for the origins of life, remains a challenge. Geologic processes such as serpentinization and bombardment by chondritic material during the late veneer might have been very active, shaping an atmospheric composition reducing enough to allow efficient photochemical synthesis of HCN, one of the key precursors of prebiotic molecules. HCN can rain out and accumulate in warm little ponds (WLPs), forming prebiotic molecules such as nucleobases and the sugar ribose. These molecules could condense to nucleotides, the building blocks of RNA molecules, one of the ingredients of life. Here, we perform a systematic study of potential sources of reducing gases on Hadean Earth and calculate the concentrations of prebiotic molecules in WLPs based on a comprehensive geophysical and atmospheric model. We find that in a reduced H$_2$-dominated atmosphere, carbonaceous bombardment can produce enough HCN to reach maximum WLP concentrations of $\sim 1-10\,\mathrm{mM}$ for nucleobases and, in the absence of seepage, $\sim 10-100\,\mathrm{μM}$ for ribose. If the Hadean atmosphere was initially oxidized and CO$_2$-rich ($90\,\%$), we find serpentinization alone can reduce the atmosphere, resulting in WLP concentrations of an order of magnitude lower than the reducing carbonaceous bombardment case. In both cases, concentrations are sufficient for nucleotide synthesis, as shown in experimental studies. RNA could have appeared on Earth immediately after it became habitable (about $100\,\mathrm{Myr}$ after the Moon-forming impact), or it could have (re)appeared later at any time up to the beginning of the Archean.

astro-ph.EP↗

arXiv2024

Atacama Large Aperture Submillimeter Telescope (AtLAST) Science: Our Galaxy

As we learn more about the multi-scale interstellar medium (ISM) of our Galaxy, we develop a greater understanding for the complex relationships between the large-scale diffuse gas and dust in Giant Molecular Clouds (GMCs), how it moves, how it is affected by the nearby massive stars, and which portions of those GMCs eventually collapse into star forming regions. The complex interactions of those gas, dust and stellar populations form what has come to be known as the ecology of our Galaxy. Because we are deeply embedded in the plane of our Galaxy, it takes up a significant fraction of the sky, with complex dust lanes scattered throughout the optically recognisable bands of the Milky Way. These bands become bright at (sub-)millimetre wavelengths, where we can study dust thermal emission and the chemical and kinematic signatures of the gas. To properly study such large-scale environments, requires deep, large area surveys that are not possible with current facilities. Moreover, where stars form, so too do planetary systems, growing from the dust and gas in circumstellar discs, to planets and planetesimal belts. Understanding the evolution of these belts requires deep imaging capable of studying belts around young stellar objects to Kuiper belt analogues around the nearest stars. Here we present a plan for observing the Galactic Plane and circumstellar environments to quantify the physical structure, the magnetic fields, the dynamics, chemistry, star formation, and planetary system evolution of the galaxy in which we live with AtLAST; a concept for a new, 50m single-dish sub-mm telescope with a large field of view which is the only type of facility that will allow us to observe our Galaxy deeply and widely enough to make a leap forward in our understanding of our local ecology.

astro-ph.GA↗

arXiv2023

X-ray, Near-Ultraviolet, and Optical Flares Produced By Colliding Magnetospheres in The Young High-Eccentricity Binary DQ Tau

DQ Tau is a unique young high-eccentricity binary system that exhibits regular magnetic reconnection flares and pulsed accretion near periastron. We conducted NuSTAR, Swift, and Chandra observations during the July 30, 2022 periastron to characterize X-ray, near-ultraviolet (NUV), and optical flaring emissions. Our findings confirm the presence of X-ray super-flares accompanied by substantial NUV and optical flares, consistent with previous discoveries of periastron flares in 2010 and 2021. These observations, supported by new evidence, strongly establish the magnetosphere collision mechanism as the primary driver of magnetic energy release during DQ Tau's periastron flares. The energetics of the observed X-ray super-flares remain consistent across the three periastrons, indicating recurring energy sources during each passage, surpassing the capabilities of single stars. The observed flaring across multiple bands supports the Adams et al. model for magnetosphere interaction in eccentric binaries. Evidence from modeling and past and current observations suggests that both the mm/X-ray periastron flares and tentatively, the magnetic reconnection-related components of the optical/NUV emissions, conform to the classical solar/stellar non-thermal thick-target model, except for the distinctive magnetic energy source. However, our NuSTAR observations suffered from high background levels, hindering the detection of anticipated non-thermal hard X-rays. Furthermore, we report serendipitous discovery of X-ray super-flares occurring away from periastron, potentially associated with interacting magnetospheres. The current study is part of a broader multi-wavelength campaign, which is planned to investigate the influence of DQ Tau's stellar radiation on gas-phase ion chemistry within its circumbinary disk.

astro-ph.SR↗

arXiv2023

Prebiotic Vitamin B$_3$ Synthesis in Carbonaceous Planetesimals

Aqueous chemistry within carbonaceous planetesimals is promising for synthesizing prebiotic organic matter essential to all life. Meteorites derived from these planetesimals delivered these life building blocks to the early Earth, potentially facilitating the origins of life. Here, we studied the formation of vitamin B$_3$ as it is an important precursor of the coenzyme NAD(P)(H), which is essential for the metabolism of all life as we know it. We propose a new reaction mechanism based on known experiments in the literature that explains the synthesis of vitamin B$_3$. It combines the sugar precursors glyceraldehyde or dihydroxyacetone with the amino acids aspartic acid or asparagine in aqueous solution without oxygen or other oxidizing agents. We performed thermochemical equilibrium calculations to test the thermodynamic favorability. The predicted vitamin B$_3$ abundances resulting from this new pathway were compared with measured values in asteroids and meteorites. We conclude that competition for reactants and decomposition by hydrolysis are necessary to explain the prebiotic content of meteorites. In sum, our model fits well into the complex network of chemical pathways active in this environment.

astro-ph.EP↗

arXiv2022

Meteorites and the RNA World: Synthesis of Nucleobases in Carbonaceous Planetesimals and the Role of Initial Volatile Content

Prebiotic molecules, fundamental building blocks for the origin of life, have been found in carbonaceous chondrites. The exogenous delivery of these organic molecules onto the Hadean Earth could have sparked the polymerization of the first RNA molecules in Darwinian ponds during wet-dry cycles. Here, we investigate the formation of the RNA and DNA nucleobases adenine, uracil, cytosine, guanine, and thymine inside parent body planetesimals of carbonaceous chondrites. An up-to-date thermochemical equilibrium model coupled with a 1D thermodynamic planetesimal model is used to calculate the nucleobase concentrations. Different from the previous study (Pearce & Pudritz 2016), we assume initial volatile concentrations more appropriate for the formation zone of carbonaceous chondrite parent bodies. This represents more accurately cosmochemical findings that these bodies have formed inside the inner, $\sim 2\mathrm{-}5\,\mathrm{au}$, warm region of the solar system. Due to these improvements, our model represents the concentrations of adenine and guanine measured in carbonaceous chondrites. Our model did not reproduce per se the measurements of uracil, cytosine, and thymine in these meteorites. This can be explained by transformation reactions between nucleobases and potential decomposition of thymine. The synthesis of prebiotic organic matter in carbonaceous asteroids could be well explained by a combination of i) radiogenic heating, ii) aqueous chemistry involving a few key processes at a specific range of radii inside planetesimals where water can exist in the liquid phase, and iii) a reduced initial volatile content (H$_2$, CO, HCN, CH$_2$O) of the protoplanetary disk material in the parent body region compared to the outer region of comets.

astro-ph.EP↗

arXiv2022

Machine learning-accelerated chemistry modeling of protoplanetary disks

Aims. With the large amount of molecular emission data from (sub)millimeter observatories and incoming James Webb Space Telescope infrared spectroscopy, access to fast forward models of the chemical composition of protoplanetary disks is of paramount importance. Methods. We used a thermo-chemical modeling code to generate a diverse population of protoplanetary disk models. We trained a K-nearest neighbors (KNN) regressor to instantly predict the chemistry of other disk models. Results. We show that it is possible to accurately reproduce chemistry using just a small subset of physical conditions, thanks to correlations between the local physical conditions in adopted protoplanetary disk models. We discuss the uncertainties and limitations of this method. Conclusions. The proposed method can be used for Bayesian fitting of the line emission data to retrieve disk properties from observations. We present a pipeline for reproducing the same approach on other disk chemical model sets.

astro-ph.EP↗

arXiv2022

Possible Ribose Synthesis in Carbonaceous Planetesimals

The origin of life might be sparked by the polymerization of the first RNA molecules in Darwinian ponds during wet-dry cycles. The key life-building block ribose was found in carbonaceous chondrites. Its exogenous delivery onto the Hadean Earth could be a crucial step toward the emergence of the RNA world. Here, we investigate the formation of ribose through a simplified version of the formose reaction inside carbonaceous chondrite parent bodies. Following up on our previous studies regarding nucleobases with the same coupled physico-chemical model, we calculate the abundance of ribose within planetesimals of different sizes and heating histories. We perform laboratory experiments using catalysts present in carbonaceous chondrites to infer the yield of ribose among all pentoses (5Cs) forming during the formose reaction. These laboratory yields are used to tune our theoretical model that can only predict the total abundance of 5Cs. We found that the calculated abundances of ribose were similar to the ones measured in carbonaceous chondrites. We discuss the possibilities of chemical decomposition and preservation of ribose and derived constraints on time and location in planetesimals. In conclusion, the aqueous formose reaction might produce most of the ribose in carbonaceous chondrites. Together with our previous studies on nucleobases, we found that life-building blocks of the RNA world could be synthesized inside parent bodies and later delivered onto the early Earth.

physics.chem-ph↗

arXiv2022

The Young Binary DQ Tau Produces Another X-ray Flare Near Periastron

This work is part of a multi-wavelength program to study the effects of X-ray/UV/optical stellar radiation on the chemistry of the circumbinary disk around the young high-eccentricity binary DQ Tau. ALMA observations for near/around December 5, 2021 periastron were postponed due to bad weather, but supporting Swift-XRT-UVOT TOO observations were successful. These Swift observations along with previous X-ray-optical-mm data show that DQ Tau keeps exhibiting powerful flares near periastron, offering a unique laboratory for studies of flare effects on the gas-phase ion chemistry in protoplanetary disks.

astro-ph.SR↗

arXiv2021

Lack of other molecules in CO-rich debris discs: is it primordial or secondary gas?

The nature of the gas in CO-rich debris discs remains poorly understood, as it could either be a remnant from the earlier Class II phase or of secondary origin, driven by the destruction of icy planetesimals. The aim of this paper was to elucidate the origin of the gas content in the debris discs via various simple molecules that are often detected in the less-evolved Class II discs. We present millimetre molecular line observations of nine circumstellar discs around A-type stars: four CO-rich debris discs (HD 21997, HD 121617, HD 131488, HD 131835) and five old Herbig Ae protoplanetary discs (HD 139614, HD 141569, HD 142666, HD 145718, HD 100453). The sources were observed with the Atacama Large Millimeter/submillimeter Array (ALMA) in Bands 5 and 6 with 1-2'' resolution. The Herbig Ae discs are detected in the CO isotopologues, CN, HCN, HCO$^+$, C2H, and CS lines. In contrast, only CO isotopologues are detected in the debris discs, showing a similar amount of CO to that found in the Herbig Ae protoplanetary discs. Using chemical and radiative transfer modelling, we show that the abundances of molecules other than CO in debris discs are expected to be very low. We consider multiple sets of initial elemental abundances with various degrees of H2 depletion. We find that the HCO+ lines should be the second brightest after the CO lines and that their intensities strongly depend on the overall CO/H$_2$ ratio of the gas. However, even in the ISM-like scenario, the simulated HCO+ emission remains weak as required by our non-detections.

astro-ph.EP↗

arXiv2021

Dark cloud-type chemistry in PDRs with moderate UV field

We present a study of emission lines of small hydrocarbons C$_2$H and $c$-C$_3$H$_2$, and COMs precursors H$_2$CO and CH$_3$OH in order to better understand the possible chemical link between the molecular abundances and UV radiation field in photodissociation regions (PDRs). We study two PDRs around extended and compact HII regions with $G \leq 50$~Habings in the S235 star-forming complex. We find the highest abundances of both hydrocarbons on the edges of molecular clumps, while $c$-C$_3$H$_2$ is also abundant in the low-density expanding PDR around compact HII region S235\,A. We see the highest methanol column density towards the positions with the UV~field $G\approx 20-30$~Habings and explain them by reactive desorption from the dust grains. The $N_{\rm C_2H}/N_{\rm CH_3OH}$ ratio is lower by a factor of few or the order of magnitude in comparison with the Horsehead and Orion Bar PDRs. The ratio is similar to the value observed in hot corinos in the Perseus cloud. We conclude that ion-molecular and grain surface chemical routes rule the molecular abundances in the PDRs, and the PDRs inherit molecular abundances from the previous dark stage of molecular cloud evolution in spite of massive stars already emitting in optics.

astro-ph.GA↗

arXiv2020

Using HCO$^+$ isotopologues as tracers of gas depletion in protoplanetary disk gaps

The widespread rings and gaps seen in the dust continuum in protoplanetary disks are sometimes accompanied by similar substructures seen in molecular line emission. One example is the outer gap at 100 au in AS 209, which shows that the H$_{13}$CO$^+$ and C$_{18}$O emission intensities decrease along with the continuum in the gap, while the DCO$^+$ emission increases inside the gap. We aim to study the behavior of DCO$^+$/H$_{13}$CO$^+$ and DCO$^+$/HCO$^+$ ratios in protoplanetary disk gaps assuming the two scenarios: the gas depletion follows the dust depletion and only the dust is depleted. We first modeled the physical disk structure using the thermo-chemical model ANDES. This 1+1D steady-state disk model calculates the thermal balance of gas and dust and includes the FUV, X-rays, cosmic rays, and other ionization sources together with the reduced chemical network for molecular coolants. Afterward, this physical structure was adopted for calculations of molecular abundances with the extended gas-grain chemical network with deuterium fractionation. Ideal synthetic spectra and 0th-moment maps were produced with LIME. We are able to qualitatively reproduce the increase in the DCO$^+$ intensity and the decrease in the H$_{13}$CO$^+$ and C$_{18}$O intensities inside the disk gap, which is qualitatively similar to what is observed in the outer AS 209 gap. The corresponding disk model assumes that both the gas and dust are depleted in the gap. The model with the gas-rich gap, where only the dust is depleted, produces emission that is too bright in all HCO$^+$ isotopologues and C$_{18}$O. The DCO$^+$/H$_{13}$CO$^+$ line ratio can be used to probe gas depletion in dust continuum gaps outside of the CO snow line. The DCO$^+$/C$_{18}$O line ratio shows a similar, albeit weaker, effect; however, these species can be observed simultaneously with a single ALMA or NOEMA setup.

astro-ph.EP↗

arXiv2020

Accretion disks around young stars: the cradles of planet formation

Protoplanetary disks around young stars are the birth sights of planetary systems like our own. Disks represent the gaseous dusty matter left after the formation of their central stars. The mass and luminosity of the star, initial disk mass and angular momentum, and gas viscosity govern disk evolution and accretion. Protoplanetary disks are the cosmic nurseries where microscopic dust grains grow into pebbles, planetesimals, and planets.

astro-ph.EP↗

arXiv2019

Luminosity outburst chemistry in protoplanetary discs: going beyond standard tracers

The chemical influence of luminosity outbursts on the environments of young solar-type stars is explored. Species are categorised into several types according to their response to the outburst. The first and second types imply chemical changes only during the outburst (with slightly different behaviours). These response types are mostly observed close to the star and are caused by icy mantle evaporation. However, mantles recover after the outburst almost immediately. A notable exception is benzene ice, which is accumulated on dust surfaces during and after the outburst, so that its abundance exceeds the pre-outburst level by orders of magnitude. The third type of response is mostly seen at the disc periphery and implies alteration of abundances during the outburst and preservation of these `abnormal' abundances for centuries. This behaviour is typical of organic compounds, like HCOOCH$_3$, CH$_3$CN, CH$_2$CO. Their presence in the dark disc regions can be a manifestation of the past outburst. CO and CO$_2$ only trace past outbursts at the remote disc regions. The outburst changes the C/O ratio, but it quickly returns to the pre-outburst value almost everywhere in the disc. An important factor determining the sensitivity of molecular composition to the outburst is the dust size distribution. The duration of the pre-outburst stage and of the outburst itself influence the chemical effects, if the burst duration is shorter than 50 yr and the duration of the quiescent phase between the bursts is shorter than 100 kyr.

astro-ph.EP↗

arXiv2017

Origin of the RNA World: The Fate of Nucleobases in Warm Little Ponds

Prior to the origin of simple cellular life, the building blocks of RNA (nucleotides) had to form and polymerize in favourable environments on the early Earth. At this time, meteorites and interplanetary dust particles delivered organics such as nucleobases (the characteristic molecules of nucleotides) to warm little ponds whose wet-dry cycles promoted rapid polymerization. We build a comprehensive numerical model for the evolution of nucleobases in warm little ponds leading to the emergence of the first nucleotides and RNA. We couple Earth's early evolution with complex prebiotic chemistry in these environments. We find that RNA polymers must have emerged very quickly after the deposition of meteorites (< a few years). Their constituent nucleobases were primarily meteoritic in origin and not from interplanetary dust particles. Ponds appeared as continents rose out of the early global ocean but this increasing availability of "targets" for meteorites was offset by declining meteorite bombardment rates. Moreover, the rapid losses of nucleobases to pond seepage during wet periods, and to UV photodissociation during dry periods means that the synthesis of nucleotides and their polymerization into RNA occurred in just one to a few wet-dry cycles. Under these conditions, RNA polymers likely appeared prior to 4.17 billion years ago. Significance: There are two competing hypotheses for the site at which an RNA world emerged: hydrothermal vents in the deep ocean and warm little ponds. Because the former lacks wet and dry cycles, which are well known to promote polymerization (in this case, of nucleotides into RNA), we construct a comprehensive model for the origin of RNA in the latter sites. Our model advances the story and timeline of the RNA world by constraining the source of biomolecules, the environmental conditions, the timescales of reaction, and the emergence of first RNA polymers.

astro-ph.EP↗

arXiv2016

Cold CO gas in the disk of the young eruptive star EX Lup

EX Lupi-type objects (EXors) form a sub-class of T Tauri stars, defined by sudden sporadic flare-ups of 1-5 magnitudes at optical wavelengths. These eruptions are attributed to enhanced mass accretion from the circumstellar disk to the star, and may constitute important events in shaping the structure of the inner disk and the forming planetary system. Although disk properties must play a fundamental role in driving the outbursts, they are surprisingly poorly known. In order to characterize the dust and gas components of EXor disks, here we report on observations of the $^{12}$CO J=3-2 and 4-3 lines, and the $^{13}$CO 3-2 line in EX Lup, the prototype of the EXor class. We reproduce the observed line fluxes and profiles with a line radiative transfer model, and compare the obtained parameters with corresponding ones of other T Tauri disks.

astro-ph.SR↗

arXiv2013

Central symmetry and antisymmetry of the microwave background inhomogeneities on Wilkinson Microwave Anisotropy Probe maps

We performed a visual and numeric analysis of the deviation of the microwave background temperature on WMAP maps. We proved that the microwave background inhomogeneities possess the property of the central symmetry resulting from the two kinds of central symmetry of the opposite signs. After the computer modeling we have established the relation between the coefficient of the central symmetry and the values of the symmetrical and antisymmetrical components of the deviation of the temperature. The obtained distribution of the symmetry coefficient on the map of the celestial sphere in Mollweide projection testifies on a contribution of both kinds of central symmetry which is approximately equal on the average in absolute magnitude but opposite by sign and where one kind of the central symmetry prevails on some sections of the celestial sphere and another kind - on the others. The average resulting value of the symmetry coefficient on the sections with angular measures less than 15-200 varies within the range from -50% to +50% with some prevalence of the antisymmetry - the average coefficient of the central symmetry for the whole celestial sphere is -4 +/- 1%. (antisymmetry 4%). Small scale structure of the distribution indicates that it is the result of the combined action of the mechanisms of the central symmetry and central antisymmetry, close to 100%.

physics.gen-ph↗

arXiv2012

Chemistry in protoplanetary disks (short review in Russian)

(English) In this lecture I discuss recent progress in the understanding of the chemical evolution of protoplanetary disks that resemble our Solar system during the first ten million years. At the verge of planet formation, strong variations of temperature, density, and radiation intensities in these disks lead to a layered chemical structure. In hot, dilute and heavily irradiated atmosphere only simple radicals, atoms, and atomic ions can survive, formed and destroyed by gas-phase processes. Beneath the atmosphere a partly UV-shielded, warm molecular layer is located, where high-energy radiation drives rich chemistry, both in the gas phase and on dust surfaces. In a cold, dense, dark disk midplane many molecules are frozen out, forming thick icy mantles where surface chemistry is active and where complex (organic) species are synthesized.

astro-ph.GA↗