arXiv subjects

E. Quirico

Publications and source records attributed to E. Quirico.

At least 19 recordsLinked to original sources

arXiv2026

Near-perihelion activity and composition of 3I/ATLAS from JUICE/MAJIS observations

We present visible-to-infrared (0.5-5.56 microns) observations of the interstellar comet 3I/ATLAS obtained with the Moons and Jupiter Imaging Spectrometer (MAJIS) aboard the Jupiter Icy Moons Explorer (JUICE) spacecraft between 2025 November 2 and 25, shortly after perihelion. The fluorescence emission from H2O at 2.7 microns and CO2 at 4.3 microns is detected at heliocentric distances of 1.36-1.68 au. A weak dust-scattered continuum is identified from which we determine the spectral slope, with values ranging from ~15% per 100 nm in the 0.65-0.9 microns region to 1-3% per 100 nm from 0.9 to 2.6 microns. Spatially resolved measurements show that the radial distributions of H2O and CO2 species are consistent with release in the near-nucleus environment. We derive H2O production rates that decreased from 8 x 1028 s-1 to 4 x 1028 s-1 over the period November 2-25, while the CO2/H2O ratio remained nearly constant at ~10%. The heliocentric evolution of the CO2 production rate indicates activity controlled by solar heating. Combined with published CO measurements and the low gas expansion velocities, our analyses support a scenario in which CO2 plays a major role in driving the activity of 3I/ATLAS near perihelion. In addition, broad emission features are identified in the 3.2-3.6 microns region that cannot be explained by the fluorescence of common cometary CH-bearing volatiles. Their spectral characteristics are consistent with aliphatic C-H functional groups and provide tentative evidence for the release of complex organic material from dust grains in the coma.

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arXiv2026

An unidentified absorption feature at 5.11 $\mu$m on the surface of Titan and Pluto from JWST spectroscopy

Titan possesses a thick N$_2$-CH$_4$ atmosphere that makes it difficult to study its surface spectroscopically. The chemical composition of the solid surface of Titan thus remains very uncertain. By leveraging JWST's high sensitivity and large spectral coverage, we searched for any signature from Titan's surface in the broad and less explored 5-$\mu$m atmospheric window. We also investigated the JWST spectrum of Pluto which has a thin Titan-like atmosphere. We made selections of JWST NIRSpec and MIRI spectra around Titan's disk center and compared the NIRSpec average spectrum with a radiative transfer model including gas and haze opacity. We detected an unidentified absorption in both NIRSpec and MIRI spectra of Titan centered at 5.113 $\mu$m (1956 cm$^{-1}$) and 6-7% deep. The width of the feature is 0.024$\pm$0.0008 $\mu$m (9.2$\pm$0.3 cm$^{-1}$) in the NIRSpec spectrum recorded on the trailing side and is possibly 25% narrower in the MIRI spectrum of the leading side. This absorption most likely originates from the surface. We could not identify this signature among published laboratory spectra of ices relevant to Titan's atmospheric compounds but present a few plausible candidates. A 4-5% deep absorption is also present in the MIRI spectrum of Pluto but is about 3 times broader than on Titan's trailing side.

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arXiv2025

Amides from the carbonaceous asteroid (162173) Ryugu: nanoscale spectral and isotopic characterizations

C-type asteroids, such as asteroid (162173) Ryugu, may have played a key role in delivering light elements to early Earth. Nitrogen (N)-bearing molecules have been chemically identified in some Ryugu grains, and based on the faint 3.06 um absorption band observed by the hyperspectral microscope MicrOmega, NH-bearing compounds appear to be globally distributed. However, the chemical forms of these NH-bearing compounds - whether organic molecules, ammonium (NH4+) salts, NH4+- or NH-organic-bearing phyllosilicates, or other forms - remain to be clarified. We report the characterization of two Ryugu particles (C0050 and C0052) using infrared spectroscopy at millimeter, micrometer, and nanometer scales, combined with NanoSIMS to constrain the nature and origin of NH-bearing components. Ryugu's C0052 particle contains rare (~1 vol.%) micrometer-sized NH-rich organic compounds with peaks at 1660 cm-1 (C=O stretching, amide I) and 1550 cm-1 (N-H bending, amide II), indicative of amides, absent in C0050. N isotopic analysis shows these amides are depleted in 15N (d15N ~ -200 permil), confirming their indigenous origin. The amides may have formed by hydrothermal alteration of carboxylic acids and amines on Ryugu's parent body or by irradiation of 15N-depleted N-bearing ice in the outer Solar System or interstellar medium. Such amides delivered by primitive small bodies may have contributed to prebiotic chemistry on early Earth.

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arXiv2024

Cosmic-ray induced sputtering of interstellar formaldehyde ices

H2CO is a ubiquitous molecule in the ISM and in the gas phase of prestellar cores, and is likely present in ice mantles, but its main desorption mechanism is unknown. In this paper our aim is to quantify the desorption efficiency of H2CO upon cosmic-ray impact in order to determine whether cosmic-ray induced sputtering could account for the H2CO abundance observed in prestellar cores. Using a heavy-ion beam as a cosmic-ray analogue at the GANIL accelerator, we irradiated pure H2CO ice films at 10 K under high vacuum conditions and monitored the ice film evolution with infrared spectroscopy and the composition of the sputtered species in the gas phase using mass spectrometry. We derived both the effective and intact sputtering yield of pure H2CO ices. We find that H2CO easily polymerises under heavy-ion irradiation in the ice, and is also radiolysed into CO and CO2. In the gas phase, the dominant sputtered species is CO and intact H2CO is only a minor species. We determine an intact sputtering yield for pure H2CO ices $2.5\times 10^3$ molecules ion$^{-1}$ for an electronic stopping power of $S_e\sim2830$ eV ($10^{15}$ molecules cm$^{-2}$)$^{-1}$. The corresponding cosmic-ray sputtering rate is $\Gamma_\mathrm{CRD}=1.5\times 10^{18}\zeta$ molecules cm$^{-2}$ s$^{-1}$, where $\zeta$ is the rate of cosmic-ray ionisation of molecular hydrogen in the ISM. In the frame of a simple steady-state chemical model of freeze-out and non-thermal desorption, we find that this experimental cosmic-ray sputtering rate is too low (by an order of magnitude) to account for the observed H2CO gas-phase abundance we derived in the prestellar core L1689B. We find however that this abundance can be reproduced if we assume that H2CO diluted in CO or CO2 ices co-desorbs at the same sputtering rate as pure CO or pure CO2 ices.

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arXiv2023

Composition and thermal properties of Ganymede's surface from JWST/NIRSpec and MIRI observations

JWST NIRSpec IFU (2.9-5.3 mu) and MIRI MRS (4.9-28.5 mu) observations were performed on both the leading and trailing hemispheres of Ganymede with a spectral resolution of ~2700. Reflectance spectra show signatures of water ice, CO2 and H2O2. An absorption feature at 5.9 mu is revealed and is tentatively assigned to sulfuric acid hydrates. The CO2 4.26-mu band shows latitudinal and longitudinal variations in depth, shape and position over the two hemispheres, unveiling different CO2 physical states. In the ice-rich polar regions, which are the most exposed to Jupiter's plasma irradiation, the CO2 band is redshifted with respect to other terrains. In the leading northern polar cap, the CO2 band is dominated by a high wavelength component at ~4.27 mu, consistent with CO2 trapped in amorphous water ice. At equatorial latitudes (and especially on dark terrains) the observed band is broader and shifted towards the blue, suggesting CO2 adsorbed on non-icy materials. Amorphous ice is detected in the ice-rich polar regions, and is especially abundant on the leading northern polar cap. In both hemispheres the north polar cap ice appears to be more processed than the south polar cap. A longitudinal modification of the H2O ice molecular structure and/or nano/micrometre-scale texture, of diurnal or geographic origin, is observed in both hemispheres. Ice frost is observed on the morning limb of the trailing hemisphere, possibly formed during the night from the recondensation of water subliming from the warmer subsurface. Reflectance spectra of the dark terrains are compatible with the presence of Na-/Mg-sulfate salts, sulfuric acid hydrates, and possibly phyllosilicates mixed with fine-grained opaque minerals, having an highly porous texture. Mid-IR brightness temperatures indicate a rough surface and a very low thermal inertia of 20-40 J m-2 s-0.5 K-1, consistent with a porous surface.

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arXiv2023

Volatile exposures on the 67P/Churyumov-Gerasimenko nucleus

We present the most extensive catalog of exposures of volatiles on the 67P/Churyumov-Gerasimenko nucleus generated from observations acquired with the OSIRIS cameras on board the Rosetta mission. We identified more than 600 volatile exposures on the comet. Bright spots are found isolated on the nucleus or grouped in clusters, usually at the bottom of cliffs, and most of them are small, typically a few square meters or smaller. Several of them are clearly correlated with the cometary activity. We note a number of peculiar exposures of volatiles with negative spectral slope values in the high-resolution post-perihelion images, which we interpret as the presence of large ice grains ($>$ 1000 $μ$m) or local frosts condensation. We observe a clear difference both in the spectral slope and in the area distributions of the bright spots pre- and post-perihelion, with these last having lower average spectral slope values and a smaller size, with a median surface of 0.7 m$^2$, even if the size difference is mainly due to the higher resolution achieved post-perihelion. The minimum duration of the bright spots shows three clusters: an area-independent cluster dominated by short-lifetime frosts; an area-independent cluster with lifetime of 0.5--2 days, probably associated with the seasonal fallout of dehydrated chunks; and an area-dependent cluster with lifetime longer than 2 days consistent with water-driven erosion of the nucleus. Even if numerous bright spots are detected, the total surface of exposed water ice is less than 0.1% of the total 67P nucleus surface, confirming that the 67P surface is dominated by refractory dark terrains, while exposed ice occupies only a tiny fraction. Moreover, the abundance of volatile exposures is six times less in the small lobe than in the big lobe, adding additional evidence to the hypothesis that comet 67P is composed of two distinct bodies.

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arXiv2021

Volatile transport modeling on Triton with new observational constraints

Neptune's moon Triton shares many similarities with Pluto, including volatile cycles of N2, CH4 and CO, and represents a benchmark case for the study of surface-atmosphere interactions on volatile-rich KBOs. Within the context of New Horizons observations of Pluto as well as recent Earth-based observations of Triton, we adapt a Plutonian VTM to Triton, and test its ability to simulate its volatile cycles, thereby aiding our understanding of its climate. We present VTM simulations exploring the volatile cycles on Triton over long-term and seasonal timescales for varying model parameters. We explore what scenarios and model parameters allow for a best match of the available observations. In particular, our set of observational constraints include Voyager 2 observations, ground-based NIR (0.8 to 2.4 μm) disk-integrated spectra and the evolution of surface pressure as retrieved from stellar occultations. Our results show that Triton's poles act as cold traps for volatile ices and favor the formation of polar caps extending to lower latitudes through glacial flow. As previously evidenced by other VTMs, North-South asymmetries in surface properties can favor the development of one cap over the other. Our best-case simulations are obtained for a global reservoir of N2 ice thicker than 200 m and a bedrock thermal inertia larger than 500 SI. The large N2 ice reservoir implies a permanent N2 southern cap extending to the equator. Our results also suggest that a small permanent polar cap exists in the northern (currently winter) hemisphere if the internal heat flux remains radiogenic (< 3 mW m-2). Finally, we provide predictions for the evolution of ice distribution, surface pressure, CO and CH4 atmospheric mixing ratios in the next decades. We also model the thermal lightcurves of Triton in 2022, which serve as predictions for future JWST observations.

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arXiv2021

The iron record of asteroidal processes in carbonaceous chondrites

The valence of iron has been used in terrestrial studies to trace the hydrolysis of primary silicate rocks. Here, we use a similar approach to characterize the secondary processes, namely thermal metamorphism and aqueous alteration, that have affected carbonaceous chondrites. X-ray absorption near-edge structure spectroscopy at the Fe-K- edge was performed on a series of 36 CM, 9 CR, 10 CV, and 2 CI chondrites. Among the four carbonaceous chondrites groups studied, a correlation between the iron oxidation index (IOI = [2 ((Fe2+) + 3(Fe3+))/FeTOT) and the hydrogen content is observed. However, within the CM group, for which a progressive alteration sequence has been defined, a conversion of Fe3+ to Fe2+ is observed with increasing degree of aqueous alteration. This reduction of iron can be explained by an evolution in the mineralogy of the secondary phases. In the case of the few CM chondrites that experienced some thermal metamorphism, in addition to aqueous alteration, a redox memory of the aqueous alteration is present: a significant fraction of 3+ 2+ 0 Fe is present, together with Fe and sometimes Fe. From our data set, the CR chondrites show a wider range of IOI from 1.5 to 2.5. In all considered CR chondrites, the three oxidation states of iron coexist. Even in the least-altered CR chondrites, the fraction of Fe3+ can be high (30% for MET 00426). This observation confirms that oxidized iron has been integrated during formation of fine-grained amorphous material in the matrix. Last, the IOI of CV chondrites does not reflect the reduced/oxidized classification based on metal and magnetite proportions, but is strongly correlated with petrographic types. The valence of iron in CV chondrites therefore appears to be most closely related to thermal history, rather than aqueous alteration, even if these processes can occur together .

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arXiv2020

Infrared detection of aliphatic organics on a cometary nucleus

The ESA Rosetta mission has acquired unprecedented measurements of comet 67/P-Churyumov-Gerasimenko (hereafter 67P) nucleus surface, whose composition, as determined by in situ and remote sensing instruments including VIRTIS (Visible, InfraRed and Thermal Imaging Spectrometer) appears to be made by an assemblage of ices, minerals, and organic material. We performed a refined analysis of infrared observations of the nucleus of comet 67P carried out by the VIRTIS-M hyperspectral imager. We found that the overall shape of the 67P infrared spectrum is similar to that of other carbon-rich outer solar system objects suggesting a possible genetic link with them. More importantly, we are also able to confirm the complex spectral structure of the wide 2.8-3.6 micron absorption feature populated by fainter bands. Among these, we unambiguously identified the presence of aliphatic organics by their ubiquitous 3.38, 3.42 and 3.47 micron bands. This novel infrared detection of aliphatic species on a cometary surface has strong implications for the evolutionary history of the primordial solar system and give evidence that comets provide an evolutionary link between interstellar material and solar system bodies.

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arXiv2020

Mineralogy, chemistry and composition of organic compounds in the fresh carbonaceous chondrite Mukundpura: CM1 or CM2?

We present here several laboratory analyses performed on the freshly fallen Mukundpura CM chondrite. Results of infrared transmission spectroscopy, thermogravimetry analysis and reflectance spectroscopy show that Mukundpura is mainly composed of phyllosilicates. The rare earth trace elements composition and ultrahigh resolution mass spectrometry of the soluble organic matter (SOM) give results consistent with CM chondrites. Finally, Raman spectroscopy shows no signs of thermal alteration of the meteorite. All the results agree that Mukundpura has been strongly altered by water on its parent body. Comparison of the results obtained on the meteorite with those of other chondrites of known petrologic types lead to the conclusion that Mukundpura is similar to CM1 chondrites, which differs from its original classification as a CM2.

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arXiv2020

Spectrophotometric characterization of the Philae landing site and surroundings with the ROSETTA/OSIRIS cameras

We investigate Abydos, the final landing site of the Philae lander after its eventful landing from the Rosetta spacecraft on comet 67P/Churyumov-Gerasimenko on 12 November 2014. Over 1000 OSIRIS level 3B images were analysed, which cover the August 2014 to September 2016 timeframe, with spatial resolution ranging from 7.6 m/px to approximately 0.06 m/px. We found that the Abydos site is as dark as the global 67P nucleus and spectrally red, with an average albedo of 6.5% at 649 nm and a spectral slope value of about 17%/(100 nm) at 50$^\circ$ phase angle. Similar to the whole nucleus, the Abydos site also shows phase reddening but with lower coefficients than other regions of the comet which may imply a thinner cover of microscopically rough regolith compared to other areas. Seasonal variations, as already noticed for the whole nucleus, were also observed. We identified some potential morphological changes near the landing site implying a total mass loss of 4.7-7.0$\times$10$^5$ kg. Small spots ranging from 0.1 m$^2$ to 27 m$^2$ were observed close to Abydos before and after perihelion. Their estimated water ice abundance reaches 30-40% locally, indicating fresh exposures of volatiles. Their lifetime ranges from a few hours up to three months for two pre-perihelion spots. The Abydos surroundings showed low level of cometary activity compared to other regions of the nucleus. Only a few jets are reported originating nearby Abydos, including a bright outburst that lasted for about one hour.

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arXiv2020

Ammonium salts are a reservoir of nitrogen on a cometary nucleus and possibly on some asteroids

The measured nitrogen-to-carbon ratio in comets is lower than for the Sun, a discrepancy which could be alleviated if there is an unknown reservoir of nitrogen in comets. The nucleus of comet 67P/Churyumov-Gerasimenko exhibits an unidentified broad spectral reflectance feature around 3.2 micrometers, which is ubiquitous across its surface. On the basis of laboratory experiments, we attribute this absorption band to ammonium salts mixed with dust on the surface. The depth of the band indicates that semivolatile ammonium salts are a substantial reservoir of nitrogen in the comet, potentially dominating over refractory organic matter and more volatile species. Similar absorption features appear in the spectra of some asteroids, implying a compositional link between asteroids, comets, and the parent interstellar cloud.

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arXiv2020

Color, Composition, and Thermal Environment of Kuiper Belt Object (486958) Arrokoth

The outer Solar System object (486958) Arrokoth (provisional designation 2014 MU$_{69}$) has been largely undisturbed since its formation. We study its surface composition using data collected by the New Horizons spacecraft. Methanol ice is present along with organic material, which may have formed through radiation of simple molecules. Water ice was not detected. This composition indicates hydrogenation of carbon monoxide-rich ice and/ or energetic processing of methane condensed on water ice grains in the cold, outer edge of the early Solar System. There are only small regional variations in color and spectra across the surface, suggesting Arrokoth formed from a homogeneous or well-mixed reservoir of solids. Microwave thermal emission from the winter night side is consistent with a mean brightness temperature of 29$\pm$5 K.

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arXiv2019

A New Two-Molecule Combination Band as Diagnostic of Carbon Monoxide Diluted in Nitrogen Ice On Triton

A combination band due to a mechanism whereby a photon excites two or more vibrational modes ({\it e.g.} a bend and a stretch) of an individual molecule is commonly seen in laboratory and astronomical spectroscopy. Here, we present evidence of a much less commonly seen combination band $-$ one where a photon simultaneously excites two adjacent molecules in an ice. In particular, we present near-infrared spectra of laboratory CO/N$_2$ ice samples where we identify a band at 4467.5 cm$^{-1}$ (2.239 $μ$m) that results from single photons exciting adjacent pairs of CO and N$_2$ molecules. We also present a near-infrared spectrum of Neptune's largest satellite Triton taken with the Gemini-South 8.1 meter telescope and the Immersion Grating Infrared Spectrograph (IGRINS) that shows this 4467.5 cm$^{-1}$ (2.239 $μ$m) CO-N$_2$ combination band. The existence of the band in a spectrum of Triton indicates that CO and N$_2$ molecules are intimately mixed in the ice rather than existing as separate regions of pure CO and pure N$_2$ deposits. Our finding is important because CO and N$_2$ are the most volatile species on Triton and so dominate seasonal volatile transport across its surface. Our result will place constraints on the interaction between the surface and atmosphere of Triton. 1

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arXiv2019

Pluto's Haze as a Surface Material

Pluto's atmospheric haze settles out rapidly compared with geological timescales. It needs to be accounted for as a surface material, distinct from Pluto's icy bedrock and from the volatile ices that migrate via sublimation and condensation on seasonal timescales. This paper explores how a steady supply of atmospheric haze might affect three distinct provinces on Pluto. We pose the question of why they each look so different from one another if the same haze material is settling out onto all of them. Cthulhu is a more ancient region with comparatively little present-day geological activity, where the haze appears to simply accumulate over time. Sputnik Planitia is a very active region where glacial convection, as well as sublimation and condensation rapidly refresh the surface, hiding recently deposited haze from view. Lowell Regio is a region of intermediate age featuring very distinct coloration from the rest of Pluto. Using a simple model haze particle as a colorant, we are not able to match the colors in both Lowell Regio and Cthulhu. To account for their distinct colors, we propose that after arrival at Pluto's surface, haze particles may be less inert than might be supposed from the low surface temperatures. They must either interact with local materials and environments to produce distinct products in different regions, or else the supply of haze must be non-uniform in time and/or location, such that different products are delivered to different places.

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arXiv2019

Formation of Charon's Red Poles From Seasonally Cold-Trapped Volatiles

A unique feature of Pluto's large satellite Charon is its dark red northern polar cap. Similar colours on Pluto's surface have been attributed to organic macromolecules produced by energetic radiation processing of hydrocarbons. The polar location of this material on Charon implicates the temperature extremes that result from Charon's high obliquity and long seasons. The escape of Pluto's atmosphere provides a potential feed stock for production of complex chemistry. Gas from Pluto that is transiently cold-trapped and processed at Charon's winter pole was proposed as an explanation on the basis of an image of Charon's northern hemisphere, but not modelled quantitatively. Here we report images of the southern hemisphere illuminated by Pluto-shine and also images taken during the approach phase showing the northern polar cap over a range of longitudes. We model the surface thermal environment on Charon, the supply and temporary cold-trapping of material escaping from Pluto, and, while cold-trapped, its photolytic processing into more complex and less volatile molecules. The model results are consistent with the proposed mechanism producing the observed colour pattern on Charon.

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arXiv2017

Comet 67P outbursts and quiescent coma at 1.3 AU from the Sun: dust properties from Rosetta/VIRTIS-H observations

We present 2-5 $μ$m spectroscopic observations of the dust coma of 67P/Churyumov-Gerasimenko obtained with the VIRTIS-H instrument onboard Rosetta during two outbursts that occurred on 2015, 13 September 13.6 h UT and 14 September 18.8 h UT at 1.3 AU from the Sun. Scattering and thermal properties measured before the outburst are in the mean of values measured for moderately active comets. The colour temperature excess (or superheat factor) can be attributed to submicrometre-sized particles composed of absorbing material or to porous fractal-like aggregates such as those collected by the Rosetta in situ dust instruments. The power law index of the dust size distribution is in the range 2-3. The sudden increase of infrared emission associated to the outbursts is correlated with a large increase of the colour temperature (from 300 K to up to 630 K) and a change of the dust colour at 2-2.5 $μ$m from red to blue colours, revealing the presence of very small grains ($\leq$ 100 nm) in the outburst material. In addition, the measured large bolometric albedos ($\sim$ 0.7) indicate bright grains in the ejecta, which could either be silicatic grains, implying the thermal degradation of the carbonaceous material, or icy grains. The 3-$μ$m absorption band from water ice is not detected in the spectra acquired during the outbursts, whereas signatures of organic compounds near 3.4 $μ$m are observed in emission. The H$_2$O 2.7-$μ$m and CO$_2$ 4.3-$μ$m vibrational bands do not show any enhancement during the outbursts.

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arXiv2016

The temporal evolution of exposed water ice-rich areas on the surface of 67P/Churyumov-Gerasimenko: spectral analysis

Water ice-rich patches have been detected on the surface of comet 67P/Churyumov-Gerasimenko by the VIRTIS hyperspectral imager on-board the Rosetta spacecraft, since the orbital insertion in late August 2014. Among those, three icy patches have been selected, and VIRTIS data are used to analyse their properties and their temporal evolution while the comet was moving towards the Sun. We performed an extensive analysis of the spectral parameters, and we applied the Hapke radiative transfer model to retrieve the abundance and grain size of water ice, as well as the mixing modalities of water ice and dark terrains on the three selected water ice rich areas. Study of the spatial distribution of the spectral parameters within the ice-rich patches has revealed that water ice follows different patterns associated to a bimodal distribution of the grains: ~50 μm sized and ~2000 μm sized. In all three cases, after the first detections at about 3.5 AU heliocentric distance, the spatial extension and intensity of the water ice spectral features increased, it reached a maximum after 60-100 days at about 3.0 AU, and was followed by an approximately equally timed decrease and disappearanceat about ~2.2 AU, before perihelion. The behaviour of the analysed patches can be assimilated to a seasonal cycle. In addition we found evidence of short-term variability associated to a diurnal water cycle. The similar lifecycle of the three icy regions indicates that water ice is uniformly distributed in the subsurface layers, and no large water ice reservoirs are present.

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