arXiv subjects

Eckhard Quandt

Publications and source records attributed to Eckhard Quandt.

8 recordsLinked to original sources

arXiv2026

Composition Design of Shape Memory Ceramics based on Gaussian Processes

We present a Gaussian process machine learning model to predict the transformation temperature and lattice parameters of ZrO$_2$-based ceramics. Our overall goal is to search for a shape memory ceramic with a reversible transformation and low hysteresis. The identification of a new low hysteresis composition is based on design criteria that have been successful in metal alloys: (1) $λ_2 = 1$, where $λ_2$ is the middle eigenvalue of the transformation stretch tensor, (2) minimizing the max$|q(f)|$, which measures the deviation from satisfying the cofactor conditions, (3) high transformation temperature, (4) low transformational volume change, and (5) solid solubility. We generate many synthetic compositions, and identify a promising composition, 31.75Zr-37.75Hf-14.5Y-14.5Ta-1.5Er, which closely satisfies all the design criteria based on predictions from machine learning. However, differential thermal analysis reveals a relatively high thermal hysteresis of 137°C for this composition, indicating that the proposed design criteria are not universally applicable to all ZrO$_2$-based ceramics. We also explore reducing tetragonality of the austenite phase by addition of Er$_2$O$_3$. The idea is to tune the lattice parameters of austenite phase towards a cubic structure will increase the number of martensite variants, thus, allowing more flexibility for them to accommodate high strain during transformation. We find the effect of Er$_2$O$_3$ on tetragonality is weak due to limited solubility. We conclude that a more effective dopant is needed to achieve significant tetragonality reduction. Overall, Gaussian process machine learning models are shown to be highly useful for prediction of compositions and lattice parameters, but the discovery of low hysteresis ceramic materials apparently involves other factors not relevant to phase transformations in metals.

cond-mat.mtrl-sci↗

arXiv2025

A Novel Helical Thin-Film Flow Diverter: Design, Fabrication, and Computational Assessment of Hemodynamic Performance

Flow diversion has become a key treatment modality for selected intracranial aneurysms, relying on the principle that a dense mesh of stent wires disrupts blood flow into the aneurysm sac, promoting thrombosis and vessel reconstruction. Despite its clinical success, a subset of patients experiences incomplete occlusion or complications. This study investigates innovative helical thin-film implants (HTFIs), aiming to evaluate their flow-diverting efficacy. Highly resolved computational fluid dynamics simulations were performed on two representative patient-specific aneurysm models. Two HTFI design variants were tested at various configurations (two rolling angles and three deployment positions). A total of 28 unsteady hemodynamic simulations were performed, comparing six hemodynamically relevant parameters against the pre-interventional state and a conventional braided flow diverter. The HTFIs induced significant changes in intra-aneurysmal flow. Both designs performed similarly overall, with the shorter configurations (smaller rolling angle) demonstrating superior efficacy. These achieved average hemodynamic reductions of 52.2% and 58.4%, outperforming the benchmark braided flow diverter device (47.4%). Sensitivity to positioning was modest, with the best configuration showing an average variation of only 5.3%, suggesting good robustness despite the helical design's heterogeneous porosity. These findings indicate that HTFIs offer promising flow-diverting capabilities. With further refinement in design and hemodynamic optimization, these implants hold potential as a next-generation alternative for the endovascular treatment of intracranial aneurysms, especially in applications requiring compatibility with smaller delivery systems.

physics.med-ph↗

arXiv2025

Effect of Ti$_2$Pd(Ni) on the Transformation Behavior in Sputtered Ti-rich TiNiPd Shape Memory Alloys

TiNiPd based shape memory alloys (SMAs) share similar microstructural features as TiNiCu-based SMAs known for their exceptional resistance to functional fatigue due to their high crystallographic compatibility, nanometer sized grains and coherent precipitates, making them an ideal system to further explore the critical factors influencing cyclic stability. In this study, we investigate the effect of heat treatments (500 °C, 600 °C, 700 °C and 800 °C) on the cyclic stability and microstructure of free-standing, magnetron-sputtered Ti$_{53.6}$Ni$_{35.2}$Pd$_{11.2}$ films. All heat treatments promote the formation of Ti$_2$Pd(Ni) precipitates and result in a similar grain size (~1-4 $μ$m). Lower heat treatment temperatures improve the cyclic stability of the stress induced transformation while reducing transformation temperatures and latent heat. Temperature dependent X-ray diffraction reveals a complex microstructure for the martensite phase with Ti$_2$Pd(Ni), Ti$_2$Ni(Pd), TiNiPd(B2), B19/B19$'$ and R-phase. The thermal phase transition changes from a distinct 1st order to a 2nd order like transition, accompanied by increasing amount of remanent austenite and R-phase, with nearly no change for the sample heat treated at 500 °C. In situ stress dependent X-ray diffraction demonstrates a significant difference between the temperature and stress induced phase transformation for this heat treatment. The observed semi crystalline microstructure, featuring nano domains of Ti$_2$Pd(Ni) precipitates in the sample heat-treated at 500 °C, leads to a mixture of long range martensitic and strain glass transition. This study highlights the impact of heat treatment and microstructure on the phase transformation behavior and functional fatigue in Ti-rich TiNiPd alloys.

cond-mat.mtrl-sci↗

arXiv2025

In-situ compression and shape recovery of Ceramic single grain micro-pillar

Most ceramic materials are known for high fracture toughness while reacting highly brittle to physical deformation. Some advancements were made by utilizing the transformation toughening effect of Yttria-doped Zirconia. However, finding a ceramic material demonstrating an effect analogous to the Shape Memory Effect (SME) in certain metals, that also allows for superelastic responses, remains a challenge. The underlying mechanism for SME and superelasticity is based on crystallographic variations within the material's grains, requiring sophisticated electron microscopy techniques for direct observation. The combination of a scanning electron microscope (SEM) with focused ion beam (FIB) milling, a Kleindiek Nanotechnik GmbH micro-manipulator with a 1.5 $μ$m diamond tip, and the ability to achieve in-situ heating up to 450 °C on a Kleindiek heating stage provides a robust platform for the preparation, deformation, and heating of micro-pillars made from ceramic materials. This setup enabled us to conduct detailed studies on the Zirconia-based ceramic, observing permanent deformation exceeding 4% strain, followed by shape recovery at 370 °C. The paper provides outlines the key experimental steps that facilitated these observations.

cond-mat.mtrl-sci↗

arXiv2025

Theory of Intermediate Twinning and Spontaneous Polarization in Ferroelectric Potassium Sodium Niobate

Potassium sodium niobate is considered a prominent material system as a substitute for lead-containing ferroelectric materials. It exhibits first-order phase transformations and ferroelectricity with potential applications ranging from energy conversion to innovative cooling technologies, thereby addressing important societal challenges. However, a major obstacle in the application of potassium sodium niobate is its multi-scale heterogeneity and the lack of understanding of its phase transition pathway and microstructure. This can be seen from the findings of Pop-Ghe et al. (Ceram Int 47(14):20579-20585, 2021, https://doi.org/10.1016/j.ceramint.2021.04.067) which also reveal the occurrence of a phenomenon they term intermediate twinning during the phase transition. Here, we show that intermediate twinning is a consequence of energy minimization. We develop a geometrically nonlinear electroelastic energy function for potassium sodium niobate, including the cubic-tetragonal-orthorhombic transformations and ferroelectricity. The construction of the minimizers is based on compatibility conditions which ensure continuous deformations and pole-free interfaces. These minimizers agree with the experimental observations, including laminates between tetragonal variants under the cubic to tetragonal transformation, crossing twins under the tetragonal to orthorhombic transformation, intermediate twinning and spontaneous polarization. This shows how the full nonlinear electroelastic model provides a powerful tool in understanding, exploring, and tailoring the electromechanical properties of complex ferroelectric ceramics.

cond-mat.mtrl-sci↗

arXiv2020

Phase Sensitivity and Phase Noise of Cantilever-Type Magnetoelastic Sensors Based on the $Δ$E Effect

Magnetoelastic sensors for the detection of low-frequency and low-amplitude magnetic fields are in the focus of research since more than 30 years. In order to minimize the limit of detection (LOD) of such sensor systems, it is of high importance to understand and to be able to quantify the relevant noise sources. In this contribution, cantilever-type electromechanic and magnetoelastic resonators, respectively, are comprehensively investigated and mathematically described not only with regard to their phase sensitivity but especially to the extent of the sensor-intrinsic phase noise. Both measurements and calculations reveal that the fundamental LOD is limited by additive phase noise due to thermal-mechanical noise of the resonator, i.e. by thermally induced random vibrations of the cantilever, and by thermal-electrical noise of the piezoelectric material. However, due to losses in the magnetic material parametric flicker phase noise arises, limiting the overall performance. In particular it is shown that the LOD is virtually independent of the magnetic sensitivity but is solely determined by the magnetic losses. Instead of the sensitivity, the magnetic losses, represented by the material's effective complex permeability, should be considered as the most important parameter for the further improvement of such sensors in the future. This implication is not only valid for magnetoelastic cantilevers but also applies to any type of magnetoelastic resonator.

physics.ins-det↗

arXiv2019

Battery Detached Energy Conversion by Pyroelectric Effect

We propose a pyroelectric energy conversion device that converts heat directly to electricity. In contrast to conventional pyroelectric energy conversion designs, this energy harvesting system is detached from any external power sources, operating only under periodically varying temperature. Such detachment unambiguously attributes the converted electricity to heat that drives the change of polarization in the pyroelectric material, not to the electric field alternation caused by the external battery. Using pure and Zr doped BaTiO$_3$, we demonstrate the electricity generation in consecutive temperature cycles. We further develop a thermodynamic model for the energy conversion system. Our model suggests that the work output is rate dependent: the work output per cycle is linearly dependent on the heat/cooling frequency below the predicted threshold. The linearity is confirmed by experiments, and the threshold frequency is derived by theory. Finally we propose a figure of merit that separates the materials intrinsic properties from the system design parameters. The figure of merit guides the future material development and device improvement. Our work clears out confusions and reforms the foundation for pyroelectric materials' resurgence as a competitor for green electricity.

physics.app-ph↗

arXiv2019

Noise Analysis of Open-Loop and Closed-Loop SAW Magnetic Field Sensor Systems

Transmission surface acoustic wave (SAW) sensors are widely used in various fields of application. In order to maximize the limit of detection (LOD) of such sensor systems, it is of high importance to understand and to be able to quantify the relevant noise sources. In this paper, low noise readout systems for the application with a SAW delay line magnetic field sensor in an open-loop and closed-loop configuration are presented and analyzed with regard to their phase noise contribution. By applying oscillator phase noise theory to closed-loop sensor systems, it is shown that the phase noise of the SAW delay line oscillator can be predicted accurately. This allows the derivation of expressions for the limits of detection for both readout structures. Based on these equations, the equivalence between the LOD of open-loop and closed-loop SAW delay line readout can be shown analytically, assuming that the sensor contributes the dominant phase noise. This equality is verified by measurements. These results are applicable to all kinds of phase sensitive delay line sensors.

physics.ins-det↗