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Eduardo R. deAzevedo

Publications and source records attributed to Eduardo R. deAzevedo.

6 recordsLinked to original sources

Experimental Investigation of Geometric Quantum Speed Limits in an Open Quantum System

We studied geometric quantum speed limits (QSL) of a qubit subject to decoherence in an ensemble of chloroform molecules in a Nuclear Magnetic Resonance experiment. The QSL is a fundamental lower bound on the evolution time for quantum systems undergoing general physical processes. To do so, we controlled the system-reservoir interaction and the spin relaxation rates by adding a paramagnetic salt, which allowed us to observe both Markovian and non-Markovian open system dynamics for the qubit. We used two distinguishability measures of quantum states to assess the speed of the qubit evolution: the quantum Fisher information (QFI) and Wigner-Yanase skew information (WY). For non-Markovian dynamics and low salt concentrations, we observed crossovers between QSLs related to the QFI and WY metrics. The WY metric sets the tighter QSL for high concentrations and Markovian dynamics. We also show that QSLs are sensitive even to small fluctuations in spin magnetization.

quant-ph↗

Coherence orders, decoherence and quantum metrology

Since the dawn of quantum theory, coherence was attributed as a key to understand the weirdness of fundamental concepts like the wave-particle duality and the Stern-Gerlach experiment. Recently, based on a resource theory approach, the notion of quantum coherence was revisited and a plethora of coherence quantifiers were proposed. In this work, we address this issue using the language of coherence orders, developed by the NMR community. This allowed us to investigate the role played by different subspaces of the Hilbert-Schmidt space into physical processes and quantum protocols. We found some links between decoherence and each coherence order. Moreover, we propose a sufficient and straightforward criterion to testify the usefulness of a given state for quantum enhanced phase estimation, relying on a minimal set of elements belonging to the density matrix.

quant-ph↗

Dipolar Filtered magic-sandwich-echoes as a tool for probing molecular motions using time domain NMR

We present a simple $^1$H NMR approach for characterizing intermediate to fast regime molecular motions using $^1$H time-domain NMR at low magnetic field. The method is based on a Goldmann Shen dipolar filter (DF) followed by a Mixed Magic Sandwich Echo (MSE). The dipolar filter suppresses the signals arising from molecular segments presenting sub kHz mobility, so only signals from mobile segments are detected. Thus, the temperature dependence of the signal intensities directly evidences the onset of molecular motions with rates higher than kHz. The DF-MSE signal intensity is described by an analytical function based on the Anderson Weiss theory, from where parameters related to the molecular motion (e.g. correlation times and activation energy) can be estimated when performing experiments as function of the temperature. Furthermore, we propose the use of the Tikhonov regularization for estimating the width of the distribution of correlation times.

physics.chem-ph↗

There is more to quantum interferometry than entanglement

Entanglement has long stood as one of the characteristic features of quantum mechanics, yet recent developments have emphasized the importance of quantumness beyond entanglement for quantum foundations and technologies. We demonstrate that entanglement cannot entirely capture the worst-case sensitivity in quantum interferometry, when quantum probes are used to estimate the phase imprinted by a Hamiltonian, with fixed energy levels but variable eigenbasis, acting on one arm of an interferometer. This is shown by defining a bipartite entanglement monotone tailored to this interferometric setting and proving that it never exceeds the so-called interferometric power, a quantity which relies on more general quantum correlations beyond entanglement and captures the relevant resource. We then prove that the interferometric power can never increase when local commutativity-preserving operations are applied to qubit probes, an important step to validate such a quantity as a genuine quantum correlations monotone. These findings are accompanied by a room-temperature nuclear magnetic resonance experimental investigation, in which two-qubit states with extremal (maximal and minimal) interferometric power at fixed entanglement are produced and characterized.

quant-ph↗

NMR Contributions to the study of Quantum Correlations

In this chapter we review the contributions of Nuclear Magnetic Resonance to the study of quantum correlations, including its capabilities to prepare initial states, generate unitary transformations, and characterize the final state. These are the three main demands to implement quantum information processing in a physical system, which NMR offers, nearly to perfection, though for a small number of qubits. Our main discussion will concern liquid samples at room temperature.

quant-ph↗

Observation of time-invariant coherence in a room temperature quantum simulator

The ability to live in coherent superpositions is a signature trait of quantum systems and constitutes an irreplaceable resource for quantum-enhanced technologies. However, decoherence effects usually destroy quantum superpositions. It has been recently predicted that, in a composite quantum system exposed to dephasing noise, quantum coherence in a transversal reference basis can stay protected for indefinite time. This can occur for a class of quantum states independently of the measure used to quantify coherence, and requires no control on the system during the dynamics. Here, such an invariant coherence phenomenon is observed experimentally in two different setups based on nuclear magnetic resonance at room temperature, realising an effective quantum simulator of two- and four-qubit spin systems. Our study further reveals a novel interplay between coherence and various forms of correlations, and highlights the natural resilience of quantum effects in complex systems.

quant-ph↗