arXiv subjects

E. Stratakis

Publications and source records attributed to E. Stratakis.

At least 19 recordsLinked to original sources

arXiv2026

Impact of Plasmonic Modes and Thermophysical Properties on the Double-Pulse Structuring of Highly-Ordered LIPSS for Biosensing Applications

The fabrication of highly ordered laser-induced periodic surface structures (LIPSS) on thin metallic films is dictated, predomaninatly, by a synergy of periodic electromagnetic energy deposition and complex fluid dynamics. In this work, we present a combined experimental and theoretical study on the formation of ultra-regular LIPSS on 32-nm-thick Au films using a double-pulse femtosecond laser scheme. We demonstrate that for thin films, the excitation of coupled Surface Plasmon Polaritons (SPPs) at both interfaces dictates the initial energy distribution. On the othe hand, the final morphology is greatly influenced by hydrodynamical processes. Interestingly, due to the low electron-phonon coupling of Au and the high thermal confinement of the thin film, single-pulse irradiation leads to uncontrolled hydrodynamic instabilities a non uniform topographies. Thus, we demonstrate that a double-pulse approach with an optimized interpulse delay ({\Delta}{\tau}=1.2 ns) effectively controls the melt duration and viscosity, suppressing complex fluid motion and promoting the growth of highly ordered arrays. These structures support narrow surface lattice resonances (SLRs) suitable for high-sensitivity plasmonic biosensing.

physics.optics↗

arXiv2025

Spin-valley polarization control in WSe$_2$ monolayers using photochemical doping

We report on the influence of a photochemical doping method on the spin-valley polarization degree ($P_{c}$) of excitons in WSe$_2$ monolayers. By varying the carrier density and transitioning from an excess of electrons (n-type) to an excess of holes (p-type), we observe a non-monotonic dependence of $P_{c}$ on the doping level. Using controlled, single-shot photochlorination steps, we unveil this non-monotonic behavior, with $P_{c}$ reaching a minimum value of less than 10$\%$ at 78 K near the charge neutrality point, while increasing by a factor of three at a hole density of $5 \times 10^{11} \,\mathrm{cm^{-2}}$. The impact of the doping on $P_{c}$ is explained using a phenomenological model that accounts for various mechanisms influencing exciton polarization dynamics, including exciton-carrier scattering processes and exciton-to-trion conversion rates. Among these, exciton-carrier collisions emerge as the dominant mechanism driving the observed variations in $P_{c}$, while the exciton effective lifetime remains nearly independent of doping. These findings highlight the potential of photochemical methods for investigating valley physics and for effectively tuning the exciton polarization degree in transition metal dichalcogenide monolayers.

cond-mat.mes-hall↗

arXiv2024

Topological photonics with scattering media

Scattering media, being ubiquitous in nature and critically important for assessments (e.g., biological tissues), are often considered as nuisance in optics. Here we show that it is not always the case and scattering media could be essential in providing elements of topological photonics. We demonstrate that topological darkness can be realised in the presence of scattering media due to the transverse nature of electromagnetic waves and the hairy ball theorem. We describe realizations of topological darkness in a scattering medium comprising composite gold nanostructures produced by a low-cost technique of laser structuring of thin metal films. Our results can be useful for a variety of tasks, including topological nanophotonics, optical label-free biosensing, and biomedical photonics.

physics.optics↗

arXiv2023

Post-melting encapsulation of glass microwires for multipath light waveguiding within phosphate glasses

Glass waveguides remain the fundamental component of advanced photonic circuits and with a significant role in other applications such as quantum information processing, light generation, imaging, data storage, and sensing platforms. Up to date, the fabrication of glass waveguides relies mainly on demanding chemical processes or on the employment of expensive ultrafast laser equipment. In this work, we demonstrate the feasibility of a simple, low-temperature, post-melting encapsulation procedure for the development of advanced glass waveguides. Namely, silver iodide phosphate glass microwires (MWs) are drawn from typical splat-quenched samples. Following this, the MWs are incorporated in a controlled manner within previously prepared transparent silver phosphate glass rectangular prisms. The composition of the employed glasses is chosen so that the host phosphate glass has a lower refractive index than the embedded MWs. In such case, the waveguide mechanism relies on the propagation of light inside the encapsulated higher refractive index MWs. Moreover, the presence of silver nanoparticles within the MWs enhances the light transmission due to scattering effects. Waveguide devices with either one or two incorporated MWs were fabricated. Remarkably, in the latter case, the transmission of light of different colors and in multipath direction is possible, rendering the developed waveguides outstanding candidates for various photonic circuits, optoelectronic, and smart sign glass applications.

physics.optics↗

arXiv2023

Biaxial strain tuning of exciton energy and polarization in monolayer WS2

We perform micro-photoluminescence and Raman experiments to examine the impact of biaxial tensile strain on the optical properties of WS2 monolayers. A strong shift on the order of -130 meV per % of strain is observed in the neutral exciton emission at room temperature. Under near-resonant excitation we measure a monotonic decrease in the circular polarization degree under applied strain. We experimentally separate the effect of the strain-induced energy detuning and evaluate the pure effect coming from biaxial strain. The analysis shows that the suppression of the circular polarization degree under biaxial strain is related to an interplay of energy and polarization relaxation channels as well as to variations in the exciton oscillator strength affecting the long-range exchange interaction.

cond-mat.mtrl-sci↗

arXiv2023

Electron density control in tungsten diselenide monolayers via photochlorination

Modulation of the Fermi level using an ultraviolet (UV)-assisted photochemical method is demonstrated in tungsten diselenide monolayers. Systematic shifts and relative intensities between charged and neutral exciton species indicate a progressive and controllable decrease of the electron density and switch tungsten diselenide from n-type to a p-type semiconductor. The presence of chlorine in the 2D crystal shifts the Fermi level closer to the valence band while the effect can be only partially reversible via continuous wave laser rastering process. The presence of chlorine species in the lattice is validated by X-ray photoelectron spectroscopy (XPS), and density functional theory (DFT) calculations predict that adsorption of chlorine on the selenium vacancy sites leads to p-type doping. The results of our study indicate that photochemical techniques have the potential to enhance the performance of various 2D materials, making them suitable for potential applications in optoelectronics.

cond-mat.mtrl-sci↗

arXiv2022

Tailoring surface topographies on solids with Mid-IR femtosecond laser pulses

Irradiation of solids with ultrashort pulses using laser sources in the mid-infrared (mid-IR) spectral region is a yet predominantly unexplored field that opens broad possibilities for efficient and precise surface texturing for a wide range of applications. In the present work, we investigate both experimentally and theoretically the impact of laser sources on the generation of surface modification related effects and on the subsequent surface patterning of metallic and semiconducting materials. Through a parametric study we correlate the mid-IR pulsed laser parameters with the onset of material damage and the formation of a variety of periodic surface structures at a laser wavelength of {\lambda}L=3200 nm and a pulse duration of {\tau}p=45 fs. Results for nickel and silicon indicate that the produced topographies comprise both high and low spatial frequency induced periodic structures, similar to those observed at lower wavelengths, while groove formation is absent. The investigation of the damage thresholds suggests the incorporation of nonlinear effects generated from three-photon-assisted excitation (for silicon) and the consideration of the role of the non-thermal excited electron population (for nickel) at very short pulse durations. The results demonstrate the potential of surface structuring with mid-IR pulses, which can constitute a systematic novel engineering approach with strong fields at long-wavelength spectral regions that can be used for advanced industrial laser applications.

physics.optics↗

arXiv2022

Biofabrication for neural tissue engineering applications

Unlike other tissue types, the nervous tissue extends to a wide and complex environment that provides a plurality of different biochemical and topological stimuli which in turn define the functions of that tissue. As a consequence of such complexity, the traditional transplantation therapeutic methods are quite ineffective; therefore, the restoration of peripheral and central nervous system injuries has been a continuous challenge. Tissue engineering and regenerative medicine in the nervous system have provided new alternative medical approaches. These methods use external biomaterial supports, known as scaffolds, in order to create platforms for the cells to migrate to the injury site and repair the tissue. The challenge in neural tissue engineering (NTE) remains the fabrication of scaffolds with precisely controlled, tunable topography, biochemical cues and surface energy, capable of directing and controlling the function of neuronal cells. At the same time, it has been shown that neural tissue engineering provides the potential to model neurological diseases in vitro, mainly via lab-on-a-chip systems, especially in cases for which it is difficult to obtain suitable animal models. As a consequence of the intense research activity in the field, a variety of synthetic approaches and 3D fabrication methods have been developed for the fabrication of NTE scaffolds, including soft lithography and self-assembly, as well as subtractive (top-down) and additive (bottom-up) manufacturing. This article aims at reviewing the existing research effort in the rapidly growing field related to the development of biomaterial scaffolds and lab-on-a-chip systems for NTE applications. Besides presenting recent advances achieved by NTE strategies, this work also delineates existing limitations and highlights emerging possibilities and future prospects in this field.

physics.bio-ph↗

arXiv2022

Strong europium luminescence in lanthan-euripium-erbium-calcium-vanadate nanocrystals, the result of codoping optimization

Co-doped with calcium, europium and erbium ions lanthanum vanadate crystalline nanoparticles are synthesized and investigated with a goal to clarify the mechanisms of calcium and erbium impurities effects on europium ions luminescence and to find compositions with enhanced luminescence intensity. The XRD analysis reveals dependence of crystal structure on dopants concentration: monoclinic crystal phase is observed for low dopant concentrations and content of tetragonal crystal phase increases with dopant concentrations increase. The SEM investigation reveals formation of nanoparticles with two types of shapes. Photoluminescence spectra consist of lines caused by inner transitions in the erbium and europium ions. It has been shown that dependence of the europium ions luminescence intensity on the calcium and erbium concentrations is caused by cumulative effects of dopants on crystal lattice structure, on defects in the first coordination sphere of the europium ions and on efficiency of excitation energy transfer.

cond-mat.mtrl-sci↗

arXiv2021

Nonlinear optical imaging of in-plane anisotropy in two-dimensional SnS

Two-dimensional (2D) tin(II) sulfide (SnS) crystals belong to a class of orthorhombic semiconducting materials that are lately attracting significant interest, given their remarkable properties, such as in-plane anisotropic optical and electronic response, multiferroic nature and lack of inversion symmetry. The 2D SnS crystals exhibit anisotropic response along the in-plane armchair (AC) and zigzag (ZZ) crystallographic directions, offering an additional degree of freedom in manipulating their behavior. Therefore, calculating the AC/ZZ directions is important in characterizing the 2D SnS crystals. In this work, we take advantage of the lack of inversion symmetry of the 2D SnS crystal, that produces second harmonic generation (SHG), to perform polarization-resolved SHG (P-SHG) nonlinear imaging of the in-plane anisotropy. We fit the P-SHG experimental data with a nonlinear optics model, that allows us to calculate the AC/ZZ orientation from every point of the 2D crystal and to map with high-resolution the AC/ZZ direction of several 2D SnS flakes belonging in the same field of view. It is found that the P-SHG intensity polar patterns are associated with the crystallographic axes of the flakes and with the relative strength of the second order nonlinear susceptibility tensor in different directions. Therefore, our method provides quantitative information of the optical in-plane anisotropy of orthorhombic 2D crystals, offering great promise for performance characterization during device operation in the emerging optoelectronic applications of such crystals.

cond-mat.mtrl-sci↗

arXiv2021

Ultrashort pulsed laser induced complex surface structures generated by tailoring the melt hydrodynamics

We present a novel approach for tailoring the laser induced surface topography upon femtosecond-fs pulsed laser irradiation. The method employs spatially controlled double fs laser pulses to actively regulate the hydrodynamic microfluidic motion of the melted layer that gives rise to the structures formation. The pulse train used, in particular, consists of a previously unexplored spatiotemporal intensity combination including one pulse with Gaussian and another with periodically modulated intensity distribution created by Direct Laser Interference Patterning (DLIP). The interpulse delay is appropriately chosen to reveal the contribution of the microfluidic melt flow, while it is found that the sequence of the Gaussian and DLIP pulses remarkably influences the surface profile attained. Results also demonstrate that both the spatial intensity of the double pulse and the effective number of pulses per irradiation spot can further be modulated to control the formation of complex surface morphologies. The underlying physical processes behind the complex patterns generation were interpreted in terms of a multiscale model combining electrodynamic excitation with melt hydrodynamics. We believe that this work can constitute a significant step forward towards producing laser induced surface structures on demand by tailoring the melt microfluidic phenomena.

physics.optics↗

arXiv2021

Optical versus electron diffraction imaging of Twist-angle in 2D transition metal dichalcogenide bilayer superlattices

Atomically thin two-dimensional (2D) materials can be vertically stacked with van der Waals bonds, which enable interlayer coupling. In the particular case of transition metal dichalcogenide (TMD) bilayers, the relative direction between the two monolayers, coined as twist-angle, modifies the crystal symmetry and creates a superlattice with exciting properties. Here, we demonstrate an all-optical method for pixel-by-pixel mapping of the twist-angle with resolution of 0.23 degrees, via polarization-resolved second harmonic generation (P-SHG) microscopy and we compare it with four-dimensional scanning transmission electron microscopy (4D-STEM). It is found that the twist-angle imaging of WS2 bilayers, using the P-SHG technique is in excellent agreement with that obtained using electron diffraction. The main advantages of the optical approach are that the characterization is performed on the same substrate that the device is created on and that it is three orders of magnitude faster than the 4D-STEM. We envisage that the optical P-SHG imaging could become the gold standard for the quality examination of TMD superlattice-based devices.

cond-mat.mtrl-sci↗

arXiv2020

Laser engineering of biomimetic surfaces

The exciting properties of micro- and nano-patterned surfaces found in natural species hide a virtually endless potential of technological ideas, opening new opportunities for innovation and exploitation in materials science and engineering. Due to the diversity of biomimetic surface functionalities, inspirations from natural surfaces are interesting for a broad range of applications in engineering, including phenomena of adhesion, friction, wear, lubrication, wetting phenomena, self-cleaning, antifouling, antibacterial phenomena, thermoregulation and optics. Lasers are increasingly proving to be promising tools for the precise and controlled structuring of materials at micro- and nano-scales. When ultrashort-pulsed lasers are used, the optimal interplay between laser and material parameters enables structuring down to the nanometer scale. Besides this, a unique aspect of laser processing technology is the possibility for material modifications at multiple (hierarchical) length scales, leading to the complex biomimetic micro- and nano-scale patterns, while adding a new dimension to structure optimization. This article reviews the current state of the art of laser processing methodologies, which are being used for the fabrication of bioinspired artificial surfaces to realize extraordinary wetting, optical, mechanical, and biological-active properties for numerous applications. The innovative aspect of laser functionalized biomimetic surfaces for a wide variety of current and future applications is particularly demonstrated and discussed. The article concludes with illustrating the wealth of arising possibilities and the number of new laser micro/nano fabrication approaches for obtaining complex high-resolution features, which prescribe a future where control of structures and subsequent functionalities are beyond our current imagination.

physics.optics↗

arXiv2020

Wide field of view crystal orientation mapping of layered materials

Layered materials (LMs) are at the centre of an ever increasing research effort due to their potential use in a variety of applications. The presence of imperfections, such as bi- or multilayer areas, holes, grain boundaries, isotropic and anisotropic deformations, etc. are detrimental for most (opto)electronic applications. Here, we present a set-up able to transform a conventional scanning electron microscope into a tool for structural analysis of a wide range of LMs. An hybrid pixel electron detector below the sample makes it possible to record two dimensional (2d) diffraction patterns for every probe position on the sample surface (2d), in transmission mode, thus performing a 2d+2d=4d STEM (scanning transmission electron microscopy) analysis. This offers a field of view up to 2 mm2, while providing spatial resolution in the nm range, enabling the collection of statistical data on grain size, relative orientation angle, bilayer stacking, strain, etc. which can be mined through automated open-source data analysis software. We demonstrate this approach by analyzing a variety of LMs, such as mono- and multi-layer graphene, graphene oxide and MoS2, showing the ability of this method to characterize them in the tens of nm to mm scale. This wide field of view range and the resulting statistical information are key for large scale applications of LMs.

physics.app-ph↗

arXiv2020

Low-temperature Benchtop-synthesis of All-inorganic Perovskite Nanowires

A facile, low-temperature precipitation-based method is utilized to demonstrate the synthesis of ultra-thin and highly-uniform cesium lead bromide perovskite nanowires (NWs). The reactions facilitate the NWs crystalline nature over micron-size lengths, while they impart tailored nanowire widths that range from the quantum confinement regime (~ 7 nm) and down to 2.6 nm. This colloidal synthesis approach is the first of its kind that is carried out on the work-bench, without demanding chemical synthesis equipment. Importantly, the NWs photoluminescence is shown to become improved over time, with no tedious post-synthesis surface treatment requirement.

cond-mat.mes-hall↗

arXiv2020

Pulsed laser deposition of the doped lanthanum vanadate nanoparticles on glass and silicon substrates

Thin films from the lanthanum vanadate nanoparticles were successfully grown by pulsed laser deposition method on glass and silicon substrates for the first time. Morphology and thickness of the films depend on a type of substrate and a number of pulses. The films are of 27 to 220 nm thickness and formed by very small particles up to 20 nm and also can contain single nanoparticles with dimensions 40 to 60 nm and sometimes agglomerates of nanoparticles. Spectral properties of the samples have been investigated and discussed. The vanadate films deposited on the silicon substrates lead to appearance of antireflection properties in the visible range. Luminescence spectra of the investigated films consist of narrow lines caused by f-f transitions in the europium ions. For the samples on glass substrates the wide bands of glass emission are also contributed to the spectra. The optimal experimental conditions those allowed to obtain films promising for applications as luminescent converters are considered.

physics.app-ph↗

arXiv2020

Modelling ultrafast non-equilibrium carrier dynamics and relaxation processes upon irradiation of hexagonal Silicon-Carbide with femtosecond laser pulses

We present a theoretical investigation of the yet unexplored dynamics of the produced excited carriers upon irradiation of hexagonal Silicon Carbide (6H-SiC) with femtosecond laser pulses. To describe the ultrafast behaviour of laser induced out-of-equilibrium carriers, a real time simulation based on Density Functional Theory (DFT) methodology is used to compute both the hot carrier dynamics and transient change of the optical properties. A Two-Temperature model (TTM) is also employed to derive the relaxation processes for laser pulses of wavelength 401 nm, duration 50 fs at normal incidence irradiation which indicate that surface damage on the material occurs for fluence ~1.88 Jcm-2. This approach of linking, for the first time, real time calculations, transient optical properties and TTM modelling, has strong implications for understanding both the ultrafast dynamics and relaxation processes and providing a precise investigation of the impact of hot carrier population in surface damage mechanisms in solids.

cond-mat.mtrl-sci↗

arXiv2019

Ultrafast dynamics and surface plasmon properties of Silicon upon irradiation with mid-infrared femtosecond laser pulses

We present a theoretical investigation of the yet unexplored ultrafast processes and dynamics of the produced excited carriers upon irradiation of Silicon with femtosecond pulsed lasers in the mid-infrared (mid-IR) spectral region. The evolution of the carrier density and thermal response of the electron-hole and lattice subsystems are analysed for various wavelengths λL in the range between 2.2 μm and 3.3 μm where the influence of two and three-photon absorption mechanisms is explored. The role of induced Kerr effect is highlighted and it manifests a more pronounced influence at smaller wavelengths in the mid-IR range. Elaboration on the conditions that leads to surface plasmon (SP) excitation indicate the formation of weakly bound SP waves on the material surface. The lifetime of the excited SP is shown to rise upon increasing wavelength yielding a larger than the one predicted for higher laser frequencies. Calculation of damage thresholds for various pulse durations τp show that they rise according to a power law (~τ_p^{ζ(λ_L) ) where the increasing rate is determined by the exponent ζ(λ_L). Investigation of the multi-photon absorption rates and impact ionization contribution at different τp manifests a lower damage for λL=2.5 μm compared to that for λL=2.2 μm for long τp.

physics.optics↗