arXiv subjects

E. Trizac

Publications and source records attributed to E. Trizac.

At least 73 records · Page 4Linked to original sources

arXiv2008

Non Poissonian statistics in a low density fluid

Our interest goes to the collisional statistics in an arbitrary interacting fluid. We show that even in the low density limit and contrary to naive expectation, the number of collisions experienced by a tagged particle in a given time does not obey Poisson law, and that conversely, the free flight time distribution is not a simple exponential. As an illustration, the hard sphere fluid case is worked out in detail. For this model, we quantify analytically those deviations and successfully compare our predictions against molecular dynamics simulations.

cond-mat.stat-mech↗

arXiv2008

Dynamics of Annihilation II: Fluctuations of Global Quantities

We develop a theory for fluctuations and correlations in a gas evolving under ballistic annihilation dynamics. Starting from the hierarchy of equations governing the evolution of microscopic densities in phase space, we subsequently restrict to a regime of spatial homogeneity, and obtain explicit predictions for the fluctuations and time correlation of the total number of particles, total linear momentum and total kinetic energy. Cross-correlations between these quantities are worked out as well. These predictions are successfully tested against Molecular Dynamics and Monte-Carlo simulations. This provides strong support for the theoretical approach developed, including the hydrodynamic treatment of the spectrum of the linearized Boltzmann operator. This article is a companion paper to arXiv:0801.2299 and makes use of the spectral analysis reported there.

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arXiv2008

Dynamics of Annihilation I : Linearized Boltzmann Equation and Hydrodynamics

We study the non-equilibrium statistical mechanics of a system of freely moving particles, in which binary encounters lead either to an elastic collision or to the disappearance of the pair. Such a system of {\em ballistic annihilation} therefore constantly looses particles. The dynamics of perturbations around the free decay regime is investigated from the spectral properties of the linearized Boltzmann operator, that characterize linear excitations on all time scales. The linearized Boltzmann equation is solved in the hydrodynamic limit by a projection technique, which yields the evolution equations for the relevant coarse-grained fields and expressions for the transport coefficients. We finally present the results of Molecular Dynamics simulations that validate the theoretical predictions.

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arXiv2007

Quasi-elastic solutions to the nonlinear Boltzmann equation for dissipative gases

The solutions of the one-dimensional homogeneous nonlinear Boltzmann equation are studied in the QE-limit (Quasi-Elastic; infinitesimal dissipation) by a combination of analytical and numerical techniques. Their behavior at large velocities differs qualitatively from that for higher dimensional systems. In our generic model, a dissipative fluid is maintained in a non-equilibrium steady state by a stochastic or deterministic driving force. The velocity distribution for stochastic driving is regular and for infinitesimal dissipation, has a stretched exponential tail, with an unusual stretching exponent $b_{QE} = 2b$, twice as large as the standard one for the corresponding $d$-dimensional system at finite dissipation. For deterministic driving the behavior is more subtle and displays singularities, such as multi-peaked velocity distribution functions. We classify the corresponding velocity distributions according to the nature and scaling behavior of such singularities.

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arXiv2007

Boltzmann equation for dissipative gases in homogeneous states with nonlinear friction

Combining analytical and numerical methods, we study within the framework of the homogeneous non-linear Boltzmann equation, a broad class of models relevant for the dynamics of dissipative fluids, including granular gases. We use the new method presented in a previous paper [J. Stat. Phys. 124, 549 (2006)] and extend our results to a different heating mechanism, namely a deterministic non-linear friction force. We derive analytically the high energy tail of the velocity distribution and compare the theoretical predictions with high precision numerical simulations. Stretched exponential forms are obtained when the non-equilibrium steady state is stable. We derive sub-leading corrections and emphasize their relevance. In marginal stability cases, power-law behaviors arise, with exponents obtained as the roots of transcendental equations. We also consider some simple BGK (Bhatnagar, Gross, Krook) models, driven by similar heating devices, to test the robustness of our predictions.

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arXiv2007

Preferential interaction coefficient for nucleic acids and other cylindrical poly-ions

The thermodynamics of nucleic acid processes is heavily affected by the electric double-layer of micro-ions around the polyions. We focus here on the Coulombic contribution to the salt-polyelectrolyte preferential interaction (Donnan) coefficient and we report extremely accurate analytical expressions valid in the range of low salt concentration (when polyion radius is smaller than the Debye length). The analysis is performed at Poisson-Boltzmann level, in cylindrical geometry, with emphasis on highly charged poly-ions (beyond ``counter-ion condensation''). The results hold for any electrolyte of the form $z_-$:$z_+$. We also obtain a remarkably accurate expression for the electric potential in the vicinity of the poly-ion.

cond-mat.soft↗

arXiv2007

Power injected in a granular gas

A granular gas may be modeled as a set of hard-spheres undergoing inelastic collisions; its microscopic dynamics is thus strongly irreversible. As pointed out in several experimental works bearing on turbulent flows or granular materials, the power injected in a dissipative system to sustain a steady-state over an asymptotically large time window is a central observable. We describe an analytic approach allowing us to determine the full distribution of the power injected in a granular gas within a steady-state resulting from subjecting each particle independently either to a random force (stochastic thermostat) or to a deterministic force proportional to its velocity (Gaussian thermostat). We provide an analysis of our results in the light of the relevance, for other types of systems, of the injected power to fluctuation relations.

cond-mat.stat-mech↗

arXiv2007

On the macroion virial contribution to the osmotic pressure in charge-stabilized colloidal suspensions

Our interest goes to the different virial contributions to the equation of state of charged colloidal suspensions. Neglect of surface effects in the computation of the colloidal virial term leads to spurious and paradoxical results. This pitfall is one of the several facets of the danger of a naive implementation of the so called One Component Model, where the micro-ionic degrees of freedom are integrated out to only keep in the description the mesoscopic (colloidal) degrees of freedom. On the other hand, due incorporation of wall induced forces dissolves the paradox brought forth in the naive approach, provides a consistent description, and confirms that for salt-free systems, the colloidal contribution to the pressure is dominated by the micro-ionic one. Much emphasis is put on the no salt case but the situation with added electrolyte is also discussed.

cond-mat.soft↗

arXiv2006

The Boltzmann equation for driven systems of inelastic soft spheres

We study a generic class of inelastic soft sphere models with a binary collision rate $g^ν$ that depends on the relative velocity $g$. This includes previously studied inelastic hard spheres ($ν=1$) and inelastic Maxwell molecules ($ν=0$). We develop a new asymptotic method for analyzing large deviations from Gaussian behavior for the velocity distribution function $f(c)$. The framework is that of the spatially uniform nonlinear Boltzmann equation and special emphasis is put on the situation where the system is driven by white noise. Depending on the value of exponent $ν$, three different situations are reported. For $ν<-2$, the non-equilibrium steady state is a repelling fixed point of the dynamics. For $ν>-2$, it becomes an attractive fixed point, with velocity distributions $f(c)$ having stretched exponential behavior at large $c$. The corresponding dominant behavior of $f(c)$ is computed together with sub-leading corrections. In the marginally stable case $ν=-2$, the high energy tail of $f(c)$ is of power law type and the associated exponents are calculated. Our analytical predictions are confronted with Monte Carlo simulations, with a remarkably good agreement.

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arXiv2006

Testing the relevance of effective interaction potentials between highly charged colloids in suspension

Combining cell and Jellium model mean-field approaches, Monte Carlo together with integral equation techniques, and finally more demanding many-colloid mean-field computations, we investigate the thermodynamic behavior, pressure and compressibility of highly charged colloidal dispersions, and at a more microscopic level, the force distribution acting on the colloids. The Kirkwood-Buff identity provides a useful probe to challenge the self-consistency of an approximate effective screened Coulomb (Yukawa) potential between colloids. Two effective parameter models are put to the test: cell against renormalized Jellium models.

cond-mat.soft↗

arXiv2006

The rich behavior of the Boltzmann equation for dissipative gases

Within the framework of the homogeneous non-linear Boltzmann equation, we present a new analytic method, without the intrinsic limitations of existing methods, for obtaining asymptotic solutions. This method permits extension of existing results for Maxwell molecules and hard spheres to large classes of particle interactions, from very hard spheres to softer than Maxwell molecules, as well as to more general forcing mechanisms, beyond free cooling and white noise driving. By combining this method with numerical solutions, obtained from the Direct Simulation Monte Carlo (DSMC) method, we study a broad class of models relevant for the dynamics of dissipative fluids, including granular gases. We establish a criterion connecting the stability of the non-equilibrium steady state to an exponentially bound form for the velocity distribution $F$, which varies depending on the forcing mechanism. Power laws arise in marginal stability cases, of which several new cases are reported. Our results provide a minimal framework for interpreting large classes of experiments on driven granular gases.

cond-mat.stat-mech↗

arXiv2006

Exact asymptotic expansions for the cylindrical Poisson-Boltzmann equation

The mathematical theory of integrable Painleve/Toda type systems sheds new light on the behavior of solutions to the Poisson-Boltzmann equation for the potential due to a long rod-like macroion. We investigate here the case of symmetric electrolytes together with that of 1:2 and 2:1 salts. Short and large scale features are analyzed, with a particular emphasis on the low salinity regime. Analytical expansions are derived for several quantities relevant for polyelectrolytes theory, such as the Manning radius. In addition, accurate and practical expressions are worked out for the electrostatic potential, which improve upon previous work and cover the full range of radial distances.

cond-mat.soft↗

arXiv2006

On the free energy within the mean-field approximation

We compare two widespread formulations of the mean-field approximation, based on minimizing an appropriately built mean-field free energy. We use the example of the antiferromagnetic Ising model to show that one of these formulations does not guarantee the existence of an underlying variational principle. This results in a severe failure where straightforward minimization of the corresponding mean-field free energy leads to incorrect results.

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arXiv2005

Energy fluctuations in vibrated and driven granular gases

We investigate the behavior of energy fluctuations in several models of granular gases maintained in a non-equilibrium steady state. In the case of a gas heated from a boundary, the inhomogeneities of the system play a predominant role. Interpreting the total kinetic energy as a sum of independent but not identically distributed random variables, it is possible to compute the probability density function (pdf) of the total energy. Neglecting correlations and using the analytical expression for the inhomogeneous temperature profile obtained from the granular hydrodynamic equations, we recover results which have been previously observed numerically and which had been attributed to the presence of correlations. In order to separate the effects of spatial inhomogeneities from those ascribable to velocity correlations, we have also considered two models of homogeneously thermostated gases: in this framework it is possible to reveal the presence of non-trivial effects due to velocity correlations between particles. Such correlations stem from the inelasticity of collisions. Moreover, the observation that the pdf of the total energy tends to a Gaussian in the large system limit, suggests that they are also due to the finite size of the system.

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arXiv2005

Fluctuations of power injection in randomly driven granular gases

We investigate the large deviation function pi(w) for the fluctuations of the power W(t)=w t, integrated over a time t, injected by a homogeneous random driving into a granular gas, in the infinite time limit. Starting from a generalized Liouville equation we obtain an equation for the generating function of the cumulants mu(lambda) which appears as a generalization of the inelastic Boltzmann equation and has a clear physical interpretation. Reasonable assumptions are used to obtain mu(lambda) in a closed analytical form. A Legendre transform is sufficient to get the large deviation function pi(w). Our main result, apart from an estimate of all the cumulants of W(t) at large times t, is that pi(w) has no negative branch. This immediately results in the failure of the Gallavotti-Cohen Fluctuation Relation (GCFR), that in previous studies had been suggested to be valid for injected power in driven granular gases. We also present numerical results, in order to discuss the finite time behavior of the fluctuations of W(t). We discover that their probability density function converges extremely slowly to its asymptotic scaling form: the third cumulant saturates after a characteristic time larger than 50 mean free times and the higher order cumulants evolve even slower. The asymptotic value is in good agreement with our theory. Remarkably, a numerical check of the GCFR is feasible only at small times, since negative events disappear at larger times. At such small times this check leads to the misleading conclusion that GCFR is satisfied for pi(w). We offer an explanation for this remarkable apparent verification. In the inelastic Maxwell model, where a better statistics can be achieved, we are able to numerically observe the failure of GCFR.

cond-mat.stat-mech↗

arXiv2005

Fluctuations of internal energy flow in a vibrated granular gas

The non-equilibrium fluctuations of power flux in a fluidized granular media have been recently measured in an experiment [Phys. Rev. Lett. 92, 164301, 2004], which was announced to be a verification of the Fluctuation Relation (FR) by Gallavotti and Cohen. An effective temperature was also identified and proposed to be a useful probe for such non equilibrium systems. We explain these results in terms of a two temperature Poisson process. Within this model, supported by independent Molecular Dynamics simulations, power flux fluctuations do not satisfy the FR and the nature of the effective temperature is clarified. In the pursue of a hypothetical global quantity fulfilling the FR, this points to the need of considering other candidates than the power flux.

cond-mat.stat-mech↗

arXiv2005

Injected power and entropy flow in a heated granular gas

Our interest goes to the power injected in a heated granular gas and to the possibility to interpret it in terms of entropy flow. We numerically determine the distribution of the injected power by means of Monte-Carlo simulations. Then, we provide a kinetic theory approach to the computation of such a distribution function. Finally, after showing why the injected power does not satisfy a Fluctuation Relation a la Gallavotti-Cohen, we put forward a new quantity which does fulfill such a relation, and is not only applicable in a variety of frameworks outside the granular world, but also experimentally accessible.

cond-mat.stat-mech↗

arXiv2004

The interplay between screening properties and colloid anisotropy: towards a reliable pair potential for disc-like charged particles

The electrostatic potential of a highly charged disc (clay platelet) in an electrolyte is investigated in detail. The corresponding non-linear Poisson-Boltzmann (PB) equation is solved numerically, and we show that the far-field behaviour (relevant for colloidal interactions in dilute suspensions) is exactly that obtained within linearized PB theory, with the surface boundary condition of a uniform potential. The latter linear problem is solved by a new semi-analytical procedure and both the potential amplitude (quantified by an effective charge) and potential anisotropy coincide closely within PB and linearized PB, provided the disc bare charge is high enough. This anisotropy remains at all scales; it is encoded in a function that may vary over several orders of magnitude depending on the azimuthal angle under which the disc is seen. The results allow to construct a pair potential for discs interaction, that is strongly orientation dependent.

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