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Doriano Brogioli

Publications and source records attributed to Doriano Brogioli.

16 recordsLinked to original sources

Covariant Lyapunov vectors as global solutions of a partial differential equation on the phase space

As a new tool to describe the behaviour of a dynamical system, we introduce the concept of "covariant Lyapunov field", i.e. a field which assigns all the components of covariant Lyapunov vectors at almost all points of the phase space. We focus on the case in which these fields are overall continuous and also differentiable along individual trajectories. We show that in ergodic systems such fields can be characterized as the global solutions of a differential equation on the phase space. Due to the arbitrariness in the choice of a multiplicative scalar factor for the Lyapunov vector at each point of the phase space, this differential equation exhibits a gauge invariance that is formally analogous to that of quantum electrodynamics. Under the hypothesis that the covariant Lyapunov field is overall differentiable, we give a geometric interpretation of our result: each 2-dimensional foliation of the space that contains whole trajectories is univocally associated with a Lyapunov exponent, and the corresponding covariant Lyapunov field is one of the generators of the foliation. In order to show with an example how this new approach can be applied to the study of concrete dynamical systems, we display an explicit solution of the differential equations that we have obtained for the covariant Lyapunov fields in a model involving a geodesic flow.

math-ph

A toy model solved by statistical mechanics for teaching reaction kinetics beyond ideality

Chemical equilibrium is fully characterized by thermodynamics, while the rates of chemical reactions can be calculated for ideal solutions by using mass-action equations. The evaluation of the rates of reactions in a non-ideal system is instead much more complex, even at equilibrium, being dependent on the microscopic features of the interactions: no universal theory exist. Here we propose a toy model to help students understand such complexity. It is formulated by means of statistical mechanics and aims at the evaluation of the exchange reaction rate at equilibrium. The toy model can be solved by the students, with various types of interactions, as an exercise. The results prove that no general rule connects the reaction rates to the thermodynamic quantities, such as the activity coefficients, dramatically proving the complexity and richness of the field.

physics.chem-ph

A no-go theorem for sequential and retro-causal hidden-variable theories based on computational complexity

The celebrated Bell's no-go theorem rules out the hidden-variable theories falling in the hypothesis of locality and causality, by requiring the theory to model the quantum correlation-at-a-distance phenomena. Here I develop an independent no-go theorem, by inspecting the ability of a theory to model quantum \emph{circuits}. If a theory is compatible with quantum mechanics, then the problems of solving its mathematical models must be as hard as calculating the output of quantum circuits, i.e., as hard as quantum computing. Rigorously, I provide complexity classes capturing the idea of sampling from sequential (causal) theories and from post-selection-based (retro-causal) theories; I show that these classes fail to cover the computational complexity of sampling from quantum circuits. The result is based on widely accepted conjectures on the superiority of quantum computers over classical ones. The result represents a no-go theorem that rules out a large family of sequential and post-selection-based theories. I discuss the hypothesis of the no-go theorem and the possible ways to circumvent them. In particular, I discuss the Schulman model and its extensions, which is retro-causal and is able to model quantum correlation-at-a-distance phenomena: I provides clues suggesting that it escapes the hypothesis of the no-go theorem.

quant-ph

How much classical information is carried by a quantum state? An approach inspired by Kolmogorov complexity

In quantum mechanics, a state is an element of a Hilbert space whose dimension exponentially grows with the increase of the number of particles (or qubits, in quantum computing). The vague question "is this huge Hilbert space really there?" has been rigorously formalized inside the computational complexity theory; the research suggests a positive answer to the question. Along this line, I give a definition of the (classical) information content of a quantum state, taking inspiration from the Kolmogorov complexity. I show that, for some well-known quantum circuits (having a number of gates polynomial in the number of qubits), the information content of the output state, evaluated according to my definition, is polynomial in the number of qubits. On the other hand, applying known results, it is possible to devise quantum circuits that generate much more complex states, having an exponentially-growing information content. A huge amount of classical information can be really present inside a quantum state, however, I show that this property is not necessarily exploited by quantum computers, not even by quantum algorithms showing an exponential speed-up with respect to classical computation.

quant-ph

Giant non-equilibrium fluctuations in diffusion in freely-suspended liquid films

Experimental work has shown that non-equilibrium concentration fluctuations arise during free diffusion in fluids and theoretical analysis has been carried on. The results show that, in usual three-dimensional fluids, the phenomenon is extremely weak, in terms of amplitude of the fluctuations and of corrugation of the diffusion wave fronts. In this paper, we show that the phenomena strongly depends on the dimensionality of the system: by extending the theory to two dimensional systems, we show that the root mean square amplitude of the fluctuations and the wave front corrugation become much stronger. We also present an evaluation of the Hausdorf dimension of the expected fluctuations. Experimentally, two-dimensional liquid systems can be realised as freely suspended liquid films; experiments and theoretical works on diffusion in such systems showed that the dynamics is deeply affected by the viscous drag exerted by the fluids (e.g. air) surrounding the film. We provide an evaluation of the drag on the fluctuations. In particular, we study the case of a concentration profile that is initially gaussian: it can be directly compared with the results from a fluorescence recovery after photobleaching (FRAP) experiment. We propose that this theory and the related experiments can be relevant for describing the diffusion along the cellular membranes of living organisms.

physics.flu-dyn

Theoretical thermodynamic analysis of a closed-cycle process for the conversion of heat into electrical energy by means of a distiller and an electrochemical cell

We analyse a device aimed at the conversion of heat into electrical energy, based on a closed cycle in which a distiller generates two solutions at different concentrations, and an electrochemical cell consumes the concentration difference, converting it into electrical current. We first study an ideal model of such a process. We show that, if the device works at a single fixed pressure (i.e. with a ``single effect''), then the efficiency of the conversion of heat into electrical power can approach the efficiency of a reversible Carnot engine operating between the boiling temperature of the concentrated solution and that of the pure solvent. When two heat reservoirs with a higher temperature difference are available, the overall efficiency can be incremented by employing an arrangement of multiple cells working at different pressures (``multiple effects''). We find that a given efficiency can be achieved with a reduced number of effects by using solutions with a high boiling point elevation.

physics.chem-ph

A new open source software for the calculation of the liquid junction potential between two solutions according to the stationary Nernst-Planck equation

We describe an open source software which we have realized and made publicly available at the website http://jljp.sourceforge.net. It provides the potential difference and the ion fluxes across a liquid junction between the solutions of two arbitrary electrolytes. The calculation is made by solving the Nernst-Planck equations for the stationary state in conditions of local electrical quasi-neutrality at all points of the junction. The user can arbitrarily assign the concentrations of the ions in the two solutions, and also specify the analytical dependence of the diffusion coefficient of each ion on its concentration.

physics.chem-ph

Correlation function of the velocity field of a thin suspended liquid film

In this paper, I consider a thin suspended liquid film, surrounded by a different fluid. Examples of such a system are soap films and liquid crystal films, surrounded by air. They are considered good models for two dimensional fluid dynamics, although air drag is known to introduce strong deviations. I exactly solve the hydrodynamic equations of the system composed by the liquid layer and the surrounding fluid in order to evaluate the correlation function of the thermally excited velocity fluctuations. Both the temporal and the spatial statistical properties are the ones of a two dimensional, hypotetical fluid, only for temporal and spatial frequencies higher than critical values; at lower frequencies they show significative deviations due to the interactions of the liquid layer with the surrounding fluid.

physics.flu-dyn

Characterization of anisotropic nano-particles by using depolarized dynamic light scattering in the near field

Light scattering techniques are widely used in many fields of condensed and sof t matter physics. Usually these methods are based on the study of the scattered light in the far field. Recently, a new family of near field detection schemes has been developed, mainly for the study of small angle light scattering. These techniques are based on the detection of the light intensity near to the sample, where light scattered at different directions overlaps but can be distinguished by Fourier transform analysis. Here we report for the first time data obtained with a dynamic near field scattering instrument, measuring both polarized and depolarized scattered light. Advantages of this procedure over the traditional far field detection include the immunity to stray light problems and the possibility to obtain a large number of statistical samples for many different wave vectors in a single instantaneous measurement. By using the proposed technique we have measured the translational and rotational diffusion coefficients of rod-like colloidal particles. The obtained data are in very good agreement with the data acquired with a traditional light scattering apparatus.

physics.optics

Design of magnetic tweezers for DNA manipulation

We study different configurations of permanent magnets and ferromagnetic circuit, in order to optimize the magnetic field for the so-called ``magnetic tweezers'' technique, for studing mechanical properties of DNA molecules. The magnetic field is used to pull and twist a micron-sized superparamagnetic bead,tethered to a microscope slide surface by a DNA molecule. The force applied to the bead must be vertical, pointing upwards, being as strong as possible, and it must decrease smoothly as the magnets are moved away from the bead. In order to rotate the bead around the vertical axis, the field must be horizontal. Moreover, the volume occupied by the magnets is limited by the optical system. We simulate different configurations by solving the equations for the static magnetic field; then, we test some of the configurations by measuring the force acting on a bead tethered by a DNA molecule. One of the configurations is able to generate a magnetic field ten times stronger than usually reported.

q-bio.BM

Near Field Speckles

Elastic light scattering has been extensively used to study samples showing a non uniform refraction index on lengthscales from a fraction of a micrometer to a fraction of a millimeter. Typically, a wide laser beam is sent through the sample, and the light scattered at any angle is measured by a detector in the far field. In this Ph. D. thesis, I describe three new techniques, which allow to measure the scattering intensities, working in the near field: hOmoyne Near Field Speckles (ONFS), hEterodyne Near Field Speckles (ENFS) and Schlieren-like Near Field Speckles (SNFS). Basically, the experimental setup consists in a wide laser beam passing through the sample; a lens forms an image of a plane at a given distance from the cell on a CCD sensor. The image, in the near field, shows speckles, since it is formed by the stochastical interference of the light coming from a random sample. I show that, under suitable conditions, the correlation function of such a field closely mirrors the correlation function of the investigated sample; moreover, in general, from the correlation function of the speckle field it is possible to calculate the scattered intensity. I present for the first time a mathematical derivation of the working formulas for the three techniques, and experimental results.

physics.optics

Nano-particle characterization by using Exposure Time Dependent Spectrum and scattering in the near field methods: how to get fast dynamics with low-speed CCD camera

Light scattering detection in the near field, a rapidly expanding family of scattering techniques, has recently proved to be an appropriate procedure for performing dynamic measurements. Here we report an innovative algorithm, based on the evaluation of the Exposure Time Dependent Spectrum (ETDS), which makes it possible to measure the fast dynamics of a colloidal suspension with the aid of a simple near field scattering apparatus and a CCD camera. Our algorithm consists in acquiring static spectra in the near field at different exposure times, so that the measured decay times are limited only by the exposure time of the camera and not by its frame rate. The experimental set-up is based on a modified microscope, where the light scattered in the near field is collected by a commercial objective, but (unlike in standard microscopes) the light source is a He-Ne laser which increases the instrument sensitivity. The apparatus and the algorithm have been validated by considering model systems of standard spherical nano-particle.

physics.optics

Heterodyne Near-Field Scattering

We describe an optical technique based on the statistical analysis of the random intensity distribution due to the interference of the near-field scattered light with the strong transmitted beam. It is shown that, from the study of the two-dimensional power spectrum of the intensity, one derives the scattered intensity as a function of the scattering wave vector. Near-field conditions are specified and discussed. The substantial advantages over traditional scattering technique are pointed out, and is indicated that the technique could be of interest for wave lengths other than visible light.

physics.optics

A schlieren method for ultra-low angle light scattering measurements

We describe a self calibrating optical technique that allows to perform absolute measurements of scattering cross sections for the light scattered at extremely small angles. Very good performances are obtained by using a very simple optical layout similar to that used for the schlieren method, a technique traditionally used for mapping local refraction index changes. The scattered intensity distribution is recovered by a statistical analysis of the random interference of the light scattered in a half-plane of the scattering wave vectors and the main transmitted beam. High quality data can be obtained by proper statistical accumulation of scattered intensity frames, and the static stray light contributions can be eliminated rigorously. The potentialities of the method are tested in a scattering experiment from non equilibrium fluctuations during a free diffusion experiment. Contributions of light scattered from length scales as long as Lambda=1 mm can be accurately determined.

physics.optics

Real-Time Wavelet-transform spectrum analyzer for the investigation of 1/f^αnoise

A wavelet transform spectrum analyzer operating in real time within the frequency range 3X10^(-5) - 1.3X10^5 Hz has been implemented on a low-cost Digital Signal Processing board operating at 150MHz. The wavelet decomposition of the signal allows to efficiently process non-stationary signals dominated by large amplitude events fairly well localized in time, thus providing the natural tool to analyze processes characterized by 1/f^alpha power spectrum. The parallel architecture of the DSP allows the real-time processing of the wavelet transform of the signal sampled at 0.3MHz. The bandwidth is about 220dB, almost ten decades. The power spectrum of the scattered intensity is processed in real time from the mean square value of the wavelet coefficients within each frequency band. The performances of the spectrum analyzer have been investigated by performing Dynamic Light Scattering experiments on colloidal suspensions and by comparing the measured spectra with the correlation functions data obtained with a traditional multi tau correlator. In order to asses the potentialities of the spectrum analyzer in the investigation of processes involving a wide range of timescales, we have performed measurements on a model system where fluctuations in the scattered intensities are generated by the number fluctuations in a dilute colloidal suspension illuminated by a wide beam. This system is characterized by a power-law spectrum with exponent -3/2 in the scattered intensity fluctuations. The spectrum analyzer allows to recover the power spectrum with a dynamic range spanning about 8 decades. The advantages of wavelet analysis versus correlation analysis in the investigation of processes characterized by a wide distribution of time scales and non-stationary processes are briefly discussed.

cond-mat.stat-mech

Diffusive mass transfer by non equilibrium fluctuations: Fick's law revisited

Recent experimental and theoretical works have shown that giant fluctuations are present during diffusion in liquid systems. We use linearized fluctuating hydrodynamics to calculate the net mass transfer due to these non equilibrium fluctuations. Surprisingly the mass flow turns out to coincide with the usual Fick's one. The renormalization of the hydrodynamic equations allows us to quantify the gravitational modifications of the diffusion coefficient induced by the gravitational stabilization of long wavelength fluctuations.

cond-mat.stat-mech