arXiv subjects

E. Bianchi

Publications and source records attributed to E. Bianchi.

At least 55 records · Page 3Linked to original sources

arXiv2019

AMBITION -- Comet Nucleus Cryogenic Sample Return (White paper for ESA's Voyage 2050 programme)

This white paper proposes that AMBITION, a Comet Nucleus Sample Return mission, be a cornerstone of ESA's Voyage 2050 programme. We summarise some of the most important questions still open in cometary science after the successes of the Rosetta mission, many of which require sample analysis using techniques that are only possible in laboratories on Earth. We then summarise measurements, instrumentation and mission scenarios that can address these questions, with a recommendation that ESA select an ambitious cryogenic sample return mission. Rendezvous missions to Main Belt comets and Centaurs are compelling cases for M-class missions, expanding our knowledge by exploring new classes of comets. AMBITION would engage a wide community, drawing expertise from a vast range of disciplines within planetary science and astrophysics. With AMBITION, Europe will continue its leadership in the exploration of the most primitive Solar System bodies.

astro-ph.EP↗

arXiv2019

Organic molecules in the protoplanetary disk of DG Tau revealed by ALMA

Planets form in protoplanetary disks and inherit their chemical compositions. It is thus crucial to map the distribution and investigate the formation of simple organics, such as formaldehyde and methanol, in protoplanetary disks. We analyze ALMA observations of the nearby disk-jet system around the T Tauri star DG Tau in the o-H$_2$CO $3_{1,2}-2_{1,1}$ and CH$_3$OH $3_{-2,2}-4_{-1,4}$ E, $5_{0,5}-4_{0,4}$ A transitions at an unprecedented resolution of $\sim0.15"$, i.e., $\sim18$ au at a distance of 121 pc. The H$_2$CO emission originates from a rotating ring extending from $\sim40$ au with a peak at $\sim62$ au, i.e., at the edge of the 1.3mm dust continuum. CH$_3$OH emission is not detected down to an r.m.s. of 3 mJy/beam in the 0.162 km/s channel. Assuming an ortho-to-para ratio of 1.8-2.8 the ring- and disk-height-averaged H$_2$CO column density is $\sim0.3-4\times10^{14}$ cm$^{-2}$, while that of CH$_3$OH is $<0.04-0.7\times10^{14}$ cm$^{-2}$. In the inner $40$ au no o-H$_2$CO emission is detected with an upper limit on its beam-averaged column density of $\sim0.5-6\times10^{13}$ cm$^{-2}$. The H$_2$CO ring in the disk of DG Tau is located beyond the CO iceline (R$_{\rm CO}\sim30$ au). This suggests that the H$_2$CO abundance is enhanced in the outer disk due to formation on grain surfaces by the hydrogenation of CO ice. The emission peak at the edge of the mm dust continuum may be due to enhanced desorption of H$_2$CO in the gas phase caused by increased UV penetration and/or temperature inversion. The CH$_3$OH/H$_2$CO abundance ratio is $<1$, in agreement with disk chemistry models. The inner edge of the H$_2$CO ring coincides with the radius where the polarization of the dust continuum changes orientation, hinting at a tight link between the H$_2$CO chemistry and the dust properties in the outer disk and at the possible presence of substructures in the dust distribution.

astro-ph.SR↗

arXiv2018

ALMA polarimetric studies of rotating jet/disk systems

We have recently obtained polarimetric data at mm wavelengths with ALMA for the young systems DG Tau and CW Tau, for which the rotation properties of jet and disk have been investigated in previous high angular resolution studies. The motivation was to test the models of magneto-centrifugal launch of jets via the determination of the magnetic configuration at the disk surface. The analysis of these data, however, reveals that self-scattering of dust thermal radiation dominates the polarization pattern. It is shown that even if no information on the magnetic field can be derived in this case, the polarization data are a powerful tool for the diagnostics of the properties and the evolution of dust in protoplanetary disks.

astro-ph.SR↗

arXiv2018

The census of interstellar complex organic molecules in the Class I hot corino of SVS13-A

We present the first census of the interstellar Complex Organic Molecules (iCOMs) in the low-mass Class I protostar SVS13-A, obtained by analysing data from the IRAM-30m Large Project ASAI (Astrochemical Surveys At IRAM). They consist of an high-sensitivity unbiased spectral survey at the 1mm, 2mm and 3mm IRAM bands. We detected five iCOMs: acetaldehyde (CH$_3$CHO), methyl formate (HCOOCH$_3$), dimethyl ether (CH$_3$OCH$_3$), ethanol (CH$_3$CH$_2$OH) and formamide (NH$_2$CHO). In addition we searched for other iCOMs and ketene (H$_2$CCO), formic acid (HCOOH) and methoxy (CH$_3$O), whose only ketene was detected. The numerous detected lines, from 5 to 37 depending on the species, cover a large upper level energy range, between 15 and 254 K. This allowed us to carry out a rotational diagram analysis and derive rotational temperatures between 35 and 110 K, and column densities between $3\times 10^{15}$ and $1\times 10^{17}$ cm$^{-2}$ on the 0."3 size previously determined by interferometric observations of glycolaldehyde. These new observations clearly demonstrate the presence of a rich chemistry in the hot corino towards SVS13-A. The measured iCOMs abundances were compared to other Class 0 and I hot corinos, as well as comets, previously published in the literature. We find evidence that (i) SVS13-A is as chemically rich as younger Class 0 protostars, and (ii) the iCOMs relative abundances do not substantially evolve during the protostellar phase.

astro-ph.SR↗

arXiv2018

Water and interstellar complex organics associated with the HH 212 protostellar disc - On disc atmospheres, disc winds, and accretion shocks

The HH 212 protostellar system, in Orion B, has been mapped thanks to ALMA-Band 7 Cycle 1 and Cycle 4 observations of dueterated water (HDO) and acetaldehyde (CH$_3$CHO) emission with an angular resolution down to $\sim$0.15 arcsec (60 au). Many emission lines due to 14 CH$_3$CHO and 1 HDO transitions at high excitation ($E_{\rm u}$ between 163 K and 335 K) have been imaged in the inner $\sim$ 70 au region. The local thermal equilibrium analysis of the CH$_3$CHO emission leads to a temperature of 78$\pm$14 K and a column density of 7.6$\pm$3.2 $\times$ 10$^{15}$ cm$^{-2}$, which, when $N_{\rm H_2}$ of 10$^{24}$ cm$^{-2}$ is assumed, leads to an abundance of $X_{\rm CH_3CHO}$ $\simeq$ 8 $\times$ 10$^{-9}$. The large velocity gradient analysis of the HDO emission also places severe constraints on the volume density, n$_{\rm H_2}$ $\geq$ 10$^8$ cm$^{-3}$. The line profiles are 5--7 km s$^{-1}$ wide, and CH$_3$CHO and HDO both show a $\pm$ 2 km s$^{-1}$ velocity gradient over a size of $\sim$ 70 au (blue-shifted emission towards the north-west and red-shifted emission towards the south-east) along the disc equatorial plane, in agreement with what was found so far using other molecular tracers. The kinematics of CH$_3$CHO and HDO are consistent with the occurrence of a centrifugal barrier, that is, the infalling envelope-rotating disc ring, which is chemically enriched through low-velocity accretion shocks. The emission radius is $\sim$ 60 au, in good agreement with what was found before for another interstellar complex organic molecule such as NH$_2$CHO. We support a vertical structure for the centrifugal barrier, suggesting the occurrence of two outflowing, expanding, and rotating rings above and below (of about 40-45 au) the optically thick equatorial disc plane. It is tempting to speculate that these rings could probe the basis of a wind launched from this region.

astro-ph.SR↗

arXiv2018

SOLIS IV. Hydrocarbons in the OMC-2 FIR 4 region, a probe of energetic particle irradiation of the region

We report new interferometric images of cyclopropenylidene, c-C$_3$H$_2$, towards the young protocluster OMC-2 FIR\,4. The observations were performed at 82 and 85 GHz with the NOrthern Extended Millimeter Array (NOEMA) as part of the project Seeds Of Life In Space (SOLIS). In addition, IRAM-30m data observations were used to investigate the physical structure of OMC-2 FIR\,4. We find that the c-C$_3$H$_2$ gas emits from the same region where previous SOLIS observations showed bright HC$_5$N emission. From a non-LTE analysis of the IRAM-30m data, the c-C$_3$H$_2$ gas has an average temperature of $\sim$40K, a H$_2$ density of $\sim$3$\times$10$^{5}$~cm$^{-3}$, and a c-C$_3$H$_2$ abundance relative to H$_2$ of ($7\pm1$)$\times$10$^{-12}$. In addition, the NOEMA observations provide no sign of significant c-C$_3$H$_2$ excitation temperature gradients across the region (about 3-4 beams), with T$_{ex}$ in the range 8$\pm$3 up to 16$\pm$7K. We thus infer that our observations are inconsistent with a physical interaction of the OMC-2 FIR\,4 envelope with the outflow arising from OMC-2 FIR\,3, as claimed by previous studies. The comparison of the measured c-C$_3$H$_2$ abundance with the predictions from an astrochemical PDR model indicates that OMC-2 FIR\,4 is irradiated by a FUV field $\sim$1000 times larger than the interstellar one, and by a flux of ionising particles $\sim$4000 times larger than the canonical value of $1\times10^{-17}$~s$^{-1}$ from the Galaxy cosmic rays, which is consistent with our previous HC$_5$N observations. This provides an important and independent confirmation of other studies that one or more sources inside the OMC-2 FIR\,4 region emit energetic ($\geq10$~MeV) particles.

astro-ph.GA↗

arXiv2018

Astrochemical evolution along star formation: Overview of the IRAM Large Program ASAI

Evidence is mounting that the small bodies of our Solar System, such as comets and asteroids, have at least partially inherited their chemical composition from the first phases of the Solar System formation. It then appears that the molecular complexity of these small bodies is most likely related to the earliest stages of star formation. It is therefore important to characterize and to understand how the chemical evolution changes with solar-type protostellar evolution. We present here the Large Program "Astrochemical Surveys At IRAM" (ASAI). Its goal is to carry out unbiased millimeter line surveys between 80 and 272 GHz of a sample of ten template sources, which fully cover the first stages of the formation process of solar-type stars, from prestellar cores to the late protostellar phase. In this article, we present an overview of the surveys and results obtained from the analysis of the 3 mm band observations. The number of detected main isotopic species barely varies with the evolutionary stage and is found to be very similar to that of massive star-forming regions. The molecular content in O- and C- bearing species allows us to define two chemical classes of envelopes, whose composition is dominated by either a) a rich content in O-rich complex organic molecules, associated with hot corino sources, or b) a rich content in hydrocarbons, typical of Warm Carbon Chain Chemistry sources. Overall, a high chemical richness is found to be present already in the initial phases of solar-type star formation.

astro-ph.GA↗

arXiv2017

Nitrogen oxide in protostellar envelopes and shocks: the ASAI survey

The high-sensitivity of the IRAM 30-m ASAI unbiased spectral survey in the mm-window allows us to detect NO emission towards both the Class I object SVS13-A and the protostellar outflow shock L1157-B1. We detect the hyperfine components of the $^2Π_{\rm 1/2}$ $J$ = 3/2 $\to$ 1/2 (at 151 GHz) and the $^2Π_{\rm 1/2}$ $J$ = 5/2 $\to$ 3/2 (250 GHz) spectral pattern. The two objects show different NO profiles: (i) SVS13-A emits through narrow (1.5 km s$^{-1}$) lines at the systemic velocity, while (ii) L1157-B1 shows broad ($\sim$ 5 km s$^{-1}$) blue-shifted emission. For SVS13-A the analysis leads to $T_{\rm ex}$ $\geq$ 4 K, $N(\rm NO)$ $\leq$ 3 $\times$ 10$^{15}$ cm$^{-2}$, and indicates the association of NO with the protostellar envelope. In L1157-B1, NO is tracing the extended outflow cavity: $T_{\rm ex}$ $\simeq$ 4--5 K, and $N(\rm NO)$ = 5.5$\pm$1.5 $\times$ 10$^{15}$ cm$^{-2}$. Using C$^{18}$O, $^{13}$C$^{18}$O, C$^{17}$O, and $^{13}$C$^{17}$O ASAI observations we derive an NO fractional abundance less than $\sim$ 10$^{-7}$ for the SVS13-A envelope, in agreement with previous measurements towards extended PDRs and prestellar objects. Conversely, a definite $X(NO)$ enhancement is measured towards L1157-B1, $\sim$ 6 $\times$ 10$^{-6}$, showing that the NO production increases in shocks. The public code UCLCHEM was used to interpret the NO observations, confirming that the abundance observed in SVS13-A can be attained in an envelope with a gas density of 10$^5$ cm$^{-3}$ and a kinetic temperature of 40 K. The NO abundance in L1157-B1 is reproduced with pre-shock densities of 10$^5$ cm$^{-3}$ subjected to a $\sim$ 45 km s$^{-1}$ shock.

astro-ph.GA↗

arXiv2017

ALMA discovery of a rotating SO/SO$_2$ flow in HH212. A possible MHD disk wind?

We wish to constrain the possible contribution of a magnetohydrodynamic disk wind (DW) to the HH212 molecular jet. We mapped the flow base with ALMA Cycle 4 at 0.13"$\sim$ 60 au resolution and compared these observations with synthetic DW predictions. We identified, in SO/SO$_2$, a rotating flow that is wider and slower than the axial SiO jet. The broad outflow cavity seen in C$^{34}$S is not carved by a fast wide-angle wind but by this slower agent. Rotation signatures may be fitted by a DW of a moderate lever arm launched out to $\sim$ 40 au with SiO tracing dust-free streamlines from 0.05-0.3 au. Such a DW could limit the core-to-star efficiency to $\leq$50%.

astro-ph.SR↗

arXiv2017

Seeds Of Life In Space (SOLIS): The organic composition diversity at 300--1000 au scale in Solar-type star forming regions

Complex organic molecules have been observed for decades in the interstellar medium. Some of them might be considered as small bricks of the macromolecules at the base of terrestrial life. It is hence particularly important to understand organic chemistry in Solar-like star forming regions. In this article, we present a new observational project: SOLIS (Seeds Of Life In Space). This is a Large Project at the IRAM-NOEMA interferometer, and its scope is to image the emission of several crucial organic molecules in a sample of Solar-like star forming regions in different evolutionary stage and environments. Here, we report the first SOLIS results, obtained from analysing the spectra of different regions of the Class 0 source NGC1333-IRAS4A, the protocluster OMC-2 FIR4, and the shock site L1157-B1. The different regions were identified based on the images of formamide (NH2CHO) and cyanodiacetylene (HC5N) lines. We discuss the observed large diversity in the molecular and organic content, both on large (3000-10000 au) and relatively small (300-1000 au) scales. Finally, we derive upper limits to the methoxy fractional abundance in the three observed regions of the same order of magnitude of that measured in few cold prestellar objects, namely ~10^-12-10^-11 with respect to H2 molecules.

astro-ph.SR↗

arXiv2017

Deuterated methanol on Solar System scale around the HH212 protostar

Context: Methanol is thought to be mainly formed during the prestellar phase and its deuterated form keeps memory of the conditions at that epoch. Thanks to the unique combination of high angular resolution and sensitivity provided by ALMA, we wish to measure methanol deuteration in the planet formation region around a Class 0 protostar and to understand its origin. Aims: We mapped both the $^{13}$CH$_3$OH and CH$_2$DOH distribution in the inner regions ($\sim$100 au) of the HH212 system in Orion B. To this end, we used ALMA Cycle 1 and Cycle 4 observations in Band 7 with angular resolution down to $\sim$0.15$"$. Results: We detected 6 lines of $^{13}$CH$_3$OH and 13 lines of CH$_2$DOH with upper level energies up to 438 K in temperature units. We derived a rotational temperature of (171 $\pm$ 52) K and column densities of 7$\times$10$^{16}$ cm$^{-2}$ ($^{13}$CH$_3$OH) and 1$\times$10$^{17}$ cm$^{-2}$ (CH$_2$DOH), respectively. Consequently, the D/H ratio is (2.4 $\pm$ 0.4)$\times$10$^{-2}$, a value lower by an order of magnitude with respect to what was previously measured using single dish telescopes toward protostars located in Perseus. Our findings are consistent with the higher dust temperatures in Orion B with respect to that derived for the Perseus cloud. The emission is tracing a rotating structure extending up to 45 au from the jet axis and elongated by 90 au along the jet axis. So far, the origin of the observed emission appears to be related with the accretion disk. Only higher spatial resolution measurements however, will be able to disentangle between different possible scenarios: disk wind, disk atmosphere, or accretion shocks.

astro-ph.SR↗

arXiv2017

Seeds of Life in Space (SOLIS) III. Formamide in protostellar shocks: evidence for gas-phase formation

Context: Modern versions of the Miller-Urey experiment claim that formamide (NH$_2$CHO) could be the starting point for the formation of metabolic and genetic macromolecules. Intriguingly, formamide is indeed observed in regions forming Solar-type stars as well as in external galaxies. Aims: How NH$_2$CHO is formed has been a puzzle for decades: our goal is to contribute to the hotly debated question of whether formamide is mostly formed via gas-phase or grain surface chemistry. Methods: We used the NOEMA interferometer to image NH$_2$CHO towards the L1157-B1 blue-shifted shock, a well known interstellar laboratory, to study how the components of dust mantles and cores released into the gas phase triggers the formation of formamide. Results: We report the first spatially resolved image (size $\sim$ 9", $\sim$ 2300 AU) of formamide emission in a shocked region around a Sun-like protostar: the line profiles are blueshifted and have a FWHM $\simeq$ 5 km s$^{-1}$. A column density of $N_{\rm NH_2CHO}$ = 8 $\times$ 10$^{12}$ cm$^{-1}$, and an abundance (with respect to H-nuclei) of 4 $\times$ 10$^{-9}$ are derived. We show a spatial segregation of formamide with respect to other organic species. Our observations, coupled with a chemical modelling analysis, indicate that the formamide observed in L1157-B1 is formed by gas-phase chemical process, and not on grain surfaces as previously suggested. Conclusions: The SOLIS interferometric observations of formamide provide direct evidence that this potentially crucial brick of life is efficiently formed in the gas-phase around Sun-like protostars.

astro-ph.EP↗

arXiv2017

SOLIS II. Carbon-chain growth in the Solar-type protocluster OMC2-FIR4

The interstellar delivery of carbon atoms locked into molecules might be one of the key ingredients for the emergence of life. Cyanopolyynes are carbon chains delimited at their two extremities by an atom of hydrogen and a cyano group, so that they might be excellent reservoirs of carbon. The simplest member, HC3N, is ubiquitous in the galactic interstellar medium and found also in external galaxies. Thus, understanding the growth of cyanopolyynes in regions forming stars similar to our Sun, and what affects it, is particularly relevant. In the framework of the IRAM/NOEMA Large Program SOLIS (Seeds Of Life In Space), we have obtained a map of two cyanopolyynes, HC3N and HC5N, in the protocluster OMC2-FIR4. Because our Sun is thought to be born in a rich cluster, OMC2-FIR4 is one of the closest and best known representatives of the environment in which the Sun may have been born. We find a HC3N/HC5N abundance ratio across the source in the range ~ 1 - 30, with the smallest values (< 10) in FIR5 and in the Eastern region of FIR4. The ratios < 10 can be reproduced by chemical models only if: (1) the cosmic-ray ionisation rate $ζ$ is ~ $4 \times 10^{-14}$ s$^{-1}$; (2) the gaseous elemental ratio C/O is close to unity; (3) O and C are largely depleted. The large $ζ$ is comparable to that measured in FIR4 by previous works and was interpreted as due to a flux of energetic (> 10 MeV) particles from embedded sources. We suggest that these sources could lie East of FIR4 and FIR5. A temperature gradient across FIR4, with T decreasing by about 10 K, could also explain the observed change in the HC3N/HC5N line ratio, without the need of a cosmic ray ionisation rate gradient. However, even in this case, a high constant cosmic-ray ionisation rate (of the order of $10^{-14}$ s$^{-1}$) is necessary to reproduce the observations.

astro-ph.GA↗

arXiv2017

Decrease of the organic deuteration during the evolution of Sun-like protostars: the case of SVS13-A

We present the results of formaldehyde and methanol deuteration measurements towards the Class I low-mass protostar SVS13-A, in the framework of the IRAM 30-m ASAI (Astrochemical Surveys At IRAM) project. We detected emission lines of formaldehyde, methanol, and their deuterated forms (HDCO, D2CO, CHD2OH, CH3OD) with Eup up to 276 K. The formaldehyde analysis indicates Tkin = 15 - 30 K, n (H2) >= 10^6 cm^-3, and a size of about 1200 AU suggesting an origin in the protostellar envelope. For methanol we find two components: (i) a high temperature (Tkin = 80 K) and very dense (> 10^8 cm^-3}) gas from a hot corino (radius about 35 AU), and (ii) a colder Tkin <= 70 K) and more extended (radius about 350 AU) region. The deuterium fractionation is 9 10^-2 for HDCO, 4 10^-3 for D2CO, and 2 - 7 10^-3 for CH2DOH, up to two orders of magnitude lower than the values measured in Class 0 sources. We derive also formaldehyde deuteration in the outflow: 4 10^-3, in agreement with what found in the L1157-B1 protostellar shock. Finally, we estimate [CH2DOH]/[CH3OD] about 2. The decrease of deuteration in the Class I source SVS13-A with respect to Class 0 sources can be explained by gas-phase processes. Alternatively, a lower deuteration could be the effect of a gradual collapse of less deuterated external shells of the protostellar evelope. The present measurements fill in the gap between prestellar cores and protoplanetary disks in the context of organics deuteration measurements.

astro-ph.SR↗

arXiv2016

Hot and dense water in the inner 25 AU of SVS13-A

In the context of the ASAI (Astrochemical Surveys At IRAM) project, we carried out an unbiased spectral survey in the millimeter window towards the well known low-mass Class I source SVS13-A. The high sensitivity reached (3-12 mK) allowed us to detect at least 6 HDO broad (FWHM ~ 4-5 km/s) emission lines with upper level energies up to Eu = 837 K. A non-LTE LVG analysis implies the presence of very hot (150-260 K) and dense (> 3 10^7 cm-3) gas inside a small radius ($\sim$ 25 AU) around the star, supporting, for the first time, the occurrence of a hot corino around a Class I protostar. The temperature is higher than expected for water molecules are sublimated from the icy dust mantles (~ 100 K). Although we cannot exclude we are observig the effects of shocks and/or winds at such small scales, this could imply that the observed HDO emission is tracing the water abundance jump expected at temperatures ~ 220-250 K, when the activation barrier of the gas phase reactions leading to the formation of water can be overcome. We derive X(HDO) ~ 3 10-6, and a H2O deuteration > 1.5 10-2, suggesting that water deuteration does not decrease as the protostar evolves from the Class 0 to the Class I stage.

astro-ph.SR↗

arXiv2015

Italian Science Case for ALMA Band 2+3

The Premiale Project "Science and Technology in Italy for the upgraded ALMA Observatory - iALMA" has the goal of strengthening the scientific, technological and industrial Italian contribution to the Atacama Large Millimeter/submillimeter Array (ALMA), the largest ground based international infrastructure for the study of the Universe in the microwave. One of the main objectives of the Science Working Group (SWG) inside iALMA, the Work Package 1, is to develop the Italian contribution to the Science Case for the ALMA Band 2 or Band 2+3 receiver. ALMA Band 2 receiver spans from ~67 GHz (bounded by an opaque line complex of ozone lines) up to 90 GHz which overlaps with the lower frequency end of ALMA Band 3. Receiver technology has advanced since the original definition of the ALMA frequency bands. It is now feasible to produce a single receiver which could cover the whole frequency range from 67 GHz to 116 GHz, encompassing Band 2 and Band 3 in a single receiver cartridge, a so called Band 2+3 system. In addition, upgrades of the ALMA system are now foreseen that should double the bandwidth to 16 GHz. The science drivers discussed below therefore also discuss the advantages of these two enhancements over the originally foreseen Band 2 system.

astro-ph.IM↗

arXiv2015

Disks, Jets and the dawn of planets, Proceedings of the 2nd JEDI meeting

This booklet contains a collection of contributions to the meeting of the JEts and Disks at INAF (JEDI) group, which took place at the Capodimonte Observatory during 9-10 April 2015. Scope of the meeting was to bring together the JEDI researchers of the Italian Istituto Nazionale di Astrofisica (INAF) working in the field of circumstellar disks and jets in young stars, to discuss together the different agents affecting the structure and the evolution of disks, namely accretion, jets and winds. More information on the JEDI group and its activities can be found at \texttt{http://www.oa-roma.inaf.it/irgroup/JEDI}.

astro-ph.SR↗

arXiv2012

Self-assembly scenarios of patchy colloidal particles

The rapid progress in precisely designing the surface decoration of patchy colloidal particles offers a new, yet unexperienced freedom to create building entities for larger, more complex structures in soft matter systems. However, it is extremely difficult to predict the large variety of ordered equilibrium structures that these particles are able to undergo under the variation of external parameters, such as temperature or pressure. Here we show that, by a novel combination of two theoretical tools, it is indeed possible to predict the self-assembly scenario of patchy colloidal particles: on one hand, a reliable and efficient optimization tool based on ideas of evolutionary algorithms helps to identify the ordered equilibrium structures to be expected at T = 0; on the other hand, suitable simulation techniques allow to estimate via free energy calculations the phase diagram at finite temperature. With these powerful approaches we are able to identify the broad variety of emerging self-assembly scenarios for spherical colloids decorated by four patches and we investigate and discuss the stability of the crystal structures on modifying in a controlled way the tetrahedral arrangement of the patches.

cond-mat.soft↗