arXiv subjects

Duncan A. Christie

Publications and source records attributed to Duncan A. Christie.

At least 19 recordsLinked to original sources

arXiv2026

JWST MEP - A World Under Spotty Starlight: Detection of CO2 and H2O in the Hot Saturn WASP-52b with JWST NIRSpec G395H

Exoplanets orbiting active stars offer distinct challenges for atmospheric characterization with the JWST. Among such worlds, the hot Saturn WASP-52b (Teq $\sim$ 1300 K) orbits an active K-dwarf that complicates transmission spectroscopy via stellar contamination. Here, we present the first JWST NIRSpec G395H (2.8-5.2 $μ$m) limb-averaged transmission spectrum of WASP-52b obtained through the JWST Morning/Evening Program (GO-3969), which aims to measure limb asymmetries across a sample of hot giant exoplanets. Our spectrum reveals the first detection of CO2 in WASP-52b's atmosphere (ln B = 54 / >10$σ$), with a retrieved abundance of log CO2 = -5.09 (+1.09/-1.14), and confirmation of H2O (ln B = 5.9 / $\sim$3-4$σ$), with an abundance of log H2O = -3.41 (+1.04/-1.04). We find a steep near-infrared slope that cannot be explained solely by H2O absorption, necessitating unocculted starspots (ln B = 5.7 / $\sim$3-4$σ$), though with properties that vary across our data reductions. The shape and amplitude of the molecular bands additionally suggest high-altitude (<10 mbar) inhomogeneous clouds covering $\approx$40 $\pm$ 20% of the terminator (ln B = 1.9 / $\sim$2.5$σ$), which provides evidence for the morning-evening terminator differences that are consensus predictions of general circulation models. WASP-52b's atmospheric metallicity can be sub-solar, solar, or super-solar, due to order-of-magnitude uncertainties in the molecular abundances caused by degeneracies between compositions, clouds, and starspots. However, chemical equilibrium retrievals provide a similar statistical fit while favoring a tighter constraint with a super-solar metallicity (M/H = 14.8 (+12.1/-5.9) $\times$ solar). These results highlight that chemical detections and aerosol properties may still be recovered for planets orbiting active stars via transmission spectroscopy.

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arXiv2026

Asymmetric Aerosol Distribution on the Terminators of the Warm Saturn WASP-69 b Revealed by JWST NIRISS/SOSS

How aerosols form, are transported, and cycle between condensation and evaporation across exoplanet temperature regimes remains poorly understood. Recent models and observations suggest that warm giant planets near $800$--$1000$ K may span a transition between homogeneous and longitudinally heterogeneous aerosol distributions. We present a robust detection of aerosol asymmetry in a giant planet with $T_{\rm eq}\lesssim1000$ K, using the $0.86$--$2.82~μ$m JWST NIRISS/SOSS transmission spectrum of WASP-69 b. The evening limb shows prominent 1.4 $μ$m H$_2$O absorption ($Δ\mathrm{BIC}_{\rm H_2O}=+22.7$), whereas H$_2$O is not detected on the morning limb ($Δ\mathrm{BIC}_{\rm H_2O}=-8.7$). Atmospheric retrievals reveal significant aerosol opacity on both limbs, with high-altitude, optically thick clouds muting molecular features on the morning limb and lower cloud opacity allowing H$_2$O to emerge on the evening limb. The evening terminator is hotter by $304^{+62}_{-91}$ K, consistent with morning-limb condensates partially evaporating during transport toward the evening limb. This mechanism is independently verified with 3D general circulation models. Stellar contamination or aerosols dominated by photochemical haze do not readily explain the asymmetry. From a limb-resolved analysis, we infer a stellar-to-superstellar atmospheric metallicity, with $\rm[M/H]=0.11^{+0.40}_{-0.46}$ from the equilibrium retrieval and [O/H]$=1.38^{+0.44}_{-0.79}$ from the free retrieval. We also detect an escaping metastable-helium tail extending to $3.08^{+0.50}_{-0.45}\,R_p$. WASP-69 b anchors the cooler edge of the emerging population of planets with asymmetric aerosol distributions and suggests that substantial aerosol opacity may persist on both limbs across this transition.

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arXiv2026

Mitigating Charge Migration in JWST NIRISS Reveals That KELT-7 b is a Metal-enriched Ultra-hot Jupiter Orbiting a Young Metal-rich Star

We present the first panchromatic JWST transmission spectrum of an ultra-hot Jupiter, combining NIRISS and NIRSpec observations to constrain KELT-7\,b's atmospheric properties. We show evidence for charge migration in our NIRISS SOSS observation between 1--1.5~$μ$m, a wavelength range crucial to test for enhanced H$^-$ previously inferred from HST WFC3/IR G141 observations. We mitigate charge migration by fitting the ramp after extracting 1D stellar spectra at the group level. This ``late-ramp-fit'' method accurately calculates KELT-7\,b's transmission spectrum between 1--1.5~$μ$m at higher signal-to-noise. Using the transit-derived stellar mean density during stellar property inference reveals that KELT-7 is a $640\pm100$ Myr-old, $[\text{Fe}/\text{H}]=0.46\pm0.02$ star. Combined with NIRSpec and re-reduced WFC3/UVIS G280 data, our free retrieval analysis shows strong evidence for H$_2$O, CO$_2$, and TiO among high-temperature species, but not H$^-$ or clouds. Unaccounted-for systematics may therefore bias longer-wavelength WFC3/IR G141 transit depths shallower. Our free retrieval, two equilibrium retrievals, and self-consistent grid fit all prefer a high metallicity but find discrepant C/O ratios. Agglomerated together, we constrain a super-stellar $\text{M/H}=92^{+24}_{-23}\times$~Solar and C/O~$\leq0.9$, suggesting enhanced metal accretion in the later stages of KELT-7\,b's formation. Our GCMs explain the observed lack of limb asymmetry with superrotating jet-driven efficient horizontal mixing. The stark contrast between our panchromatic analysis and prior analyses on subsets of these data demonstrates the value of broad wavelength coverage for the comprehensive study of exoplanet atmospheres.

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arXiv2026

Cloudy mornings and clear evenings on a gas giant exoplanet

The spectra of exoplanet atmospheres are affected by aerosols (clouds and hazes) of uncertain origin. Proposed aerosol formation mechanisms include gas condensation or photochemical reactions. We measure the transmission spectrum of the tidally locked gas giant exoplanet WASP-94A b and identify asymmetry in its atmosphere. The morning limb is cooler and cloudy, while the evening limb is hotter and exhibits gaseous H$_2$O absorption features. We interpret this difference as due to the formation of cloud droplets near the morning limb, which evaporate during circulation to the evening limb. The dominant aerosols are clouds cycling between the day and night sides of the atmosphere, not photochemical hazes. The resulting asymmetry can severely bias chemical abundance measurements, unless limb-resolved spectroscopy is available.

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arXiv2026

BOWIE-ALIGN: Exploring degeneracies in the muted transmission spectrum of the aligned hot Jupiter NGTS-2b with NIRSpec/G395H

We present the first atmospheric observation and characterisation of the aligned, 1468 K hot Jupiter, NGTS-2b, with one JWST NIRSpec/G395H transit. These observations complete the GO 3838 observing campaign of the BOWIE-ALIGN program, which aims to investigate the link between hot Jupiter atmospheric composition and formation history through the atmospheric analysis of planets orbiting F stars that are aligned and misaligned with the host stellar spin axis. The 2.84-5.18 micron spectrum shows weak absorption features attributed to H$_2$O and CO$_2$ absorption, which our free chemistry retrievals fit with posteriors that converge on high mean molecular weight solutions attained through significant H$_2$O mixing ratios. By comparing our results to interior modelling, we show that some of these solutions exceed the 43.5x solar upper limit we obtained from our interior structure models. Such solutions are likely due to cloud-metallicity degeneracies and insufficient wavelength coverage to resolve them. We show that, in the case of our observations, the likelihood distribution of H$_2$O abundances is flat and uninformative, such that our retrievals are biased by the prior. Additionally, our statistically favoured atmospheric solution contains absorption from SO. The chemical abundances retrieved with this model are likely not astrophysically feasible and we demonstrate that the presence of SO is driven by only two data points. Our equilibrium chemistry retrievals hint at a subsolar C/O ratio and supersolar metallicity; however, we find wide posterior distributions that extend to solar values.

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arXiv2026

BOWIE-ALIGN: Sub-solar C/O ratio and metallicity atmosphere of the misaligned hot Jupiter HAT-P-30b

We present the JWST NIRSpec/G395H transmission spectrum of the misaligned hot Jupiter HAT-P-30b from 2.8--5.2 $μ$m as part of the BOWIE-ALIGN survey, a comparative survey designed to probe the link between planet formation and atmospheric composition in samples of misaligned and aligned hot Jupiters orbiting F-type stars. Through independent data reductions and retrieval analyses, we find evidence for absorption features of H$_2$O and CO$_2$ in the atmosphere of HAT-P-30b. Our retrieved abundances are consistent with equilibrium chemistry, from which we infer a sub-solar C/O ratio (0.16--0.45), and sub-solar and sub-stellar metallicity (0.2--0.8$\times$solar, compared to a stellar metallicity of 1.1--1.6$\times$solar), with muted spectral features. This composition challenges formation models of continuous migration and accretion within a steady disc of stellar metallicity, and could be the result of low C/O ratio gas accretion within the water ice line, low metallicity accretion due to the trapping of volatiles further out in the disc, or the combined accretion of low metallicity gas and carbon-poor solids.

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arXiv2025

Limb Asymmetries on WASP-39b: A Multi-GCM Comparison of Chemistry, Clouds, and Hazes

With JWST, observing separate spectra of the morning and evening limbs of hot Jupiters has finally become a reality. The first such observation was reported for WASP-39b, where the evening terminator was observed to have a larger transit radius by about 400 ppm and a stronger 4.3 $μ$m CO$_2$ feature than the morning terminator. Multiple factors, including temperature differences, photo/thermochemistry, clouds and hazes, could cause such limb asymmetries. To interpret these new limb asymmetry observations, a detailed understanding of how the relevant processes affect morning and evening spectra grounded in forward models is needed. Focusing on WASP-39b, we compare simulations from five different general circulation models (GCMs), including one simulating disequilibrium thermochemistry and one with cloud radiative feedback, to the recent WASP-39b limb asymmetry observations. We also post-process the temperature structures of all simulations with a 2D photochemical model and one simulation with a cloud microphysics model. Although the temperatures predicted by the different models vary considerably, the models are remarkably consistent in their predicted morning--evening temperature differences. Several equilibrium-chemistry simulations predict strong methane features in the morning spectrum, not seen in the observations. When including disequilibrium processes, horizontal transport homogenizes methane, and these methane features disappear. However, even after including photochemistry and clouds, our models still cannot reproduce the observed ${\sim}2000$ ppm asymmetry in the CO$_2$ feature. A combination of factors, such as varying metallicity and unexplored parameters in cloud models, may explain the discrepancy, emphasizing the need for future models integrating cloud microphysics and feedback across a broader parameter space.

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arXiv2025

BOWIE-ALIGN: Weak spectral features in KELT-7b's JWST NIRSpec/G395H transmission spectrum imply a high cloud deck or a low-metallicity atmosphere

Hot Jupiters and their atmospheres are prime targets for transmission spectroscopy due to their extended atmospheres and the corresponding large signal-to-noise, providing the best possible constraints for the atmospheric carbon-to-oxygen (C/O) ratio and metallicity of exoplanets. Within BOWIE-ALIGN, we aim to compare JWST spectra of a sample of orbitally aligned and misaligned hot Jupiters orbiting F-type stars to probe the link between hot Jupiter atmospheres and planet formation history. Here, we present a near-infrared transmission spectrum of the aligned planet KELT-7b using one transit observed with JWST NIRSpec/G395H. We find weak features, only tentative evidence for H$_2$O and CO$_2$ in the atmosphere of KELT-7b. This poses a challenge to constrain the atmospheric properties of KELT-7b and two possible scenarios emerge from equilibrium chemistry and free chemistry retrievals: a high-altitude cloud deck muting all features or an extremely low metallicity atmosphere, respectively. The retrieved C/O ratios from our data reductions range from $0.43 - 0.74$, while the atmospheric metallicity is suggested to be solar to super-solar ($1-16 \times$ solar). Although these wide constraints prevent detailed conclusions about KELT-7b's formation history, a solar-to-super-solar metallicity would imply the accretion of solid material during its formation, which is valuable information for the survey's wider goals of understanding the relative importance of gaseous to solid accretion.

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arXiv2025

Geometric Considerations in Hot Jupiter Magnetic Drag Models

Magnetic fields are expected to impact the atmospheric dynamics of hot and ultra-hot Jupiters due to their increased ionization fractions, compared to that of cooler exoplanets, but our ability to model these magnetic processes is limited by the different coupling regimes between the day and night sides of the planets. One common approach is to approximate the magnetic interactions as a drag acting on the atmosphere. In this work, we examine, within the context of this drag approximation, the impact of including vertical and meridional drag, in addition to zonal drag, from a background dipole magnetic field on the flows in hot Jupiter atmospheres as well as a relaxation of the assumption of solely meridional currents and demonstrate that the inclusion of meridional and vertical drag can limit flows over the poles in hotter atmospheres, something not seen in models that only consider zonal drag, and the assumption of only meridional currents results in an underestimation of the equatorial drag in all cases examined.

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arXiv2025

The Effects of Cuboid Particle Scattering on Reflected Light Phase Curves: Insights from Laboratory Data and Theory

Understanding the optical properties of exoplanet cloud particles is a top priority. Many cloud condensates form as nonspherical particles and their optical properties can be very different from those of spheres. In this study, we focus on KCl particles, which likely form as cuboids in warm (T=500-1000K) exoplanet atmospheres. We compare the phase functions (at 532 nm wavelength) of KCl particles computed with Mie theory, the two-term Henyey-Greenstein (TTHG) approximation, laboratory data, and the discrete dipole approximation (DDA). Mie theory assumes scattering from spheres, while TTHG functions are used to approximate cloud scattering in two-stream radiative transfer models like PICASO. Laboratory measurements and DDA allow for a robust understanding of scattering from cuboid and deformed cuboid particle shapes. We input these phase functions into PICASO using cloud distributions from the cloud model Virga, to determine how different phase functions can impact the reflected-light intensities of the benchmark sub-Neptune, GJ 1214b. Simulated reflected light phase curves of GJ1214b produced using the TTHG, laboratory, and DDA phase curves differ by less than 3ppm. Our findings suggest that TTHG phase functions may be useful for approximating the scattering intensity of certain cuboid and irregular particle shapes. Future work should expand upon the wavelengths and particles considered to better determine when scattering approximations, like TTHG, may be useful in lieu of more accurate, but time-consuming laboratory measurements and/or nonspherical scattering theory.

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arXiv2025

Tracing the formation and migration history: molecular signatures in the atmosphere of misaligned hot Jupiter WASP-94Ab using JWST NIRSpec/G395H

The discovery of hot Jupiters that orbit very close to their host stars has long challenged traditional models of planetary formation and migration. Characterising their atmospheric composition - mainly in the form of the carbon-to-oxygen (C/O) ratio and metallicity - can provide insights into their formation locations and evolution pathways. With JWST we can characterise the atmospheres of these types of planets more precisely than previously possible, primarily because it allows us to determine both their atmospheric oxygen and carbon composition. Here, we present a JWST NIRSpec/G395H transmission spectrum from 2.8-5.1$μm$ of WASP-94Ab, an inflated hot Jupiter with a retrograde misaligned orbit around its F-type host star. We find a relatively cloud-free atmosphere, with absorption features of H$_2$O and CO$_2$ at detection significances of $\sim 4σ$ and $\sim 11σ$, respectively. In addition, we detect tentative evidence of CO absorption at $\sim3σ$, as well as hints of sulphur with the detection of H$_2$S at a $\sim 2.5σ$ confidence level. Our favoured equilibrium chemistry model determines a C/O ratio of $0.49^{+0.08}_{-0.13}$ for WASP-94Ab's atmosphere, which is substellar compared to the star's C/O ratio of $0.68 \pm 0.10$. The retrieved atmospheric metallicity is similar to the star's metallicity as both are $\sim 2\times$ solar. We find that this sub-stellar C/O ratio and stellar metallicity can be best explained by pebble accretion or planetesimal accretion in combination with large-distance migration of the planet.

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arXiv2025

SiO and a super-stellar C/O ratio in the atmosphere of the giant exoplanet WASP-121b

Refractory elements such as iron, magnesium, and silicon can be detected in the atmospheres of ultrahot giant planets. This provides an opportunity to quantify the amount of refractory material accreted during formation, along with volatile gases and ices. However, simultaneous detections of refractories and volatiles have proved challenging, as the most prominent spectral features of associated atoms and molecules span a broad wavelength range. Here, using a single JWST observation of the ultrahot giant planet WASP-121b, we report detections of H$_2$O (5.5-13.5$σ$), CO (10.8-12.8$σ$), and SiO (5.7-6.2$σ$) in the planet's dayside atmosphere, and CH$_4$ (3.1-5.1$σ$) in the nightside atmosphere. We measure super-stellar values for the atmospheric C/H, O/H, Si/H, and C/O ratios, which point to the joint importance of pebbles and planetesimals in giant planet formation. The CH$_4$-rich nightside composition is also indicative of dynamical processes, such as strong vertical mixing, having a profound influence on the chemistry of ultrahot giant planets.

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arXiv2025

BOWIE-ALIGN: Sub-stellar metallicity and carbon depletion in the aligned TrES-4b with JWST NIRSpec transmission spectroscopy

The formation and migration history of a planet is expected to be imprinted in its atmosphere, in particular its carbon-to-oxygen (C/O) ratio and metallicity. The BOWIE-ALIGN programme is performing a comparative study of JWST spectra of four aligned and four misaligned hot Jupiters, with the aim of characterising their atmospheres and corroborating the link between the observables and the formation history. In this work, we present the $2.8-5.2$ micron transmission spectrum of TrES-4b, a hot Jupiter with an orbit aligned with the rotation axis of its F-type host star. Using free chemistry atmospheric retrievals, we report a confident detection of H$_2$O at an abundance of $\log X_\mathrm{H_2O}=-2.98^{+0.68}_{-0.73}$ at a significance of $8.4σ$. We also find evidence for CO and small amounts of CO$_2$, retrieving abundances $\log X_\mathrm{CO}= -3.76^{+0.89}_{-1.01}$ and $\log X_\mathrm{CO_2}= -6.86^{+0.62}_{-0.65}$ ($3.1σ$ and $4.0σ$ respectively). The observations are consistent with the the atmosphere being in chemical equilibrium; our retrievals yield $\mathrm{C/O}$ between $0.30-0.42$ and constrain the atmospheric metallicity to the range $0.4-0.7\times$ solar. The inferred sub-stellar properties (C/O and metallicity) challenge traditional models, and could have arisen from an oxygen-rich gas accretion scenario, or a combination of low-metallicity gas and carbon-poor solid accretion.

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arXiv2025

BOWIE-ALIGN: JWST reveals hints of planetesimal accretion and complex sulphur chemistry in the atmosphere of the misaligned hot Jupiter WASP-15b

We present a transmission spectrum of the misaligned hot Jupiter WASP-15b from 2.8-5.2 microns observed with JWST's NIRSpec/G395H grating. Our high signal to noise data, which has negligible red noise, reveals significant absorption by H$_2$O ($4.2σ$) and CO$_2$ ($8.9σ$). From independent data reduction and atmospheric retrieval approaches, we infer that WASP-15b's atmospheric metallicity is super-solar ($\gtrsim 15\times$ solar) and its carbon-to-oxygen ratio is consistent with solar, that together imply planetesimal accretion. Our general circulation model simulations for WASP-15b suggest that the carbon-to-oxygen we measure at the limb is likely representative of the entire photosphere due to the mostly uniform spatial distribution of H$_2$O, CO$_2$ and CO. We additionally see evidence for absorption by SO$_2$ and absorption at 4.9$μ$m, for which the current leading candidate is OCS, albeit with several caveats. If confirmed, this would be the first detection of OCS in an exoplanet atmosphere and point towards complex photochemistry of sulphur-bearing species in the upper atmosphere. These are the first observations from the BOWIE-ALIGN survey which is using JWST's NIRSpec/G395H instrument to compare the atmospheric compositions of aligned/low-obliquity and misaligned/high-obliquity hot Jupiters around F stars above the Kraft break. The goal of our survey is to determine whether the atmospheric composition differs across two populations of planets that have likely undergone different migration histories (disc versus disc-free) as evidenced by their obliquities (aligned versus misaligned).

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arXiv2024

BOWIE-ALIGN: How formation and migration histories of giant planets impact atmospheric compositions

Hot Jupiters present a unique opportunity for measuring how planet formation history shapes present-day atmospheric composition. However, due to the myriad pathways influencing composition, a well-constructed sample of planets is needed to determine whether formation history can be accurately traced back from atmospheric composition. To this end, the BOWIE-ALIGN survey will compare the compositions of 8 hot Jupiters around F stars, 4 with orbits aligned with the stellar rotation axis and 4 misaligned. Using the alignment as an indicator for planets that underwent disc migration or high-eccentricity migration, one can determine whether migration history produces notable differences in composition between the two samples of planets. This paper describes the planet formation model that motivates our observing programme. Our model traces the accretion of chemical components from the gas and dust in the disc over a broad parameter space to create a full, unbiased model sample from which we can estimate the range of final atmospheric compositions. For high metallicity atmospheres (O/H > 10 times solar), the C/O ratios of aligned and misaligned planets diverge, with aligned planets having lower C/O (< 0.25) due to the accretion of oxygen-rich silicates from the inner disc. However, silicates may rain out instead of releasing their oxygen into the atmosphere. This would significantly increase the C/O of aligned planets (C/O > 0.6), inverting the trend between the aligned and misaligned planets. Nevertheless, by comparing statistically significant samples of aligned and misaligned planets, we expect atmospheric composition to constrain how planets form.

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arXiv2024

BOWIE-ALIGN: A JWST comparative survey of aligned vs misaligned hot Jupiters to test the dependence of atmospheric composition on migration history

A primary objective of exoplanet atmosphere characterisation is to learn about planet formation and evolution, however, this is challenged by degeneracies. To determine whether differences in atmospheric composition can be reliably traced to differences in evolution, we are undertaking a transmission spectroscopy survey with JWST to compare the compositions of a sample of hot Jupiters that have different orbital alignments around F stars above the Kraft break. Under the assumption that aligned planets migrate through the inner disc, while misaligned planets migrate after disc dispersal, the act of migrating through the inner disc should cause a measurable difference in the C/O between aligned and misaligned planets. We expect the amplitude and sign of this difference to depend on the amount of planetesimal accretion and whether silicates accreted from the inner disc release their oxygen. Here, we identify all known exoplanets that are suitable for testing this hypothesis, describe our JWST survey, and use noise simulations and atmospheric retrievals to estimate our survey's sensitivity. With the selected sample of four aligned and four misaligned hot Jupiters, we will be sensitive to the predicted differences in C/O between aligned and misaligned hot Jupiters for a wide range of model scenarios.

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arXiv2024

The CUISINES Framework for Conducting Exoplanet Model Intercomparison Projects, Version 1.0

As JWST begins to return observations, it is more important than ever that exoplanet climate models can consistently and correctly predict the observability of exoplanets, retrieval of their data, and interpretation of planetary environments from that data. Model intercomparisons play a crucial role in this context, especially now when few data are available to validate model predictions. The CUISINES Working Group of NASA's Nexus for Exoplanet System Science (NExSS) supports a systematic approach to evaluating the performance of exoplanet models, and provides here a framework for conducting community-organized exoplanet Model Intercomparison Projects (exoMIPs). The CUISINES framework adapts Earth climate community practices specifically for the needs of exoplanet researchers, encompassing a range of model types, planetary targets, and parameter space studies. It is intended to help researchers to work collectively, equitably, and openly toward common goals. The CUISINES framework rests on five principles: 1) Define in advance what research question(s) the exoMIP is intended to address. 2) Create an experimental design that maximizes community participation, and advertise it widely. 3) Plan a project timeline that allows all exoMIP members to participate fully. 4) Generate data products from model output for direct comparison to observations. 5) Create a data management plan that is workable in the present and scalable for the future. Within the first years of its existence, CUISINES is already providing logistical support to 10 exoMIPs, and will continue to host annual workshops for further community feedback and presentation of new exoMIP ideas.

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arXiv2024

Quenching-driven equatorial depletion and limb asymmetries in hot Jupiter atmospheres: WASP-96b example

Transport-induced quenching in hot Jupiter atmospheres is a process that determines the boundary between the part of the atmosphere at chemical equilibrium and the part of the atmosphere at thermochemical (but not photothermochemical) disequilibrium. The location of this boundary, the quench level, depends on the interplay between the dynamical and chemical timescales in the atmosphere, with quenching occurring when these timescales are equal. We explore the sensitivity of the quench level position to an increase in the planet's atmospheric metallicity using aerosol-free 3D GCM simulations of a hot Jupiter WASP-96b. We find that the temperature increase at pressures of $\sim$$10^{4}-10^{7}$ Pa that occurs when metallicity is increased could shift the position of the quench level to pressures dominated by the jet, and cause an equatorial depletion of $CH_4$, $NH_3$ and $HCN$. We discuss how such a depletion affects the planet's transmission spectrum, and how the analysis of the evening-morning limb asymmetries, especially within $\sim3-5 μm$, could help distinguish atmospheres of different metallicities that are at chemical equilibrium from those with the upper layers at thermochemical disequilibrium.

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