arXiv subjects

Dong Yan

Publications and source records attributed to Dong Yan.

67 records · Page 4Linked to original sources

arXiv2019

CuIr2Te4: A Quasi-Two-Dimensional Ternary Telluride Chalcogenide Superconductor

Here we report the first observation of superconductivity in the AB2X4-type ternary telluride CuIr2Te4, which is synthesized by a solid-state method in an evacuated quartz jacket. It adopts a disordered trigonal structure with space group P3m1 (No. 164), which embodies a two-dimensional IrTe2 layers and intercalated by Cu between the layers. We use a combination of experimental and first principles calculation analysis to look insight into the structural and physical properties. CuIr2Te4 consistently exhibited a bulk superconductivity transition at 2.5 K in electrical resistivity, magnetic susceptibility and specific heat measurements. Resistivity and magnetization measurements suggest a charge density wave transition (TCDW = 250 K) coexists in CuIr2Te4, which further signify the coexistence of superconductivity and CDW in the ternary telluride chalcogenide CuIr2Te4. Our discovery of the new CDW-bearing superconductor CuIr2Te4 opens a door for experimental and theoretical studies of the interplay between CDW and superconductivity quantum state in the condensed matter field.

cond-mat.supr-con↗

arXiv2019

High CO2-tolerance oxygen permeation dual-phase membranes Ce0.9Pr0.1O2-δ-Pr0.6Sr0.4Fe0.8Al0.2O3-δ

High stability and oxygen permeability are two prominent requirements for the oxygen transport membrane candidates used as industrialization. Herein, we report several composite membranes based on xwt.%Ce0.9Pr0.1O2(CPO)-(100-x)wt.%Pr0.6Sr0.4Fe0.8Al0.2O3(PSFAO) (x = 50, 60 and 75) prepared via a modified Pechini method. Oxygen permeability test reveals that the 60CPO-40PSFAO composition exhibits the highest oxygen permeability. The oxygen permeation flux through the optimal uncoated 0.33 mm-thickness 60CPO-40PSFAO composite can reach 1.03 mL cm-2 min-1 (over the general requirement value of 1 mL cm-2 min-1) in air/He atmosphere at 1000 °C. In situ XRD performance confirms the optimal 60CPO-40PSFAO sample shows excellent stability in CO2-containing atmospheres. The 60CPO-40PSFAO membrane still exhibits simultaneously excellent oxygen permeability and phase stability after operating for over 100 h at air/CO2 condition at 1000 °C, which further indicates that the 60CPO-40PSFAO composite is likely to be used for oxygen supply in CO2 capture

physics.app-ph↗

arXiv2019

NbSeTe -A New Layered Transition Metal Dichalcogenide Superconductor

Transition metal dichalcogenides (TMDCs) usually exhibit layered polytypic structures due to the weak interlayer coupling. 2H-NbSe2 is one of the most widely studied in the pristine TMDC family due to its high superconducting transition temperature (Tc = 7.3K) and the occurrence of a charge-density wave (CDW) order below 33 K. The coexistence of CDW with superconductivity poses an intriguing open question about the relationship between Fermi surface nesting and Cooper pairing. Past studies of this issue have mostly been focused on doping 2H-NbSe2 by 3d transition metals without significantly changing its crystal structure. Here we replaced the Se by Te in 2H-NbSe2 in order to design a new 1T polytype layered TMDC NbSeTe, which adopts a trigonal structure with space group P-3m1. We successfully grew large size and high-quality single crystals of 1T-NbSeTe via the vapor transport method using I2 as the transport agent. Temperature-dependent resistivity and specific heat data revealed a bulk Tc at 1.3 K, which is the first observation of superconductivity in pure 1T-NbSeTe phase. This compound enlarged the family of superconducting TMDCs and provides an opportunity to study the interplay between CDW and superconductivity in the trigonal structure.

cond-mat.supr-con↗

arXiv2019

High-flux dual-phase percolation membrane for oxygen separation

A series of composites based on (100-x)wt.%Ce0.9Pr0.1O2-δ-xwt.%Pr0.6Ca0.4FeO3-δ (x = 25, 40 and 50) doped with the cheap and abundant alkaline earth metal Ca2+ at the A-site has been successfully designed and fabricated. The crystal structure, oxygen permeability, phase and CO2 stability were evaluated. The composition of 60wt.%Ce0.9Pr0.1O2-δ-40wt.%Pr0.6Ca0.4FeO3-δ(60CPO-40PCFO) possesses the highest oxygen permeability among three studied composites. At 1000 oC, the oxygen permeation fluxes through the 0.3 mm-thickness 60CPO-40PCFO membranes after porous La0.6Sr0.4CoO3-δ each to 1.00 mL cm-2 min-1 and 0.62 mL cm-2 min-1 under air/He and air/CO2 gradients, respectively. In situ XRD results demonstrated that the 60CPO-40PCFO sample displayed a perfect structural stability in air as well as CO2-containing atmosphere. Thus, low-cost, Co-free and Sr-free 60CPO-40PCFO has high CO2 stability and is economical and environmental friendly since the expensive and volatile element Co was replaced by Fe and Sr was waived since it easily forms carbonates.

physics.app-ph↗

arXiv2019

Effects of Al content on the oxygen permeability through dual-phase membrane 60Ce$_{0.9}$Pr$_{0.1}$O$_{2-δ}$-40Pr$_{0.6}$Sr$_{0.4}$Fe$_{1-x}$Al$_x$O$_{3-δ}$

Ceramic dual-phase oxygen transport membranes with the composition of 60wt.% Ce0.9Pr0.1O2-δ-40wt.%Pr0.6Sr0.4Fe1-xAlxO3-δ (x = 0.05, 0.1, 0.2, 0.3, 0.4, 0.6, 0.8, 1.0) (60CPO-40PSF1-xAxO) based on 60Ce0.9Pr0.1O2-δ-40Pr0.6Sr0.4FeO3-δ doped Al was successfully synthesized through a modified Pechini method. Crystal structure, surface microtopography and oxygen permeability are investigated systematically. The cell parameters of perovskite phase first increased and then decreased with the increase of Al content, which is related to the radius of the Al3+ and the formation of impurity phase. As x ranges from 0.1 to 0.8, the oxygen permeability of the materials first increases and then decreases, and the maximum value of oxygen permeation rate for 60CPO-40PSF1-xAxO membranes with 0.4mm thickness at 1000 °C is 1.12 mL min-1 cm-2 when x = 0.4. XRD measurements revealed high temperature stability and CO2-tolerant property of the dual-phase composites. The partial replacement of Fe$^{3+}$/Fe$^{4+}$ by Al$^{3+}$ causes the material not only to exhibit good stability, but also to increase the oxygen permeability of the membranes.

physics.app-ph↗

arXiv2019

The Unusual Suppression of Superconducting Transition Temperature in Double-Doping 2H-NbSe$_2$

2H-NbSe2 is one of the most widely researched transition metal dichalcogenide (TMD) superconductors, which undergoes charge-density wave (CDW) transition at TCDW about 33 K and superconducting transition at Tc of 7.3 K. To explore the relation between its superconductivity and Fermi surface nesting, we combined S substitution with Cu intercalation in 2H-NbSe2 to make CuxNbSe2-ySy. Upon systematic substitution of S and intercalation of Cu ions into 2H-NbSe2, we found that when the Cu and S contents increases, the Tc decreases in CuxNbSe2-ySy. While at higher x and y values, Tc keeps a constant value near 2 K, which is not commonly observed for a layered TMD. For comparison, we found the simultaneous substitution of Nb by Cu and Se by S in CuxNb1-xSe2-ySy lowered the Tc substantially faster. We construct a superconducting phase diagrams for our double-doping compounds in contrast with the related single-ions doping systems.

cond-mat.supr-con↗

arXiv2019

The Smooth Selection Embedding Method with Chebyshev Polynomials

We propose an implementation of the Smooth Selection Embedding Method (SSEM) in the setting of Chebyshev polynomials. The SSEM is a hybrid fictitious domain / collocation method which solves boundary value problems in complex domains by recasting them as constrained optimization problems in a simple encompassing set. Previously, the SSEM was introduced and implemented using a periodic box (read a torus) using Fourier series; here, it is implemented on a (non-periodic) rectangle using Chebyshev polynomial expansions. This implementation has faster convergence on smaller grids. Numerical experiments will demonstrate that the method provides a simple, robust, efficient, and high order fictitious domain method which can solve problems in complex geometries, with non-constant coefficients, and for general boundary conditions.

math.NA↗

arXiv2019

Reward Shaping via Meta-Learning

Reward shaping is one of the most effective methods to tackle the crucial yet challenging problem of credit assignment in Reinforcement Learning (RL). However, designing shaping functions usually requires much expert knowledge and hand-engineering, and the difficulties are further exacerbated given multiple similar tasks to solve. In this paper, we consider reward shaping on a distribution of tasks, and propose a general meta-learning framework to automatically learn the efficient reward shaping on newly sampled tasks, assuming only shared state space but not necessarily action space. We first derive the theoretically optimal reward shaping in terms of credit assignment in model-free RL. We then propose a value-based meta-learning algorithm to extract an effective prior over the optimal reward shaping. The prior can be applied directly to new tasks, or provably adapted to the task-posterior while solving the task within few gradient updates. We demonstrate the effectiveness of our shaping through significantly improved learning efficiency and interpretable visualizations across various settings, including notably a successful transfer from DQN to DDPG.

cs.LG↗

arXiv2018

Lazy-CFR: fast and near optimal regret minimization for extensive games with imperfect information

Counterfactual regret minimization (CFR) is the most popular algorithm on solving two-player zero-sum extensive games with imperfect information and achieves state-of-the-art performance in practice. However, the performance of CFR is not fully understood, since empirical results on the regret are much better than the upper bound proved in \cite{zinkevich2008regret}. Another issue is that CFR has to traverse the whole game tree in each round, which is time-consuming in large scale games. In this paper, we present a novel technique, lazy update, which can avoid traversing the whole game tree in CFR, as well as a novel analysis on the regret of CFR with lazy update. Our analysis can also be applied to the vanilla CFR, resulting in a much tighter regret bound than that in \cite{zinkevich2008regret}. Inspired by lazy update, we further present a novel CFR variant, named Lazy-CFR. Compared to traversing $O(|\mathcal{I}|)$ information sets in vanilla CFR, Lazy-CFR needs only to traverse $O(\sqrt{|\mathcal{I}|})$ information sets per round while keeping the regret bound almost the same, where $\mathcal{I}$ is the class of all information sets. As a result, Lazy-CFR shows better convergence result compared with vanilla CFR. Experimental results consistently show that Lazy-CFR outperforms the vanilla CFR significantly.

cs.LG↗

arXiv2018

Bayesian inverse problems with partial observations

We study a nonparametric Bayesian approach to linear inverse problems under discrete observations. We use the discrete Fourier transform to convert our model into a truncated Gaussian sequence model, that is closely related to the classical Gaussian sequence model. Upon placing the truncated series prior on the unknown parameter, we show that as the number of observations $n\rightarrow\infty,$ the corresponding posterior distribution contracts around the true parameter at a rate depending on the smoothness of the true parameter and the prior, and the ill-posedness degree of the problem. Correct combinations of these values lead to optimal posterior contraction rates (up to logarithmic factors). Similarly, the frequentist coverage of Bayesian credible sets is shown to be dependent on a combination of smoothness of the true parameter and the prior, and the ill-posedness of the problem. Oversmoothing priors lead to zero coverage, while undersmoothing priors produce highly conservative results. Finally, we illustrate our theoretical results by numerical examples.

math.ST↗

arXiv2018

Stable lattices in modular Galois representations and Hida deformation

In this paper, we discuss the variation of the numbers of the isomorphic classes of stable lattices when the weight and the level varies in a Hida deformation by using the Kubota-Leopoldt $p$-adic $L$-function. As a corollary, we give a sufficient condition for the numbers of the isomorphic classes of stable lattices in Hida deformation to be infinite.

math.NT↗

arXiv2013

The Krein Matrix: General Theory and Concrete Applications in Atomic Bose-Einstein Condensates

When finding the nonzero eigenvalues for Hamiltonian eigenvalue problems it is especially important to locate not only the unstable eigenvalues (i.e., those with positive real part), but also those which are purely imaginary but have negative Krein signature. These latter eigenvalues have the property that they can become unstable upon collision with other purely imaginary eigenvalues, i.e., they are a necessary building block in the mechanism leading to the so-called Hamiltonian-Hopf bifurcation. In this paper we review a general theory for constructing a meromorphic matrix-valued function, the so-called Krein matrix, which has the property of not only locating the unstable eigenvalues, but also those with negative Krein signature. These eigenvalues are realized as zeros of the determinant. The resulting finite dimensional problem obtained by setting the determinant of the Krein matrix to zero presents a valuable simplification. In this paper the usefulness of the technique is illustrated through prototypical examples of spectral analysis of states that have arisen in recent experimental and theoretical studies of atomic Bose-Einstein condensates. In particular, we consider one-dimensional settings (the cigar trap) possessing real-valued multi-dark-soliton solutions, and two-dimensional settings (the pancake trap) admitting complex multi-vortex stationary waveforms.

math-ph↗

arXiv2007

Entanglement conditions for tripartite systems via indeterminacy relations

Based on the S-R indeterminacy relations in conjugation with the partial transposition, we derive a class of inequalities for detecting entanglement in several tripartite systems, including bosonic, SU(2), and SU(1,1) systems. These inequalities are in general stronger than those based on the usual Heisenberg relations for detecting entanglement. We also discuss the reduction from SU(2) and SU(1,1) to bosonic systems and the generalization to multipartite case.

quant-ph↗