arXiv subjects

E. F. van Dishoeck

Publications and source records attributed to E. F. van Dishoeck.

At least 289 records · Page 16Linked to original sources

arXiv2008

An interferometric study of the low-mass protostar IRAS 16293-2422: small scale organic chemistry

Aims: To investigate the chemical relations between complex organics based on their spatial distributions and excitation conditions in the low-mass young stellar objects IRAS 16293-2422 A and B. Methods: Interferometric observations with the Submillimeter Array have been performed at 5''x3'' resolution revealing emission lines of HNCO, CH3CN, CH2CO, CH3CHO and C2H5OH. Rotational temperatures are determined from rotational diagrams when a sufficient number of lines are detected. Results: Compact emission is detected for all species studied here. For HNCO and CH3CN it mostly arises from source A, CH2CO and C2H5OH have comparable strength for both sources and CH3CHO arises exclusively from source B. HNCO, CH3CN and CH3CHO have rotational temperatures >200 K. The (u,v)-visibility data reveal that HNCO also has extended cold emission. Conclusions: The abundances of the molecules studied here are very similar within factors of a few to those found in high-mass YSOs. Thus the chemistry between high- and low-mass objects appears to be independent of luminosity and cloud mass. Bigger abundance differences are seen between the A and B source. The HNCO abundance relative to CH3OH is ~4 times higher toward A, which may be due to a higher initial OCN- ice abundances in source A compared to B. Furthermore, not all oxygen-bearing species are co-existent. The different spatial behavior of CH2CO and C2H5OH compared with CH3CHO suggests that hydrogenation reactions on grain-surfaces are not sufficient to explain the observed gas phase abundances. Selective destruction of CH3CHO may result in the anti-coincidence of these species in source A. These results illustrate the power of interferometric compared with single dish data in terms of testing chemical models.

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arXiv2008

Organic Matter in Space - an Overview

Organic compounds are ubiquitous in space: they are found in diffuse clouds, in the envelopes of evolved stars, in dense star-forming regions, in protoplanetary disks, in comets, on the surfaces of minor planets, and in meteorites and interplanetary dust particles. This brief overview summarizes the observational evidence for the types of organics found in these regions, with emphasis on recent developments. The Stardust sample-return mission provides the first opportunity to study primitive cometary material with sophisticated equipment on Earth. Similarities and differences between the types of compounds in different regions are discussed in the context of the processes that can modify them. The importance of laboratory astrophysics is emphasized.

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arXiv2008

Laboratory evidence for efficient water formation in interstellar ices

Even though water is the main constituent in interstellar icy mantles, its chemical origin is not well understood. Three different formation routes have been proposed following hydrogenation of O, O2, or O3, but experimental evidence is largely lacking. We present a solid state astrochemical laboratory study in which one of these routes is tested. For this purpose O2 ice is bombarded by H- or D-atoms under ultra high vacuum conditions at astronomically relevant temperatures ranging from 12 to 28 K. The use of reflection absorption infrared spectroscopy (RAIRS) permits derivation of reaction rates and shows efficient formation of H2O (D2O) with a rate that is surprisingly independent of temperature. This formation route converts O2 into H2O via H2O2 and is found to be orders of magnitude more efficient than previously assumed. It should therefore be considered as an important channel for interstellar water ice formation as illustrated by astrochemical model calculations.

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arXiv2008

Characterizing the nature of embedded young stellar objects through silicate, ice and millimeter observations

(Abridged) Classification schemes for YSOs are based on evaluating the degree of dissipation of the surrounding envelope, whose main effects are the extinction of the optical radiation from the central YSO and re-emission in the far-infrared. Since extinction is a property of column density along the line of sight, the presence of a protoplanetary disk may lead to a misclassification when the system is viewed edge-on. We performed radiative transfer calculations, using the axysimmetric 3D radiative transfer codes RADMC and RADICAL, to show the effects of different geometries on the main indicators of YSO evolutionary stage, like the slope of the flux between 2 and 24mum, the bolometric temperature and the optical depth of silicates and ices. We show that for systems viewed at intermediate angles the 'classical' indicators of evolution accurately trace the envelope column density, and they all agree with each other. On the other hand, edge-on system are misclassified for inclinations larger than ~65deg. In particular, silicate emission, typical of pre-main sequence stars with disks, turns into absorption when the disk column density reaches 1e22cm-2, corresponding e.g. to a 5e-3 Msun flaring disk viewed at 64deg. A similar effect is noticed in all the other classification indicators studied alpha, Tbol, and the H2O and CO2 ices absorption strengths. This misclassification has a big impact on the nature of the flat-spectrum sources (alpha ~0), whose number can be explained by simple geometrical arguments without invoking evolution. A reliable classification scheme using a minimal number of observations is constituted by observations of the mm-flux with both a single dish and an interferometer.

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arXiv2008

Photodissociation of small carbonaceous molecules of astrophysical interest

Astronomical observations have shown that small carbonaceous molecules can persist in interstellar clouds exposed to intense ultraviolet radiation. Current astrochemical models lack quantitative information on photodissociation rates in order to interpret these data. We here present ab initio multi-reference configuration-interaction calculations of the vertical excitation energies, transition dipole moments and oscillator strengths for a number of astrophysically relevant molecules: C3, C4, C2H, l- and c-C3H, l- and c-C3H2, HC3H, l-C4H and l-C5H. Highly excited states up to the 9'th root of each symmetry are computed, and several new states with large oscillator strengths are found below the ionization potentials. These data are used to calculate upper limits on photodissociation rates in the unattenuated interstellar radiation field by assuming that all absorptions above the dissociation limit lead to dissociation.

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arXiv2008

Photoprocesses in protoplanetary disks

Circumstellar disks are exposed to intense ultraviolet radiation from the young star. In the inner disks, the UV radiation can be enhanced by more than seven orders of magnitude compared with the average interstellar field, resulting in a physical and chemical structure that resembles that of a dense photon-dominated region (PDR). This intense UV field affects the chemistry, the vertical structure of the disk, and the gas temperature, especially in the surface layers of the disk. The parameters which make disks different from traditional PDRs are discussed, including the shape of the UV radiation field, grain growth, the absence of PAHs, the gas/dust ratio and the presence of inner holes. New photorates for selected species, including simple ions, are presented. Also, a summary of available cross sections at Lyman alpha 1216 A is made. Rates are computed for radiation fields with color temperatures ranging from 4000 to 30,000 K, and can be applied to a wide variety of astrophysical regions including exo-planetary atmospheres. The importance of photoprocesses is illustrated for a number of representative disk models, including disk models with grain growth and settling.

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arXiv2008

Modeling water emission from low-mass protostellar envelopes

Within low-mass star formation, water vapor plays a key role in the chemistry and energy balance of the circumstellar material. The Herschel Space Observatory will open up the possibility to observe water lines originating from a wide range of excitation energies.Our aim is to simulate the emission of rotational water lines from envelopes characteristic of embedded low-mass protostars. A large number of parameters that influence the water line emission are explored: luminosity, density,density slope and water abundances.Both dust and water emission are modelled using full radiative transfer in spherical symmetry. The temperature profile is calculated for a given density profile. The H2O level populations and emission profiles are in turn computed with a non-LTE line code. The results are analyzed to determine the diagnostic value of different lines, and are compared with existing observations. Lines can be categorized in: (i) optically thick lines, including ground-state lines, mostly sensitive to the cold outer part; (ii) highly excited (E_u>200-250 K) optically thin lines sensitive to the abundance in the hot inner part; and (iii) lines which vary from optically thick to thin depending on the abundances. Dust influences the emission of water significantly by becoming optically thick at the higher frequencies, and by pumping optically thin lines. A good physical model of a source, including a correct treatment of dust, is a prerequisite to infer the water abundance structure and possible jumps at the evaporation temperature from observations. The inner warm (T>100 K) envelope can be probed byhighly-excited lines, while a combination of excited and spectrally resolved ground state lines probes the outer envelope. Observations of H218O lines, although weak, provide even stronger constraints on abundances.

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arXiv2008

H2O and OH gas in the terrestrial planet-forming zones of protoplanetary disks

We present detections of numerous 10-20 micron H2O emission lines from two protoplanetary disks around the T Tauri stars AS 205A and DR Tau, obtained using the InfraRed Spectrograph on the Spitzer Space Telescope. Follow-up 3-5 micron Keck-NIRSPEC data confirm the presence of abundant water and spectrally resolve the lines. We also detect the P4.5 (2.934 micron) and P9.5 (3.179 micron) doublets of OH and 12CO/13CO v=1-0 emission in both sources. Line shapes and LTE models suggest that the emission from all three molecules originates between ~0.5 and 5 AU, and so will provide a new window for understanding the chemical environment during terrestrial planet formation. LTE models also imply significant columns of H2O and OH in the inner disk atmospheres, suggesting physical transport of volatile ices either vertically or radially; while the significant radial extent of the emission stresses the importance of a more complete understanding of non-thermal excitation processes.

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arXiv2007

Spatially extended PAHs in circumstellar disks around T Tauri and Herbig Ae stars

Our aim is to determine the presence and location of the emission from polycyclic aromatic hydrocarbons (PAHs) towards low and intermediate mass young stars with disks using large aperture telescopes. VLT-VISIR N-band spectra and VLT-ISAAC and VLT-NACO L-band spectra of 29 sources are presented, spectrally resolving the 3.3, 8.6, 11.2, and 12.6 micron PAH features. Spatial-extent profiles of the features and the continuum emission are derived and used to associate the PAH emission with the disks. The results are discussed in the context of recent PAH-emission disk models. The 3.3, 8.6, and 11.2 micron PAH features are detected toward a small fraction of the T Tauri stars, with typical upper limits between 1E-15 and 5E-17 W/m^2. All 11.2 micron detections from a previous Spitzer survey are confirmed with (tentative) 3.3 micron detections, and both the 8.6 and the 11.2 micron features are detected in all PAH sources. For 6 detections, the spatial extent of the PAH features is confined to scales typically smaller than 0.12-0.34'', consistent with the radii of 12-60 AU disks at their distances (typically 150 pc). For 3 additional sources, WL 16, HD 100546, and TY CrA, one or more of the PAH features are more extended than the hot dust continuum of the disk, whereas for Oph IRS 48, the size of the resolved PAH emission is confirmed as smaller than for the large grains. For HD 100546, the 3.3 micron emission is confined to a small radial extent of 12 +- 3 AU, most likely associated with the outer rim of the gap in this disk. Gaps with radii out to 10-30 AU may also affect the observed PAH extent for other sources. For both Herbig Ae and T Tauri stars, the small measured extents of the 8.6 and 11.2 micron features are consistent with larger (>= 100 carbon atoms) PAHs.

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arXiv2007

H-atom bombardment of CO2, HCOOH and CH3CHO containing ices

Context: Hydrogenation reactions are expected to be among the most important surface reactions on interstellar ices. However, solid state astrochemical laboratory data on reactions of H-atoms with common interstellar ice constituents are largely lacking. Aims: The goal of our laboratory work is to determine whether and how carbon dioxide (CO2), formic acid (HCOOH) and acetaldehyde (CH3CHO) react with H-atoms in the solid state at low temperatures and to derive reaction rates and production yields. Methods: Pure CO2, HCOOH and CH3CHO interstellar ice analogues are bombarded by H-atoms in an ultra-high vacuum experiment. The ices are monitored by reflection absorption infrared spectroscopy and the reaction products are detected in the gas phase through temperature programmed desorption to determine the destruction and formation yields as well as the corresponding reaction rates. Results: Within the sensitivity of our set-up we conclude that H-atom bombardment of pure CO2 and HCOOH ice does not result in detectable reaction products. The upper limits on the reaction rates are less or equal to 7e(-17) cm^2/s which make it unlikely that these species play a major role in the formation of more complex organics in interstellar ices due to reactions with H-atoms. In contrast, CH3CHO does react with H-atoms. At most 20% is hydrogenated to ethanol (C2H5OH) and a second reaction route leads to the break-up of the C-C bond to form solid state CH4 (~20%) as well as H2CO and CH3OH (15-50%). The methane production yield is expected to be equal to the summed yield of H2CO and CH3OH and therefore CH4 most likely evaporates partly after formation due to the high exothermicity of the reaction. The reaction rates for CH3CHO destruction depend on ice temperature and not on ice thickness.

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arXiv2007

Energetic radiation and the sulfur chemistry of protostellar envelopes: Submillimeter interferometry of AFGL 2591

CONTEXT: The chemistry in the inner few thousand AU of accreting envelopes around young stellar objects is predicted to vary greatly with far-UV and X-ray irradiation by the central star. Aim We search for molecular tracers of high-energy irradiation by the protostar in the hot inner envelope. METHODS: The Submillimeter Array (SMA) has observed the high-mass star forming region AFGL 2591 in lines of CS, SO, HCN, HCN(v2=1), and HC15N with 0.6" resolution at 350 GHz probing radial scales of 600-3500 AU for an assumed distance of 1 kpc. The SMA observations are compared with the predictions of a chemical model fitted to previous single-dish observations. RESULTS: The CS and SO main peaks are extended in space at the FWHM level, as predicted in the model assuming protostellar X-rays. However, the main peak sizes are found smaller than modeled by nearly a factor of 2. On the other hand, the lines of CS, HCN, and HC15N, but not SO and HCN(v2=1), show pedestal emissions at radii of about 3500 AU that are not predicted. All lines except SO show a secondary peak within the approaching outflow cone. A dip or null in the visibilities caused by a sharp decrease in abundance with increasing radius is not observed in CS and only tentatively in SO. CONCLUSIONS: The emission of protostellar X-rays is supported by the good fit of the modeled SO and CS amplitude visibilities including an extended main peak in CS. The broad pedestals can be interpreted by far-UV irradiation in a spherically non-symmetric geometry, possibly comprising outflow walls on scales of 3500 -- 7000 AU. The extended CS and SO main peaks suggest sulfur evaporation near the 100 K temperature radius.

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arXiv2007

Cold Disks: Spitzer Spectroscopy of Disks around Young Stars with Large Gaps

We have identified four circumstellar disks with a deficit of dust emission from their inner 15-50 AU. All four stars have F-G spectral type, and were uncovered as part of the Spitzer Space Telescope ``Cores to Disks'' Legacy Program Infrared Spectrograph (IRS) first look survey of ~100 pre-main sequence stars. Modeling of the spectral energy distributions indicates a reduction in dust density by factors of 100-1000 from disk radii between ~0.4 and 15-50 AU, but with massive gas-rich disks at larger radii. This large contrast between the inner and outer disk has led us to use the term `cold disks' to distinguish these unusual systems. However, hot dust [0.02-0.2 Mmoon] is still present close to the central star (R ~0.8 AU). We introduce the 30/13 micron, flux density ratio as a new diagnostic for identifying cold disks. The mechanisms for dust clearing over such large gaps are discussed. Though rare, cold disks are likely in transition from an optically thick to an optically thin state, and so offer excellent laboratories for the study of planet formation.

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arXiv2007

Infrared Molecular Starburst Fingerprints in Deeply Obscured (U)LIRG Nuclei

High resolution spectra of the Spitzer Space Telescope show vibration-rotation absorption bands of gaseous C2H2, HCN, and CO2 molecules toward a sample of deeply obscured (U)LIRG nuclei. The observed bands reveal the presence of dense (n>~ 10^7 cm^-3), warm (T_ex = 200-700 K) molecular gas with high column densities of these molecules ranging from a few 10^15 - 10^17 cm^-2. Abundances relative to H2, inferred from the silicate optical depth, range from ~10^-7 to 10^-6 and show no correlation with temperature. Theoretical studies show that the high abundances of both C2H2 and HCN exclude a X-ray dominated region (XDR) associated with the toroid surrounding an AGN as the origin of this dense warm molecular gas. Galactic massive protostars in the so-called Hot Core phase have similar physical characteristics with comparable high abundances of C2H2, HCN, and CO2 in the hot phase. However, the abundances of C2H2 and HCN and the C2H2/CO2 and HCN/CO2 ratios are much higher toward the (U)LIRGs in the cooler (T_ex <= 400 K) phase. We suggest that the warm dense molecular gas revealed by the mid-IR absorption lines is associated with a phase of deeply embedded star formation where the extreme pressures and densities of the nuclear starburst environment have inhibited the expansion of HII regions and the global disruption of the star forming molecular cloud cores, and `trapped' the star formation process in an `extended' Hot Core phase.

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arXiv2007

Spatial separation of small and large grains in the transitional disk around the young star IRS 48

We present spatially resolved mid-infrared images of the disk surrounding the young star IRS 48 in the Ophiuchus cloud complex. The disk exhibits a ring-like structure at 18.7 micron, and is dominated by very strong emission from polycyclic aromatic hydrocarbons at shorter wavelengths. This allows a detailed study of the relative distributions of small and large dust grains. Images of IRS 48 in 5 mid-infrared bands from 8.6 to 18.7 micron as well as a low resolution N-band spectrum are obtained with VLT-VISIR. Optical spectroscopy is used to determine the spectral type of the central star and to measure the strength of the Halpha line. The 18.7 micron ring peaks at a diameter of 110 AU, with a gap of ~ 60 AU. The shape of the ring is consistent with an inclination of i = 48 +- 8 degrees. In contrast, the 7.5-13 micron PAH emission bands are centered on the source and appear to fill the gap within the ring. The measured PAH line strengths are 10-100x stronger than those typically measured for young M0 stars and can only be explained with a high PAH abundance and/or strong excess optical/UV emission. The morphology of the images, combined with the absence of a silicate emission feature, imply that the inner disk has been cleared of micron-sized dust but with a significant population of PAHs remaining. We argue that the gap can be due to grain growth and settling or to clearing by an unseen planetary or low-mass companion. IRS 48 may represent a short-lived transitional phase from a classical to a weak-line T Tauri star.

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arXiv2007

The IC1396N proto-cluster at a scale of 250 AU

We investigate the mm-morphology of IC1396N with unprecedented spatial resolution to analyze its dust and molecular gas properties, and draw comparisons with objects of similar mass. We have carried out sensitive observations in the most extended configurations of the IRAM Plateau de Bure interferometer, to map the thermal dust emission at 3.3 and 1.3mm, and the emission from the $J$=13$_k\to12_k$ hyperfine transitions of methyl cyanide (CH$_3$CN). We unveil the existence of a sub-cluster of hot cores in IC1396N, distributed in a direction perpendicular to the emanating outflow. The cores are embedded in a common envelope of extended and diffuse dust emission. We find striking differences in the dust properties of the cores ($β\simeq$ 0) and the surrounding envelope ($β\simeq$ 1), very likely testifying to differences in the formation and processing of dust material. The CH$_3$CN emission peaks towards the most massive hot core and is marginally extended in the outflow direction.

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arXiv2007

Infrared spectroscopy of HCOOH in interstellar ice analogues

Context: HCOOH is one of the more common species in interstellar ices with abundances of 1-5% with respect to solid H2O. Aims: This study aims at characterizing the HCOOH spectral features in astrophysically relevant ice mixtures in order to interpret astronomical data. Methods: The ices are grown under high vacuum conditions and spectra are recorded in transmission using a Fourier transform infrared spectrometer. Pure HCOOH ices deposited at 15 K and 145 K are studied, as well as binary and tertiary mixtures containing H2O, CO, CO2 and CH3OH. The mixture concentrations are varied from 50:50% to ~10:90% for HCOOH:H2O. Binary mixtures of HCOOH:X and tertiary mixtures of HCOOH:H2O:X with X = CO, CO2, and CH3OH, are studied for concentrations of ~10:90% and ~7:67:26%, respectively. Results: Pure HCOOH ice spectra show broad bands which split around 120 K due to the conversion of a dimer to a chain-structure. Broad single component bands are found for mixtures with H2O. Additional spectral components are present in mixtures with CO, CO2 and CH3OH. The resulting peak position, full width at half maximum and band strength depend strongly on ice structure, temperature, matrix constituents and the HCOOH concentration. Comparison of the solid HCOOH 5.9, 7.2, and 8.1 micron features with astronomical data toward the low mass source HH 46 and high mass source W 33A shows that spectra of binary mixtures do not reproduce the observed ice features. However, our tertiary mixtures especially with CH3OH match the astronomical data very well. Thus interstellar HCOOH is most likely present in tertiary or more complex mixtures with H2O, CH3OH and potentially also CO or CO2, providing constraints on its formation.

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arXiv2007

Protostellar clusters in intermediate-mass (IM) star forming regions

The transition between the low density groups of T Tauri stars and the high density clusters around massive stars occurs in the intermediate-mass (IM) range (M$_*$$\sim$2--8 M$_\odot$). High spatial resolution studies of IM young stellar objects (YSO) can provide important clues to understand the clustering in massive star forming regions. Aims: Our aim is to search for clustering in IM Class 0 protostars. The high spatial resolution and sensitivity provided by the new A configuration of the Plateau de Bure Interferometer (PdBI) allow us to study the clustering in these nearby objects. Methods: We have imaged three IM Class 0 protostars (Serpens-FIRS 1, IC 1396 N, CB 3) in the continuum at 3.3 and 1.3mm using the PdBI. The sources have been selected with different luminosity to investigate the dependence of the clustering process on the luminosity of the source. Results: Only one millimeter (mm) source is detected towards the low luminosity source Serpens--FIRS 1. Towards CB 3 and IC1396 N, we detect two compact sources separated by $\sim$0.05 pc. The 1.3mm image of IC 1396 N, which provides the highest spatial resolution, reveal that one of these cores is splitted in, at least, three individual sources.

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arXiv2007

Testing grain-surface chemistry in massive hot-core regions

A partial submillimeter line-survey was performed toward 7 high-mass young stellar objects (YSOs) aimed at detecting H2CO, CH3OH, CH2CO, CH3CHO, C2H5OH, HCOOH, HNCO and NH2CHO. In addition, other organic species such as CH3CN have been observed. The aim is to establish the chemical origin of a set of complex organic molecules thought to be produced by grain surface chemistry in high mass YSOs. Rotation temperatures and beam-averaged column densities are determined. Based on their rotation diagrams, molecules can be classified as either cold (<100 K) or hot (>100 K). This implies that complex organics are present in at least two distinct regions. Furthermore, the abundances of the hot oxygen-bearing species are correlated, as are those of HNCO and NH2CHO. This is suggestive of chemical relationships within, but not between, those two groups of molecules. The most likely explanation for the observed correlations of the various hot molecules is that they are ``first generation'' species that originate from solid-state chemistry. This includes H2CO, CH3OH, C2H5OH, HCOOCH3, CH3OCH3, HNCO, NH2CHO, and possibly CH3CN, and C2H5CN. The correlations between sources implies very similar conditions during their formation or very similar doses of energetic processing. Cold species such as CH2CO, CH3CHO, and HCOOH, some of which are seen as ices along the same lines of sight, are probably formed in the solid state as well, but appear to be destroyed at higher temperatures. A low level of non-thermal desorption by cosmic rays can explain their low rotation temperatures and relatively low abundances in the gas phase compared to the solid state. The CH3CCH abundances can be fully explained by low temperature gas phase chemistry. No cold N-containing molecules are found.

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