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E. Redaelli

Publications and source records attributed to E. Redaelli.

At least 19 recordsLinked to original sources

Corona Australis 151: an extremely young protostar

Context. Prestellar cores are the birthplace of stars and planetary systems, but they are short-lived objects, since the initial stages of dense core evolution, collapse, and the formation of a protostellar seed are fast. In an effort to build a catalogue of bona-fide prestellar cores in the Solar neighbourhood, we used APEX observations to identify dynamically evolved cores among dense cores observed with Herschel. One of them, Corona Australis 151, stood out because of its centrally peaked structure, with densities above 1e7cm-3 in the central 500-1000 au, and high deuteration levels (N2D+/N2H+~0.5), suggestive of an evolved, prestellar stage. Aims. Corona Australis 151 appears to be an evolved prestellar core, but the presence of broad wings in some of the detected lines and a tentative 70micron detection with Herschel partially challenges its prestellar stage. We intend to assess its evolutionary stage. Methods. We analyse new ALMA data of the continuum emission and of several line tracers (including typical outflow tracers) at a resolution of~150-200au, tracing the envelope. Results. We unveil the presence of a compact and young outflow (projected dynamical age:~500yr), traced by SiO, CO, and H2CO emission. The continuum emission traces an envelope structure of size~1000 au and mass 0.33M_sun(assuming Tdust=20 K). Conclusions. Corona Australis 151 is an extremely young protostar, possibly one of the youngest known in the Solar neighbourhood, and hence a new laboratory to study the chemical and dynamical evolution at the dawn of star formation.

astro-ph.GA

A differentiable and optimizable 3D model for interpretation of observed spectral data cubes

Molecular spectral cubes of prestellar cores encode the information on the physical and chemical properties of these objects along the line of sight. To retrieve this information, we need an interpretable model that reproduces the observed spectra. We designed a differentiable 3D geometrical model that produces synthetic observations from the parameterized density and velocity fields, and that can be efficiently optimized to reproduce the real data cubes. The model has been applied to p-NH2D and N2D+ spectral cubes in the prestellar core L1544. The optimized model suggests that to reproduce the observed velocity difference between p-NH2D and N2D+ in L1544, an asymmetric structure in density and velocity is necessary.

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Projection effects in star-forming regions: I. Nearest-neighbour statistics and observational biases

Stars form as molecular clouds fragment into networks of dense cores, filaments, and subclusters. The characteristic spacing of these cores is a key observable imprint of fragmentation physics and is commonly measured using nearest-neighbour (NN) statistics. However, NN separations are derived from projected two-dimensional (2D) positions, while fragmentation occurs in three dimensions (3D). Using spherical and fractal toy models, we show that the standard geometric deprojection factor of $4/\pi\simeq1.27$ is inadequate because projection not only foreshortens separations but also rewires the NN network, while finite angular resolution merges close neighbours and inflates apparent spacings. We quantify these competing biases with Monte Carlo experiments spanning a wide range of morphologies, sample sizes, and effective resolutions. From these we derive an empirical correction factor that depends on both sample size and resolution: for small ($N\lesssim10$) or poorly resolved samples ($\lesssim$10 resolution elements across the field), intrinsic NN spacings exceed projected values by only 20 to 40%, whereas for well-sampled ($N\gtrsim100$), well-resolved data ($\gtrsim$30-50 resolution elements), true 3D separations are typically larger by a factor of $\sim$2. This calibration enables observers to convert measured 2D NN spacings into corresponding 3D estimates, with typical morphology-driven uncertainties of order 30 to 40%, and we demonstrate how it alters inferred fragmentation scales in observed and simulated core populations. [abridged]

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High deuteration of methanol in L1544

Isotopic fractionation is a very powerful tool to follow the evolution of material from one stage to the next in the star-formation process. Pre-stellar cores exhibit some of the highest levels of deuteration because their physical conditions greatly favor deuteration processes. Deuteration maps are a measure of the effectiveness of the deuteration across the core, and they are useful to study both the deuteration as well as the formation mechanism of the main species. Methanol is the simplest O-bearing complex organic molecule (COM) detected in the interstellar medium (ISM). It represents the beginning of molecular complexity in star-forming regions, thus a complete understanding of its formation and deuteration is a necessary step to understand the development of further chemical complexity. In this paper, we use single-dish observations with the IRAM 30 m telescope and state-of-the-art chemical models to investigate the deuteration of methanol towards the prototypical pre-stellar core L1544. We also compare the results of the chemical models with previous observations of deuterated methanol towards the pre-stellar cores HMM1 and L694-2. The spectra extracted from the CHD$_2$OH map show that the emission is concentrated in the center and towards the north-west of the core. Using deep observations towards the dust and the methanol peaks of the core, we derive a very large deuterium fraction for methanol ($\sim20\%$) towards both peaks. The comparison of our observational results with chemical models has highlighted the importance of H-abstraction processes in the formation and deuteration of methanol. Deep observations combined with state-of-the-art chemical models are of fundamental importance in understanding the development of molecular complexity in the ISM. Our analysis also shows the importance of non-LTE effects when measuring the D/H ratios in methanol.

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Hunting pre-stellar cores with APEX: overview

[Abridged] $Context.$ Pre-stellar cores are centrally concentrated starless cores on the verge of star formation and they represent the initial conditions for star and planet formation. Pre-stellar cores host an active organic chemistry and isotopic fractionation, kept stored into thick icy mantles, which can be inherited by the future protoplanetary disks and planetesimals. So far, only a few have been studied in detail, with special attention being paid to L1544 in the Taurus Molecular Cloud. $Aims.$ The aim is to identify nearby ($<$200 pc) pre-stellar cores in an unbiased way, to build a sample that can then be studied in detail. $Methods.$ We first used the Herschel Gould Belt Survey archival data, selecting all those starless cores with central H$_2$ number densities higher than or equal to 3$\times$10$^5$ cm$^{-3}$, the density of L1544 within the Herschel beam. The selected 40 (out of 1746) cores have then been observed in N$_2$H$^+$(3-2) and N$_2$D$^+$(4-3) using the APEX antenna. $Results.$ A total of 17 bona-fide (i.e., with a deuterium fraction larger than 10%) pre-stellar cores have been identified. Other 16 objects can also be considered pre-stellar, as they are dynamically evolved starless cores, but their deuterium fraction is relatively low ($<$10%). The remaining 7 objects have been found associated with very young stellar objects. $Conclusions.$ Dust continuum emission, together with spectroscopic observations of N$_2$H$^+$(3-2) and N$_2$D$^+$(4-3), is a powerful tool to identify pre-stellar cores in molecular clouds. Detailed modeling of the physical structure of the objects is now required for reconstructing the chemical composition as a function of radius. This work has provided a statistically significant sample of 33 pre-stellar cores, a crucial step in the understanding of the process of star and planet formation.

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High sensitivity molecular line observations towards the L1544 pre-stellar core challenge current models

The increased sensitivity and spectral resolution of observed spectra towards the pre-stellar core L1544 are challenging the current physical and chemical models. With the aim of further constraining the structure of L1544 as well as assessing the completeness of chemical networks, we turn to radiative transfer modelling of observed molecular lines towards this source. We obtained high-sensitivity and high-spectral resolution observations of HCO+ (J = 1 - 0), CS (J = 2 - 1), C34S (J = 2 - 1), H2CO (J ,Ka,Kc = 2,1,2 - 1,1,1), c-C3H2 (J,Ka,Kc = 2,1,2 - 1,0,1), SO (N,J = 2,3 - 1,2) and 34SO (N,J = 2,3 - 1,2) with the IRAM 30m telescope towards the dust peak of L1544. A non-Local Thermodynamic Equilibrium radiative transfer code is coupled to the Markov Chain Monte Carlo method to model the observations. We find that with just one transition for each isotope, the modelling cannot find a global minimum that fits the observations. The derived fractional abundance profiles are compared to those computed with chemical models. The observed transitions trace gas components with distinct dynamics at different distances along the radius of the core. Moreover, the results evidence a poor reproduction of sulphur chemistry by chemical modelling and stresses the need to include a more consistent S-depletion process to accurately reproduce the S-chemistry towards dense cores.

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Cosmic-ray ionisation rate in low-mass cores: the role of the environment

Context: Cosmic rays drive several key processes for the chemistry and dynamical evolution of star-forming regions. Their effect is quantified mainly by means of the cosmic-ray ionisation rate $\zeta_2$. Aims: We aim to obtain a sample of $\zeta_2$ measurements in 20 low-mass starless cores embedded in different parental clouds, to assess the average level of ionisation in this kind of sources and to investigate the role of the environment in this context. The warmest clouds in our sample are Ophiuchus and Corona Australis, where star formation activity is higher than in the Taurus cloud and the other isolated cores we targeted. Methods: We compute $\zeta_2$ using an analytical method based on the {column density} of ortho-$\rm H_2D^+$, the CO abundance, and the deuteration level of HCO$^+$. To estimate these quantities, we analysed new, high-sensitivity molecular line observations obtained with the Atacama Pathfinder EXperiment (APEX) single-dish telescope and archival continuum data from Herschel. Results: We report $\zeta_2$ estimates in 17 cores in our sample and provide upper limits on the three remaining sources. The values span almost two orders of magnitude, from $1.3 \times 10^{-18}\, \rm s^{-1}$ to $8.5 \times 10^{-17}\, \rm s^{-1}$. Conclusions: We find no significant correlation between $\zeta_2$ and the core's column densities $N\rm (H_2)$. On the contrary, we find a positive correlation between $\zeta_2$ and the cores' temperature, estimated via Herschel data: cores embedded in warmer environments present higher ionisation levels. The warmest clouds in our sample are Ophiuchus and Corona Australis, where star formation activity is higher than in the other clouds we targeted. The higher ionisation rates in these regions support the scenario that low-mass protostars in the vicinity of our targeted cores contribute to the re-acceleration of local cosmic rays.

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Hunting pre-stellar cores with APEX: Corona Australis 151, the densest pre-stellar core or the youngest protostar?

Context. Pre-stellar cores are the birthplaces of Sun-like stars and represent the initial conditions for the assembly of protoplanetary systems. Due to their short lifespans, they are rare. In recent efforts to increase the number of such sources identified in the Solar neighbourhood, we have selected a sample of 40 starless cores from the publicly available core catalogs of the Herschel Gould Belt survey. In this work, we focus on one of the sources that stands out for its high central density: Corona Australis 151. Aims. We use molecular lines that trace dense gas (n>=10^6 cm-3) to confirm the exceptionally high density of this object, to study its physical structure, and to understand its evolutionary stage. Methods. We detected the N2H+ 3-2 and 5-4 transitions, and the N2D+ 3-2, 4-3, and 6-5 lines with the APEX telescope. We use the Herschel continuum data to infer a spherically symmetric model of the core's density and temperature. This is used as input to perform non-local-thermodynamic-equilibrium radiative transfer to fit the observed five lines. Results. Our analysis confirms that this core is characterised by very high densities (a few x 10^7 cm-3 at the centre) and cold temperatures. We infer a high deuteration level of N2D+/N2H+=0.50, indicative of an advanced evolutionary stage. In the large bandwidth covered by the APEX data, we detect several other deuterated species, including CHD2OH, D2CO, and ND3. We also detect multiple sulphurated species that present broader lines with signs of high-velocity wings. Conclusions. The observation of high-velocity wings and the fact that the linewidths of N2H+ and N2D+ become larger with increasing frequency can be interpreted either as an indication of supersonic infall motions developing in the central parts of a very evolved pre-stellar core or as the signature of outflows from a very low luminosity object (VeLLO). *SHORTENED*

astro-ph.SR

Mapping Synthetic Observations to Prestellar Core Models: An Interpretable Machine Learning Approach

Observations of molecular lines are a key tool to determine the main physical properties of prestellar cores. However, not all the information is retained in the observational process or easily interpretable, especially when a larger number of physical properties and spectral features are involved. We present a methodology to link the information in the synthetic spectra with the actual information in the simulated models (i.e., their physical properties), in particular, to determine where the information resides in the spectra. We employ a 1D gravitational collapse model with advanced thermochemistry, from which we generate synthetic spectra. We then use neural network emulations and the SHapley Additive exPlanations (SHAP), a machine learning technique, to connect the models' properties to the specific spectral features. Thanks to interpretable machine learning, we find several correlations between synthetic lines and some of the key model parameters, such as the cosmic-ray ionization radial profile, the central density, or the abundance of various species, suggesting that most of the information is retained in the observational process. Our procedure can be generalized to similar scenarios to quantify the amount of information lost in the real observations. We also point out the limitations for future applicability.

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Hunting pre-stellar cores with APEX: IRAS16293E (Oph464)

Pre-stellar cores are the first steps in the process of star and planet formation. However, the dynamical and chemical evolution of pre-stellar cores is still not well understood. We aim at estimating the central density of the pre-stellar core IRAS16293E and at carrying out an inventory of molecular species towards the density peak of the core. We observed high-$J$ rotational transitions of N$_2$H$^+$ and N$_2$D$^+$, and several other molecular lines towards the dust emission peak using the Atacama Pathfinder EXperiment (APEX) telescope, and derived the density and temperature profiles of the core using far-infrared surface brightness maps from $Herschel$. The N$_2$H$^+$ and N$_2$D$^+$ lines were analysed by non-LTE radiative transfer modelling. Our best-fit core model consists in a static inner region, embedded in an infalling envelope with an inner radius of approximately 3000 au (21" at 141 pc). The observed high-J lines of N$_2$H$^+$ and N$_2$D$^+$ (with critical densities greater than 10$^6$ cm$^{-3}$) turn out to be very sensitive to depletion; the present single-dish observations are best explained with no depletion of N$_2$H$^+$ and N$_2$D$^+$ in the inner core. The N$_2$D$^+$/N$_2$H$^+$ ratio that best reproduces our observations is 0.44, one of the largest observed to date in pre-stellar cores. Additionally, half of the molecules that we observed are deuterated isotopologues, confirming the high-level of deuteration towards this source. Non-LTE radiative transfer modelling of N$_2$H$^+$ and N$_2$D$^+$ lines proved to be an excellent diagnostic of the chemical structure and dynamics of a pre-stellar core. Probing the physical conditions immediately before the protostellar collapse is a necessary reference for theoretical studies and simulations with the aim of understanding the earliest stages of star and planet formation and the time scale of this process.

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Time evolution of o-H$_2$D$^+$, N$_2$D$^+$, and N$_2$H$^+$ during the high-mass star formation process

Deuterium fractionation is a well-established evolutionary tracer in low-mass star formation, but its applicability to the high-mass regime remains an open question. The abundances and ratios of deuterated species have often been proposed as reliable evolutionary indicators for different stages of the high-mass star formation. We investigate the role of N$_2$H$^+$ and key deuterated molecules as tracers of the different stages of the high-mass star formation, and test whether their abundance ratios can serve as reliable evolutionary indicators. We conducted APEX observations of o-H$_2$D$^+$ (1$_{10}$-1$_{11}$), N$_2$H$^+$ (4-3), and N$_2$d$^+$ (3-2) in 40 high-mass clumps at different evolutionary stages, selected from the ATLASGAL survey. Molecular column densities ($N$) and abundances ($X$), were derived through spectral line modelling, both under local thermodynamic equilibrium (LTE) and non-LTE conditions. The $N$(o-H$_2$D$^+$) show the smallest deviation from LTE results when derived under non-LTE assumptions. In contrast, N$_2$D$^+$ shows the largest discrepancy between the $N$ derived from LTE and non-LTE. In all the cases discussed, we found that $X$(o-H$_2$D$^+$) decreases more significantly with time than in the case of $X$(N$_2$D$^+$); whereas $X$(N$_2$H$^+$) increases slightly. Therefore, the validity of the recently proposed $X$(o-H$_2$D$^+$)/$X$(N$_2$D$^+$) ratio as a reliable evolutionary indicator was not observed for this sample. While the deuteration fraction derived from N$_2$D$^+$ and N$_2$H$^+$ clearly decreases with clump evolution, the interpretation of this trend is complex, given the different distribution of the two tracers. Our results suggest that a careful consideration of the observational biases and beam-dilution effects are crucial for an accurate interpretation of the evolution of the deuteration process during the high-mass star formation process.

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ALMA-IMF XVIII: The assembly of a star cluster: Dense N$_2$H$^+$ (1-0) kinematics in the massive G351.77 protocluster

ALMA-IMF observed 15 massive protoclusters capturing multiple spectral lines and the continuum emission. We focus on the G351.77 protocluster ($\sim$ 2500 M$_{\odot}$, estimated from single-dish continuum observations) located at 2 kpc. We trace the dense gas emission and kinematics with N$_2$H$^+$ (1-0) at $\sim$ 4 kau resolution. We estimate an N$_2$H$^+$ relative abundance $\sim (1.7 \pm 0.5) \times 10^{-10}$. We decompose the N$_2$H$^+$ emission into up to two velocity components, highlighting the kinematic complexity in the dense gas. By examining the position-velocity (PV) diagrams on small scales, we observe clear inflow signatures (V-shapes) associated with dense cores. The most prominent V-shape has a mass inflow rate of $\sim 13.5 \times 10^{-4}$ M$_{\odot}$ yr$^{-1}$ and a short timescale of $\sim$ 11.4 kyr. We also observe V-shapes without associated cores. This suggests both that cores or centers of accretion exist below the 1.3 mm detection limit, and that the V-shapes may be viable tracers of very early accretion and star formation on $\sim$ 4 kau scales. The large-scale PV diagram shows that the protocluster is separated into 2 principal velocity structures. Combined with smaller scale DCN and H$_2$CO emission, we propose a scenario of larger scale slow contraction with rotation in the center based on simple toy models. This scenario leads the suggestion of outside-in evolution of the protocluster as it collapses. The gas depletion times implied by the V-shapes are short ($\sim$ 0.3 Myr), requiring either very fast cluster formation, and/or continuous mass feeding of the protocluster. The latter is possible via the Mother Filament G351.77 is forming out of. The similarities in the properties of G351.77 and the recently published work in G353.41 indicate that many of the physical conditions inferred via the ALMA-IMF N$_2$H$^+$ observations may be generic to protoclusters.

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Astrochemistry on Galactic scales

The increasing number of observations towards different environments in the Milky Way, as well as theoretical and experimental works, are improving our knowledge of the astrochemical processes in the interstellar medium (ISM). In this chapter we report some of the main projects to study the chemical complexity and isotopic ratios across the Galaxy. High-sensitivity spectral surveys covering broad bandwidths towards Galactic Center molecular clouds (e.g. G+0.693-0.027) and star-forming regions (e.g. the hot core G31.41+0.31) are revealing very rich astrochemical reservoirs, which include molecules of prebiotic interest. At the same time, isotopic ratios (e.g. $^{12}$C/$^{13}$C and $^{14}$N/$^{15}$N) can give important information on the Galactic chemical evolution, as well as on chemical local processes due to the physical conditions of the molecular clouds. We also highlight the role of cosmic rays as a key agent affecting the interstellar chemistry described above.

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Fractionation in young cores: Direct determinations of nitrogen and carbon fractionation in HCN

We aim to determine the $^{14}$N/$^{15}$N and $^{12}$C/$^{13}$C ratios for HCN in six starless and prestellar cores and compare the results between the direct method using radiative transfer modeling and the indirect double isotope method assuming a fixed $^{12}$C/$^{13}$C ratio. We present IRAM 30m observations of the HCN 1-0, HCN 3-2, HC15N 1-0 and H13CN 1-0 transitions toward six embedded cores. The ${}^{14}$N/${}^{15}$N ratio was derived using both the indirect double isotope method and directly through non-local thermodynamic equilibrium (NLTE) 1D radiative transfer modeling of the HCN emission. The latter also provides the ${}^{12}$C/${}^{13}$C ratio, which we compared to the local interstellar value. The derived ${}^{14}$N/${}^{15}$N ratios using the indirect method are generally in the range of 300-550. This result could suggest an evolutionary trend in the nitrogen fractionation of HCN between starless cores and later stages of the star formation process. However, the direct method reveals lower fractionation ratios of around $\sim$250, mainly resulting from a lower ${}^{12}$C/${}^{13}$C ratio in the range $\sim$20-40, as compared to the local interstellar medium value of 68. This study reveals a significant difference between the nitrogen fractionation ratio in HCN derived using direct and indirect methods. This can influence the interpretation of the chemical evolution and reveal the pitfalls of the indirect double isotope method for fractionation studies. However, the direct method is challenging, as it requires well-constrained source models to produce accurate results. No trend in the nitrogen fractionation of HCN between earlier and later stages of the star formation process is evident when the results of the direct method are considered.

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Testing analytical methods to derive the cosmic-ray ionisation rate in cold regions via synthetic observations

Cosmic rays (CRs) heavily impact the chemistry and physics of cold and dense star-forming regions. However, characterising their ionisation rate is still challenging from an observational point of view. In the past, a few analytical formulas have been proposed to infer the cosmic-ray ionization rate $\zeta_2$ from molecular line observations. These have been derived from the chemical kinetics of the involved species, but they have not been validated using synthetic data processed with a standard observative pipeline. We aim to bridge this gap. We perform the radiative transfer on a set of three-dimensional magneto-hydrodynamical simulations of prestellar cores, exploring different initial $\zeta_2$, evolutionary stages, types of radiative transfer (e.g. assuming local-thermodynamic-equilibrium conditions), and telescope responses. We then compute the column densities of the involved tracers to determine $\zeta_2$, using, in particular, the equation proposed by Bovino et. al (2020) and by Caselli et al. (1998) both used nowadays. Our results confirm that the method of Bovino et al. (2020) accurately retrieves the actual $\zeta_2$ within a factor of $2-3$, in the physical conditions explored in our tests. Since we also explore a non-local thermodynamic equilibrium radiative transfer, this work indirectly offers insights into the excitation temperatures of common transitions at moderate volume densities ($n\approx 10^5 \, \rm cm^{-3}$). We have also performed a few tests using the formula proposed by Caselli et al. (1998), which overestimates the actual $\zeta_2$ by at least two orders of magnitudes. We also consider a new derivation of this method, which, however, still leads to large overestimates.

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Modelling Deuterated Isotopologues of Methanol toward the Pre-Stellar Core L1544

Aims. We aim to improve a previous model for the prediction of column densities and deuterium fractions of non- and singly deuterated methanol. Thereby, we try to identify crucial chemical and physical parameters, for which the study of deuteration could provide valuable additional constraints. Methods. We employed a gas-grain chemical code to devise a model that is in agreement with the observed column density and deuterium fraction profiles of the innermost region of the pre-stellar core L1544. For that purpose, we developed a new treatment of reactive desorption, deriving an individual reactive desorption efficiency for every product species in a chemical reaction, that depends on the reaction enthalpy and type of underlying surface. Furthermore, we explored several options to promote the diffusion of hydrogen and deuterium atoms over the surface of interstellar dust grains, in order to increase methanol formation. Results. Our fiducial model employs diffusion by quantum tunneling of hydrogen and deuterium atoms, resulting in CH$_3$OH and CH$_2$DOH column densities that are approximately an order of magnitude lower than the observed values, which improves the results compared to the previous model by a factor 10. The $N$(CH$_2$DOH)/$N$(CH$_3$OH) ratio is reproduced within a factor of 1.2 for the centre and 1.8 for the position of the methanol peak. Given the large uncertainties that chemical models typically have, we consider our predictions to be in agreement with the observations. In general, we conclude that a diffusion process with a high diffusion rate needs to be employed to obtain methanol column densities that are in accordance with the observed values. Also, we find that the introduction of abstraction reactions into the methanol formation scheme suppresses deuteration, when used in combination with a high diffusion rate.

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Alignment of dense molecular core morphology and velocity gradients with ambient magnetic fields

Studies of dense core morphologies and their orientations with respect to gas flows and the local magnetic field have been limited to only a small sample of cores with spectroscopic data. Leveraging the Green Bank Ammonia Survey alongside existing sub-millimeter continuum observations and Planck dust polarization, we produce a cross-matched catalogue of 399 dense cores with estimates of core morphology, size, mass, specific angular momentum, and magnetic field orientation. Of the 399 cores, 329 exhibit 2D $\mathrm{v}_\mathrm{LSR}$ maps that are well fit with a linear gradient, consistent with rotation projected on the sky. We find a best-fit specific angular momentum and core size relationship of $J/M \propto R^{1.82 \pm 0.10}$, suggesting that core velocity gradients originate from a combination of solid body rotation and turbulent motions. Most cores have no preferred orientation between the axis of core elongation, velocity gradient direction, and the ambient magnetic field orientation, favouring a triaxial and weakly magnetized origin. We find, however, strong evidence for a preferred anti-alignment between the core elongation axis and magnetic field for protostellar cores, revealing a change in orientation from starless and prestellar populations that may result from gravitational contraction in a magnetically-regulated (but not dominant) environment. We also find marginal evidence for anti-alignment between the core velocity gradient and magnetic field orientation in the L1228 and L1251 regions of Cepheus, suggesting a preferred orientation with respect to magnetic fields may be more prevalent in regions with locally ordered fields.

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Similar levels of deuteration in the pre-stellar core L1544 and the protostellar core HH211

In the centre of pre-stellar cores, deuterium fractionation is enhanced due to the low temperatures and high densities. Therefore, the chemistry of deuterated molecules can be used to study the earliest stages of star formation. We analyse the deuterium fractionation of simple molecules, comparing the level of deuteration in the envelopes of the pre-stellar core L1544 in Taurus and the protostellar core HH211 in Perseus. We used single-dish observations of CCH, HCN, HNC, HCO$^+$, and their $^{13}$C-, $^{18}$O- and D-bearing isotopologues, detected with the Onsala 20m telescope. We derived the column densities and the deuterium fractions of the molecules. Additionally, we used radiative transfer simulations and results from chemical modelling to reproduce the observed molecular lines. We used new collisional rate coefficients for HNC, HN$^{13}$C, DNC, and DCN that consider the hyperfine structure of these molecules. We find high levels of deuteration for CCH (10%) in both sources, consistent with other carbon chains, and moderate levels for HCN (5-7%) and HNC (8%). The deuterium fraction of HCO$^+$ is enhanced towards HH211, most likely caused by isotope-selective photodissociation of C$^{18}$O. Similar levels of deuteration show that the process is likely equally efficient towards both cores, suggesting that the protostellar envelope still retains the chemical composition of the original pre-stellar core. The fact that the two cores are embedded in different molecular clouds also suggests that environmental conditions do not have a significant effect on the deuteration within dense cores. Radiative transfer modelling shows that it is necessary to include the outer layers of the cores to consider the effects of extended structures. Besides HCO$^+$ observations, HCN observations towards L1544 also require the presence of an outer diffuse layer where the molecules are relatively abundant.

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