arXiv subjects

Dominique Toublanc

Publications and source records attributed to Dominique Toublanc.

7 recordsLinked to original sources

arXiv2026

CosmicPAH-IRDB: A Web Application for Including Anharmonicity in Simulated PAH Spectra for Astrophysics

Advances in infrared observations with the James Webb Space Telescope (JWST) call for new tools to exploit the information associated with the Aromatic Infrared Bands (AIBs), now observed in both distant galaxies and the embryos of planetary systems. The AIBs contain information about their carriers as well as the excitation conditions, making them powerful probes of the chemical and physical conditions of their environments - if their spectral information can be decoded. While large datasets of theoretical infrared spectra are becoming available, efforts have primarily focused on the contribution of chemical diversity to the AIBs. However, the results remain limited by the impact of the excitation process on the band profiles. The AIB carriers, thought to be polycyclic aromatic hydrocarbons (PAHs), are hot molecules, which affects their spectral characteristics. We report here our approach to quantify these effects empirically by collecting IR spectra - both experimental and theoretical - and studying the evolution of band positions and widths with temperature. We present our methodology, including the development of the CosmicPAH-IRDB web application and spectral database, along with the associated cosmicPAHmfit multi-component spectral fitting tool. Our philosophy emphasizes open sharing, user-friendly access, and machine readability. The web application, tool and their update are accessible via the Cosmic PAH portal (https://cosmic-pah.irap.omp.eu/)

astro-ph.IM↗

arXiv2026

Infrared spectroscopy of gas-phase hydrogenated and methylated pyrenes: from laboratory spectra to the simulated 3.4 $\mu$m emission band

Observations of the aromatic infrared emission band at 3.3 $\mu$m often reveal satellite emission features in the 3.4 - 3.6 $\mu$m range. While the 3.3 $\mu$m band is attributed to the CH stretching vibration of polycylic aromatic hydrocarbons (PAHs), the satellite bands - particularly its prominent 3.4 $\mu$m component - is assigned to aliphatic CH stretching vibrations in hydrogenated and methylated PAH-like species. Our aim is to derive state-of-the-art infrared emission spectra for aliphatic-containing pyrene derivatives and compare them with astronomical observations. This will help refine our understanding of the contribution of these species to the 3.4 $\mu$m emission band. Mid-infrared spectra (1.4-25 $\mu$m) of gas-phase dihydropyrene, tehtrahydropyrene, hexahydropyrene methylated pyrene, and pyrene were recorded at temperatures ranging from 373 to 673 K, depending on the species. The band profiles were analyzed using a multi-component fitting tool, and empirical anharmonicity laws were derived to quantify the evolution of the band positions and widths with temperature. The obtained spectral data was combined with the results of a Monte Carlo emission model to simulate the emission spectra following UV-photon absorption, up to the dissociation limit ($\lesssim$6 eV). The resulting synthetic spectra were compared with James Webb Space Telescope observations of the Orion Bar region (PDRs4All program). Based on these state-of-the-art simulated spectra, we propose 1,2,3,6,7,8-hexahydropyrene as the carrier of the red component of the 3.4 $\mu$m band observed at 3.403 $\mu$m. While 1-methylpyrene may also contribute to the underlying emission plateau, its lack of a strong infrared band complicates detection in observed spectra, unlike hexahydropyrene. All experimental spectra and their temperature-dependent analyses are available in the new cosmicPAH-IRDB database.

astro-ph.GA↗

arXiv2019

Photo-processing of astro-PAHs

Polycyclic aromatic hydrocarbons (PAHs) are key species in astrophysical environments in which vacuum ultraviolet (VUV) photons are present, such as star-forming regions. The interaction with these VUV photons governs the physical and chemical evolution of PAHs. Models show that only large species can survive. However, the actual molecular properties of large PAHs are poorly characterized and the ones included in models are only an extrapolation of the properties of small and medium-sized species. We discuss here experiments performed on trapped ions including some at the SOLEIL VUV beam line DESIRS. We focus on the case of the large dicoronylene cation, C48H20+ , and compare its behavior under VUV processing with that of smaller species. We suggest that C2H2 is not a relevant channel in the fragmentation of large PAHs. Ionization is found to largely dominate fragmentation. In addition, we report evidence for a hydrogen dissociation channel through excited electronic states. Although this channel is minor, it is already effective below 13.6 eV and can significantly influence the stability of astro-PAHs. We emphasize that the competition between ionization and dissociation in large PAHs should be further evaluated for their use in astrophysical models.

astro-ph.GA↗

arXiv2015

Theory for planetary exospheres: III. Radiation pressure effect on the Circular Restricted Three Body Problem and its implication on planetary atmospheres

The planetary exospheres are poorly known in their outer parts, since the neutral densities are low compared with the instruments detection capabilities. The exospheric models are thus often the main source of information at such high altitudes. We present a new way to take into account analytically the additional effect of the stellar radiation pressure on planetary exospheres. In a series of papers, we present with an Hamiltonian approach the effect of the radiation pressure on dynamical trajectories, density profiles and escaping thermal flux. Our work is a generalization of the study by Bishop and Chamberlain (1989). In this third paper, we investigate the effect of the stellar radiation pressure on the Circular Restricted Three Body Problem (CR3BP), called also the photogravitational CR3BP, and its implication on the escape and the stability of planetary exospheres, especially for Hot Jupiters. In particular, we describe the transformation of the equipotentials and the location of the Lagrange points, and we provide a modified equation for the Hill sphere radius that includes the influence of the radiation pressure. Finally, an application to the hot Jupiter HD 209458b reveals the existence of a blow-off escape regime induced by the stellar radiation pressure.

astro-ph.EP↗

arXiv2015

Theory for planetary exospheres: II. Radiation pressure effect on exospheric density profiles

The planetary exospheres are poorly known in their outer parts, since the neutral densities are low compared with the instruments detection capabilities. The exospheric models are thus often the main source of information at such high altitudes. We present a new way to take into account analytically the additional effect of the radiation pressure on planetary exospheres. In a series of papers, we present with an Hamiltonian approach the effect of the radiation pressure on dynamical trajectories, density profiles and escaping thermal flux. Our work is a generalization of the study by Bishop and Chamberlain (1989). In this second part of our work, we present here the density profiles of atomic Hydrogen in planetary exospheres subject to the radiation pressure. We first provide the altitude profiles of ballistic particles (the dominant exospheric population in most cases), which exhibit strong asymmetries that explain the known geotail phenomenon at Earth. The radiation pressure strongly enhances the densities compared with the pure gravity case (i.e. the Chamberlain profiles), in particular at noon and midnight. We finally show the existence of an exopause that appears naturally as the external limit for bounded particles, above which all particles are escaping.

astro-ph.EP↗

arXiv2015

Theory for planetary exospheres: I. Radiation pressure effect on dynamical trajectories

The planetary exospheres are poorly known in their outer parts, since the neutral densities are low compared with the instruments detection capabilities. The exospheric models are thus often the main source of information at such high altitudes. We present a new way to take into account analytically the additional effect of the radiation pressure on planetary exospheres. In a series of papers, we present with an Hamiltonian approach the effect of the radiation pressure on dynamical trajectories, density profiles and escaping thermal flux. Our work is a generalization of the study by Bishop and Chamberlain (1989). In this first paper, we present the complete exact solutions of particles trajectories, which are not conics, under the influence of the solar radiation pressure. This problem was recently partly solved by Lantoine and Russell (2011) and completely by Biscani and Izzo (2014). We give here the full set of solutions, including solutions not previously derived, as well as simpler formulations for previously known cases and comparisons with recent works. The solutions given may also be applied to the classical Stark problem (Stark,1914): we thus provide here for the first time the complete set of solutions for this well-known effect in term of Jacobi elliptic functions.

astro-ph.EP↗

arXiv2011

Spin-orbit inclinations of the exoplanetary systems HAT-P-8, HAT-P-9, HAT-P-16 and HAT-P-23

We report the measurement of the spin-orbit angle of the extra-solar planets HAT-P-8 b, HAT-P-9 b, HAT-P-16 b and HAT-P-23 b, thanks to spectroscopic observations performed at the Observatoire de Haute-Provence with the SOPHIE spectrograph on the 1.93-m telescope. Radial velocity measurements of the Rossiter-McLaughlin effect show the detection of an apparent prograde, aligned orbit for all systems. The projected spin-orbit angles are found to be lambda=-17 deg (+9.2,-11.5), -16 deg (8), -10 deg (16), +15 deg (22) for HAT-P-8, HAT-P-9, HAT-P-16 and HAT-P-23 respectively, with corresponding projected rotational velocities of 14.5 (0.8), 12.5 (1.8), 3.9 (0.8), and 7.8 (1.6) km/s. These new results increase to 37 the number of accurately measured spin-orbit angles in transiting extrasolar systems. We conclude by drawing a tentative picture of the global behaviour of orbital alignement, involving the complexity and diversity of possible mechanisms.

astro-ph.EP↗