Drew C. Pendergrass | Searcharxiv

arXiv2024

Model underestimates of OH reactivity cause overestimate of hydrogen's climate impact

Deploying hydrogen technologies is one option to reduce energy carbon dioxide emissions, but recent studies have called attention to the indirect climate implications of fugitive hydrogen emissions. We find that biases in hydroxyl (OH) radical concentrations and reactivity in current atmospheric chemistry models may cause a 20% overestimate of the hydrogen Global Warming Potential (GWP). A better understanding of OH chemistry is critical for reliable estimates of the hydrogen GWP.

physics.ao-ph↗

arXiv2022

Coarse particulate matter air quality in East Asia: implications for fine particulate nitrate

Coarse particulate matter (PM) is a serious air pollution problem in East Asia. Analysis of air quality network observations in the North China Plain and the Seoul Metropolitan Area shows that it is mainly anthropogenic and has decreased by 21% over 2015-2019. This anthropogenic coarse PM is generally not included in air quality models but scavenges nitric acid to suppress the formation of fine particulate (PM2.5) nitrate, a major contributor to PM2.5 pollution. Including it in the GEOS-Chem model decreases simulated PM2.5 nitrate to improve agreement with observations. Decreasing anthropogenic coarse PM over 2015-2019 directly increases PM2.5 nitrate in summer, offsetting the effect of other emission controls, while in winter it increases the sensitivity of PM2.5 nitrate to ammonia and sulfur dioxide emissions. Our work implies the need for stronger ammonia and nitrogen oxides emission controls to improve PM2.5 air quality as coarse PM continues to decrease.

physics.ao-ph↗