arXiv subjects

Donal P. Finegan

Publications and source records attributed to Donal P. Finegan.

6 recordsLinked to original sources

arXiv2026

Review of ultrasonic methods for monitoring, damage detection, and processing of lithium-ion batteries throughout their life-cycle

Lithium-ion batteries (LIBs) are the leading technology used in consumer electronics, electric vehicles, and grid-level electrochemical energy storage applications. The ever-increasing use of LIBs has highlighted a gap in understanding of their behavior throughout their life cycle. Current monitoring systems rely on electrical and sometimes temperature measurements to assess the internal state which limits information about complex electrochemical processes. In response, ultrasonic testing (UT) has shown promise for non-invasive assessment due to its ease of use and sensitivity to mechanical changes which are correlated with electrochemical changes within the battery. We summarize the research in UT methods applied to LIBs throughout their life cycle. We also discuss physics-based and data-driven modeling approaches used to interpret ultrasonic signals in the context of LIBs, with an emphasis on the existing challenge of establishing rigorous links between electrochemical behavior and elastic and poroelastic wave physics to gain insight regarding physical changes in the LIB that can be directly measured using UT. Finally, we discuss the challenges of implementing UT across the LIB life cycle and identify opportunities for further research. This review aims to provide helpful guidance to researchers and practitioners of UT in the growing field of UT for electrochemical battery systems.

physics.app-ph↗

arXiv2026

Particulate analysis of post-thermal runaway soot of Li-ion battery using X-ray computed tomography

The microstructural characteristics of soot generated during thermal runaway events in lithium-ion batteries have been examined, with a focus on the associated health risks. X-ray computed tomography (Nano-CT) offers advanced 3D imaging for accurate analysis of particle shape, size, and distribution. Its primary benefit is the detection of core-shell structures that contain thin shell of carcinogenic materials. In contrast, traditional techniques like X-ray diffraction can only quantify the mass fraction of these hazardous phases, which is often minimal. Nevertheless, even a small mass fraction of carcinogenic materials on carbonaceous surfaces poses significant health risks when inhaled, potentially compromising internal organ function. This research underscores the need for a deeper understanding of particulate composition to inform safety regulations and respiratory protection measures.

physics.ins-det↗

arXiv2024

Stochastic 3D reconstruction of cracked polycrystalline NMC particles using 2D SEM data

Li-ion battery performance is strongly influenced by their cathodes' properties and consequently by the 3D microstructure of the particles the cathodes are comprised of. During calendaring and cycling, cracks develop within cathode particles, which may affect performance in multiple ways. On the one hand, cracks reduce internal connectivity such that electron transport within cathode particles is hindered. On the other hand, intra-particle cracks can increase the cathode reactive surface. Due to these contradictory effects, it is necessary to quantitatively investigate how battery cycling effects cracking and how cracking in-turn influences battery performance. Thus, it is necessary to characterize the 3D particle morphology with structural descriptors and quantitatively correlate them with effective battery properties. Typically, 3D structural characterization is performed using image data. However, informative 3D imaging techniques are time-consuming, costly and rarely available, such that analyses often have to rely on 2D image data. This paper presents a novel stereological approach for generating virtual 3D cathode particles that exhibit crack networks that are statistically equivalent to those observed in 2D sections of experimentally measured particles. Consequently, more easily available 2D image data suffices for deriving a full 3D characterization of cracked cathodes particles. In future research, the virtually generated 3D particles will be used as geometry input for spatially resolved electro-chemo-mechanical simulations, to enhance our understanding of structure-property relationships of cathodes in Li-ion batteries.

cond-mat.mtrl-sci↗

arXiv2024

Generating multi-scale NMC particles with radial grain architectures using spatial stochastics and GANs

Understanding structure-property relationships of Li-ion battery cathodes is crucial for optimizing rate-performance and cycle-life resilience. However, correlating the morphology of cathode particles, such as in NMC811, and their inner grain architecture with electrode performance is challenging, particularly, due to the significant length-scale difference between grain and particle sizes. Experimentally, it is currently not feasible to image such a high number of particles with full granular detail to achieve representivity. A second challenge is that sufficiently high-resolution 3D imaging techniques remain expensive and are sparsely available at research institutions. To address these challenges, a stereological generative adversarial network (GAN)-based model fitting approach is presented that can generate representative 3D information from 2D data, enabling characterization of materials in 3D using cost-effective 2D data. Once calibrated, this multi-scale model is able to rapidly generate virtual cathode particles that are statistically similar to experimental data, and thus is suitable for virtual characterization and materials testing through numerical simulations. A large dataset of simulated particles with inner grain architecture has been made publicly available.

physics.app-ph↗

arXiv2021

Principles of the Battery Data Genome

Electrochemical energy storage is central to modern society -- from consumer electronics to electrified transportation and the power grid. It is no longer just a convenience but a critical enabler of the transition to a resilient, low-carbon economy. The large pluralistic battery research and development community serving these needs has evolved into diverse specialties spanning materials discovery, battery chemistry, design innovation, scale-up, manufacturing and deployment. Despite the maturity and the impact of battery science and technology, the data and software practices among these disparate groups are far behind the state-of-the-art in other fields (e.g. drug discovery), which have enjoyed significant increases in the rate of innovation. Incremental performance gains and lost research productivity, which are the consequences, retard innovation and societal progress. Examples span every field of battery research , from the slow and iterative nature of materials discovery, to the repeated and time-consuming performance testing of cells and the mitigation of degradation and failures. The fundamental issue is that modern data science methods require large amounts of data and the battery community lacks the requisite scalable, standardized data hubs required for immediate use of these approaches. Lack of uniform data practices is a central barrier to the scale problem. In this perspective we identify the data- and software-sharing gaps and propose the unifying principles and tools needed to build a robust community of data hubs, which provide flexible sharing formats to address diverse needs. The Battery Data Genome is offered as a data-centric initiative that will enable the transformative acceleration of battery science and technology, and will ultimately serve as a catalyst to revolutionize our approach to innovation.

physics.soc-ph↗

arXiv2021

Bridging Nano and Micro-scale X-ray Tomography for Battery Research by Leveraging Artificial Intelligence

X-ray Computed Tomography (X-ray CT) is a well-known non-destructive imaging technique where contrast originates from the materials' absorption coefficients. Novel battery characterization studies on increasingly challenging samples have been enabled by the rapid development of both synchrotron and laboratory-scale imaging systems as well as innovative analysis techniques. Furthermore, the recent development of laboratory nano-scale CT (NanoCT) systems has pushed the limits of battery material imaging towards voxel sizes previously achievable only using synchrotron facilities. Such systems are now able to reach spatial resolutions down to 50 nm. Given the non-destructive nature of CT, in-situ and operando studies have emerged as powerful methods to quantify morphological parameters, such as tortuosity factor, porosity, surface area, and volume expansion during battery operation or cycling. Combined with powerful Artificial Intelligence (AI)/Machine Learning (ML) analysis techniques, extracted 3D tomograms and battery-specific morphological parameters enable the development of predictive physics-based models that can provide valuable insights for battery engineering. These models can predict the impact of the electrode microstructure on cell performances or analyze the influence of material heterogeneities on electrochemical responses. In this work, we review the increasing role of X-ray CT experimentation in the battery field, discuss the incorporation of AI/ML in analysis, and provide a perspective on how the combination of multi-scale CT imaging techniques can expand the development of predictive multiscale battery behavioral models.

cond-mat.mtrl-sci↗