arXiv subjects

Dmitry S. Golubev

Publications and source records attributed to Dmitry S. Golubev.

At least 19 recordsLinked to original sources

arXiv2026

System-bath model for quantum chemistry

We propose an approximate mapping of a molecular Hamiltonian to a Hamiltonian of qubits, which allows for high accuracy quantum chemistry calculations of vertical excitation energies of some molecules. The mapping is based on separating of a very small active space of only two orbitals and on modeling the electronic excitations in the remaining orbitals by a set of qubits or, equivalently, by a set of oscillators. This approach is inspired by the Random Phase Approximation (RPA), in which the excitations of electron gas are described by bosonic degrees of freedom. As a result, the Hamiltonian of the molecule is reduced to that of a system-bath model. The "system" part of the Hamiltonian describes the two molecular orbitals -- the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) -- which are populated by two electrons. Two qubits are sufficient to encode the Hamiltonian of such a system. The "bath" consists of oscillators or, equivalently, of two level systems with each of them corresponding to an electron excitation from a doubly occupied orbital below the Fermi level to an empty orbital above the Fermi level. We hope that this mapping can inspire new approaches and algorithms aimed at calculating excitation energies of molecules on near term quantum computers.

quant-ph↗

arXiv2024

Efficient Random Phase Approximation for Diradicals

We apply the analytically solvable model of two electrons in two orbitals to diradical molecules, characterized by two unpaired electrons. The effect of the doubly occupied and empty orbitals is taken into account by means of random phase approximation (RPA). We show that in the static limit the direct RPA leads to the renormalization of the parameters of the two-orbital model. We test our model by comparing its predictions for the singlet-triplet splitting with the results from multi-reference CASSCF and NEVPT2 simulations for a set of ten molecules. We find that, for the whole set, the average relative difference between the singlet-triplet gaps predicted by the RPA-corrected two-orbital model and by NEVPT2 is about 40%. For the five molecules with the smallest singlet-triplet splitting the accuracy is better than 20%.

physics.chem-ph↗

arXiv2023

Bolometric detection of Josephson inductance in a highly resistive environment

The Josephson junction is a building block of quantum circuits. Its behavior, well understood when treated as an isolated entity, is strongly affected by coupling to an electromagnetic environment. In 1983, Schmid predicted that a Josephson junction shunted by a resistance exceeding the resistance quantum $\mathbf{\textit{R}}_\mathrm{Q} = h/4e^2 \approx 6.45$ k$\mathbfΩ$ for Cooper pairs would become insulating since the phase fluctuations would destroy the coherent Josephson coupling. However, recent microwave measurements have questioned this interpretation. Here, we insert a small Josephson junction in a Johnson-Nyquist-type setup where it is driven by weak current noise arising from thermal fluctuations. Our heat probe minimally perturbs the junction's equilibrium, shedding light on features not visible in charge transport. We find that the Josephson critical current completely vanishes in DC charge transport measurement, and the junction demonstrates Coulomb blockade in agreement with the theory. Surprisingly, thermal transport measurements show that the Josephson junction acts as an inductor at high frequencies, unambiguously demonstrating that a supercurrent survives despite the Coulomb blockade observed in DC measurements. The discrepancy between these two measurements highlights the difference between the low and the high frequency response of a junction and calls for further theoretical and experimental inputs on the dynamics of Josephson junctions \textcolor{black}{operating at high frequencies in highly resistive environments.

cond-mat.mes-hall↗

arXiv2023

Microwave quantum diode

The fragile nature of quantum circuits is a major bottleneck to scalable quantum applications. Operating at cryogenic temperatures, quantum circuits are highly vulnerable to amplifier backaction and external noise. Non-reciprocal microwave devices such as circulators and isolators are used for this purpose. These devices have a considerable footprint in cryostats, limiting the scalability of quantum circuits. We present a compact microwave diode architecture, which exploits the non-linearity of a superconducting flux qubit. At the qubit degeneracy point we experimentally demonstrate a significant difference between the power levels transmitted in opposite directions. The observations align with the proposed theoretical model. At -99 dBm input power, and near the qubit-resonator avoided crossing region, we report the transmission rectification ratio exceeding 90% for a 50 MHz wide frequency range from 6.81 GHz to 6.86 GHz, and over 60% for the 250 MHz range from 6.67 GHz to 6.91 GHz. The presented architecture is compact, and easily scalable towards multiple readout channels, potentially opening up diverse opportunities in quantum information, microwave read-out and optomechanics.

quant-ph↗

arXiv2022

Photonic heat transport from weak to strong coupling

Superconducting circuits provide a favorable platform for quantum thermodynamic experiments. An important component for such experiments is a heat valve, i.e. a device which allows one to control the heat power flowing through the system. Here we theoretically study the heat valve based on a superconducting quantum interference device (SQUID) coupled to two heat baths via two resonators. The heat current in such system can be tuned by magnetic flux. We investigate how does the heat current modulation depend on the coupling strength g between the SQUID and the resonators. In the weak coupling regime the heat current modulation grows as g2, but, surprisingly, at the intermediate coupling it can be strongly suppressed. This effect is linked to the resonant nature of the heat transport at weak coupling, where the heat current dependence on the magnetic flux is a periodic set of narrow peaks. At the intermediate coupling, the peaks become broader and overlap, thus reducing the heat modulation. At very strong coupling the heat modulation grows again and finally saturates at a constant value.

cond-mat.mes-hall↗

arXiv2022

Robust strong coupling architecture in circuit quantum electrodynamics

We report on a robust method to achieve strong coupling between a superconducting flux qubit and a high-quality quarter-wavelength coplanar waveguide resonator. We demonstrate the progression from the strong to ultrastrong coupling regime by varying the length of a shared inductive coupling element, ultimately achieving a qubit-resonator coupling strength of 655 MHz, $10\%$ of the resonator frequency. We derive an analytical expression for the coupling strength in terms of circuit parameters and also discuss the maximum achievable coupling within this framework. We experimentally characterize flux qubits coupled to superconducting resonators using one and two-tone spectroscopy methods, demonstrating excellent agreement with the proposed theoretical model.

quant-ph↗

arXiv2022

Local and non-local two-electron tunneling processes in a Cooper pair splitter

We measure the tunneling rates and coupling coefficients for local Andreev, non-local Andreev and elastic cotunneling processes. The non-local Andreev process, giving rise to Cooper pair splitting, exhibits the same coupling coefficient as the elastic co-tunneling whereas the local Andreev process is more than two orders of magnitude stronger than the corresponding non-local one. Theory estimates describe the findings and explain the large difference in the non-local and local coupling arising from competition between electron diffusion in the superconductor and tunnel junction transparency.

cond-mat.mes-hall↗

arXiv2021

Photonic heat transport in three terminal superconducting circuit

Quantum heat transport devices are currently intensively studied in theory. Experimental realization of quantum heat transport devices is a challenging task. So far, they have been mostly investigated in experiments with ultra-cold atoms and single atomic traps. Experiments with superconducting qubits have also been carried out and heat transport and heat rectification has been studied in two terminal devices. The structures with three independent terminals offer additional opportunities for realization of heat transistors, heat switches, on-chip masers and even more complicated devices. Here we report an experimental realization of a three-terminal photonic heat transport device based on a superconducting quantum circuit. Its central element is a flux qubit made of a superconducting loop containing three Josephson junctions, which is connected to three resonators terminated by resistors. By heating one of the resistors and monitoring the temperatures of the other two, we determine photonic heat currents in the system and demonstrate their tunability by magnetic field at the level of 1 aW. We determine system parameters by performing microwave transmission measurements on a separate nominally identical sample and, in this way, demonstrate clear correlation between the level splitting of the qubit and the heat currents flowing through it. Our experiment is an important step in the development of on-chip quantum heat transport devices. On the one hand, such devices are of great interest for fundamental science because they allow one to investigate the effect of quantum interference and entanglement on the transport of heat. On the other hand, they also have great practical importance for the rapidly developing field of quantum computing, in which management of heat generated by qubits is a problem.

cond-mat.mes-hall↗

arXiv2021

Joule heating effects in high transparency Josephson junctions

We study, both theoretically and experimentally, the features on the current-voltage characteristic of a highly transparent Josephson junction caused by transition of the superconducting leads to the normal state. These features appear due to the suppression of the Andreev excess current. We show that by tracing the dependence of the voltage, at which the transition occurs, on the bath temperature and by analyzing the suppression of the excess current by the bias voltage one can recover the temperature dependence of the heat flow out of the junction. We verify theory predictions by fabricating two highly transparent superconductor-graphene-superconductor (SGS) Josephson junctions with suspended and non-suspended graphene as a non-superconducting section between Al leads. Applying the above mentioned technique we show that the cooling power of the suspended junction depends on the bath temperature as $\propto T_{\rm bath}^{3.1}$ close to the superconducting critical temperature.

cond-mat.supr-con↗

arXiv2021

Frequency to power conversion by an electron turnstile

Direct frequency to power conversion (FPC), to be presented here, links both quantities through a known energy, like single-electron transport relates an operation frequency $f$ to the emitted current $I$ through the electron charge $e$ as $I=ef$. FPC is a natural candidate for a power standard resorting to the most basic definition of the watt -- energy, which is traceable to Planck's constant $h$, emitted per unit of time. This time is in turn traceable to the unperturbed ground state hyperfine transition frequency of the caesium 133 atom $Δν_\mathrm{Cs}$; hence, FPC comprises a simple and elegant way to realize the watt. In this spirit, single-photon emission and detection at known rates have been proposed and experimented as radiometric standard. However, nowadays power standards are only traceable to electrical units, i.e., volt and ohm. In this letter, we demonstrate the feasibility of an alternative proposal based on solid-state direct FPC using a SINIS (S = superconductor, N = normal metal, I = insulator) single-electron transistor (SET) accurately injecting $N$ (integer) quasiparticles (qps) per cycle to both leads with discrete energies close to their superconducting gap $Δ$, even at zero drain-source voltage. Furthermore, the bias voltage plays an important role in the distribution of the power among the two leads, allowing for an almost equal injection $NΔf$ to the two. We estimate that under appropriate conditions errors can be well below $1\%$.

cond-mat.mes-hall↗

arXiv2021

Single-photon detection with a Josephson junction coupled to a resonator

We use semiclassical formalism to optimize a microwave single photon detector based on switching events of a current biased Josephson junction coupled to a resonator. In order to detect very rare events, the average time between dark counts $τ_{\rm dark}$ should be maximized taking into account that the switching time $τ_{\rm sw}$ should be sufficiently small. We demonstrate that these times can be tuned in the wide range by changing the junction parameters, and the ratios $τ_{\rm dark}/τ_{\rm sw} \sim 10^9$ can be achieved. Therefore, a junction-resonator arrangement can be used for detecting extremely low photon fluxes, for instance for searching galactic axions.

cond-mat.supr-con↗

arXiv2020

Thermally pumped on-chip maser

We present a theoretical model of an on-chip three-level maser in a superconducting circuit based on a single artificial atom and pumped by a temperature gradient between thermal baths coupled to different interlevel transitions. We show that maser powers of the order of a few femtowatts, well exceeding the resolution of the sensitive bolometry, can be achieved with typical circuit parameters. We also demonstrate that population inversion in the artificial atom can be detected without measuring coherent radiation output of the maser. For that purpose, the system should operate as a three-terminal heat transport device. The hallmark of population inversion is the influx of heat power into the weakly coupled output terminal even though its temperature exceeds the temperatures of the two other terminals. The proposed method of on-chip conversion of heat into microwave radiation and control of energy-level populations by heating provide additional useful tools for circuit quantum electrodynamics experiments.

cond-mat.supr-con↗

arXiv2020

Electric field control of radiative heat transfer in a superconducting circuit

Heat is detrimental for the operation of quantum systems, yet it fundamentally behaves according to quantum mechanics, being phase coherent and universally quantum-limited regardless of its carriers. Due to their robustness, superconducting circuits integrating dissipative elements are ideal candidates to emulate many-body phenomena in quantum heat transport, hitherto scarcely explored experimentally. However, their ability to tackle the underlying full physical richness is severely hindered by the exclusive use of a magnetic flux as a control parameter and requires complementary approaches. Here, we introduce a dual, magnetic field-free circuit where charge quantization in a superconducting island enables thorough electric field control. We thus tune the thermal conductance, close to its quantum limit, of a single photonic channel between two mesoscopic reservoirs. We observe heat flow oscillations originating from the competition between Cooper-pair tunnelling and Coulomb repulsion in the island, well captured by a simple model. Our results demonstrate that the duality between charge and flux extends to heat transport, with promising applications in thermal management of quantum devices.

cond-mat.mes-hall↗

arXiv2019

Hanbury Brown and Twiss Exchange Correlations in Graphene Box

Quadratic detection in linear mesoscopic transport systems produces cross terms that can be viewed as interference signals reflecting statistical properties of charge carriers. In electronic systems these cross term interferences arise from exchange effects due to Pauli principle. Here we demonstrate fermionic Hanbury Brown and Twiss (HBT) exchange phenomena due to indistinguishability of charge carriers in a diffusive graphene system. These exchange effects are verified using current-current cross correlations in combination with regular shot noise (autocorrelation) experiments at microwave frequencies. Our results can be modeled using semiclassical analysis for a square-shaped metallic diffusive conductor, including contributions from contact transparency. The experimentally determined HBT exchange factor values lie between the calculated ones for coherent and hot electron transport.

cond-mat.mes-hall↗

arXiv2019

Photonic heat transport across a Josephson junction

We present a detailed study of photonic heat transport across a Josephson junction coupled to two arbitrary linear circuits having different temperatures. First, we consider the linear approximation, in which a nonlinear Josephson potential is replaced by a quadratic one and the junction acts as an inductor. Afterwards, we discuss the effects of junction anharmonicity. We separately consider the weak-coupling limit, in which the Bloch band structure of the junction energy spectrum plays an important role, and the opposite strong-coupling regime. We apply our general results to two specific models: a Josephson junction coupled to two Ohmic resistors and two resonators. We derive simple analytical approximations for the photonic heat flux in many limiting cases. We demonstrate that electric circuits with embedded Josephson junctions provide a useful platform for quantum thermodynamics experiments.

cond-mat.supr-con↗

arXiv2019

Cross-correlated shot noise in three-terminal superconducting hybrid nanostructures

We work out a unified theory describing both non-local electron transport and cross-correlated shot noise in a three-terminal normal-superconducting-normal (NSN) hybrid nanostructure. We describe noise cross correlations both for subgap and overgap bias voltages and for arbitrary distribution of channel transmissions in NS contacts. We specifically address a physically important situation of diffusive contacts and demonstrate a non-trivial behavior of non-local shot noise exhibiting both positive and negative cross correlations depending on the bias voltages. For this case, we derive a relatively simple analytical expression for cross-correlated noise power which contains only experimentally accessible parameters.

cond-mat.supr-con↗

arXiv2019

Extreme reductions of entropy in an electronic double dot

We experimentally study negative fluctuations of stochastic entropy production in an electronic double dot operating in nonequilibrium steady-state conditions. We record millions of random electron tunneling events at different bias points, thus collecting extensive statistics. We show that for all bias voltages the experimental average values of the minima of stochastic entropy production lie above $-k_B$, where $k_B$ is the Boltzmann constant, in agreement with recent theoretical predictions for nonequilibrium steady states. Furthermore, we also demonstrate that the experimental cumulative distribution of the entropy production minima is bounded, at all times and for all bias voltages, by a universal expression predicted by the theory. We also extend our theory by deriving a general bound for the average value of the maximum heat absorbed by a mesoscopic system from the environment and compare this result with experimental data. Finally, we show by numerical simulations that these results are not necessarily valid under non-stationary conditions.

cond-mat.stat-mech↗

arXiv2018

Intrinsic dissipation in superconducting junctions probed by qubit spectroscopy

We propose to study frequency dependent intrinsic dissipation in a highly transparent Josephson junction by means of qubit spectroscopy. The spectral density of the effective dissipative bath may contain significant contributions from Andreev bound states coupled to fluctuations of the Josephson phase. Varying either the bias current applied to the junction or magnetic flux through a superconducting ring in the rf-SQUID setup, one can tune the level splitting value close to the bottom of the Josephson potential well. Monitoring the qubit energy relaxation time one can probe the spectral density of the effective dissipative bath and unambiguously identify the contribution emerging from Andreev levels.

cond-mat.supr-con↗