arXiv subjects

Donghui Quan

Publications and source records attributed to Donghui Quan.

At least 37 records · Page 2Linked to original sources

arXiv2025

First Search for Pulsed CH Maser Emission Stimulated by a Pulsar

We present the first search for pulsed CH maser emission potentially stimulated by PSR J1644$-$4559, conducted using the ultra-wide-bandwidth low-frequency receiver on Murriyang, CSIRO's Parkes Radio Telescope. Observations targeted three CH $Λ$-doublet transitions at 3264, 3335, and 3349 MHz, with a variability timescale of 78 ms. We detected ten CH emission features at 3335 and 3349 MHz, and seven features at 3264 MHz, during both pulsar-ON and pulsar-OFF phases. The observed velocities align with the OH emission and absorption reported by a previous study, suggesting a close spatial association between CH and OH molecules. The derived column densities for CH clouds within the Parkes beam range from $0.05$ to $9.8 \times 10^{13}$ cm$^{-2}$, indicating that these clouds are likely in diffuse and translucent states. Upper limits for CH column densities within the pulsar beam ranged from $0.3$ to $9.8 \times 10^{13}$ cm$^{-2}$. Comparison of these column densities suggests that CH clouds may exhibit clumpiness and substructure. No significant stimulated emission feature was detected in the optical depth spectra. Additionally, as part of our search for pulsed stimulated emission, we investigated the potential CH absorption of the pulsar signal and found none, in agreement with astrophysical expectations. The upper limits for the potential maser amplification factors towards PSR J1644$-$4559 at 3264, 3335, and 3349 MHz are 1.014, 1.009, and 1.009, respectively. This study demonstrates the feasibility of detecting pulsed CH maser emission in the interstellar medium stimulated by pulsar photons.

astro-ph.GA↗

arXiv2024

A Theory of Formalisms for Representing Knowledge

There has been a longstanding dispute over which formalism is the best for representing knowledge in AI. The well-known "declarative vs. procedural controversy" is concerned with the choice of utilizing declarations or procedures as the primary mode of knowledge representation. The ongoing debate between symbolic AI and connectionist AI also revolves around the question of whether knowledge should be represented implicitly (e.g., as parametric knowledge in deep learning and large language models) or explicitly (e.g., as logical theories in traditional knowledge representation and reasoning). To address these issues, we propose a general framework to capture various knowledge representation formalisms in which we are interested. Within the framework, we find a family of universal knowledge representation formalisms, and prove that all universal formalisms are recursively isomorphic. Moreover, we show that all pairwise intertranslatable formalisms that admit the padding property are also recursively isomorphic. These imply that, up to an offline compilation, all universal (or natural and equally expressive) representation formalisms are in fact the same, which thus provides a partial answer to the aforementioned dispute.

cs.AI↗

arXiv2024

3 mm Spectroscopic Observations of Massive Star-Forming Regions with IRAM 30-m

Broadband spectroscopic observations with high sensitivity provide an unbiased way to detect emissions of molecules in space. We present deep observations from ~ 105.8 GHz to 113.6 GHz toward 50 Galactic massive star-forming regions using IRAM 30-m millimeter telescope, with noise levels ranging from 6 to 29 at frequency channel spacing of 195 kHz, which corresponds to ~ 0.54 km/s at 110 GHz. Totally, 27 molecular species have been identified, of which 16 are complex organic molecules. The related parameters, such as peak temperature, integrated intensity, and line width of the identified molecular lines were obtained. The line widths of the chemically related molecules show strong positive correlations, suggesting they likely originate from similar gases within star-forming regions. This work highlights the fundamental properties of the detected molecular lines and offers a valuable dataset for further studies on the astrochemical evolution of molecules in massive star-forming cores.

astro-ph.SR↗

arXiv2024

Modeling Complex Organic Molecules Formation in Cold Cores: Multi-phase Models with Non-thermal Mechanisms

In recent years, a significant number of oxygen-bearing complex organic molecules (COMs) have been detected in the gas phase of cold dark clouds such as TMC-1. The formation of these COMs cannot be explained by diffusive mechanisms on grains and gas phase reactions. This study investigates the formation of oxygen-bearing COMs in cold dark clouds using multiphase gas-grain models that incorporate cosmic ray-induced non-diffusive radiation chemistry and non-thermal sputtering desorption mechanisms. Additionally, we present the effects of varying elemental C/O ratio and different sputtering rates. We utilized an accelerated Gillespie algorithm, based on the regular Gillespie algorithm. The results of our models for dimethyl ether (CH3OCH3), methyl formate (HCOOCH3), acetaldehyde (CH3CHO), ethanol (C2H5OH), and methanol (CH3OH) show reasonable agreement with observations toward TMC-1, within a factor of 3. Out of the 94 species compared with observations, 63 show agreement within 1 order of magnitude, accounting for 67.02%. Overall inclusion of non-thermal mechanisms in multi-phase models shows notable improvement of modeling on oxygen-bearing COMs in the interstellar medium.

astro-ph.GA↗

arXiv2024

The deuterium fractionation of NH$_3$ in massive star-forming regions

Deuteration is sensitive to environmental conditions in star-forming regions. To investigate NH$_2$D chemistry, we compared the spatial distribution of ortho-NH$_2$D $1_{11}^s-1_{01}^a$, NH$_3$(1,1) and NH$_3$(2,2) in 12 late-stage massive star-forming regions. By averaging several pixels along the spatial slices of ortho-NH$_2$D $1_{11}^s-1_{01}^a$, we obtained the deuterium fractionation of NH$_3$. In seven targets, the deuterium fractionation of NH$_3$ shows a decreasing trend with increasing rotational temperature. This trend is less clear in the remaining five sources, likely due to limited spatial resolution. However, when considering all 12 sources together, the anticorrelation between NH$_3$ deuterium fractionation and rotational temperature becomes less significant, suggesting that other physical parameters may influence the fractionation. Additionally, we found that the region of highest deuterium fractionation of NH$_3$ is offset from the NH$_3$ peak in each source, likely because the temperature is higher near the NH$_3$ peaks and NH$_2$D may be depleted from the gas phase as the molecular cloud core evolves, as well as the increased release of CO from grains into the gas phase.

astro-ph.GA↗

arXiv2024

Automated Identification and Segmentation of Hi Sources in CRAFTS Using Deep Learning Method

Identifying neutral hydrogen (\hi) galaxies from observational data is a significant challenge in \hi\ galaxy surveys. With the advancement of observational technology, especially with the advent of large-scale telescope projects such as FAST and SKA, the significant increase in data volume presents new challenges for the efficiency and accuracy of data processing.To address this challenge, in this study, we present a machine learning-based method for extracting \hi\ sources from the three-dimensional (3D) spectral data obtained from the Commensal Radio Astronomy FAST Survey (CRAFTS). We have carefully assembled a specialized dataset, HISF, rich in \hi\ sources, specifically designed to enhance the detection process. Our model, Unet-LK, utilizes the advanced 3D-Unet segmentation architecture and employs an elongated convolution kernel to effectively capture the intricate structures of \hi\ sources. This strategy ensures a reliable identification and segmentation of \hi\ sources, achieving notable performance metrics with a recall rate of 91.6\% and an accuracy of 95.7\%. These results substantiate the robustness of our dataset and the effectiveness of our proposed network architecture in the precise identification of \hi\ sources. Our code and dataset is publicly available at \url{https://github.com/fishszh/HISF}.

cs.CV↗

arXiv2024

FAST Observations of Four Comets to Search for the Molecular Line Emissions between 1.0 and 1.5 GHz Frequencies

We used the Five-hundred-meter Aperture Spherical radio Telescope (FAST) to search for the molecular emissions in the L-band between 1.0 and 1.5 GHz toward four comets, C/2020 F3 (NEOWISE), C/2020 R4 (ATLAS), C/2021 A1 (Leonard), and 67P/Churyumov-Gerasimenko during or after their perihelion passages. Thousands of molecular transition lines fall in this low-frequency range, many attributed to complex organic or prebiotic molecules. We conducted a blind search for the possible molecular lines in this frequency range in those comets and could not identify clear signals of molecular emissions in the data. Although several molecules have been detected at high frequencies of great than 100 GHz in comets, our results confirm that it is challenging to detect molecular transitions in the L-band frequency ranges. The non-detection of L-band molecular lines in the cometary environment could rule out the possibility of unusually strong lines, which could be caused by the masers or non-LTE effects. Although the line strengths are predicted to be weak, for FAST, using the ultra-wide bandwidth receiver and improving the radio frequency interference environments would enhance the detectability of those molecular transitions at low frequencies in the future.

astro-ph.EP↗

arXiv2024

Chemical models of interstellar glycine and adenine precursor aminoacetonitrile (NH2CH2CN)

Aminoacetonitrile (AAN), also known as glycinenitrile, has been suggested as a possible precursor of glycine and adenine in the interstellar medium. Here we present the chemical modeling of AAN and its isomers in hot cores using the three-phase chemical model NAUTILUS with the addition of over 300 chemical reactions of the three AAN isomers and related species. Our models predicted a peak gas phase abundance of AAN reaching the order of 10-8, which is consistent with observation towards Sgr B2(N). Regarding the reaction pathways of AAN and its isomers, we found that AAN is primarily formed via free radical reactions on grain surfaces during the early evolutionary stages. Subsequently, it is thermally desorbed into the gas phase as the temperature rises and is then destroyed by positive ions and radicals in gas phase. The isomers of AAN are formed through the hydrogenation reaction of CH3NCN on the grain surface and via electron recombination reactions of ion C2H5N2+ in gas phase. We speculate that there is a possibility for NCCN and AAN to react with each other, eventually leading to the formation of adenine in hot cores. However, further investigation is required to understand the efficiency of grain surfaces in adenine formation, through theoretical calculations or laboratory experiments in future research.

astro-ph.GA↗

arXiv2024

Turbulent Diffuse Molecular Media with Non-ideal Magnetohydrodynamics and Consistent Thermochemistry: Numerical Simulations and Dynamic Characteristics

Turbulent diffuse molecular clouds can exhibit complicated morphologies caused by the interactions among radiation, chemistry, fluids, and fields. We performed full 3D simulations for turbulent diffuse molecular interstellar media, featuring time-dependent non-equilibrium thermochemistry co-evolved with magnetohydrodynamics (MHD). Simulation results exhibit the relative abundances of key chemical species (e.g., C, CO, OH) vary by more than one order of magnitude for the "premature" epoch of chemical evolution ($t\lesssim 2\times 10^5~{\rm yr}$). Various simulations are also conducted to study the impacts of physical parameters. Non-ideal MHD effects are essential in shaping the behavior of gases, and strong magnetic fields ($\sim 10~μ{\rm G}$) tend to inhibit vigorous compressions and thus reduce the fraction of warm gases ($T\gtrsim 10^2~{\rm K}$). Thermodynamical and chemical conditions of the gas are sensitive to modulation by dynamic conditions, especially the energy injection by turbulence. Chemical features, including ionization (cosmic ray and diffuse interstellar radiation), would not directly affect the turbulence power spectra. Nonetheless, their effects are prominent in the distribution profiles of temperatures and gas densities. Comprehensive observations are necessary and useful to eliminate the degeneracies of physical parameters and constrain the properties of diffuse molecular clouds with confidence.

astro-ph.GA↗

arXiv2024

Investigating Sulfur Chemistry in the HD 163296 disk

Sulfur chemistry in the formation process of low-mass stars and planets remains poorly understood. The protoplanetary disks (PPDs) are the birthplace of planets and its distinctive environment provides an intriguing platform for investigating models of sulfur chemistry. We analyzed the ALMA observations of CS 7-6 transitions in the HD 163296 disk and perform astrochemical modeling to explore its sulfur chemistry. We simulated the distribution of sulfur-containing molecules and compared it with observationally deduced fractional column densities. We have found that the simulated column density of CS is consistent with the observationally deduced fractional column densities, while the simulated column density of C$_2$S is lower than the observationally deduced upper limits on column densities. This results indicate that we have a good understanding of the chemical properties of CS and C$_2$S in the disk. We also investigated the influence of the C/O ratio on sulfur-containing molecules and found that the column densities of SO, SO$_2$, and H$_2$S near the central star are dependent on the C/O ratio. Additionally, we found that the $N$[CS]/$N$[SO] ratio can serve as a promising indicator of the disk's C/O ratio in the HD 163296. Overall, the disk of HD 163296 provides a favorable environment for the detection of sulfur-containing molecules.

astro-ph.EP↗

arXiv2024

Astrochemical effect of the fundamental grain surface processes I. The diffusion of grain surface species and the pre-exponential factor

Abbreviation. Thermal diffusion is one of the basic processes for the mobility and formation of species on cosmic dust grains. Recent laboratory measurements have found that the diffusion pre-exponential factor can differ from that for desorption by several orders of magnitude. We aim to evaluate the effect of the newly experimentally measured diffusion pre-exponential factor on the chemistry under cold molecular cloud conditions. We found that statistically, more than half of the total gas-phase and grain surface species are not affected by the new pre-exponential factor after a chemical evolution of 10$^5$ yr. The most abundant gas-phase CO and grain surface water ice are not affected by the new pre-exponential factor. For the grain surface species that are affected, compared to the commonly adopted value of the pre-exponential factor for diffusion used in the chemical models, they could be either overproduced or underproduced with the lower diffusion pre-factor used in this work. The former case applies to radicals and the species that serve as reactants, while the latter case applies to complex organic molecules (COMs) on the grain and the species that rarely react with other species. Gas-phase species could also be affected due to the desorption of the grain surface species. The abundance of some gas-phase COMs could be varied by over one order of magnitude depending on the adopted grain surface temperature and/or the ratio of diffusion to desorption energy in the model. Key species whose diffusion pre-exponential factor significantly affects the model predictions were also evaluated, and these specie include CH3OH, H2CO, and NO. The results presented in this study show that the pre-exponential factor is one of the basic and important parameters in astrochemical models.

astro-ph.GA↗

arXiv2024

A $λ$ 3 mm line survey towards the circumstellar envelope of the carbon-rich AGB star IRC+10216 (CW Leo)

We present an unbiased $λ$ 3 mm spectral line survey (between 84.5 and 115.8 GHz), conducted by the Purple Mountain Observatory 13.7 meter radio telescope, together with updated modeling results, towards the carbon-rich Asymptotic Giant Branch star, IRC+10216 (CW Leo). A total of 75 spectral lines (96 transitions) are detected, and identified to arise from 19 molecules: C$_2$H, $l$-C$_3$H, C$_4$H, CN, C$_3$N, HC$_3$N, HC$_5$N, HCN, HNC, CH$_3$CN, MgNC, CO, $c$-C$_3$H$_2$, SiC$_2$, SiO, SiS, CS, C$_2$S, C$_3$S, and their isotopologues. Among them, one molecular emission line (H$^{13}$CCCN $J=13-12$) is discovered in IRC+10216 for the first time. The excitation temperature, column density, and fractional abundance of the detected species are deduced by assuming they are in local thermodynamic equilibrium. In addition, the isotopic ratios of [$^{12}$C]/[$^{13}$C], [$^{32}$S]/[$^{34}$S], [$^{28}$Si]/[$^{29}$Si], and [$^{12}$C$^{34}$S]/[$^{13}$C$^{32}$S] are obtained and found to be consistent with previous studies. Finally, we summarize all of the 106 species detected in IRC+10216 to date with their observed and modeled column densities for the convenience of future studies.

astro-ph.SR↗

arXiv2023

$α$-enhanced Astrochemistry: the Carbon cycle in extreme galactic conditions

Astrochemistry has been widely developed as a power tool to probe physical properties of the interstellar medium (ISM) in various conditions of the Milky Way (MW) Galaxy, and in near and distant galaxies. Most current studies conventionally apply linear scaling to all elemental abundances based on the gas-phase metallicity. However, these elements, including carbon and oxygen, are enriched differentially by stellar nucleosynthesis and the overall galactic chemical evolution, evident from $α$-enhancement in multiple galactic observations such as starbursts, high-redshift star-forming galaxies, and low-metallicity dwarfs. We perform astrochemical modeling to simulate the impact of an $α$-enhanced ISM gas cloud on the abundances of the three phases of carbon (C$^+$, C, CO) dubbed as `the carbon cycle'. The ISM environmental parameters considered include two cosmic-ray ionization rates ($ζ_{\rm CR}=10^{-17}$ and $10^{-15}\,{\rm s}^{-1}$), two isotropic FUV radiation field strengths ($χ/χ_0=1$ and $10^2$), and (sub-)linear dust-to-gas relations against metallicity, mimicking the ISM conditions of different galaxy types. In galaxies with [C/O] $<$ 0, CO, C and C$^+$ all decrease in both abundances and emission, though with differential biases. The low-$J$ CO emission is found to be the most stable tracer for the molecular gas, while C and C$^+$ trace H$_2$ gas only under limited conditions, in line with recent discoveries of [CI]-dark galaxies. We call for caution when using [CII]~$158μ$m and [CI](1-0) as alternative H$_2$-gas tracers for both diffuse and dense gas with non-zero [C/O] ratios.

astro-ph.GA↗

arXiv2023

Tentative detection of cyanoformamide NCCONH2 in space

The peptide-like molecules, cyanoformamide (NCCONH2), is the cyano (CN) derivative of formamide (NH2CHO). It is known to play a role in the synthesis of nucleic acid precursors under prebiotic conditions. In this paper, we present a tentative detection of NCCONH2 in the interstellar medium (ISM) with the Atacama Large Millimeter/submillimeter Array (ALMA) archive data. Ten unblended lines of NCCONH2 were seen around 3sigma noise levels toward Sagittarius B2(N1E), a position that is slightly offset from the continuum peak. The column density of NCCONH2 was estimated to be 2.4\times 10^15 cm ^-2, and the fractional abundance of NCCONH2 toward Sgr B2(N1E) was 6.9\times10^-10. The abundance ratio between NCCONH2 and NH2CHO is estimated to be ~0.01. We also searched for other peptide-like molecules toward Sgr B2(N1E). The abundances of NH2CHO, CH3NCO and CH3NHCHO toward Sgr B2(N1E) were about one tenth of those toward Sgr B2(N1S), while the abundances of CH3CONH2 was only one twentieth of that toward Sgr B2(N1S).

astro-ph.GA↗

arXiv2023

Mapping Observations of Peptide-like molecules around Sagittarius B2

Peptide-like molecule, which has a close connection with the origin of life, has been detected in universe. Mapping observations of HCONH$_2$ and CH$_3$CONH$_2$, two simplest peptide-like molecules, are performed towards Sagittarius B2 (Sgr B2) complex with the IRAM 30m telescope. Seven transitions of HCONH$_2$ and five transitions of CH$_3$CONH$_2$ are used in analysis. The spatial distribution of excitation temperature and column density of HCONH$_2$ in the molecular envelope of Sgr B2 are obtained by the rotation diagrams. Assuming the same excitation temperature as HCONH$_2$, the column densities of CH$_3$CONH$_2$ are also calculated. The results show that excitation temperature ranges from 6 K to 46 K in the molecular envelope of Sgr B2. The abundance ratio between HCONH$_2$ and CH$_3$CONH$_2$ are calculated to explore the relationship among them, as well as HNCO mentioned in our pervious research. The abundance ratio of CH$_3$CONH$_2$/HCONH$_2$ varies from 10% to 20%, while that of HCONH$_2$/HNCO ranges from 1.5% to 10%. CH$_3$CONH$_2$ is enhanced with respect to HCONH$_2$ in the northwest region of Sgr B2. One transition of H$^{13}$CONH$_2$ is detected toward 12 positions of Sgr B2, from which a $^{12}$C/$^{13}$C ratio of 28.7 is obtained. A time-dependent chemical model with a short duration of X-ray burst is used to explain the observed abundances of HCONH$_2$ and CH$_3$CONH$_2$, with the best fitting result at T$\rm_{dust}$ = 53-56 K. More chemical reactions are required to be included into the model since the modeled abundance is lower than the observed one at the observed T$\rm_{dust}$.

astro-ph.GA↗

arXiv2023

Coverage Dependent H$_2$ Desorption Energy: a Quantitative Explanation Based on Encounter Desorption Mechanism

Recent experiments show that the desorption energy of H$_2$ on a diamond-like carbon (DLC) surface depends on the H$_2$ coverage of the surface. We aim to quantitatively explain the coverage dependent H$_2$ desorption energy measured by the experiments. We derive a math formula to calculate an effective H$_2$ desorption energy based on the encounter desorption mechanism. The effective H$_2$ desorption energy depends on two key parameters, the desorption energy of H$_2$ on H$_2$ substrate and the ratio of H$_2$ diffusion barrier to its desorption energy. The calculated effective H$_2$ desorption energy qualitatively agrees with the coverage dependent H$_2$ desorption energy measured by the experiments if the values of these two parameters in literature are used in the calculations. We argue that the difference between the effective H$_2$ desorption energy and the experimental results is due to the lacking of knowledge about these two parameters. So, we recalculate these two parameters based on experimental data. Good agreement between theoretical and experimental results can be achieved if these two updated parameters are used in the calculations.

astro-ph.GA↗

arXiv2023

Photochemical origin of SiC$_2$ in the circumstellar envelope of carbon-rich AGB stars revealed by ALMA

Whether SiC$_2$ is a parent species, that is formed in the photosphere or as a by-product of high-temperature dust formation, or a daughter species, formed in a chemistry driven by the photodestruction of parent species in the outer envelope, has been debated for a long time. Here, we analyze the ALMA observations of four SiC$_2$ transitions in the CSEs of three C-rich AGB stars (AI Vol, II Lup, and RAFGL 4211), and found that SiC$_2$ exhibits an annular, shell-like distribution in these targets, suggesting that SiC$_2$ can be a daughter species in the CSEs of carbon-rich AGB stars. The results can provide important references for future chemical models.

astro-ph.SR↗

arXiv2023

Imaging Molecular Outflow in Massive Star-forming Regions with HNCO Lines

Protostellar outflows are considered a signpost of star formation. These outflows can cause shocks in the molecular gas and are typically traced by the line wings of certain molecules. HNCO (4--3) has been regarded as a shock tracer because of the high abundance in shocked regions. Here we present the first imaging results of HNCO (4--3) line wings toward nine sources in a sample of twenty three massive star-forming regions using the IRAM 30\,m telescope. We adopt the velocity range of the full width of HC$_{3}$N (10--9) and H$^{13}$CO$^+$ (1--0) emissions as the central emission values, beyond which the emission from HNCO (4--3) is considered to be from line wings. The spatial distributions of the red- and/or blue-lobes of HNCO (4--3) emission nicely associate with those lobes of HCO$^{+}$ (1--0) in most of the sources. High intensity ratios of HNCO (4--3) to HCO$^+$ (1--0) are obtained in the line wings. The derived column density ratios of HNCO to HCO$^+$ are consistent with those previously observed towards massive star-forming regions. These results provide direct evidence that HNCO could trace outflow in massive star-forming regions. This work also implies that the formation of some HNCO molecules is related to shock, either on the grain surface or within the shocked gas.

astro-ph.GA↗