arXiv subjects

Domingo Prato

Publications and source records attributed to Domingo Prato.

7 recordsLinked to original sources

arXiv2004

Bulk Mediated Surface Diffusion: Non Markovian Desorption with Finite First Moment

Here we address a fundamental issue in surface physics: the dynamics of adsorbed molecules. We study this problem when the particle's desorption is characterized by a non Markovian process, while the particle's adsorption and its motion in the bulk are governed by a Markovian dynamics. We study the diffusion of particles in a semi-infinite cubic lattice, and focus on the effective diffusion process at the interface $z = 1$. We calculate analytically the conditional probability to find the particle on the $z=1$ plane as well as the surface dispersion as functions of time. The comparison of these results with Monte Carlo simulations show an excellent agreement.

cond-mat.stat-mech↗

arXiv2003

Bulk Mediated Surface Diffusion: Finite System Case

We address the dynamics of adsorbed molecules (a fundamental issue in surface physics) within the framework of a Master Equation scheme, and study the diffusion of particles in a finite cubic lattice whose boundaries are at the $z=1$ and the $z=L$ planes where $L = 2,3,4,...$, while the $x$ and $y$ directions are unbounded. As we are interested in the effective diffusion process at the interface $z = 1$, we calculate analytically the conditional probability for finding the system on the $z=1$ plane as well as the surface dispersion as a function of time and compare these results with Monte Carlo simulations finding an excellent agreement.

cond-mat.stat-mech↗

arXiv2003

Bulk Mediated Surface Diffusion: The Infinite System Case

An analytical soluble model based on a Continuous Time Random Walk (CTRW) scheme for the adsorption-desorption processes at interfaces, called bulk-mediated surface diffusion, is presented. The time evolution of the effective probability distribution width on the surface is calculated and analyzed within an anomalous diffusion framework. The asymptotic behavior for large times shows a sub-diffusive regime for the effective surface diffusion but, depending on the observed range of time, other regimes may be obtained. Montecarlo simulations show excellent agreement with analytical results. As an important byproduct of the indicated approach, we present the evaluation of the time for the first visit to the surface.

cond-mat↗

arXiv2003

Nonextensive statistical mechanics: Some links with astronomical phenomena

A variety of astronomical phenomena appear to not satisfy the ergodic hypothesis in the relevant stationary state, if any. As such, there is no reason for expecting the applicability of Boltzmann-Gibbs (BG) statistical mechanics. Some of these phenomena appear to follow, instead, nonextensive statistical mechanics. In the same manner that the BG formalism is based on the entropy $S_{BG}=-k \sum_i p_i \ln p_i$, the nonextensive one is based on the form $S_q=k(1-\sum_ip_i^q)/(q-1)$ (with $S_1=S_{BG}$). The stationary states of the former are characterized by an {\it exponential} dependence on the energy, whereas those of the latter are characterized by an (asymptotic) {\it power-law}. A brief review of this theory is given here, as well as of some of its applications, such as the solar neutrino problem, polytropic self-gravitating systems, galactic peculiar velocities, cosmic rays and some cosmological aspects. In addition to these, an analogy with the Keplerian elliptic orbits {\it versus} the Ptolemaic epicycles is developed, where we show that optimizing $S_q$ with a few constraints is equivalent to optimizing $S_{BG}$ with an infinite number of constraints.

cond-mat.stat-mech↗

arXiv2002

Separable-entangled frontier in a bipartite harmonic system

We consider a statistical mixture of two identical harmonic oscillators which is characterized by four parameters, namely, the concentrations (x and y) of diagonal and nondiagonal bipartite states, and their associated thermal-like noises (T/a and T, respectively). The fully random mixture of two spins 1/2 as well as the Einstein-Podolsky-Rosen (EPR) state are recovered as particular instances. By using the conditional nonextensive entropy as introduced by Abe and Rajagopal, we calculate the separable-entangled frontier. Although this procedure is known to provide a necessary but in general not sufficient condition for separability, it does recover, in the particular case x=T=0 (for all a), the 1/3 exact result known as Peres' criterion. This is an indication of reliability of the calculation of the frontier in the entire parameter space. The x=0 frontier remarkably resembles to the critical line associated with standard diluted ferromagnetism where the entangled region corresponds to the ordered one and the separable region to the paramagnetic one. The entangled region generically shrinks for increasing T or increasing a.

quant-ph↗

arXiv2000

A nonextensive critical phenomenon scenario for quantum entanglement

We discuss the paradigmatic bipartite spin-1/2 system having the probabilities $\frac{1+3x}{4}$ of being in the Einstein-Podolsky-Rosen fully entangled state $|Ψ^-$$> \equiv \frac{1}{\sqrt 2}(|$$\uparrow>_A|$$\downarrow>_B$$-|$$\downarrow>_A|$$\uparrow>_B)$ and $\frac{3(1-x)}{4}$ of being orthogonal. This system is known to be separable if and only if $x\le1/3$ (Peres criterion). This critical value has been recently recovered by Abe and Rajagopal through the use of the nonextensive entropic form $S_q \equiv \frac{1- Tr ρ^q}{q-1} (q \in \cal{R}; $$S_1$$= -$ $Tr$ $ ρ\ln ρ)$ which has enabled a current generalization of Boltzmann-Gibbs statistical mechanics. This result has been enrichened by Lloyd, Baranger and one of the present authors by proposing a critical-phenomenon-like scenario for quantum entanglement. Here we further illustrate and discuss this scenario through the calculation of some relevant quantities.

cond-mat.stat-mech↗

arXiv1999

Functions of linear operators: Parameter differentiation

We derive a useful expression for the matrix elements $[\frac{\partial f[A(t)]}{\partial t}]_{i j}$ of the derivative of a function $f[A(t)]$ of a diagonalizable linear operator $A(t)$ with respect to the parameter $t$. The function $f[A(t)]$ is supposed to be an operator acting on the same space as the operator $A(t)$. We use the basis which diagonalizes A(t), i.e., $A_{i j}=λ_i δ_{i j}$, and obtain $[\frac{\partial f[A(t)]}{\partial t}]_{i j}=[\frac{\partial A}{\partial t}]_ {i j}\frac{f(λ_j) - f(λ_i)} {λ_j - λ_i}$. In addition to this, we show that further elaboration on the (not necessarily simple) integral expressions given by Wilcox 1967 (who basically considered $f[A(t)]$ of the exponential type) and generalized by Rajagopal 1998 (who extended Wilcox results by considering $f[A(t)]$ of the $q$-exponential type where $\exp_q(x) \equiv [1+(1-q)x]^{1/(1-q)}$ with $q \in {\cal {R}}$; hence, $\exp_1 (x)=\exp(x))$ yields this same expression. Some of the lemmas first established by the above authors are easily recovered.

cond-mat.stat-mech↗