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Donato Giovannelli

Publications and source records attributed to Donato Giovannelli.

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Phosphorus abundances and multi-element co-enrichment in nearby FGK stars

The distribution of bio-essential elements is key to assessing the chemical fertility of galactic environments. We analyse phosphorus abundances for 233 nearby FGK stars from the Hypatia Catalog, separating thin- and thick-disk populations. We study [P/Fe] as a function of [Fe/H] and other elemental abundances using non-parametric tests and bootstrap resampling, and we examine residual correlations at fixed [Fe/H] together with molar ratios involving P. We find a [P/Fe]-[Fe/H] trend broadly similar to that of alpha elements, supporting a dominant origin in core-collapse supernovae, while deviations point to additional nucleosynthetic channels. Phosphorus shows strong positive correlations with several CHNOPS, alpha, and Fe-peak elements, especially in the thin disk. These co-enrichment patterns remain significant at fixed [Fe/H], indicating that they are not a trivial consequence of global metallicity. Thin-disk stars are also more enriched than thick-disk stars in many elements. The solar P/Mg and P/Si ratios are representative of the local stellar population, whereas solar P/O is relatively elevated. Overall, phosphorus emerges as a tracer of genuine multi-element co-enrichment and of the chemical fertility of the solar neighbourhood.

astro-ph.SR

Transition metal abundance as a key parameter for the search of Life in the Universe

The search for Life in the Universe generally assumes three basic life's needs: I) building block elements (i.e., CHNOPS), II) a solvent to life's reactions (generally, liquid water) and III) a thermodynamic disequilibrium. It is assumed that similar requirements might be universal in the Cosmos. On our planet, life is able to harvest energy from a wide array of thermodynamic disequilibria, generally in the form of redox disequilibrium. The amount of different redox couples used by living systems has been estimated to be in the range of several thousands of reactions. Each of these energy yielding reactions requires specialised proteins called oxidoreductases, that have one or more metal cofactors acting as catalytic centres to exchange electrons. These metals are de facto the key component of the engines that life uses to tap into the thermodynamic disequilibria needed to fuel metabolism. The availability of these transition metals is not uniform in the Universe, and it is a function of the distribution (in time and space) of complex dynamics. Despite this, Life's need for specific metals to access thermodynamic disequilibria has been so far completely overlooked in identifying astrobiological targets. We argue that the availability of at least some transition elements appears to be an essential feature of habitability, and should be considered a primary requisite in selecting exoplanetary targets in the search for life.

astro-ph.EP