arXiv subjects

Du Chen

Publications and source records attributed to Du Chen.

12 recordsLinked to original sources

arXiv2026

Non-uniform swelling of polyelectrolyte hydrogels: effects of charge regulation

We investigate the impact of charge regulation (CR) on the non-uniform swelling behavior of polyelectrolyte hydrogels. The Poisson-Boltzmann theory with electro-elastic coupling between the local polymer density and elastic deformation is considered. We investigate the spatial distributions of the elastic displacement and polymer density under different salt concentrations and compare charge-regulated gels with fixed-charge (non-CR) gels of the same net charge. Our results show that the CR induces spatially varying charge fractions, which strengthen the electro-elastic response and lead to stronger non-uniform swelling compared with non-CR gels. These findings provide a theoretical basis for understanding and controlling non-uniform swelling in responsive polyelectrolyte hydrogels.

cond-mat.soft↗

arXiv2026

ColorFM: An Optimization-to-Learning Framework for Color Transfer via Flow Matching

Color transfer aims to align the color distribution of a source image with that of a reference image while preserving structural and semantic consistency. However, existing methods often suffer from inaccurate global mapping, semantic misalignment, and visual artifacts. To address these issues, we propose ColorFM, an optimization-to-learning framework. ColorFM connects online optimization to offline inference by reformulating color transfer as the transport of pixel distributions along velocity fields via Flow Matching. Specifically, we introduce ColorFM-O, an instance-specific optimization scheme that fits the velocity field through hierarchical color coupling guided by semantic priors. By numerically integrating the induced flow trajectories, ColorFM-O produces precise and semantically consistent color transfer results, while generating high-quality paired data as pseudo-supervision. Building upon this, we design ColorFM-L, an efficient feed-forward model trained on the generated pairs. Through implicit state modeling, ColorFM-L extracts deep semantic features to predict flow parameters for bidirectional linearized transport, ensuring accurate color transfer. Extensive experiments demonstrate that ColorFM-L outperforms state-of-the-art methods in visual quality, structural fidelity, and semantic consistency, successfully combining the accuracy of optimization with the speed of feed-forward inference.

cs.CV↗

arXiv2026

Ultraviolet Exciton-Polaritons in Silver Phenylthiolate

Ultraviolet (UV) exciton-polaritons (EPs) enable nonlinear optics, polaritonic lasing, and polariton-mediated photochemistry in the short-wavelength regime, yet progress has been limited due to the scarcity of materials that combine large oscillator strength with stable and narrow UV excitons. Here, we demonstrate UV EPs in silver phenylthiolate (Thiorene, AgSPh), a van der Waals (vdW) layered metal-organic chalcogenolate (MOC) that forms a natural multi-quantum-well (MQW) architecture showing strong excitonic features. Imaging spectroscopic ellipsometry reveals a pronounced in-plane excitonic resonance at 3.46 eV with a narrow linewidth of ~ 60 meV, strong UV birefringence ({\Delta}n ~ 0.3), and a high refractive index (n ~ 2.1). Temperature-dependent photoluminescence (PL) shows excitonic emission with a large Stokes shift and substantial exciton-phonon coupling. In both open (self-cavity) and closed cavities, thickness-dependent and angle-resolved reflectance spectra exhibit clear anticrossing, yielding large Rabi splittings of approximately 500 meV. These values are among the largest reported in the UV, positioning thiorene as a promising platform for UV polariton lasers and polariton-enabled photochemistry.

physics.optics↗

arXiv2026

Photoinduced metastable cation disorder in metal halide double perovskites

Lead-free perovskites have emerged as environmentally benign alternatives to lead-halide counterparts for optoelectronics. Among them, the double perovskite Cs2AgInCl6 family exhibits remarkable white-light emission with proper composition engineering, enabled by strong electron-phonon coupling and the formation of self-trapped excitons (STEs). Despite these advantages, the fundamental photo- and structural dynamics governing their excited-state behavior remain poorly understood. Here, we report a long-lived metastable phase in the Cs2AgInCl6 double perovskite family and unravel this process and the concomitant electronic and structural evolution using a suite of tools including transient optical spectroscopy, time-resolved X-ray diffraction (TR-XRD) and X-ray absorption (TR-XAS). We show that the photoinduced, transient metastable phase is associated with B-site (Ag-In) disorder, which induces a dramatically reduced optical bandgap. Supported by TR-XRD and first-principles calculations, the Ag-In disorder drives the formation of Ag-rich and In-rich domains with millisecond lifetimes, with lifetimes increasing at lower temperatures. TR-XAS further reveals that photogenerated STEs oxidize Ag+ to Ag2+, facilitating this highly temporally asymmetric order-disorder transition. Our findings demonstrate a new mechanism, mediated by hole-localized STE formation, that enables prolongation of transient light-induced states to the multi-millisecond regime in double perovskites, opening possibilities to harvesting the functional properties of metastable phases of these materials.

cond-mat.mtrl-sci↗

arXiv2025

The Unanticipated Asymmetry Between Perceptual Optimization and Assessment

Perceptual optimization is primarily driven by the fidelity objective, which enforces both semantic consistency and overall visual realism, while the adversarial objective provides complementary refinement by enhancing perceptual sharpness and fine-grained detail. Despite their central role, the correlation between their effectiveness as optimization objectives and their capability as image quality assessment (IQA) metrics remains underexplored. In this work, we conduct a systematic analysis and reveal an unanticipated asymmetry between perceptual optimization and assessment: fidelity metrics that excel in IQA are not necessarily effective for perceptual optimization, with this misalignment emerging more distinctly under adversarial training. In addition, while discriminators effectively suppress artifacts during optimization, their learned representations offer only limited benefits when reused as backbone initializations for IQA models. Beyond this asymmetry, our findings further demonstrate that discriminator design plays a decisive role in shaping optimization, with patch-level and convolutional architectures providing more faithful detail reconstruction than vanilla or Transformer-based alternatives. These insights advance the understanding of loss function design and its connection to IQA transferability, paving the way for more principled approaches to perceptual optimization.

cs.CV↗

arXiv2025

Toward Generalized Image Quality Assessment: Relaxing the Perfect Reference Quality Assumption

Full-reference image quality assessment (FR-IQA) generally assumes that reference images are of perfect quality. However, this assumption is flawed due to the sensor and optical limitations of modern imaging systems. Moreover, recent generative enhancement methods are capable of producing images of higher quality than their original. All of these challenge the effectiveness and applicability of current FR-IQA models. To relax the assumption of perfect reference image quality, we build a large-scale IQA database, namely DiffIQA, containing approximately 180,000 images generated by a diffusion-based image enhancer with adjustable hyper-parameters. Each image is annotated by human subjects as either worse, similar, or better quality compared to its reference. Building on this, we present a generalized FR-IQA model, namely Adaptive Fidelity-Naturalness Evaluator (A-FINE), to accurately assess and adaptively combine the fidelity and naturalness of a test image. A-FINE aligns well with standard FR-IQA when the reference image is much more natural than the test image. We demonstrate by extensive experiments that A-FINE surpasses standard FR-IQA models on well-established IQA datasets and our newly created DiffIQA. To further validate A-FINE, we additionally construct a super-resolution IQA benchmark (SRIQA-Bench), encompassing test images derived from ten state-of-the-art SR methods with reliable human quality annotations. Tests on SRIQA-Bench re-affirm the advantages of A-FINE. The code and dataset are available at https://tianhewu.github.io/A-FINE-page.github.io/.

cs.CV↗

arXiv2025

Generalized and Efficient 2D Gaussian Splatting for Arbitrary-scale Super-Resolution

Implicit Neural Representations (INR) have been successfully employed for Arbitrary-scale Super-Resolution (ASR). However, INR-based models need to query the multi-layer perceptron module numerous times and render a pixel in each query, resulting in insufficient representation capability and low computational efficiency. Recently, Gaussian Splatting (GS) has shown its advantages over INR in both visual quality and rendering speed in 3D tasks, which motivates us to explore whether GS can be employed for the ASR task. However, directly applying GS to ASR is exceptionally challenging because the original GS is an optimization-based method through overfitting each single scene, while in ASR we aim to learn a single model that can generalize to different images and scaling factors. We overcome these challenges by developing two novel techniques. Firstly, to generalize GS for ASR, we elaborately design an architecture to predict the corresponding image-conditioned Gaussians of the input low-resolution image in a feed-forward manner. Each Gaussian can fit the shape and direction of an area of complex textures, showing powerful representation capability. Secondly, we implement an efficient differentiable 2D GPU/CUDA-based scale-aware rasterization to render super-resolved images by sampling discrete RGB values from the predicted continuous Gaussians. Via end-to-end training, our optimized network, namely GSASR, can perform ASR for any image and unseen scaling factors. Extensive experiments validate the effectiveness of our proposed method. The code and models are available at https://github.com/ChrisDud0257/GSASR.

eess.IV↗

arXiv2024

Simple But Not Secure: An Empirical Security Analysis of Two-factor Authentication Systems

To protect users from data breaches and phishing attacks, service providers typically implement two-factor authentication (2FA) to add an extra layer of security against suspicious login attempts. However, since 2FA can sometimes hinder user experience by introducing additional steps, many websites aim to reduce inconvenience by minimizing the frequency of 2FA prompts. One approach to achieve this is by storing the user's ``Remember the Device'' preference in a cookie. As a result, users are only prompted for 2FA when this cookie expires or if they log in from a new device. To understand and improve the security of 2FA systems in real-world settings, we propose SE2FA, a vulnerability evaluation framework designed to detect vulnerabilities in 2FA systems. This framework enables us to analyze the security of 407 2FA systems across popular websites from the Tranco Top 10,000 list. Our analysis and evaluation found three zero-day vulnerabilities on three service providers that could allow an attacker to access a victim's account without possessing the victim's second authentication factor, thereby bypassing 2FA protections entirely. A further investigation found that these vulnerabilities stem from design choices aimed at simplifying 2FA for users but that unintentionally reduce its security effectiveness. We have disclosed these findings to the affected websites and assisted them in mitigating the risks. Based on the insights from this research, we provide practical recommendations for countermeasures to strengthen 2FA security and address these newly identified threats.

cs.CR↗

arXiv2024

SSL: A Self-similarity Loss for Improving Generative Image Super-resolution

Generative adversarial networks (GAN) and generative diffusion models (DM) have been widely used in real-world image super-resolution (Real-ISR) to enhance the image perceptual quality. However, these generative models are prone to generating visual artifacts and false image structures, resulting in unnatural Real-ISR results. Based on the fact that natural images exhibit high self-similarities, i.e., a local patch can have many similar patches to it in the whole image, in this work we propose a simple yet effective self-similarity loss (SSL) to improve the performance of generative Real-ISR models, enhancing the hallucination of structural and textural details while reducing the unpleasant visual artifacts. Specifically, we compute a self-similarity graph (SSG) of the ground-truth image, and enforce the SSG of Real-ISR output to be close to it. To reduce the training cost and focus on edge areas, we generate an edge mask from the ground-truth image, and compute the SSG only on the masked pixels. The proposed SSL serves as a general plug-and-play penalty, which could be easily applied to the off-the-shelf Real-ISR models. Our experiments demonstrate that, by coupling with SSL, the performance of many state-of-the-art Real-ISR models, including those GAN and DM based ones, can be largely improved, reproducing more perceptually realistic image details and eliminating many false reconstructions and visual artifacts. Codes and supplementary material can be found at https://github.com/ChrisDud0257/SSL

cs.CV↗

arXiv2024

Orion-14B: Open-source Multilingual Large Language Models

In this study, we introduce Orion-14B, a collection of multilingual large language models with 14 billion parameters. We utilize a data scheduling approach to train a foundational model on a diverse corpus of 2.5 trillion tokens, sourced from texts in English, Chinese, Japanese, Korean, and other languages. Additionally, we fine-tuned a series of models tailored for conversational applications and other specific use cases. Our evaluation results demonstrate that Orion-14B achieves state-of-the-art performance across a broad spectrum of tasks. We make the Orion-14B model family and its associated code publicly accessible https://github.com/OrionStarAI/Orion, aiming to inspire future research and practical applications in the field.

cs.CL↗

arXiv2023

Human Guided Ground-truth Generation for Realistic Image Super-resolution

How to generate the ground-truth (GT) image is a critical issue for training realistic image super-resolution (Real-ISR) models. Existing methods mostly take a set of high-resolution (HR) images as GTs and apply various degradations to simulate their low-resolution (LR) counterparts. Though great progress has been achieved, such an LR-HR pair generation scheme has several limitations. First, the perceptual quality of HR images may not be high enough, limiting the quality of Real-ISR outputs. Second, existing schemes do not consider much human perception in GT generation, and the trained models tend to produce over-smoothed results or unpleasant artifacts. With the above considerations, we propose a human guided GT generation scheme. We first elaborately train multiple image enhancement models to improve the perceptual quality of HR images, and enable one LR image having multiple HR counterparts. Human subjects are then involved to annotate the high quality regions among the enhanced HR images as GTs, and label the regions with unpleasant artifacts as negative samples. A human guided GT image dataset with both positive and negative samples is then constructed, and a loss function is proposed to train the Real-ISR models. Experiments show that the Real-ISR models trained on our dataset can produce perceptually more realistic results with less artifacts. Dataset and codes can be found at https://github.com/ChrisDud0257/HGGT

cs.CV↗

arXiv2019

Deep Neural Network for Fast and Accurate Single Image Super-Resolution via Channel-Attention-based Fusion of Orientation-aware Features

Recently, Convolutional Neural Networks (CNNs) have been successfully adopted to solve the ill-posed single image super-resolution (SISR) problem. A commonly used strategy to boost the performance of CNN-based SISR models is deploying very deep networks, which inevitably incurs many obvious drawbacks (e.g., a large number of network parameters, heavy computational loads, and difficult model training). In this paper, we aim to build more accurate and faster SISR models via developing better-performing feature extraction and fusion techniques. Firstly, we proposed a novel Orientation-Aware feature extraction and fusion Module (OAM), which contains a mixture of 1D and 2D convolutional kernels (i.e., 5 x 1, 1 x 5, and 3 x 3) for extracting orientation-aware features. Secondly, we adopt the channel attention mechanism as an effective technique to adaptively fuse features extracted in different directions and in hierarchically stacked convolutional stages. Based on these two important improvements, we present a compact but powerful CNN-based model for high-quality SISR via Channel Attention-based fusion of Orientation-Aware features (SISR-CA-OA). Extensive experimental results verify the superiority of the proposed SISR-CA-OA model, performing favorably against the state-of-the-art SISR models in terms of both restoration accuracy and computational efficiency. The source codes will be made publicly available.

eess.IV↗