arXiv subjects

Edoardo G. Carnio

Publications and source records attributed to Edoardo G. Carnio.

18 recordsLinked to original sources

arXiv2026

Optimally driving multi-photon transitions in the perturbative single-mode regime

The rate of $m$-photon transitions in matter, induced by an incident light field, depends on the field's $m$th order coherence function. Consequently, the coherence properties of the light field may be shaped to increase the rate of multi-photon transitions. Here, we determine the optimal state of a weak fixed-intensity, narrow-band incident light field, with a restricted maximal photon number, that optimally drives $m$-photon transitions in the case of a short-lived atomic multilevel system. We show that, in this case, no quantum properties of the light field need to be exploited, but that classical mixtures of coherent states are optimal.

quant-ph↗

arXiv2025

Many-body interference at the onset of chaos

We unveil the signature of many-body interference across dynamical regimes of the Bose-Hubbard model. Increasing the particles' indistinguishability enhances the temporal fluctuations of few-body observables, with a dramatic amplification at the onset of quantum chaos. By resolving the exchange symmetries of partially distinguishable particles, we explain this amplification as the fingerprint of the initial state's coherences in the eigenbasis.

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arXiv2025

How to seed ergodic dynamics of interacting bosons under conditions of many-body quantum chaos

We demonstrate how the initial state of ultracold atoms in an optical lattice controls the emergence of ergodic dynamics as the underlying spectral structure is tuned into the quantum chaotic regime. Distinct initial states' chaos threshold values in terms of tunneling as compared to interaction strength are identified, as well as dynamical signatures of the chaos transition, on the level of experimentally accessible observables and time scales.

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arXiv2024

Entanglement structures in disordered chains of nitrogen-vacancy centers

A recent study [Phys. Rev. B 17 174111 (2022)] has hypothesized the assembly, along a specific type of one-dimensional defects of diamond, of chains of nitrogen-vacancy (NV) centers, potentially enabling the creation of qubit registers via their dipole-coupled electron spins. Here we investigate the connectivity of chains of up to ten coupled spins, mediated by the bi- and multipartite entanglement of their eigenstates. Rather conveniently, for regularly spaced spins the vast majority of the eigenstates displays strong connectivity, especially towards the center of the spectrum and for longer chains. Furthermore, positional disorder can change, and possibly reduce, the connectivity of the register, but seldom suppresses it.

quant-ph↗

arXiv2024

Machine-learning certification of multipartite entanglement for noisy quantum hardware

Entanglement is a fundamental aspect of quantum physics, both conceptually and for its many applications. Classifying an arbitrary multipartite state as entangled or separable -- a task referred to as the separability problem -- poses a significant challenge, since a state can be entangled with respect to many different of its partitions. We develop a certification pipeline that feeds the statistics of random local measurements into a non-linear dimensionality reduction algorithm, to determine with respect to which partitions a given quantum state is entangled. After training a model on randomly generated quantum states, entangled in different partitions and of varying purity, we verify the accuracy of its predictions on simulated test data, and finally apply it to states prepared on IBM quantum computing hardware.

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arXiv2023

An Energy Estimation Benchmark for Quantum Computers

Certifying the performance of quantum computers requires standardized tests. We propose a simple energy estimation benchmark that is motivated from quantum chemistry. With this benchmark we statistically characterize the noisy outcome of the IBM Quantum System One in Ehningen, Germany. We find that the benchmark results hardly correlate with the gate errors and readout errors reported for the device. In a time-resolved analysis, we monitor the device over several hours and find two-hour oscillations of the benchmark results, as well as outliers, which we cannot explain from the reported device status. We then show that the implemented measurement error mitigation techniques cannot resolve these oscillations, which suggests that deviations from the theoretical benchmark outcome statistics do not stem solely from the measurement noise of the device.

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arXiv2022

Quantized fields for optimal control in the strong coupling regime

We tailor the quantum statistics of a bosonic field to deterministically drive a quantum system into a target state. Experimentally accessible states of the field achieve good control of multi-level or -qubit systems, notably also at coupling strengths beyond the rotating-wave approximation. This extends optimal control theory to the realm of fully quantized, strongly coupled control and target degrees of freedom.

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arXiv2022

Optimal route to quantum chaos in the Bose-Hubbard model

The dependence of the chaotic phase of the Bose-Hubbard Hamiltonian on particle number $N$, system size $L$ and particle density is investigated in terms of spectral and eigenstate features. We analyze the development of the chaotic phase as the limit of infinite Hilbert space dimension is approached along different directions, and show that the fastest route to chaos is the path at fixed density $n \lesssim 1$. The limit $N \to \infty$ at constant $L$ leads to a slower convergence of the chaotic phase towards the random matrix theory benchmarks. In this case, from the distribution of the eigenstate generalized fractal dimensions, the ergodic phase becomes more distinguishable from random matrix theory for larger $N$, in a similar way as along trajectories at fixed density.

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arXiv2022

Chaos in the Bose-Hubbard model and random two-body Hamiltonians

We investigate the chaotic phase of the Bose-Hubbard model [L. Pausch et al, Phys. Rev. Lett. 126, 150601 (2021)] in relation to the bosonic embedded random matrix ensemble, which mirrors the dominant few-body nature of many-particle interactions, and hence the Fock space sparsity of quantum many-body systems. The energy dependence of the chaotic regime is well described by the bosonic embedded ensemble, which also reproduces the Bose-Hubbard chaotic eigenvector features, quantified by the expectation value and eigenstate-to-eigenstate fluctuations of fractal dimensions. Despite this agreement, in terms of the fractal dimension distribution, these two models depart from each other and from the Gaussian orthogonal ensemble as Hilbert space grows. These results provide further evidence of a way to discriminate among different many-body Hamiltonians in the chaotic regime.

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arXiv2021

Theory of multiple quantum coherence signals in dilute thermal gases

Manifestations of dipole-dipole interactions in dilute thermal gases are difficult to sense because of strong inhomogeneous broadening. Recent experiments reported signatures of such interactions in fluorescence detection-based measurements of multiple quantum coherence (MQC) signals, with many characteristic features hitherto unexplained. We develop an original open quantum systems theory of MQC in dilute thermal gases, which allows us to resolve this conundrum. Our theory accounts for the vector character of the atomic dipoles as well as for driving laser pulses of arbitrary strength, includes the far-field coupling between the dipoles, which prevails in dilute ensembles, and effectively incorporates atomic motion via a disorder average. We show that collective decay processes -- which were ignored in previous treatments employing the electrostatic form of dipolar interactions -- play a key role in the emergence of MQC signals.

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arXiv2021

Pulse area dependence of multiple quantum coherence signals in dilute thermal gases

In the general framework of open quantum systems, we assess the impact of the pulse area on single and double quantum coherence (1QC and 2QC) signals extracted from fluorescence emitted by dilute thermal gases. We show that 1QC and 2QC signals are periodic functions of the pulse area, with distinctive features which reflect the particles' interactions via photon exchange, the polarizations of the laser pulses, and the observation direction.

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arXiv2021

Optimization of selective two-photon absorption in cavity polaritons

We investigate optimal states of photon pairs to excite a target transition in a multilevel quantum system. With the help of coherent control theory for two-photon absorption with quantum light, we infer the maximal population achievable by optimal entangled vs. separable states of light. Interference between excitation pathways, as well as the presence of nearby states, may hamper the selective excitation of a particular target state, but we show that quantum correlations can help to overcome this problem, and enhance the achievable "selectivity" between two energy levels, i.e. the relative difference in population transferred into each of them. We find that the added value of optimal entangled states of light increases with broadening linewidths of the target states.

quant-ph↗

arXiv2021

Chaos and ergodicity across the energy spectrum of interacting bosons

We identify the chaotic phase of the Bose-Hubbard Hamiltonian by the energy-resolved correlation between spectral features and structural changes of the associated eigenstates as exposed by their generalized fractal dimensions. The eigenvectors are shown to become ergodic in the thermodynamic limit, in the configuration space Fock basis, in which random matrix theory offers a remarkable description of their typical structure. The distributions of the generalized fractal dimensions, however, are ever more distinguishable from random matrix theory as the Hilbert space dimension grows.

cond-mat.quant-gas↗

arXiv2019

Wave-particle Duality in Complex Quantum Systems

Stunning progresses in the experimental resolution and control of natural or man-made complex systems at the level of their quantum mechanical constituents raises the question, across diverse subdisciplines of physics, chemistry and biology, whether that fundamental quantum nature may condition the dynamical and functional system properties on mesoscopic if not macroscopic scales. But which are the distinctive signatures of quantum properties in complex systems, notably when modulated by environmental stochasticity and dynamical instabilities? It appears that, to settle this question across the above communities, a shared understanding is needed of the central feature of quantum mechanics: wave-particle duality. In this Perspective, we elaborate how randomness induced by this very quantum property can be discerned from the stochasticity ubiquitous in complex systems already on the classical level. We argue that in the study of increasingly complex systems such distinction requires the analysis of single incidents of quantum dynamical processes.

quant-ph↗

arXiv2019

Multifractality of ab initio wave functions in doped semiconductors

In Refs. [1,2] we have shown how a combination of modern linear-scaling DFT, together with a subsequent use of large, effective tight-binding Hamiltonians, allows to compute multifractal wave functions yielding the critical properties of the Anderson metal-insulator transition (MIT) in doped semiconductors. This combination allowed us to construct large and atomistically realistic samples of sulfur-doped silicon (Si:S). The critical properties of such systems and the existence of the MIT are well known, but experimentally determined values of the critical exponent $ν$ close to the transition have remained different from those obtained by the standard tight-binding Anderson model. In Ref. [1], we found that this ``exponent puzzle'' can be resolved when using our novel \emph{ab initio} approach based on scaling of multifractal exponents in the realistic impurity band for Si:S. Here, after a short review of multifractality, we give details of the multifractal analysis as used in [1] and show the obtained \emph{critical} multifractal spectrum at the MIT for Si:S.

cond-mat.dis-nn↗

arXiv2018

Resolution of the exponent puzzle for the Anderson transition in doped semiconductors

The Anderson metal-insulator transition (MIT) is central to our understanding of the quantum mechanical nature of disordered materials. Despite extensive efforts by theory and experiment, there is still no agreement on the value of the critical exponent $ν$ describing the universality of the transition --- the so-called "exponent puzzle". In this work, going beyond the standard Anderson model, we employ ab initio methods to study the MIT in a realistic model of a doped semiconductor. We use linear-scaling DFT to simulate prototypes of sulfur-doped silicon (Si:S). From these we build larger tight-binding models close to the critical concentration of the MIT. When the dopant concentration is increased, an impurity band forms and eventually delocalizes. We characterize the MIT via multifractal finite-size scaling, obtaining the phase diagram and estimates of $ν$. Our results suggest an explanation of the long-standing exponent puzzle, which we link to the hybridization of conduction and impurity bands.

cond-mat.dis-nn↗

arXiv2016

Generating and protecting correlated quantum states under collective dephasing

We study the collective dephasing process of a system of non-interacting atomic qubits, immersed in a spatially uniform magnetic field of fluctuating intensity. The correlation properties of bipartite states are analysed based on a geometric representation of the state space. Particular emphasis is put on the dephasing-assisted generation of states with a high correlation rank, which can be related to discord-type correlations and allow for direct applications in quantum information theory. Finally we study the conditions that ensure the robustness of initial entanglement and discuss the phenomenon of time-invariant entanglement.

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arXiv2015

Robust asymptotic entanglement under multipartite collective dephasing

We derive an analytic solution for the ensemble-averaged collective dephasing dynamics of $N$ noninteracting atoms in a fluctuating homogeneous external field. The obtained Kraus map is used to specify families of states whose entanglement properties are preserved at all times under arbitrary field orientations, even for states undergoing incoherent evolution. Our results apply to arbitrary spectral distributions of the field fluctuations.

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