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E. F. van Dishoeck

Publications and source records attributed to E. F. van Dishoeck.

At least 235 records · Page 13Linked to original sources

The complete far-infrared and submillimeter spectrum of the Class 0 protostar Serpens SMM1 obtained with Herschel. Characterizing UV-irradiated shocks heating and chemistry

We present the first complete 55-671 um spectral scan of a low-mass Class 0 protostar (Serpens SMM1) taken with the PACS and SPIRE spectrometers on board Herschel. More than 145 lines have been detected, most of them rotationally excited lines of 12CO (full ladder from J=4-3 to 42-41), H2O, OH, 13CO, HCN and HCO+ . Bright [OI]63,145um and weaker [CII]158 and [CI]370,609um lines are also detected. Mid-IR spectra retrieved from the Spitzer archive are also first discussed here, they show clear detections of [NeII], [FeII], [SiII] and [SI] fine structure lines as well as weaker H2 S(1) and S(2) pure rotational lines. The observed line luminosity is dominated by CO (~54%), H2O (~22%), [OI] (~12%) and OH (~9%) emission. A non-LTE radiative transfer model allowed us to quantify the contribution of the 3 different temperature components suggested by the 12CO rotational ladder (Tk(hot)~800 K, Tk(warm)~375 K and Tk(cool)~150 K). Gas densities n(H2)~5x10^6 cm^-3 are needed to reproduce the observed far-IR lines arising from shocks in the inner protostellar envelope for which we derive upper limit abundances of x(CO)~10^-4, x(H2O)~0.2x10^-5 and x(OH)~10^-6. The lower energy submm 12CO and H2O lines show more extended emission that we associate with the cool entrained outflow gas. Fast dissociative J-shocks (v_s > 60 km s^-1) as well as lower velocity non-dissociative shocks (v_s < 20 km s^-1) are needed to explain both the atomic lines and the hot CO and H2O lines respectively. Observations also show the signature of UV radiation and thus, most observed species likely arise in UV-irradiated shocks. Dissociative J-shocks produced by an atomic jet are the most probable origin of [OI] and OH emission and of a significant fraction of the warm CO emission. In addition, H2O photodissociation in UV-irradiated non-dissociative shocks can also contribute to the [OI] and OH emission.

astro-ph.GA↗

H2O line mapping at high spatial and spectral resolution - Herschel observations of the VLA1623 outflow

Apart from being an important coolant, H2O is known to be a tracer of high-velocity molecular gas. Recent models predict relatively high abundances behind interstellar shockwaves. The dynamical and physical conditions of the H2O emitting gas, however, are not fully understood yet. We aim to determine the abundance and distribution of H2O, its kinematics and the physical conditions of the gas responsible for the H2O emission. The observed line profile shapes help us understand the dynamics in molecular outflows. We mapped the VLA1623 outflow, in the ground-state transitions of o-H2O, with the HIFI and PACS instruments. We also present observations of higher energy transitions of o-H2O and p-H2O obtained with HIFI and PACS towards selected outflow positions. From comparison with non-LTE radiative transfer calculations, we estimate the physical parameters of the water emitting regions. The observed water emission line profiles vary over the mapped area. Spectral features and components, tracing gas in different excitation conditions, allow us to constrain the density and temperature of the gas. The H2O emission originates in a region where temperatures are comparable to that of the warm H2 gas (T\gtrsim200K). Thus, the H2O emission traces a gas component significantly warmer than the gas responsible for the low-J CO emission. The H2O column densities at the CO peak positions are low, i.e. N(H2O) \simeq (0.03-10)x10e14 cm-2. The H2O abundance with respect to H2 in the extended outflow is estimated at X(H2O)<1x10e-6, significantly lower than what would be expected from most recent shock models. The H2O emission traces a gas component moving at relatively high velocity compared to the low-J CO emitting gas. However, other dynamical quantities such as the momentum rate, energy and mechanical luminosity are estimated to be the same, independent of the molecular tracer used, CO or H2O.

astro-ph.GA↗

Warm H2O and OH in the disk around the Herbig star HD 163296

We present observations of far-infrared (50-200 micron) OH and H2O emission of the disk around the Herbig Ae star HD 163296 obtained with Herschel/PACS in the context of the DIGIT key program. In addition to strong [OI] emission, a number of OH doublets and a few weak highly excited lines of H2O are detected. The presence of warm H2O in this Herbig disk is confirmed by a line stacking analysis, enabled by the full PACS spectral scan, and by lines seen in Spitzer data. The line fluxes are analyzed using an LTE slab model including line opacity. The water column density is 10^14 - 10^15 cm^-2, and the excitation temperature is 200-300 K implying warm gas with a density n > 10^5 cm^-3. For OH we find a column density of 10^14 - 2x10^15 cm^-2 and T_ex ~ 300-500 K. For both species we find an emitting region of r ~ 15-20 AU from the star. We argue that the molecular emission arises from the protoplanetary disk rather than from an outflow. This far-infrared detection of both H2O and OH contrasts with near- and mid-infrared observations, which have generally found a lack of water in the inner disk around Herbig AeBe stars due to strong photodissociation of water. Given the similarity in column density and emitting region, OH and H2O emission seems to arise from an upper layer of the disk atmosphere of HD 163296, probing a new reservoir of water. The slightly lower temperature of H2O compared to OH suggests a vertical stratification of the molecular gas with OH located higher and water deeper in the disk, consistent with thermo-chemical models.

astro-ph.SR↗

The massive protostar W43-MM1 as seen by Herschel-HIFI water spectra: high turbulence and accretion luminosity

We present Herschel/HIFI observations of fourteen water lines in W43-MM1, a massive protostellar object in the luminous star cluster-forming region W43. We analyze the gas dynamics from the line profiles using Herschel-HIFI observations (WISH-KP) of fourteen far-IR water lines (H2O, H217O, H218O), CS(11-10), and C18O(9-8) lines, and using our modeling of the continuum spectral energy distribution. As for lower mass protostellar objects, the molecular line profiles are a mix of emission and absorption, and can be decomposed into 'medium', and 'broad' velocity components. The broad component is the outflow associated with protostars of all masses. Our modeling shows that the remainder of the water profiles can be well fitted by an infalling and passively heated envelope, with highly supersonic turbulence varying from 2.2 km/s in the inner region to 3.5 km/s in the outer envelope. Also, W43-MM1 has a high accretion rate, between 4.0 x 10^{-4} and 4.0 x 10^{-2} \msun /yr, derived from the fast (0.4-2.9 km/s) infall observed. We estimate a lower mass limit of gaseous water of 0.11 \msun and total water luminosity of 1.5 \lsun (in the 14 lines presented here). The central hot core is detected with a water abundance of 1.4 x 10^{-4} while the water abundance for the outer envelope is 8 x10^{-8}. The latter value is higher than in other sources, most likely related to the high turbulence and the micro-shocks created by its dissipation. Examining water lines of various energies, we find that the turbulent velocity increases with the distance to the center. While not in clear disagreement with the competitive accretion scenario, this behavior is predicted by the turbulent core model. Moreover, the estimated accretion rate is high enough to overcome the expected radiation pressure.

astro-ph.GA↗

Water in star-forming regions with Herschel (WISH): II. Evolution of 557 GHz 110-101 emission in low-mass protostars

(Abridged) Water is a key tracer of dynamics and chemistry in low-mass protostars, but spectrally resolved observations have so far been limited in sensitivity and angular resolution. In this first systematic survey of spectrally resolved water emission in low-mass protostellar objects, H2O was observed in the ground-state transition at 557 GHz with HIFI on Herschel in 29 embedded Class 0 and I protostars. Complementary far-IR and sub-mm continuum data (including PACS data from our program) are used to constrain the spectral energy distribution of each source. H2O intensities are compared to inferred envelope and outflow properties and CO 3-2 emission. H2O emission is detected in all objects except one. The line profiles are complex and consist of several kinematic components. The profiles are typically dominated by a broad Gaussian emission feature, indicating that the bulk of the water emission arises in outflows, not the quiescent envelope. Several sources show multiple shock components in either emission or absorption, thus constraining the internal geometry of the system. Furthermore, the components include inverse P-Cygni profiles in 7 sources (6 Class 0, 1 Class I) indicative of infalling envelopes, and regular P-Cygni profiles in 4 sources (3 Class I, 1 Class 0) indicative of expanding envelopes. "Bullets" moving at >50 km/s are seen in 4 Class 0 sources; 3 of these are new detections. In the outflow, the H2O/CO abundance ratio as a function of velocity is nearly the same for all sources, increasing from 10^-3 at <5 km/s to >10^-1 at >10 km/s. The H2O abundance in the outer envelope is low, ~10^-10. The different H2O profile components show a clear evolutionary trend: in the Class 0 sources, emission is dominated by outflow components originating inside an infalling envelope. When the infall diminishes during the Class I phase, the outflow weakens and H2O emission disappears.

astro-ph.SR↗

Multi-line detection of O2 toward rho Oph A

Models of pure gas-phase chemistry in well-shielded regions of molecular clouds predict relatively high levels of molecular oxygen, O2, and water, H2O. Contrary to expectation, the space missions SWAS and Odin found only very small amounts of water vapour and essentially no O2 in the dense star-forming interstellar medium. Only toward rho Oph A did Odin detect a weak line of O2 at 119 GHz in a beam size of 10 arcmin. A larger telescope aperture such as that of the Herschel Space Observatory is required to resolve the O2 emission and to pinpoint its origin. We use the Heterodyne Instrument for the Far Infrared aboard Herschel to obtain high resolution O2 spectra toward selected positions in rho Oph A. These data are analysed using standard techniques for O2 excitation and compared to recent PDR-like chemical cloud models. The 487.2GHz line was clearly detected toward all three observed positions in rho Oph A. In addition, an oversampled map of the 773.8GHz transition revealed the detection of the line in only half of the observed area. Based on their ratios, the temperature of the O2 emitting gas appears to vary quite substantially, with warm gas (> 50 K) adjacent to a much colder region, where temperatures are below 30 K. The exploited models predict O2 column densities to be sensitive to the prevailing dust temperatures, but rather insensitive to the temperatures of the gas. In agreement with these model, the observationally determined O2 column densities seem not to depend strongly on the derived gas temperatures, but fall into the range N(O2) = (3 to >6)e15/cm^2. Beam averaged O2 abundances are about 5e-8 relative to H2. Combining the HIFI data with earlier Odin observations yields a source size at 119 GHz of about 4 - 5 arcmin, encompassing the entire rho Oph A core.

astro-ph.GA↗

A KInetic Database for Astrochemistry (KIDA)

We present a novel chemical database for gas-phase astrochemistry. Named the KInetic Database for Astrochemistry (KIDA), this database consists of gas-phase reactions with rate coefficients and uncertainties that will be vetted to the greatest extent possible. Submissions of measured and calculated rate coefficients are welcome, and will be studied by experts before inclusion into the database. Besides providing kinetic information for the interstellar medium, KIDA is planned to contain such data for planetary atmospheres and for circumstellar envelopes. Each year, a subset of the reactions in the database (kida.uva) will be provided as a network for the simulation of the chemistry of dense interstellar clouds with temperatures between 10 K and 300 K. We also provide a code, named Nahoon, to study the time-dependent gas-phase chemistry of 0D and 1D interstellar sources.

astro-ph.GA↗

First Detection of Near-Infrared Line Emission from Organics in Young Circumstellar Disks

We present an analysis of high-resolution spectroscopy of several bright T Tauri stars using the VLT/CRIRES and Keck/NIRSPEC spectrographs, revealing the first detections of emission from HCN and C2H2 in circumstellar disks at near-infrared wavelengths. Using advanced data reduction techniques we achieve a dynamic range with respect to the disk continuum of ~500 at 3 microns, revealing multiple emission features of H2O, OH, HCN, and C2H2. We also present stringent upper limits for two other molecules thought to be abundant in the inner disk, CH4 and NH3. Line profiles for the different detected molecules are broad but centrally peaked in most cases, even for disks with previously determined inclinations of greater than 20 degrees, suggesting that the emission has both a Keplerian and non-Keplerian component as observed previously for CO emission. We apply two different modeling strategies to constrain the molecular abundances and temperatures: we use a simplified single-temperature LTE slab model with a Gaussian line profile to make line identifications and determine a best-fit temperature and initial abundance ratios, and we compare these values with constraints derived from a detailed disk radiative transfer model assuming LTE excitation but utilizing a realistic temperature and density structure. Abundance ratios from both sets of models are consistent with each other and consistent with expected values from theoretical chemical models, and analysis of the line shapes suggests the molecular emission originates from within a narrow region in the inner disk (R < 1 AU).

astro-ph.EP↗

Modelling Herschel observations of hot molecular gas emission from embedded low-mass protostars

Aims. Young stars interact vigorously with their surroundings, as evident from the highly rotationally excited CO (up to Eup=4000 K) and H2O emission (up to 600 K) detected by the Herschel Space Observatory in embedded low-mass protostars. Our aim is to construct a model that reproduces the observations quantitatively, to investigate the origin of the emission, and to use the lines as probes of the various heating mechanisms. Methods. The model consists of a spherical envelope with a bipolar outflow cavity. Three heating mechanisms are considered: passive heating by the protostellar luminosity, UV irradiation of the outflow cavity walls, and C-type shocks along the cavity walls. Line fluxes are calculated for CO and H2O and compared to Herschel data and complementary ground-based data for the protostars NGC1333 IRAS2A, HH 46 and DK Cha. The three sources are selected to span a range of evolutionary phases and physical characteristics. Results. The passively heated gas in the envelope accounts for 3-10% of the CO luminosity summed over all rotational lines up to J=40-39; it is best probed by low-J CO isotopologue lines such as C18O 2-1 and 3-2. The UV-heated gas and the C-type shocks, probed by 12CO 10-9 and higher-J lines, contribute 20-80% each. The model fits show a tentative evolutionary trend: the CO emission is dominated by shocks in the youngest source and by UV-heated gas in the oldest one. This trend is mainly driven by the lower envelope density in more evolved sources. The total H2O line luminosity in all cases is dominated by shocks (>99%). The exact percentages for both species are uncertain by at least a factor of 2 due to uncertainties in the gas temperature as function of the incident UV flux. However, on a qualitative level, both UV-heated gas and C-type shocks are needed to reproduce the emission in far-infrared rotational lines of CO and H2O.

astro-ph.SR↗

The Herschel HIFI water line survey in the low-mass proto-stellar outflow L1448

As part of the WISH (Water In Star-forming regions with Herschel) key project, we report on the observations of several ortho- and para-H2O lines performed with the HIFI instrument towards two bright shock spots (R4 and B2) along the outflow driven by the L1448 low-mass proto-stellar system, located in the Perseus cloud. These data are used to identify the physical conditions giving rise to the H2O emission and infer any dependence with velocity. These observations provide evidence that the observed water lines probe a warm (T_kin~400-600 K) and very dense (n 10^6 - 10^7 cm^-3) gas, not traced by other molecules, such as low-J CO and SiO, but rather traced by mid-IR H2 emission. In particular, H2O shows strong differences with SiO in the excitation conditions and in the line profiles in the two observed shocked positions, pointing to chemical variations across the various velocity regimes and chemical evolution in the different shock spots. Physical and kinematical differences can be seen at the two shocked positions. At the R4 position, two velocity components with different excitation can be distinguished, with the component at higher velocity (R4-HV) being less extended and less dense than the low velocity component (R4-LV). H2O column densities of about 2 10^13 and 4 10^14 cm^-2 have been derived for the R4-LV and the R4-HV components, respectively. The conditions inferred for the B2 position are similar to those of the R4-HV component, with H2O column density in the range 10^14 - 5 10^14 cm^-2, corresponding to H2O/H2 abundances in the range 0.5 - 1 10^-5. The observed line ratios and the derived physical conditions seem to be more consistent with excitation in a low velocity J-type shock with large compression rather than in a stationary C-shock, although none of these stationary models seems able to reproduce all the characteristics of the observed emission.

astro-ph.SR↗

Water emission from the chemically rich outflow L1157

In the framework of the Herschel-WISH key program, several ortho-H2O and para-H2O emission lines, in the frequency range from 500 to 1700 GHz, were observed with the HIFI instrument in two bow-shock regions (B2 and R) of the L1157 cloud. The primary aim is to analyse water emission lines as a diagnostic of the physical conditions in the blue (B2) and red-shifted (R) lobes to compare the excitation conditions. A total of 5 ortho- and para-H216O plus one o-H218O transitions were observed in B2 and R with a wide range of excitation energies (27 K<=Eu<=215 K). The H2O spectra, observed in the two shocked regions, show that the H2O profiles are markedly different in the two regions. In particular, at the bow-shock R, we observed broad (~30 km s-1 with respect to the ambient velocity) red-shifted wings where lines at different excitation peak at different red-shifted velocities. The B2 spectra are associated with a narrower velocity range (~6 km s-1), peaking at the systemic velocity. The excitation analysis suggests, for B2, low values of column density NH2O <=5{\times}1013 cm-2, a density range of 105 <=nH2 <=107 cm-3, and warm temperatures (>=300 K). The presence of the broad red-shifted wings and multiple peaks in the spectra of the R region, prompted the modelling of two components. High velocities are associated with relatively low temperatures (~100K),NH2O{\simeq}5{\times}1012-5{\times}1013 cm-2 and densities nH2{\simeq}106-108 cm-3.Lower velocities are associated with higher excitation conditions with Tkin>=300 K, very dense gas (nH2 ~108 cm-3) and low column density (NH2O<5{\times}1013 cm-2).

astro-ph.GA↗

The chemical history of molecules in circumstellar disks. II. Gas-phase species

Context: The chemical composition of a molecular cloud changes dramatically as it collapses to form a low-mass protostar and circumstellar disk. Two-dimensional (2D) chemodynamical models are required to properly study this process. Aims: The goal of this work is to follow, for the first time, the chemical evolution in two dimensions all the way from a pre-stellar core into a circumstellar disk. Of special interest is the question whether the chemical composition of the disk is a result of chemical processing during the collapse phase, or whether it is determined by in situ processing after the disk has formed. Methods: Our model combines a semi-analytical method to get 2D axisymmetric density and velocity structures with detailed radiative transfer calculations to get temperature profiles and UV fluxes. Material is followed in from the core to the disk and a full gas-phase chemistry network -- including freeze-out onto and evaporation from cold dust grains -- is evolved along these trajectories. The abundances thus obtained are compared to the results from a static disk model and to observations of comets. Results: The chemistry during the collapse phase is dominated by a few key processes, such as the evaporation of CO or the photodissociation of H2O. At the end of the collapse phase, the disk can be divided into zones with different chemical histories. The disk is not in chemical equilibrium at the end of the collapse, so care must be taken when choosing the initial abundances for stand-alone disk chemistry models. Our model results imply that comets must be formed from material with different chemical histories: some of it is strongly processed, some of it remains pristine. Variations between individual comets are possible if they formed at different positions or different times in the solar nebula.

astro-ph.GA↗

First hyperfine resolved far-infrared OH spectrum from a star-forming region

OH is an important molecule in the H2O chemistry and the cooling budget of star-forming regions. The goal of the Herschel key program `Water in Star-forming regions with Herschel' (WISH) is to study H2O and related species during protostellar evolution. Our aim in this letter is to assess the origin of the OH emission from star-forming regions and constrain the properties of the emitting gas. High-resolution observations of the OH 2Pi1/2 J = 3/2-1/2 triplet at 1837.8 GHz (163.1 micron) towards the high-mass star-forming region W3 IRS 5 with the Heterodyne Instrument for the Far-Infrared (HIFI) on Herschel reveal the first hyperfine velocity-resolved OH far-infrared spectrum of a star-forming region. The line profile of the OH emission shows two components: a narrow component (FWHM approx. 4-5 km/s) with partially resolved hyperfine structure resides on top of a broad (FWHM approx. 30 km/s) component. The narrow emission agrees well with results from radiative transfer calculations of a spherical envelope model for W3 IRS 5 with a constant OH abundance of approx. 8e-9. Comparison with H2O yields OH/H2O abundance ratios of around 1e-3 for T > 100 K and around unity for T < 100K, consistent with the current picture of the dense cloud chemistry with freeze-out and photodesorption. The broad component is attributed to outflow emission. An abundance ratio of OH/H2O > 0.028 in the outflow is derived from comparison with results of water line modeling. This ratio can be explained by a fast J-type shock or a slower UV-irradiated C-type shock.

astro-ph.SR↗

Water in low-mass star-forming regions with Herschel (WISH-LM): High-velocity H2O bullets in L1448-MM observed with HIFI

Herschel-HIFI observations of water in the low-mass star-forming object L1448-MM, known for its prominent outflow, are presented, as obtained within the `Water in star-forming regions with Herschel' (WISH) key programme. Six H2-16O lines are targeted and detected (E_up/k_B ~ 50-250 K), as is CO J= 10-9 (E_up/k_B ~ 305 K), and tentatively H2-18O 110-101 at 548 GHz. All lines show strong emission in the "bullets" at |v| > 50 km/s from the source velocity, in addition to a broad, central component and narrow absorption. The bullets are seen much more prominently in H$_2$O than in CO with respect to the central component, and show little variation with excitation in H2O profile shape. Excitation conditions in the bullets derived from CO lines imply a temperature >150 K and density >10^5 cm^-3, similar to that of the broad component. The H2O/CO abundance ratio is similar in the "bullets" and the broad component, ~ 0.05-1.0, in spite of their different origins in the molecular jet and the interaction between the outflow and the envelope. The high H2O abundance indicates that the bullets are H2 rich. The H2O cooling in the "bullets" and the broad component is similar and higher than the CO cooling in the same components. These data illustrate the power of Herschel-HIFI to disentangle different dynamical components in low-mass star-forming objects and determine their excitation and chemical conditions.

astro-ph.SR↗

Molecular dynamics simulations of D2O ice photodesorption

Molecular dynamics calculations have been performed to study the ultraviolet photodissociation of D2O in an amorphous D2O ice surface at 10-90 K, in order to investigate the influence of isotope effects on the photodesorption processes. As for H2O, the main processes after UV photodissociation are trapping and desorption. There are three desorption processes: D atom, OD radical, and D2O molecule photodesorption. D2O desorption takes places either by direct desorption of a recombined D2O molecule, or when an energetic D atom produced by photodissociation kicks a surrounding D2O molecule out of the surface by transferring part of its momentum. Desorption probabilities are compared quantitatively with those for H2O obtained from previous MD simulations of UV photodissociation of amorphous water ice. The main conclusions are the same, but the average D atom photodesorption probability is smaller than that of the H atom (by about a factor of 0.9) because D has lower kinetic energy than H, whereas the average OD radical photodesorption probability is larger than that of OH (by about a factor of 2.5-2.9 depending on Tice) because OD has higher translational energy than OH for every Tice studied. The average D2O photodesorption probability is larger than that of H2O (by about a factor of 1.4-2.3 depending on Tice), and this is entirely due to a larger contribution of the D2O kick-out mechanism. This is an isotope effect: the kick-out mechanism is more efficient for D2O ice, because the D atom formed after D2O photodissociation has a larger momentum than photogenerated H atoms from H2O, and D transfers momentum more easily to D2O than H to H2O. The total yield has been compared with experiments and the total yield from previous simulations. We find better agreement when we compare experimental yields with calculated yields for D2O ice than when we compare with calculated yields for H2O ice.

physics.chem-ph↗

Warm dust resolved in the cold disk around T Cha with VLTI/AMBER

The transition between massive Class II circumstellar disks and Class III debris disks, with dust residuals, has not yet been clearly understood. Disks are expected to dissipate with time, and dust clearing in the inner regions can be the consequence of several mechanisms. Planetary formation is one of them that will possibly open a gap inside the disk. According to recent models based on photometric observations, T Cha is expected to present a large gap within its disk, meaning that an inner dusty disk is supposed to have survived close to the star. We investigate this scenario with new near-infrared interferometric observations. We observed T Cha in the H and K bands using the AMBER instrument at VLTI and used the MCFOST radiative transfer code to model the SED of T Cha and the interferometric observations simultaneously and to test the scenario of an inner dusty structure. We also used a toy model of a binary to check that a companion close to the star can reproduce our observations. The scenario of a close (few mas) companion cannot satisfactorily reproduce the visibilities and SED, while a disk model with a large gap and an inner ring producing the bulk of the emission (in H and K-bands) close to 0.1 AU is able to account for all the observations. With this study, the presence of an optically thick inner dusty disk close to the star and dominating the H and K- bands emission is confirmed. According to our model, the large gap extends up to ~ 7.5 AU. This points toward a companion (located at several AU) gap-opening scenario to explain the morphology of T Cha.

astro-ph.SR↗

Water deuterium fractionation in the low-mass protostar NGC1333-IRAS2A

Although deuterium enrichment of water may provide an essential piece of information in the understanding of the formation of comets and protoplanetary systems, only a few studies up to now have aimed at deriving the HDO/H2O ratio in low-mass star forming regions. Previous studies of the molecular deuteration toward the solar-type class 0 protostar, IRAS 16293-2422, have shown that the D/H ratio of water is significantly lower than other grain-surface-formed molecules. It is not clear if this property is general or particular to this source. In order to see if the results toward IRAS 16293-2422 are particular, we aimed at studying water deuterium fractionation in a second low-mass solar-type protostar, NGC1333-IRAS2A. Using the 1-D radiative transfer code RATRAN, we analyzed five HDO transitions observed with the IRAM 30m, JCMT, and APEX telescopes. We assumed that the abundance profile of HDO in the envelope is a step function, with two different values in the inner warm (T>100 K) and outer cold (T<100 K) regions of the protostellar envelope. The inner and outer abundance of HDO is found to be well constrained at the 3 sigma level. The obtained HDO inner and outer fractional abundances are x_in=6.6e-8 - 1e-7 and x_out=9e-11 - 1.8e-9 (3 sigma). These values are close to those in IRAS 16293-2422, which suggests that HDO may be formed by the same mechanisms in these two solar-type protostars. Taking into account the (rather poorly constrained) H2O abundance profile deduced from Herschel observations, the derived HDO/H2O in the inner envelope is larger than 1% and in the outer envelope it is 0.9%-18%. These values are more than one order of magnitude higher than what is measured in comets. If the same ratios apply to the protosolar nebula, this would imply that there is some efficient reprocessing of the material between the protostellar and cometary phases. The H2O inner fractional [...]

astro-ph.GA↗

Ice and Dust in the Quiescent Medium of Isolated Dense Cores

The relation between ices in the envelopes and disks surrounding YSOs and those in the quiescent interstellar medium is investigated. For a sample of 31 stars behind isolated dense cores, ground-based and Spitzer spectra and photometry in the 1-25 um wavelength range are combined. The baseline for the broad and overlapping ice features is modeled, using calculated spectra of giants, H2O ice and silicates. The adopted extinction curve is derived empirically. Its high resolution allows for the separation of continuum and feature extinction. The extinction between 13-25 um is ~50% relative to that at 2.2 um. The strengths of the 6.0 and 6.85 um absorption bands are in line with those of YSOs. Thus, their carriers, which, besides H2O and CH3OH, may include NH4+, HCOOH, H2CO and NH3, are readily formed in the dense core phase, before stars form. The 3.53 um C-H stretching mode of solid CH3OH was discovered. The CH3OH/H2O abundance ratios of 5-12% are larger than upper limits in the Taurus molecular cloud. The initial ice composition, before star formation occurs, therefore depends on the environment. Signs of thermal and energetic processing that were found toward some YSOs are absent in the ices toward background stars. Finally, the peak optical depth of the 9.7 um band of silicates relative to the continuum extinction at 2.2 um is significantly shallower than in the diffuse interstellar medium. This extends the results of Chiar et al. (2007) to a larger sample and higher extinctions.

astro-ph.GA↗