SearcharxivSearch

arXiv subjects

Eiichi Obataya

Publications and source records attributed to Eiichi Obataya.

2 recordsLinked to original sources

Shrinkage of cane (Arundo donax L.) II Effect of drying condition on the intensity of cell collapse

To improve the drying method in the manufacture of woodwind reeds, green canes (Arundo donax L.) were dried under various humidity-temperature conditions and the intensity of cell collapse was evaluated from the swelling due to steaming involving the recovery of collapse. At 30 C, the intensity of collapse was increased by slower drying. It was considered that: 1) slower drying resulted in higher sample temperature in the early stage of drying to increase the collapse; 2) rapid drying stiffened the surface of sample and such "shell" prohibited the following collapse; 3) slower drying i.e. longer loading of liquid tension caused more remarkable and/or frequent viscoelastic yields of cells. Consequently the intensity of collapse increased when the cane was dried from its waxy outer surface or in the presence of node: both of them retarded the drying. On the other hand, higher drying temperature caused greater intensity of collapse in spite of faster drying. It was suggested that the thermal softening of cane cells leads to easier yield of the cell wall, at the same time the rapid drying does not allow the recovery of collapse after the disappearance of free water. These results indicated that faster drying at lower temperature is preferable for drying cane with less collapse.

cond-mat.mtrl-sci

Swelling of acetylated wood in organic liquids

To investigate the affinity of acetylated wood for organic liquids, Yezo spruce wood specimens were acetylated with acetic anhydride, and their swelling in various liquids were compared to those of untreated specimens. The acetylated wood was rapidly and remarkably swollen in aprotic organic liquids such as benzene and toluene in which the untreated wood was swollen only slightly and/or very slowly. On the other hand, the swelling of wood in water, ethylene glycol and alcohols remained unchanged or decreased by the acetylation. Consequently the maximum volume of wood swollen in organic liquids was always larger than that in water. The effect of acetylation on the maximum swollen volume of wood was greater in liquids having smaller solubility parameters. The easier penetration of aprotic organic liquids into the acetylated wood was considered to be due to the scission of hydrogen bonds among the amorphous wood constituents by the substitution of hydroxyl groups with hydrophobic acetyl groups.

physics.chem-ph