arXiv subjects

E. Vavilova

Publications and source records attributed to E. Vavilova.

14 recordsLinked to original sources

arXiv2023

Magnetic phase diagram and possible Kitaev-like behavior of honeycomb-lattice antimonate Na3Co2SbO6

Recent theoretical studies have suggested that Kitaev physics and such effects as formation of a mysterious spin-liquid state can be expected not only in RuCl3 and iridates, but also in conventional $3d$ transition metal compounds. Using DC and AC magnetometry, thermodynamic and $^{23}$Na nuclear magnetic resonance measurements (NMR) we studied such a candidate material Na3Co2SbO6. A full phase diagram of Na3Co2SbO6 in a wide range of magnetic fields and temperatures is presented. The results demonstrate transformation of the antiferromagnetic structure under the external magnetic field, gradual development of the saturation phase, as well as evidence of gapped behavior in certain parts of the phase diagram

cond-mat.str-el↗

arXiv2022

Static magnetic and ESR spectroscopic properties of the dimer-chain antiferromagnet BiCoPO$_5$

We report a comprehensive study of the static susceptibility, high-field magnetization and high-frequency/high-magnetic field electron spin resonance (HF-ESR) spectroscopy of polycrystalline samples of the bismuth cobalt oxy-phosphate BiCoPO$_5$. This compound features a peculiar spin system that can be considered as antiferromagnetic (AFM) chains built of pairs of ferromagnetically coupled Co spins and interconnected in all three spatial directions. It was previously shown that BiCoPO$_5$ orders antiferromagnetically at $T_{\rm N} \approx 10$ K and this order can be continuously suppressed by magnetic field towards the critical value $μ_0H_{\rm c} \approx 15$ T. In our experiments we find strongly enhanced magnetic moments and spectroscopic $g$ factors as compared to the expected spin-only values, suggesting a strong contribution of orbital magnetism for the Co$^{2+}$ ions. This is quantitatively confirmed by ab initio quantum chemical calculations. Within the AFM ordered phase, we observe a distinct field-induced magnetic phase transition. Its critical field rises to $\sim 6$ T at $T \ll T_{\rm N}$. The HF-ESR spectra recorded at $T\ll T_{\rm N}$ are very rich comprising up to six resonance modes possibly of the multimagnonic nature that soften towards the critical region around 6 T. Interestingly, we find that the Co moments are not yet fully polarized at $H_{\rm c}$ which supports a theoretical proposal identifying $H_{\rm c}$ as the quantum critical point for the transition of the spin system in BiCoPO$_5$ to the quantum disordered state at stronger fields.

cond-mat.str-el↗

arXiv2020

Ground state and low-temperature magnetism of the quasi-two-dimensional honeycomb compound InCu$_{2/3}$V$_{1/3}$O$_3$

We report a combined $^{115}$In NQR, $^{51}$V NMR and $μ$SR spectroscopic study of the low-temperature magnetic properties of InCu$_{2/3}$V$_{1/3}$O$_3$, a quasi-two dimensional (2D) compound comprising in the spin sector a honeycomb lattice of antiferromagnetically coupled spins $S=1/2$ associated with Cu$^{2+}$ ions. Despite substantial experimental and theoretical efforts, the ground state of this material was has not been ultimately identified. In particular, two characteristic temperatures of about $\sim 40$ K and $\sim 20$ K manifesting themselves as anomalies in different magnetic measurements are discussed controversially. A combined analysis of the experimental data complemented with theoretical calculations of exchange constants enabled us to identify below 39 K an ``intermediate'' quasi-2D static spin state. This spin state is characterized by a staggered magnetization with a temperature evolution that agrees with the predictions for the 2D XY model. We observe that this state gradually transforms at 15 K into a fully developed 3D antiferromagnetic Néel state. We ascribe such an extended quasi-2D static regime to an effective magnetic decoupling of the honeycomb planes due to a strong frustration of the interlayer exchange interactions which inhibits long-range spin-spin correlations across the planes. Interestingly, we find indications of the topological Berezinsky-Kosterlitz-Thouless transition in the quasi-2D static state of the honeycomb spin-1/2 planes of InCu$_{2/3}$V$_{1/3}$O$_3$.

cond-mat.str-el↗

arXiv2017

Magnetic properties of the spin-1 chain compound NiCl$_3$C$_6$H$_5$CH$_2$CH$_2$NH$_3$

We report experimental results of the static magnetization, ESR and NMR spectroscopic measurements of the Ni-hybrid compound NiCl$_3$C$_6$H$_5$CH$_2$CH$_2$NH$_3$. In this material NiCl$_3$ octahedra are structurally arranged in chains along the crystallographic $a$-axis. According to the static susceptibility and ESR data Ni$^{2+}$ spins $S = 1$ are isotropic and are coupled antiferromagnetically (AFM) along the chain with the exchange constant $J = 25.5$ K. These are important prerequisites for the realization of the so-called Haldane spin-1 chain with the spin-singlet ground state and a quantum spin gap. However, experimental results evidence AFM order at $T_{\rm N} \approx 10$ K presumably due to small interchain couplings. Interestingly, frequency-, magnetic field-, and temperature-dependent ESR measurements, as well as the NMR data, reveal signatures which could presumably indicate an inhomogeneous ground state of co-existent mesoscopically spatially separated AFM ordered and spin-singlet state regions similar to the situation observed before in some spin-diluted Haldane magnets.

cond-mat.str-el↗

arXiv2016

Evidence for a magnetic field-induced unconventional nematic state in the frustrated and anisotropic spin-chain cuprate LiCuSbO$_4$

Modern theories of quantum magnetism predict exotic multipolar states in weakly interacting strongly frustrated spin-1/2 Heisenberg chains with ferromagnetic nearest neighbor (NN) inchain exchange in high magnetic fields. Experimentally these states remained elusive so far. Here we report the evidence for a long-sought magnetic field-induced nematic state arising above a field of $\sim 13$ T in the edge-sharing chain cuprate LiSbCuO$_4$ $\equiv$ LiCuSbO$_4$. This interpretation is based on the observation of a field induced spin-gap in the measurements of the $^7$Li NMR spin relaxation rate $T_1^{-1}$ as well as a contrasting field-dependent power-law behavior of $T_1^{-1}$ vs. $T$ and is further supported by static magnetization and ESR data. An underlying theoretical microscopic approach favoring a nematic scenario is based essentially on the NN XYZ exchange anisotropy within a model for frustrated spin-1/2 chains. It is investigated by the DMRG technique. The employed exchange parameters are justified qualitatively by electronic structure calculations for LiCuSbO$_4$.

cond-mat.str-el↗

arXiv2016

Non-collinear antiferromagnetism of coupled spins and pseudospins in the double perovskite La2CuIrO6

We report the structural, magnetic and thermodynamic properties of the double perovskite compound La2CuIrO6 from X-ray, neutron diffraction, neutron depolarization, dc magnetization, ac susceptibility, specific heat, muon-spin-relaxation (uSR), electron-spin-resonance (ESR) and nuclear magnetic resonance (NMR) measurements. Below ~113 K, short-range spin-spin correlations occur within the Cu2+ sublattice. With decreasing temperature, the Ir4+ sublattice progressively involves in the correlation process. Below T = 74 K, the magnetic sublattices of Cu (spin s = 1/2) and Ir (pseudospin j = 1/2) in La2CuIrO6 are strongly coupled and exhibit an antiferromagnetic phase transition into a non-collinear magnetic structure accompanied by a small uncompensated transverse moment. A weak anomaly in ac-susceptibility as well as in the NMR and μSR spin lattice relaxation rates at 54 K is interpreted as a cooperative ordering of the transverse moments which is influenced by the strong spin-orbit coupled 5d ion Ir4+. We argue that the rich magnetic behaviour observed in La2CuIrO6 is related to complex magnetic interactions between the strongly correlated spin-only 3d ions with the strongly spin-orbit coupled 5d transition ions where a combination of the spin-orbit coupling and the low-symmetry of the crystal lattice plays a special role for the spin structure in the magnetically ordered state.

cond-mat.str-el↗

arXiv2012

Microwave absorption study of pinning regimes in $\bf Ba(Fe_{1-x}Co_x)_2As_2$ single crystals

Magnetic field dependent modulated microwave absorption (MMWA) measurements have been carried out to investigate vortex pinning effects in single crystals of the iron-based high-Tc superconductor Ba(Fe_{1-x}Co_x)_2As_2 with three different cobalt doping levels of x = 0.07, 0.09, and 0.11. The dependence of the MMWA hysteresis loops on temperature, magnetic field, and Co-concentration have been measured and analyzed using a theoretical model of microwave absorption in superconductors. The analysis reveals that in an underdoped crystal (x = 0.07) the so called \dtc-pinning due to magnetically ordered regions defines the temperature dependence of the critical current density, while in the optimally doped (x = 0.09) and overdoped (x = 0.11) samples the pinning is governed by structural imperfections due to inhomogeneous distribution of cobalt dopant and has the so called δ-l character.

cond-mat.supr-con↗

arXiv2011

Magnetic properties of the low-dimensional spin-1/2 magnet α-Cu_2As_2O_7

In this work we study the interplay between the crystal structure and magnetism of the pyroarsenate α-Cu_2As_2O_7 by means of magnetization, heat capacity, electron spin resonance and nuclear magnetic resonance measurements as well as density functional theory (DFT) calculations and quantum Monte Carlo (QMC) simulations. The data reveal that the magnetic Cu-O chains in the crystal structure represent a realization of a quasi-one dimensional (1D) coupled alternating spin-1/2 Heisenberg chain model with relevant pathways through non-magnetic AsO_4 tetrahedra. Owing to residual 3D interactions antiferromagnetic long range ordering at T_N\simeq10K takes place. Application of external magnetic field B along the magnetically easy axis induces the transition to a spin-flop phase at B_{SF}~1.7T (2K). The experimental data suggest that substantial quantum spin fluctuations take place at low magnetic fields in the ordered state. DFT calculations confirm the quasi-one-dimensional nature of the spin lattice, with the leading coupling J_1 within the structural dimers. QMC fits to the magnetic susceptibility evaluate J_1=164K, the weaker intrachain coupling J'_1/J_1 = 0.55, and the effective interchain coupling J_{ic1}/J_1 = 0.20.

cond-mat.str-el↗

arXiv2010

Finite size effects and magnetic order in the spin-1/2 honeycomb lattice compound InCu{2/3}V{1/3}O{3}

High field electron spin resonance, nuclear magnetic resonance and magnetization studies addressing the ground state of the quasi two-dimensional spin-1/2 honeycomb lattice compound InCu{2/3}V{1/3}O{3} are reported. Uncorrelated finite size structural domains occurring in the honeycomb planes are expected to inhibit long range magnetic order. Surprisingly, ESR data reveal the development of two collinear antiferromagnetic (AFM) sublattices below ~ 20 K whereas NMR results show the presence of the staggered internal field. Magnetization data evidence a spin reorientation transition at ~ 5.7 T. Quantum Monte-Carlo calculations show that switching on the coupling between the honeycomb spin planes in a finite size cluster yields a Neel-like AFM spin structure with a substantial staggered magnetization at finite temperatures. This may explain the occurrence of a robust AFM state in InCu{2/3}V{1/3}O{3} despite an unfavorable effect of structural disorder.

cond-mat.str-el↗

arXiv2009

High temperature ferromagnetism of Li-doped vanadium oxide nanotubes

The nature of a puzzling high temperature ferromagnetism of doped mixed-valent vanadium oxide nanotubes reported earlier by Krusin-Elbaum et al., Nature 431 (2004) 672, has been addressed by static magnetization, muon spin relaxation, nuclear magnetic and electron spin resonance spectroscopy techniques. A precise control of the charge doping was achieved by electrochemical Li intercalation. We find that it provides excess electrons, thereby increasing the number of interacting magnetic vanadium sites, and, at a certain doping level, yields a ferromagnetic-like response persisting up to room temperature. Thus we confirm the surprising previous results on the samples prepared by a completely different intercalation method. Moreover our spectroscopic data provide first ample evidence for the bulk nature of the effect. In particular, they enable a conclusion that the Li nucleates superparamagnetic nanosize spin clusters around the intercalation site which are responsible for the unusual high temperature ferromagnetism of vanadium oxide nanotubes.

cond-mat.str-el↗

arXiv2009

Quantum electric dipole glass and frustrated magnetism near a critical point in Li2ZrCuO4

We report a new peculiar effect of the interaction between a sublattice of frustrated quantum spin-1/2 chains and a sublattice of pseudospin-1/2 centers (quantum electric dipoles) uniquely co-existing in the complex oxide Li2ZrCuO4. 7Li nuclear magnetic-, Cu2+ electron spin resonance and a complex dielectric constant data reveal that the sublattice of Li+-derived electric dipoles orders glass like at Tg ~ 70 K yielding a spin site nonequivalency in the CuO2 chains. We suggest that such a remarkable interplay between electrical and spin degrees of freedom might strongly influence the properties of the spiral spin state in Li2ZrCuO4 that is close to a quantum ferromagnetic critical point. In particular that strong quantum fluctuations and/or the glassy behavior of electric dipoles might renormalize the exchange integrals affecting this way the pitch angle of the spiral as well as be responsible for the missing multiferroicity present in other helicoidal magnets.

cond-mat.str-el↗

arXiv2008

Spin-state polaron in lightly hole-doped LaCoO_3

Inelastic neutron scattering (INS), electron spin (ESR) and nuclear magnetic resonance (NMR) measurements were employed to establish the origin of the strong magnetic signal in lightly hole-doped La_{1-x}Sr_xCoO_3, x=0.002. Both, INS and ESR low temperature spectra show intense excitations with large effective g-factors ~10-18. NMR data indicate the creation of extended magnetic clusters. From the Q-dependence of the INS magnetic intensity we conclude that the observed anomalies are caused by the formation of octahedrally shaped spin-state polarons comprising seven Co ions.

cond-mat.str-el↗

arXiv2007

Insulator to semiconductor transition and magnetic properties of the one-dimensional S = 1/2 system In_2VO_5

We report structural, magnetization, electrical resistivity and nuclear- and electron spin resonance data of the complex transition metal oxide In_2VO_5 in which structurally well-defined V-O chains are realized. An itinerant character of the vanadium d-electrons and ferromagnetic correlations, revealed at high temperatures, are contrasted with the insulating behavior and predominantly antiferromagnetic exchange between the localized V^{4+} S = 1/2-magnetic moments which develop below a certain characteristic temperature T* ~ 120 K. Eventually the compound exhibits short-range magnetic order at $T_SRO ~ 20 K. We attribute this crossover occurring around T* to the unusual anisotropic thermal contraction of the lattice which changes significantly the overlap integrals and the character of magnetic intra- and interchain interactions.

cond-mat.str-el↗

arXiv2006

Magnetic properties of vanadium-oxide nanotubes probed by static magnetization and {51}V NMR

Measurements of the static magnetic susceptibility and of the nuclear magnetic resonance of multiwalled vanadium-oxide nanotubes are reported. In this nanoscale magnet the structural low-dimensionality and mixed valency of vanadium ions yield a complex temperature dependence of the static magnetization and the nuclear relaxation rates. Analysis of the different contributions to the magnetism allows to identify individual interlayer magnetic sites as well as strongly antiferromagnetically coupled vanadium spins (S = 1/2) in the double layers of the nanotube's wall. In particular, the data give strong indications that in the structurally well-defined vanadium-spin chains in the walls, owing to an inhomogeneous charge distribution, antiferromagnetic dimers and trimers occur. Altogether, about 30% of the vanadium ions are coupled in dimers, exhibiting a spin gap of the order of 700 K, the other ~ 30% comprise individual spins and trimers, whereas the remaining \~ 40% are nonmagnetic.

cond-mat.str-el↗