arXiv subjects

E. W. Larsen

Publications and source records attributed to E. W. Larsen.

4 recordsLinked to original sources

arXiv2021

Correlation Driven Transient Hole Dynamics Resolved in Space and Time in the Isopropanol Molecule

The possibility of suddenly ionized molecules undergoing extremely fast electron hole dynamics prior to significant structural change was first recognized more than 20 years ago and termed charge migration. The accurate probing of ultrafast electron hole dynamics requires measurements that have both sufficient temporal resolution and can detect the localization of a specific hole within the molecule. We report an investigation of the dynamics of inner valence hole states in isopropanol where we use an x-ray pump/x-ray probe experiment, with site and state-specific probing of a transient hole state localized near the oxygen atom in the molecule, together with an ab initio theoretical treatment. We record the signature of transient hole dynamics and make the first observation of dynamics driven by frustrated Auger-Meitner transitions. We verify that the hole lifetime is consistent with our theoretical prediction. This state-specific measurement paves the way to widespread application for observations of transient hole dynamics localized in space and time in molecules and thus to charge transfer phenomena that are fundamental in chemical and material physics.

physics.chem-ph↗

arXiv2016

Sub-cycle ionization dynamics revealed by trajectory resolved, elliptically-driven high-order harmonic generation

The sub-cycle dynamics of electrons driven by strong laser fields is central to the emerging field of attosecond science. We demonstrate how the dynamics can be probed through high-order harmonic generation, where different trajectories leading to the same harmonic order are initiated at different times, thereby probing different field strengths. We find large differences between the trajectories with respect to both their sensitivity to driving field ellipticity and resonant enhancement. To accurately describe the ellipticity dependence of the long trajectory harmonics we must include a sub-cycle change of the initial velocity distribution of the electron and its excursion time. The resonant enhancement is observed only for the long trajectory contribution of a particular harmonic when a window resonance in argon, which is off-resonant in the field-free case, is shifted into resonance due to a large dynamic Stark shift.

physics.atom-ph↗

arXiv2015

Phase measurement of a Fano window resonance using tunable attosecond pulses

We study the photoionization of argon atoms close to the 3s$^2$3p$^6$ $\rightarrow$ 3s$^1$3p$^6$4p $\leftrightarrow$ 3s$^2$3p$^5$ $\varepsilon \ell$, $\ell$=s,d Fano window resonance. An interferometric technique using an attosecond pulse train, i.e. a frequency comb in the extreme ultraviolet range, and a weak infrared probe field allows us to study both amplitude and phase of the photoionization probability amplitude as a function of photon energy. A theoretical calculation of the ionization process accounting for several continuum channels and bandwidth effects reproduces well the experimental observations and shows that the phase variation of the resonant two-photon amplitude depends on the interaction between the channels involved in the autoionization process.

physics.atom-ph↗

arXiv2012

Asymptotic Derivation and Numerical Investigation of Time-Dependent Simplified Pn Equations

The steady-state simplified Pn (SPn) approximations to the linear Boltzmann equation have been proven to be asymptotically higher-order corrections to the diffusion equation in certain physical systems. In this paper, we present an asymptotic analysis for the time-dependent simplified Pn equations up to n = 3. Additionally, SPn equations of arbitrary order are derived in an ad hoc way. The resulting SPn equations are hyperbolic and differ from those investigated in a previous work by some of the authors. In two space dimensions, numerical calculations for the Pn and SPn equations are performed. We simulate neutron distributions of a moving rod and present results for a benchmark problem, known as the checkerboard problem. The SPn equations are demonstrated to yield significantly more accurate results than diffusion approximations. In addition, for sufficiently low values of n, they are shown to be more efficient than Pn models of comparable cost.

physics.comp-ph↗